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An integrated strategy towards the facile synthesis of core-shell SiC-derived carbon@N-doped carbon for high-performance supercapacitors

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Journal of Energy Chemistry 2021年第5期30卷 512-521页

作者： Zhongya Pang Guangshi Li xingli Zou Chenteng Sun Conghui Hu Wei Tang Li Ji Hsien-Yi Hsu Qian Xu Xionggang lu State Key Laboratory of Advanced Special Steel&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of ASIC and System School of MicroelectronicsFudan UniversityShanghai 200433China School of Energy and Environment&Department of Materials Science and Engineering City University of Hong KongKowloon Tong 999077Hong KongChina Shenzhen Research Institute of City University of Hong Kong Shenzhen 518057GuangdongChina

Porous active core-shell carbon material with excellent synergistic effect has been regarded as a prospective material for ***,we report an integrated method for the facile synthesis of carbide-derived carbon(CDC)encapsulated with porous N-doped carbon(CDC@NC)towards highperformance ***(PDA)as nitrogen and carbon sources was simply coated on SiC nanospheres to form SiC@PDA,which was then directly transformed into CDC@NC via a onestep molten salt electro-etching/in-situ doping *** synthesized CDC@NC with hierarchically porous structure has a high specific surface area of 1191 m^(2) g^(-1).The CDC core and NC shell are typical amorphous carbon and more ordered N-doped carbon,*** from its unique dual porous structures,the CDC@NC demonstrates high specific capacitances of 255 and 193 F g^(-1) at 0.5 and20 A g^(-1),*** reaction mechanism of the electro-etching/in-situ doping process has also been investigated through experimental characterizations and theoretical density functional theory *** is suggested that the molten salt electro-etching/in-situ doping strategy is promising for the synthesis of active core-shell porous carbon materials with synergistic properties for supercapacitors without the need for additional doping/activation processes.

关键词： Molten salt Electrochemical etching Core-shell structure Porous carbon In-situ nitrogen doping Supercapacitors

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尾矿库溃坝对公路路基冲击破坏计算分析

路基工程 2022年第4期 190-194页

作者：苏兴矩钟元庆曾祥锦林峰卢兴利王军伟张瑞俊福建厦蓉高速公路漳龙段扩建工程有限公司福建龙岩360000 中国科学院武汉岩土力学研究所武汉430071 中铁十六局集团第一工程有限公司北京100018

通过建立平面二维水动力模块对尾矿库溃坝进行数值模拟,得出溃坝影响区域内的尾砂淹没范围、淹没深度及演进过程等。在此基础上,计算尾矿库溃坝后尾砂是否淹没下游高速公路路基,并对路基的稳定性和抗倾覆能力进行了验算。结果表明:恒鑫... 详细信息

通过建立平面二维水动力模块对尾矿库溃坝进行数值模拟,得出溃坝影响区域内的尾砂淹没范围、淹没深度及演进过程等。在此基础上,计算尾矿库溃坝后尾砂是否淹没下游高速公路路基,并对路基的稳定性和抗倾覆能力进行了验算。结果表明:恒鑫尾矿库在最不利条件下发生溃坝时,高速公路路基整体稳定性满足要求,泥石流不会侵害路面,且不会对下游造成影响,该尾矿库可继续生产但需加强监测。

关键词：尾矿库溃坝数值模拟计算溃坝冲击力路基稳定性路基排水验算

Bimetallic site substitution of NiCoP nanoneedles as bifunctional electrocatalyst for boosted water splitting

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Nano Research 2024年第11期17卷 9540-9549页

作者： Ya Gao Yuhui Qiao Xuanrong Li Chengyu Huang Jing Zhang Yirong Wang xingli Zou Zhonghong Xia Xinxin Yang Xionggang lu Yufeng Zhao College of Sciences and Institute for Sustainable Energy Shanghai University Shanghai 200444 China School of Materials Science and Engineering Shanghai University Shanghai 200444 China State Key Laboratory of Advanced Special Steel and Shanghai Key Laboratory of Advanced Ferrometallurgy Shanghai University Shanghai 200444 China

The bimetallic nickel-cobalt phosphide (NiCoP) has been confirmed as an efficient electrocatalyst in water splitting. But little attention is paid to the selectivity and affinity of metal sites on hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a trace-Zn-doping (2.18 wt.%) NiCoP (Zn-NiCoP) whereby the nanoparticles self-aggregated to form elongated nanoneedles. We discover that both Co and Ni sites can be replaced by Zn. The Co substitution improves HER, while the Ni substitution dramatically reduces the energy barrier of the rate-determining step (*O → *OOH). The negative shift of d-band centers after Zn doping ameliorates the intermediate desorption. Therefore, Zn-NiCoP demonstrates superior electrocatalytic activity with overpotentials of 48 and 240 mV for HER and OER at 10 and 50 mA·cm^(−2), respectively. The cell voltage with Zn-NiCoP as both anode and cathode in water splitting was as low as 1.35 V at 10 mA·cm^(−2).

关键词： Zn doping bimetallic phosphides bifunctional electrocatalyst overall water splitting

Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability

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Chinese Chemical Letters 2024年第5期35卷 441-446页

作者： Xiping Dong Xuan Wang Zhixiu lu Qinhao Shi Zhengyi Yang Xuan Yu Wuliang Feng xingli Zou Yang Liu Yufeng Zhao Institute for Sustainable Energy&College of Sciences Shanghai UniversityShanghai 200444China Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province Yancheng Institute of TechnologyYancheng 224051China State Key Laboratory of Advanced Special Steel&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering Shanghai UniversityShanghai 200444China

Due to its high operational voltage and energy density,P2-type Na_(0.67)Ni_(0.3)Mn_(0.7)O_(2) has become a leading cathode material for sodium-ion batteries(SIBs),which is an ideal option for large-scale energy ***,the practical application of P2-type Na_(0.67)Ni_(0.3)Mn_(0.7)O_(2) is limited by the capacity constraints and unwanted phase transitions,presenting significant challenges to the widespread application of *** address these challenges and optimize the electrochemical properties of the P2 phase cathode material,this study proposes a Cu and Zn co-doped strategy to improve the electrochemical *** incorporation of Cu/Zn can stabilize the P2-phase structure against P2-O2 phase transitions,thus enhancing its electrochemical *** as-obtained P2-type Na0.67[Ni_(0.3)Mn_(0.58)Cu_(0.09)Zn_(0.03)]O_(2) cathode material shows an impressive cycling stability,maintaining 80%capacity retention after 1000 cycles at 2 *** cyclic voltammetry(CV)tests show that the Cu^(2+)/Cu^(3+)redox reaction is also involved in charge compensation during the charge/discharge process.

关键词： Sodium-ion batteries Cathode material Cycle performance Cu/Zn co-doped P2-type Na_(0.67)Ni_(0.3)Mn_(0.7)O_(2)

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间作对作物产量效应的Meta分析

中国农学通报 2020年第14期36卷 101-106页

作者：禄兴丽段雅欣岳衡刘继虎康建宏吴宏亮代晓华吴娜贾彪宁夏大学农学院银川750021

旨在探明间作模式对作物产量的影响,为间作措施的合理应用和推广提供理论依据。该研究以单作为对照,利用Meta分析方法定量分析间作对作物产量的影响及其影响因素。结果表明,间作较单作显著降低了作物产量,尤其在温带地区。此外,在地面... 详细信息

旨在探明间作模式对作物产量的影响,为间作措施的合理应用和推广提供理论依据。该研究以单作为对照,利用Meta分析方法定量分析间作对作物产量的影响及其影响因素。结果表明,间作较单作显著降低了作物产量,尤其在温带地区。此外,在地面覆盖和豆科作物条件下,间作也降低了作物产量。然而,当降雨量超过600 mm时,间作较单作的作物产量显著增加了29.6%。而当降雨量小于600 mm时,间作较单作的作物产量降低了18.7%。年均气温也显著影响间作的产量效应,当年均气温高于20℃时,间作较单作的作物产量降低了55.1%,长期间作(>5年)有利于提高产量,然而当年数少于3年时,间作较单作却降低了作物产量。高有机质含量(>20 g/kg)和低有机质含量(1 g/kg)条件下,间作均不利于作物产量提高。与此类似,当土壤全氮高于1.5 g/kg时,间作较单作的作物产量降低48.6%。间作对作物产量的降低幅度在pH 6.5~7.5时是最大的。当土壤有效磷、氮和钾含量分别为>30 mg/kg、<50 mg/kg和50~100 mg/kg时间作较单作降低作物产量。因此,间作的产量效应受气候、试验年限和土壤性状等多种因素的影响。

关键词：间作作物产量试验年数 Meta分析

Highly efficient and stable electrocatalyst for hydrogen evolution by molybdenum doped Ni-Co phosphide nanoneedles at high current density

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Nano Research 2024年第3期17卷 1066-1074页

作者： Chengyu Huang Zhonghong Xia Jing Wang Jing Zhang Chenfei Zhao xingli Zou Shichun Mu Jiujun Zhang Xionggang lu Hong Jin Fan Shengjuan Huo Yufeng Zhao College of Sciences&Institute for Sustainable Energy Shanghai UniversityShanghai 200444China State Key Laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseYanshan UniversityQinhuangdao 066004China State Key Laboratory of Advanced Special Steel and Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and EngineeringShanghai UniversityShanghai 200444China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore639798

There is an increasingly urgent need to develop cost-effective electrocatalysts with high catalytic activity and stability as alternatives to the traditional Pt/C in catalysts in water *** this study,microspheres composed of Mo-doped NiCoP nanoneedles supported on nickel foam were prepared to address this *** results show that the nanoneedles provide sufficient active sites for efficient electron transfer;the small-sized effect and the micro-scale roughness enhance the entry of reactants and the release of hydrogen bubbles;the Mo doping effectively improves the electrocatalytic performance of NiCoP in alkaline *** catalyst exhibits low hydrogen evolution overpotentials of 38.5 and 217.5 mV at a current density of 10 mA·cm^(-2) and high current density of 500 mA·cm^(-2),respectively,and only 1.978 V is required to achieve a current density of 1000 mA·cm^(-2) for overall water *** functional theory(DFT)calculations show that the improved hydrogen evolution performance can be explained as a result of the Mo doping,which serves to reduce the interaction between NiCoP and intermediates,optimize the Gibbs free energy of hydrogen adsorption(△G_(*H)),and accelerate the desorption rate of **** study provides a promising solution to the ongoing challenge of designing efficient electrocatalysts for high-current-density hydrogen production.

关键词： transition metal phosphides Mo-doped NiCoP hydrogen evolution reaction gradient hydrothermal water splitting

Recent Advances in Electrochemical-Based Silicon Production Technologies with Reduced Carbon Emission

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Research 2024年第1期2023卷 209-236页

作者： Feng Tian Zhongya Pang Shen Hu Xueqiang Zhang Fei Wang Wei Nie Xuewen Xia Guangshi Li Hsien-Yi Hsu Qian Xu xingli Zou Li Ji Xionggang lu State Key Laboratory of Advanced Special Steel&Shanghai Key Laboratory of Advanced Ferrometallurgy&School of Materials Science and Engineering Shanghai University99#Shangda RoadShanghai 200444China Center for Hydrogen Metallurgy Technology Shanghai UniversityShanghai 200444China State Key Laboratory of ASIC and System School of MicroelectronicsFudan University220#Handan RoadShanghai 200433China School of Energy and Environment Department of Materials Science and EngineeringCity University of Hong KongKowloon TongHong KongChina

Sustainable and low-carbon-emission silicon production is currently one of the main focuses for the metallurgical and materials science ***,considered a promising strategy,has been explored to produce silicon due to prominent advantages:(a)high electricity utilization efficiency;(b)low-cost silica as a raw material;and(c)tunable morphologies and structures,including films,nanowires,and *** review begins with a summary of early research on the extraction of silicon by *** has been placed on the electro-deoxidation and dissolution–electrodeposition of silica in chloride molten salts since the 21st century,including the basic reaction mechanisms,the fabrication of photoactive Si films for solar cells,the design and production of nanoSi and various silicon components for energy conversion,as well as storage ***,the feasibility of silicon electrodeposition in room-temperature ionic liquids and its unique opportunities are *** this basis,the challenges and future research directions for silicon electrochemical production strategies are proposed and discussed,which are essential to achieve large-scale sustainable production of silicon by electrochemistry.

关键词： directions electrodeposition electricity

Inactivated SARS-CoV-2 booster vaccine enhanced immune responses in patients with chronic liver diseases

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Virologica Sinica 2023年第5期38卷 723-734页

作者： Yongmei Liu Jianhua lu Haoting Zhan Wenfang Yuan Xiaomeng Li Haiyan Kang Haolong Li Yongliang Chen Linlin Cheng xingli Sun Haojie Zheng Wei Wang Erhei Dai Yongzhe Li Department of Clinical Laboratory State Key Laboratory of ComplexSevere and Rare DiseasesPeking Union Medical College HospitalPeking Union Medical College and Chinese Academy of Medical SciencesBeijing100730China Division of Liver Diseases The Fifth Hospital of ShijiazhuangHebei Medical UniversityShijiazhuang050021China Department of Clinical Laboratory The Fifth Hospital of ShijiazhuangHebei Medical UniversityShijiazhuang050021China Department of Clinical Laboratory Peking University People's HospitalBeijing100035China

Chronic liver disease(CLD)entails elevated risk of COVID-19 severity and *** effectiveness of the booster dose of inactivated SARS-CoV-2 vaccine in stimulating antibody response in CLD patients is ***,we conducted a cross-sectional study involving 237 adult CLD patients and 170 healthy controls(HC)to analyze neutralizing antibodies(NAbs)against SARS-CoV-2 prototype and BA.4/5 variant,anti-receptor binding domain(RBD)IgG,and total anti-SARS-CoV-2 *** levels of the total anti-SARS-CoV-2 antibodies,anti-RBD IgG and inhibition efficacy of NAbs were significantly elevated in CLD patients after the booster dose compared with the pre-booster dose,but were relatively lower than those of *** humoral responses decreased over time after booster *** neutralization efficiency of the serum against BA.4/5 increased but remained below the inhibition *** four SARS-CoV-2 antibodies,including total anti-SARS-CoV-2 antibodies,anti-RBD IgG and NAbs against prototype and BA.4/5,were lower in patients with severe CLD than those with non-severe *** booster shot,age and time after the last vaccine were the risk factors for seropositivity of NAb against BA.4/5 in CLD ***,white blood cell counts and hepatitis B core antibodies were the protective factors,and severe liver disease was the risk factor associated with seropositivity of total anti-SARS-CoV-2 ***,our data uncovered that antibody responses were improved in CLD patients and peaked at 120 days after the booster *** antibodies excepting total anti-SARS-CoV-2 antibodies declined after *** patients exhibited impaired immunologic responses to vaccination and weakened NAbs against BA.4/5,which hindered the protective effect of the booster shot against Omicron *** immune responses should be further evaluated to determine the optimal vaccine regimen for CLD patients.

关键词： Chronic liver disease(CLD) SARS-CoV-2 inactivated vaccines Booster vaccination Antibody response Immune response

Evaluation of coronary plaque and stent deployment by intravascular optical coherence tomography in elderly patients with unstable angina and non-ST-elevation myocardial infarction

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Journal of Geriatric Cardiology 2007年第1期4卷 3-9页

作者： Caiyi lu Shiwen WANG Wei YAN xingli WU Yuxiao ZHANG Qiao XUE Muyang YAN Peng LIU Rui CHEN Jinyue ZHAI Institute of Geriatric Cardiology Chinese PLA General HospitalBeijing 100853China

Objective To evaluate the feasibility and efficacy of intravascular optical coherence tomography(OCT)in the assessment of plaque characteristics and drug eluting stent deployment quality in the elderly patients with unstable angina(UA)and non-ST segment elevation myocardial infarction(NSTEMI).Methods OCT was used in elderly patients undergoing percutaneous coronary *** patients,9 males and 6 females with mean age of 72.6±5.3 years(range 67-92 years)were enrolled in the *** were obtained before initial balloon dilatation and following stent *** plaque characteristics before dilation,vessel dissection,tissue prolapse,stent apposition and strut distribution after stent implantation were *** Fifteen lesions were selected from 32 angiographic lesions as study lesions for OCT imaging after diagnostic coronary *** were 7 lesions in the left anterior descending artery,5 lesions in the right coronary artery and 3 lesions in the left circumflex coronary *** them,12(80.0%)were lipid-rich plaques,and 10(66.7%)were vulnerable plaques with fibrous cap thickness 54.2±7.3μ*** ruptured culprit plaques(46.7%)were found;4 in UA patients and 3 in NSTEMI *** prolapse was observed in 11 lesions(73.3%).Irregular stent strut distribution was detected in 8 lesions(53.3%).Vessel dissections were found in 5 lesions(33.3%).Incomplete stent apposition was observed in 3 stents(20%)with mean spacing between the struts and the vessel wall 172±96 mm(range 117-436 mm).Conclusions 1)It is safe and feasible to perform intravascular OCT to differentiate vulnerable coronary plaque and monitor stent deployment in elderly patients with UA and USTEMI.2)Coronary plaques in elderly patients with UA and USTEMI could be divided into acute ruptured plaque,vulnerable plaque,lipid-rich plaque,and stable plaque.3)Minor or critical plaque rupture is one of the mechanisms of UA in elderly patients.4)Present drug eluting stent

关键词： optical coherence tomography acute coronary syndrome percutaneous coronary intervention stent elderly