检索结果-南通市图书馆

维普期刊数据库

Nanomaterials for Clean Air, Energy and Water

在线全文

学校读者我要写书评

暂无评论

Progress in Natural Science:Materials International 2018年第2期28卷 97-98页

作者： g.q.(max) lu University of Surrey

In the last decade,environmental pressures due to air and water pollution and the drive for clean energy supply are rising,which have led to the tremendous interest and investment in sustainable materials *** has been at the forefront of research and development of clean technologies for air,water and energy not surprisingly because of the strong need for such technologies to balance development and

关键词： Energy and Water Nanomaterials for Clean Air

Rational design of AggaS/ZnS/ZnS quantum dots with a near-unity photoluminescence quantum yield via double shelling scheme

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2024年第2期169卷 235-242页

作者： H.X.lu H.Liu Z.Z.Fu Y.Y.Chen H.q.Dai Z.Hu W.L.Zhang R.q.guo Institute for Electric Light Sources School of Information Science and TechnologyFudan UniversityShanghai 200433China Institute of Future Lighting Academy for Engineering and TechnologyFudan UniversityShanghai 200433China Yiwu Research Institute of Fudan University YiwuZhejiang 322000China Zhongshan-Fudan Joint Innovation Center Zhongshan 528437China

In this study,a two-step method was used to synthesize highly luminescent AggaS/ZnS/ZnS quantum dots(qDs).In the first step,an inner ZnS shell was formed via a one-pot method,which resulted in a smaller lattice mismatch between the AggaS core and the outer ZnS shell,thereby facilitating the formation of a thick outer *** the two-step shelling process,the synthesized AggaS/ZnS/ZnS qDs showed an excellent photoluminescence quantum yield(PLqY)of 96.4%with a peak wavelength of 508 nm,repre-senting the highest PLqY reported thus far for AggaS ***,the effect of halogen ions in Zn precursors on the shelling process was *** was proposed that the capacity of halogen ions to coordinate with the qDs influenced the balance between Zn cation diffusion and ZnS shelling ***,the ZnS shelling reaction was dominant when ZnCl_(2)was employed,while Zn cation diffusion was the dominant process under the I^(−)-rich *** work provides insights into the interfacial restructuring during the ZnS shelling and offers a clear map for the tailored synthesis of core/shell qDs.

关键词： AggaS quantum dots Photoluminescence Core/shell Alloyed core/shell interface

p-d Orbital Hybridization Engineered Single-Atom Catalyst for Electrocatalytic Ammonia Synthesis

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Energy & Environmental Materials 2024年第2期7卷 119-125页

作者： Jingkun Yu Xue Yong Siyu lu green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou 450001China Department of Chemistry University of SheffieldSheffieldS37HFUK

The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is ***-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising *** to now,the roles of individual metals,coordination atoms,and their synergy effect on the electroanalytic performance remain ***,in this work,a series of 2DMOFs with different metals and coordinating atoms are systematically investigated as electrocatalysts for ammonia synthesis using density functional theory *** a specific metal,a proper metal-intermediate atoms p-d orbital hybridization interaction strength is found to be a key indicator for their NRR catalytic *** hybridization interaction strength can be quantitatively described with the p-/d-band center energy difference(Δd-p),which is found to be a sufficient descriptor for both the p-d hybridization strength and the NRR *** maximum free energy change(Δg_(max))andΔd-p have a volcanic relationship with OsC_(4)(Se)_(4)located at the apex of the volcanic curve,showing the best NRR *** asymmetrical coordination environment could regulate the band structure subtly in terms of band overlap and *** work may shed new light on the application of orbital engineering in electrocatalytic NRR activity and especially promotes the rational design for SACs.

关键词： first-principle calculations Nitrogen reduction p-d orbital hybridization single-atom catalysts

维普期刊数据库

Construction of hollow mesoporous silica nanoreactors for enhanced photo-oxidations over Au-Pt catalysts

在线全文

学校读者我要写书评

暂无评论

National Science Review 2020年第11期7卷 1647-1655页

作者： Hao Tian Jinhui Zhao Xinyao Wang Lizhuo Wang Hao Liu guoxiu Wang Jun Huang Jian Liu g.q.(max) lu State Key Laboratory of Catalysis Dalian Institute of Chemical Physics (DICP)Chinese Academy of Sciences Centre for Clean Energy Technology School of Mathematical and Physical SciencesFaculty of ScienceUniversity of Technology Sydney Laboratory for Catalysis Engineering School of Chemical and Biomolecular Engineering Sydney Nano Institute The University of Sydney DICP-Surrey Joint Centre for Future Materials Department of Chemical and Process Engineering and Advanced Technology Institute University of Surrey University of Surrey

It is highly desirable to design hollow structures with multi-scale functions by mimicking cells for the construction of micro/nanoreactors. Herein, we report the construction of hollow-structured submicrometer-photoreactors with bimetallic catalysts loaded within mesoporous silicas. The synthesis parameters are optimized to study the evolution of hollow structure through hydrothermal treatment and an ‘adhesive-contraction’ formation mechanism is proposed. Au Pt@HMZS catalysts exhibited a broader absorbance region under visible light and the adsorption edge displayed a red-shift, indicating the strong metal–metal interactions at the alloy interface. The reaction performance of the coupled Au-Pt catalysts can be tuned to achieve excellent catalytic activity in cinnamyl alcohol oxidation to cinnamic acid for 3.1 mmol g-1with 99%selectivity. The proposed strategy to build hollow structures as multifunctional micro/nanoreactors is promising for the design of high-performance and sustainable catalysts for chemical synthesis.

关键词： nanoreactors photocatalytic oxidation metal nanoparticles mesoporous materials surface plasmonic resonance

From non-carbon host toward carbon-free lithium-sulfur batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第3期17卷 1337-1365页

作者： Yanqi Feng Hui Liu qiongqiong lu School of Materials Science and Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic MaterialsShaanxi University of Science and TechnologyXi’an 710021China Institute of Materials Henan Key Laboratory of Advanced Conductor MaterialsHenan Academy of SciencesZhengzhou 450046China Leibniz Institute for Solid State and Materials Research(IFW)Dresden e.V. Helmholtzstraβe 2001069 DresdenGermany School of Materials&Environment Engineering Chengdu Technological UniversityChengdu 611730China

Lithium-sulfur(Li-S)batteries with advantages of high energy densities(2600 Wh·kg^(-1)/2800 Wh·L^(-1))and sulfur abundance are regarded as promising candidates for next-generation high-energy ***,the conventional carbon host used in sulfur cathodes suffers from poor chemical adsorption towards Li-polysulfides(LPS)in liquid electrolyte and sluggish redox kinetics,leading to low capacity and rate ***,carbon host used in Li metal anode with the intrinsic property of poor lithiophilicity and high Li-nucleation barrier gives rise to uncontrollable dendrite growth and further battery ***,non-carbon hosts with chemical adsorption toward LPS and catalytic activity for accelerating LPS redox conversion as well as lithiophilic property for guiding uniform Li deposition are proposed and demonstrated a high efficiency in both sulfur cathodes and Li metal *** this review,the principle and challenges of Li-S batteries are first presented,then recent work using non-carbon hosts in Li-S batteries is summarized comprehensively,and the mechanism of non-carbon host in improving sulfur utilization and stabilizing Li metal anode is discussed in ***,remaining challenges and outlook on the implementation of non-carbon host for practical carbon-free Li-S batteries are also provided.

关键词： sulfur cathode Li metal anode polysulfides adsorption catalytic effect Li dendrite carbon-free lithium-sulfur batteries

A Degree Condition for graphs Having All(a,b)-parity Factors

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Acta Mathematicae Applicatae Sinica 2024年第3期40卷 656-664页

作者： Hao-dong LIU Hong-liang lu School of Mathematics and Statistics Xi'an Jiaotong UniversityXi'an 710049China

Let a and b be positive integers such that a≤b and a≡b(mod 2).We say that g has all(a,b)-parity factors if g has an h-factor for every function h:V(g)→{a,a+2,…,b-2,b} with b|V(g)| even and h(v)≡b(mod 2) for all v∈V(g).In this paper,we prove that every graph g with n≥2(b+1)(a+b) vertices has all(a,b)-parity factors if δ(g)≥(b^(2)-b)/a,and for any two nonadjacent vertices u,v ∈V(g),max{d_(g)(u),d_(g)(v)}≥bn/a+***,we show that this result is best possible in some sense.

关键词： degree condition all(a,b)-factors

维普期刊数据库

APPROXIMATION PROBLEMS ON THE SMOOTHNESS CLASSES

在线全文

学校读者我要写书评

暂无评论

Acta Mathematica Scientia 2024年第5期44卷 1721-1734页

作者： Yongping LIU Man lu School of Mathematical Sciences Beijing Normal UniversityBeijing100875China

This paper investigates the relative Kolmogorov n-widths of 2π-periodic smooth classes in■.We estimate the relative widths of■and its generalized class K_(p)■(P_(r)),where K_(p)H^(ω)(Pr)is defined by a self-conjugate differential operator P_(r)(D)induced by■Also,the modulus of continuity of the r-th derivative,or r-th self-conjugate differential,does not exceed a given modulus of continuityω.Then we obtain the asymptotic results,especially for the case p=∞,1≤q≤∞.

关键词： relative width self-conjugate differential operator asymptotic estimate

Rational Design of Plasmonic Nanoparticle-Molecule Complexes for Chirality Sensing

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第8期42卷 903-919页

作者： Chen Wang Dandan lu Lichao Sun qingfeng Zhang College of Chemistry and Molecular Sciences Wuhan UniversityWuhanHubei430072 China

Comprehensive Summary,Sensing the chirality of molecules is of great importance to fields such as enantioselective synthesis,pharmaceutical industry,and *** nanoparticles are ideal candidates for molecular sensing due to their inherent plasmonic properties that significantly enhance their sensitivity to surrounding *** plasmonic nanoparticle-molecule complexes for chirality sensing has drawn enormous attention in recent years due to their intriguing properties and potential ***,in this review,we believe it is timely to circumnavigate the rational design of plasmonic nanoparticle-molecule complexes and widen the scope of their emerging applications in chirality ***,we present different fundamental mechanisms for plasmon-based chirality that are built on the system of plasmonic nanoparticle-molecule ***,we review the typical applications of plasmonic nanoparticle-molecule complexes in chirality ***,we discuss the emerging biomedical applications that the plasmon-based chirality has attracted enormous ***,we provide an outlook on the challenges and opportunities in the field of plasmonic approaches for chirality sensing.

关键词： Chirality Surface plasmon resonance Nanoparticles Chiral molecules Chirality sensing

geometric phase-encoded stimuli-responsive cholesteric liquid crystals for visualizing real-time remote monitoring:humidity sensing as a proof of concept

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Light(Science & Applications) 2024年第2期13卷 283-293页

作者： Shi-Long Li Zhao-Yi Chen Peng Chen Wei Hu Chaohong Huang Sen-Sen Li Xuejia Hu Yan-qing lu lu-Jian Chen Department of Electronic Engineering School of Electronic Science and EngineeringXiamen University361005 XiamenChina College of Engineering and Applied Sciences Nanjing University210093 NanjingChina Fujian Key Laboratory of Ultrafast Laser Technology and Applications Xiamen University361005 XiamenChina

Liquid crystals are a vital component of modern photonics,and recent studies have demonstrated the exceptional sensing properties of stimuli-responsive cholesteric liquid ***,existing cholesteric liquid crystal-based sensors often rely on the naked eye perceptibility of structural color or the measurement of wavelength changes by spectrometric tools,which limits their practical ***,developing a platform that produces recognizable sensing signals is *** this study,we present a visual sensing platform based on geometric phase encoding of stimuli-responsive cholesteric liquid crystal polymers that generates real-time visual patterns,rather than frequency *** demonstrate this platform’s effectiveness,we used a humidity-responsive cholesteric liquid crystal polymer film encoded with a q-plate pattern,which revealed that humidity causes a shape change in the vortex beam reflected from the encoded cholesteric liquid crystal ***,we developed a prototype platform towards remote humidity monitoring benefiting from the high directionality and long-range transmission properties of laser beams carrying orbital angular *** approach provides a novel sensing platform for cholesteric liquid crystals-based sensors that offers promising practical *** ability to generate recognizable sensing signals through visual patterns offers a new level of practicality in the sensing field with stimuli-responsive cholesteric liquid *** platform might have significant implications for a broad readership and will be of interest to researchers working in the field of photonics and sensing technology.

关键词： humidity visual liquid