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Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO_(2) photoreduction

Science China Chemistry 2025年第1期68卷 201-208页

作者： Hui-Feng Wang Wen-Jie Shi Yu-Xin Yang Bao-xia Dong Tong-Bu lu Di-Chang zhong School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002China Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China

Dinuclear metal synergistic catalysis(DMSC)has been proved powerful in boosting CO_(2)reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework(MOF),obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center(M-In),three MOFs with dinuclear homometallic catalytic centers(MM-In),and three MOFs with dinuclear heterometallic catalytic centers(MM’-In,M/M’=Co(II),Ni(II),Zn(II)).It was found that all these MOFs can serve as catalysts for photochemical CO_(2)reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g^(-1)h^(-1),which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO_(2)reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO_(2)reduction.

关键词： metal-organic frameworks dinuclear metal centers synergistic catalysis CO_(2)reduction photocatalysis

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Some rigid results on doubly twisted product complex Finsler manifolds

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Science China Mathematics 2025年第2期68卷 421-432页

作者： Hongchuan xia Wei xiao Chunping zhong School of Mathematics and Statistics Xinyang Normal UniversityXinyang 464000China School of Mathematical Sciences Xiamen UniversityXiamen 361005China

Let(M1×(λ_(1),λ_(2))M_(2),F)be a doubly twisted product complex Finsler manifold of two strongly pseudoconvex complex Finsler manifolds(M_(1),F_(1))and(M_(2),F_(2)).Denote by M the product manifold of M1and M_(2).In this paper,we first give the characterization for(M,F)to be of constant holomorphic curvature,and prove that(M,F)is of constant holomorphic curvature if and only if(M,F),(M_(1),F_(1)),and(M_(2),F_(2))all have vanishing holomorphic curvature under the condition that lnλ_(1)and lnλ_(2)are both pluriharmonic ***,we obtain the classification for(M,F)to be a complex Landsberg ***,we prove that a strongly convex doubly twisted product complex Finsler manifold(M,F)is projectively flat(*** flat)if and only ifλ_(1)F1andλ_(2)F_(2)are both complex Minkowski metrics.

关键词： doubly twisted product complex Finsler manifold holomorphic curvature complex Landsberg manifold

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Cross-subcarrier precoder design for massive MIMO-OFDM downlink with symplectic optimization

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Science China(Information Sciences) 2025年第2期68卷 216-229页

作者： Yuxuan ZHANG An-An lu xiang-Gen xia Xiqi GAO National Mobile Communications Research Laboratory Southeast University Purple Mountain Laboratories Department of Electrical and Computer Engineering University of Delaware

We propose a cross-subcarrier precoder design(CSPD) for massive multiple-input multiple-output(MIMO) orthogonal frequency division multiplexing(OFDM) downlink. This work aims to significantly improve the channel estimation and signal detection performance by enhancing the smoothness of the frequency domain effective channel. This is accomplished by designing a few vectors known as the transform domain precoding vectors(TDPVs), which are then transformed into the frequency domain to generate the precoders for a set of subcarriers. To combat the effect of channel aging, the TDPVs are optimized under imperfect channel state information(CSI). The optimal precoder structure is derived by maximizing an upper bound of the ergodic weighted sum-rate(WSR) and utilizing the a posteriori beam-based statistical channel model(BSCM). To avoid the large-dimensional matrix inversion, we propose an algorithm with symplectic optimization. Simulation results indicate that the proposed cross-subcarrier precoder design significantly outperforms conventional methods.

关键词： massive MIMO-OFDM cross subcarrier precoder design transform domain precoding vectors effective channel symplectic optimization

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Mitochondrial dysfunction in the pathogenesis of acute pancreatitis

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Hepatobiliary & Pancreatic Diseases International 2025年第1期24卷 76-83页

作者： xia Chen Rui zhong Bing Hu Department of Gastroenterology and Hepatology West China HospitalSichuan UniversityChengdu 610041China Department of Gastroenterology Clinical Medical College and The First Affiliated Hospital of Chengdu Medical CollegeChengdu 610500China

The mechanism of cell damage during acute pancreatitis (AP) has not been fully elucidated, and there is still a lack of specific or effective treatments. Increasing evidence has implicated mitochondrial dysfunction as a key event in the pathophysiology of AP. Mitochondrial dysfunction is closely related to calcium (Ca^(2+)) overload, intracellular adenosine triphosphate depletion, mitochondrial permeability transition pore openings, loss of mitochondrial membrane potential, mitophagy damage and inflammatory responses. Mitochondrial dysfunction is an early triggering event in the initiation and development of AP,and this organelle damage may precede the release of inflammatory cytokines, intracellular trypsin activation and vacuole formation of pancreatic acinar cells. This review provides further insight into the role of mitochondria in both physiological and pathophysiological aspects of AP, aiming to improve our understanding of the underlying mechanism which may lead to the development of therapeutic and preventive strategies for AP.

关键词： Acute pancreatitis Autophagy Calcium Cell death Inflammation Mitochondria Mitophagy

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Different fates of Sb(Ⅲ)and Sb(V)during the formation of jarosite mediated by Acidithiobacillus ferrooxidans

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Journal of Environmental Sciences 2025年第1期147卷 342-358页

作者： lu Chen Yirong Wang Hongchang Liu Yuhang Zhou Zhenyuan Nie Jinlan xia Wensheng Shu School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China Key Lab of Biometallurgy of Ministry of Education of China Central South UniversityChangsha 410083China School of Life Sciences South China Normal UniversityGuangzhou 510631China

Secondary iron-sulfate minerals such as jarosite,which are easily formed in acid mine drainage,play an important role in controlling metal *** this work,the typical iron-oxidizing bacterium Acidithiobacillus ferrooxidans ATCC 23270 was selected to synthesize jarosite in the presence of antimony ions,during which the solution behavior,synthetic product composition,and bacterial metabolism were *** results show that in the presence of Sb(V),Fe^(2+)was rapidly oxidized to Fe^(3+)by *** and Sb(V)had no obvious effect on the biooxidation of Fe^(2+)under the current experimental *** presence of Sb(Ⅲ)inhibited bacterial growth and Fe^(2+)*** the group with Sb(Ⅲ),products with amorphous phaseswere formed 72 hr later,whichwere mainly ferrous sulfate and pentavalent antimony oxide,and the amorphous precursor was finally transformed into a more stable crystal *** the group with Sb(V),the morphology and structure of jarosite were changed in comparison with those without *** biomineralization process was accompanied by the removal of 94%Sb(V)to form jarosite containing the Fe-Sb-O *** transcriptome analysis shows differential effects of Sb(Ⅲ)and Sb(V)on bacterial *** expression levels of functional genes related to cell components were much more downregulated for the group with Sb(Ⅲ)butmuch more regulated for that with Sb(V).Notably,cytochrome c and nitrogen fixation-relevant genes for the A.f_Fe^(2+)_Sb(Ⅲ)group were enhanced significantly,indicating their role in Sb(Ⅲ)*** study is of great value for the development of antimony pollution control and remediation technology.

关键词： Jarosite Acidithiobacillus ferrooxidans Bacterial iron oxidation Sb(Ⅲ)and Sb(V)transformation Transcriptome analysis

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The effect of fine grits and fine debris concentrations on the MLVSS/MLSS ratio of an activated sludge system

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Journal of Environmental Sciences 2025年第1期147卷 607-616页

作者： Zhao Jiang Zhiheng xia Shuai Liu QiWei Haitao Fan lu Qi Guohua Liu Hongchen Wang Low-carbon Water Environment Technology Research Center School of Environment&Natural ResourcesRenmin University of ChinaBeijing 100872China

This study embarks on an explorative investigation into the effects of typical concentrations and varying particle sizes of fine grits(FG,the involatile portion of suspended solids)and fine debris(FD,the volatile yet unbiodegradable fraction of suspended solids)within the influent on themixed liquor volatile suspended solids(MLVSS)/mixed liquor suspended solids(MLSS)ratio of an activated sludge *** meticulous experimentation,it was discerned that the addition of FG or FD,the particle size of FG,and the concentration of FD bore no substantial impact on the pollutant removal efficiency(denoted by the removal rate of COD and ammonia nitrogen)under constant operational ***,a notable decrease in the MLVSS/MLSS ratio was observed with a typical FG concentration of 20 mg/L,with smaller FG particle sizes exacerbating this ***,variations in FD concentrations influenced both MLSS andMLVSS/MLSS ratios;a higher FD concentration led to an increased MLSS and a reduced MLVSS/MLSS ratio,indicating FD accumulation in the system.A predictive model for MLVSS/MLSS was constructed based on quality balance calculations,offering a tool for foreseeing the MLVSS/MLSS ratio under stable long-term influent conditions of FG and *** model,validated using data from the BXH wastewater treatment plant(WWTP),showcased remarkable accuracy.

关键词： Fine grits and fine debris Activated sludge system MLVSS/MLSS ratio Predictive model

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Folding encapsulation toward Lindqvist polyoxometalates within adaptive coordination cages for catalysis

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Science China Chemistry 2025年第2期68卷 561-569页

作者： Ying-Mei zhong Jin-Jin Xuan Xujie Qin Han xiao Zi-Jun xia Li-Peng Zhou xiao-Qing Guo Yu-Hang Hu lu Zhang Chunsen Li Li-Xuan Cai Qing-Fu Sun State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100049China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China

In nature,enzymes at specific folded conformations exhibit high substrate complementarity,enabling them to efficiently and selectively catalyze biochemical *** by enzymes,coordination cages with conformational dynamics have been designed and are receiving increasing attention due to their versatile applications in allosteric guest binding and *** present here two enzyme-mimicking adaptive macrocycle-based coordination cages,Pd_(2)L_(2)^(1) and Pd_(2)L_(2)^(2),from macrocycle-based ligands(L^(1) and L^(2))and the encapsulation and stabilization of Lindqvist polyoxometalates anions M6O192−(M=W or Mo)in neutral aqueous solution.X-ray crystallographic studies have verified the formation of 1:1 host-guest complexes of two Pd_(2)L_(2) cages and the W6O192−anion,via an induced-fit folding *** with the free host,Pd_(2)L_(2)^(1) exhibited an induced-fit semi-folded conformation in the inclusion complex,while Pd_(2)L_(2)^(2) adopted an induced-fit fully-folded ***,the Mo_(6)O_(19)⊂Pd_(2)L_(2) host-guest complexes demonstrate high yield and selectivity in the oxidative decontamination reaction of the sulfur mustard simulant,2-chloroethyl ethyl *** work not only sheds light on the importance of conformational adaptability in enzyme-like systems but also paves the way for protecting labile POM clusters via host-guest encapsulation toward enhanced catalytic performance in aqueous solution.

关键词： coordination cage induced-fit polyoxometalates host-guest chemistry supramolecular catalysis

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Autophagy serves as a protective effect against inflammatory injury of oxidative stress in ARPE-19 cell

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International Journal of Ophthalmology(English edition) 2025年第1期18卷 28-38页

作者： Na-Na Meng Lei-Zhou xia Yi-Qing Gong Pei-Rong lu Department of Ophthalmology the First Affiliated Hospital of Soochow UniversitySuzhou 215006Jiangsu ProvinceChina Department of Ophthalmology Affiliated People’s HospitalJiangsu UniversityZhenjiang 212002Jiangsu ProvinceChina Zhenjiang Kangfu Eye Hospital Zhenjiang 212002Jiangsu ProvinceChina Department of General Surgery Affiliated People’s HospitalJiangsu UniversityZhenjiang 212002Jiangsu ProvinceChina

AIM:To test the effect of autophagy on inflammatory damage resulting from oxidative stress in adult retinal pigment epithelial cell line(ARPE-19).METHODS:ARPE-19 cells were pretreated with 200 and 600μmol/L hydrogen peroxide(H_(2)O_(2))at various time *** changes of cell morphology,cell viability,reactive oxygen species(ROS)level,autophagic activity,and the inflammatory cytokines(TNFα,IL-6,and TGFβ)were measured at baseline and after treatment with autophagy inducer rapamycin(Rapa)and suppressor wortmannin(Wort)or ***:The levels of ROS,cytokines(TNFα,IL-6,and TGFβ),and autophagic activity were significantly increased in ARPE-19 cells after pretreated with H2O2(all PluSION:Autophagy demonstrates a protective effect on ARPE-19 cell through mitigating oxidative damage and oxidative stress-induced inflammatory *** of autophagy may be a potential way for agerelated macular degeneration.

关键词： retinal pigment epithelium autophagy reactive oxygen species inflammation

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Apoptosis mechanism of gastric cancer cell SGC-7901 induced by Omphalia lapidescens protein pPeOp

Apoptosis mechanism of gastric cancer cell SGC-7901 induced ...

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2017年浙江省微生物学会青年论坛——微生物与健康专题研讨会

作者：赵肖涯 lu zhong-xia DU Li-jun LIANG Hao-wei 陈宜涛 College of Life Science Zhejiang Chinese Medicine University

To investigate the apoptosis mechanism of human gastric cancer cell SGC-7901 induced by Omphalia lapidescens protein ***:CCK-8 and flow cytometry were used to detect the inhibitory effect of different concentrations of pPeOp(30,60,90 mg·L) on *** mRNA and protein expression of TNF-R1,Fas/FasL,Bcl-2,caspase-3 and caspase-8 were detected by qRT-PCR and Western ***:SGC-7901 cells were treated with different concentrations of pPeOp(30,60,90 mg·L) for 24 ***-8 test showed that there was no significant difference between PVP group and the control *** survival rate of the 5-Fu group was(53.71±7.34)%(Plusion:pPeOp can significantly inhibit the proliferation of gastric cancer cell line SGC-7901 and induce apoptosis in a dose-dependent *** receptor pathway and mitochondrial pathway may be related to pPeOp-induced apoptosis of gastric cancer SGC-7901.

关键词： Apoptosis caspases Gastric cancer SGC-7901 Mitochondrial apoptosis pathway Death receptor apoptosis pathway Omphalia lapidescens

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Advanced pancreatic cancer treated with camrelizumab combined with apatinib:A case report

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World Journal of Gastrointestinal Oncology 2025年第2期17卷 284-290页

作者： Yun-Hao luo Ting He lu Lin Rong-Qiu Wang Hong-xia Cai Wen Hu Department of Critical Care Medicine Chengdu First People's HospitalChengdu 610000Sichuan ProvinceChina Department of Radiology Sichuan Second Hospital of Traditional Chinese MedicineChengdu 610000Sichuan ProvinceChina Department of Oncology Chengdu Seventh People's HospitalChengdu 610000Sichuan ProvinceChina Department of Oncology West China Tianfu HospitalSichuan UniversityChengdu 610000Sichuan ProvinceChina

BACKGROUND The 5-year survival rate for patients with pancreatic cancer(PC)is 4%-12%.Surgery is the only treatment that offers curative potential,but only 15%-20%of patients are eligible for *** is prone to recurrence and metastasis,and the antitumor effect of chemotherapy is notably *** SUMMARY Histopathological analysis of a 53-year-old female PC patient who underwent Whipple surgery revealed poorly differentiated tumor cells infiltrating nerves,lymphatics,and blood *** patient received two different first-line chemotherapy regimens consecutively;however,both regimens struggled to control disease *** this period,the patient underwent liver metastasis ablation surgery,Candida albicans liver abscess,and stereotactic body *** the addition of camrelizumab to the modified FOLFIRINOX regimen,tumor control was *** patient subsequently refused to continue chemotherapy,and the antitumor regimen was changed to a combination of camrelizumab and *** patients received a combination of immunotherapy and targeted therapy,the length of hospital stay was significantly ***,all side effects were within acceptable limits,leading to an improved quality of life and prolonged progression-free ***,the pain associated with cancer,coupled with the side effects of opioid analgesics,has led the patient to reject all available anticancer treatment *** one month after camrelizumab and apatinib were discontinued without medical authorization,the PC recurred and rapidly progressed to widespread metastasis,ultimately leading to the patient's death approximately one month *** overall survival was 2 *** Immunotherapy and targeted therapy have the potential to increase both the quality of life and survival time of PC patients,particularly those whose tumor progression is not effectively controlled by chemotherapy ***,further clinical trials a

关键词： Advanced pancreatic cancer Immunotherapy Camrelizumab Targeted therapy Apatinib Case report

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