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The Electric Mechanism of Surface Pretreatments for Dye-Sensitized Solar Cells Based on Internal Equivalent Resistance Analysis

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Chinese Physics Letters 2012年第1期29卷 279-282页

作者： XU Wei-Wei HU Lin-Hua LUO Xiang-Dong liu pei-sheng DAI Song-Yuan Jiangsu Provincial Key Lab of ASIC Design Nantong UniversityNantong 226019 Division of Solar Energy Materials and Engineering Institute of Plasma PhysicsChinese Academy of SciencesHefei 230031

Based on the optimization of dye-sensitized solar cell (DSC) photoelectrodes pretreated with different methods such as electrodeposition,spin-coating and TiCl_(4) pretreatment,theoretical calculations are carried out to interpret the internal electric *** numerical values,including the series resistance R_(s) and the shunt resistance R_(sh) corresponding to the equivalent circuit model,are well evaluated and confirm that the DSC has good performance with a high R_(sh) and a low R_(s) due to good electrical contact and a low charge recombination after the different *** Ⅰ-Ⅴ curves are fifted in the case without series resistance,and account for the role of R_(s) in the output *** is found that when R_(s) tends to the infinitesimal,the short-circuit current Isc,the open-circuit voltage V_(oc) and the fill factor can be improved by almost 0.8-1.4,2.9 and 2.1-6.8%,respectively.

关键词： resistance coating Internal

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泡沫金属双向承载的力学模型

中国有色金属学报 2006年第4期16卷 567-574页

作者：刘培生北京师范大学材料科学与工程系射线束技术与材料改性教育部重点实验室北京100875

根据开孔泡沫金属材料的结构特点提出其抽象化的新型简化结构模型,即“八面体模型”,在此基础上建立起该类材料在双向拉伸条件下的力学分析模型。从该分析模型出发,推导得出了该类材料在双向拉伸破坏时两向名义应力与孔率三者的数学关... 详细信息

根据开孔泡沫金属材料的结构特点提出其抽象化的新型简化结构模型,即“八面体模型”,在此基础上建立起该类材料在双向拉伸条件下的力学分析模型。从该分析模型出发,推导得出了该类材料在双向拉伸破坏时两向名义应力与孔率三者的数学关系式。结果表明:该关系式还可进一步描述成“偏应力”、“平均应力”和孔率三者之间的关系。本理论模型与Gibson和Ashby的有关理论体系的不同之处是,前者可直接运用“梁理论”进行方便的分析和推演,而后者则不能。验证实验结果显示,本理论模型的数学关系与实际数据吻合良好。

关键词：泡沫金属多孔金属泡沫材料多孔材料

多孔材料在压缩载荷作用下的屈曲失效模式分析

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物理学报 2010年第12期59卷 8801-8806页

作者：刘培生北京师范大学核科学与技术学院射线束技术与材料改性教育部重点实验室北京100875

压缩是工程材料最基本的承载方式之一,多孔材料中的孔棱受到压缩载荷时可能产生屈曲行为.建立了各向同性三维网状高孔率多孔材料的简化结构失效模型,分析了这种材料在不同压缩载荷作用下由于孔棱发生屈曲而引起的失效模式,系统地得出了... 详细信息

压缩是工程材料最基本的承载方式之一,多孔材料中的孔棱受到压缩载荷时可能产生屈曲行为.建立了各向同性三维网状高孔率多孔材料的简化结构失效模型,分析了这种材料在不同压缩载荷作用下由于孔棱发生屈曲而引起的失效模式,系统地得出了单向压缩、双向压缩和三向压缩等三种承载形式下这种多孔体受压而导致孔棱屈曲时名义主应力与孔率的数理关系.在此基础上,进一步得出了此类材料在压缩载荷作用下发生孔棱屈曲的载荷条件.

关键词：多孔材料泡沫材料压缩载荷屈曲失效

多孔材料在压缩载荷作用下的剪切破坏模式分析

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物理学报 2010年第7期59卷 4849-4856页

作者：刘培生北京师范大学核科学与技术学院射线束技术与材料改性教育部重点实验室北京100875

压缩行为是工程材料最为基本的力学性能之一.本文通过简化结构模型分析了各向同性的三维网状高孔率多孔材料在压缩载荷作用下的破坏模式,其中包括单向压缩、双向压缩和三向压缩等三种承载情形.在此基础上,得出了这种多孔体受压破坏源于... 详细信息

压缩行为是工程材料最为基本的力学性能之一.本文通过简化结构模型分析了各向同性的三维网状高孔率多孔材料在压缩载荷作用下的破坏模式,其中包括单向压缩、双向压缩和三向压缩等三种承载情形.在此基础上,得出了这种多孔体受压破坏源于剪切断裂模式时名义主应力与孔率之间的数理关系.结果表明,该类材料承受压缩载荷时的破坏模式与其材质的种类有关,脆性材质多孔体的孔棱呈拉断破坏模式,而韧性材质多孔体的孔棱则可能出现剪切断裂的破坏模式.对应得出的强度设计判据可为该类材料在这种承载破坏模式下的应用提供参考.

关键词：多孔材料泡沫材料压缩载荷剪切破坏

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泡沫金属在单双向拉压载荷作用下的表征分析

中国有色金属学报 2008年第11期18卷 2062-2067页

作者：刘培生北京师范大学射线束技术与材料改性教育部重点实验室北京100875 北京师范大学核科学与技术学院北京100875

探讨泡沫金属的单向压缩以及双向拉压行为,并研究了该材料单双向拉伸性能,进一步分析该材料在承受各种单双向拉压载荷时的不同响应方式。结果表明:在泡沫金属材料受到不同的单双向拉压载荷作用而产生破坏时,其承受的各向名义应力大小与... 详细信息

探讨泡沫金属的单向压缩以及双向拉压行为,并研究了该材料单双向拉伸性能,进一步分析该材料在承受各种单双向拉压载荷时的不同响应方式。结果表明:在泡沫金属材料受到不同的单双向拉压载荷作用而产生破坏时,其承受的各向名义应力大小与多孔体的孔率都可表达为一个统一的数理关系;对于一个确定的多孔体材料,其单双向压缩负载能力要分别大于其单双向拉伸负载能力。

关键词：泡沫金属多孔金属多孔材料多向载荷

Design of efficient thermoelectric generators

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Science China Materials 2024年第1期67卷 377-378页

作者： Min liu Yanzhong pei Interdisciplinary Materials Research Center School of Materials Science and EngineeringTongji UniversityShanghai 201804China

Thermoelectricity,which enables direct conversion between heat and electricity,undergoes impressive developments in recent decades,and is particularly promising for recovering low-grade heat of<600 K[1,2].Currently,only Bi2Te3-based thermoelectric devices are commercialized[3].However,the scarcity of tellurium(Te)(Fig.1a)is the main *** leads to numerous recent efforts on the development of efficient nonBi2Te3 thermoelectrics as potential alternatives,and successful examples(Fig.1b)include Mg3Sb2-alloys[2,3]and MgAgSb[1,2].

关键词： enable efficient electricity

High-performance sodium storage for cobalt phosphide composite array electrodes

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Rare Metals 2024年第8期43卷 3724-3734页

作者： Man Zhang Xiao-Xu liu Tian-Yi Ji Yang Li Da-Wei sheng Shao-Dong Li pei-pei Ren Ze-Xiang Shen School of Material Science and Engineering Shaanxi University of Science and TechnologyXi'an 710021China School of Physical and Mathematical Sciences Nanyang Technological UniversitySingapore 637371Singapore

Transition metal phosphides hold great potential as sodium-ion batteries anode materials owing to their high theoretical capacity and modest ***,volume changes and low intrinsic conductivity seriously largely hinder the further development of metal phosphide *** design of phosphide anode materials with reasonable structure is conducive to solving the problems of volume expansion and slow reaction kinetics during the *** this work,a composite material integrating zeolite imidazolate backbone(ZIF) and carbon materials was synthesized by the original growth ***,by the oxidation-phosphating process,CoP nanoarray composites riveted to carbon fiber(CoP@CF) were *** the CoP@CF,CoP nanoparticles are uniformly distributed on ZIF-derived carbon,reducing agglomeration and volume change during *** also provides a highly conductive network for the active material,improving the electrode ***,when evaluated as an anode for sodium-ion batteries,CoP@CF electrode displays enhanced reversible capacity(262 mAh·g^(-1) at 0.1 A·g^(-1)after 100 cycles),which is much better than that of pure CF electrode(57 mAh·g^(-1) at 0.1 A·g^(-1) after 100 cycles)prepared without the addition of *** rate performance of CoP@CF electrode is also superior to that of pure CF electrode at various current densities from 0.05 to1 A·g^(-1).The sodium storage behavior of CoP@CF was revealed by ex-situ X-ray photoelectron spectroscopy,X-ray diffraction,and synchrotron radiation absorption *** method provides a reference for the design and synthesis of anode materials in sodium-ion batteries.

关键词： Cobalt phosphide Array structure Freestanding anodes Sodium-ion batteries

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多孔材料在三向载荷作用下的力学模型

材料科学与工艺 2010年第5期18卷 609-613页

作者：刘培生北京师范大学核科学与技术学院北京100875

为更全面掌握三维网状多孔材料在工程应用中的安全承载问题,分析了各向同性的该类材料在三向载荷(多向载荷)作用下的力学性能.在其结构简化的基础上,提出了该类材料在三向载荷作用下相应的承载力学模型,其中三向载荷中的任何一个载荷都... 详细信息

为更全面掌握三维网状多孔材料在工程应用中的安全承载问题,分析了各向同性的该类材料在三向载荷(多向载荷)作用下的力学性能.在其结构简化的基础上,提出了该类材料在三向载荷作用下相应的承载力学模型,其中三向载荷中的任何一个载荷都可以任意为拉伸和压缩.运用这一模型,可以判断当该类材料在承受上述载荷条件时是否会发生破坏,其用来判断的材料固有指标即是多孔体的孔率,该指标是多孔材料最基本的参量.

关键词：多孔材料泡沫材料多向载荷

Oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)particles in the air:Nonisothermal kinetic and reaction mechanism

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International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1839-1848页

作者： Junyi Xiang Xi Lu Luwei Bai Hongru Rao sheng liu Qingyun Huang shengqin Zhang Guishang pei Xuewei Lü School of Metallurgy and Materials Engineering Chongqing University of Science and TechnologyChongqing 401331China Department of Materials Science and Engineering Seoul National UniversitySeoul 08826Rep.of Korea College of Materials Science and Engineering Chongqing UniversityChongqing 400044China

High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium vanadium ***,the nonisothermal oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)prepared by high-temperature solid-state reaction was examined by thermogravimetry and X-ray diffraction(XRD)at heating rates of 5,10,and 15 K/*** apparent activation energy was determined by the Kissinger-Akahira-Sunose(KAS)method,whereas the mechanism function was elucidated by the Malek ***,in-situ XRD was conducted to deduce the phase transformation of the oxidation mechanism for FeV_(2)O_(4)and FeCr_(2)O_(4).The results reveal a gradual increase in the overall apparent activation energies for FeV_(2)O_(4)and FeCr_(2)O_(4)during *** stages of the oxidation process are observed based on the oxidation conversion rate of each *** oxidation mechanisms of FeV_(2)O_(4)and FeCr_(2)O_(4)are complex and have distinct *** particular,the chemical reaction controls the entire oxidation process for FeV_(2)O_(4),whereas that for FeCr_(2)O_(4)transitions from a three-dimensional diffusion model to a chemical reaction *** to the in-situ XRD results,numerous intermediate products are observed during the oxidation process of both compounds,eventually resulting in the final products FeVO_(4)and V2O_(5)for FeV_(2)O_(4)and Fe_(2)O_(3)and Cr_(2)O_(3)for FeCr_(2)O_(4),respectively.

关键词： FeV_(2)O_(4) FeCr_(2)O_(4) oxidation nonisothermal kinetics mechanism

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