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基于离散元的钢渣透水沥青混合料疲劳损伤数值仿真

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江苏大学学报（自然科学版） 2025年第1期46卷 98-104页

作者：刘振辉陈雪琴董侨姚波范进南京理工大学理学院江苏南京210094 南京理工大学安全科学与工程学院江苏南京210094 东南大学交通学院江苏南京211189 东南大学道路交通工程国家级实验教学示范中心江苏南京211189

采用钢渣替换透水沥青混合料中部分玄武岩粗集料,开展室内疲劳试验及数值仿真,研究钢渣透水沥青混合料的疲劳性能.基于CT扫描获取图像,通过阈值分割将混合料中钢渣、玄武岩、沥青砂浆和孔隙进行区分,导入颗粒流程序(PFC),建立颗粒直径为... 详细信息

采用钢渣替换透水沥青混合料中部分玄武岩粗集料,开展室内疲劳试验及数值仿真,研究钢渣透水沥青混合料的疲劳性能.基于CT扫描获取图像,通过阈值分割将混合料中钢渣、玄武岩、沥青砂浆和孔隙进行区分,导入颗粒流程序(PFC),建立颗粒直径为0.4 mm的钢渣透水沥青混合料离散元模型,基于宏观和细观力学参数转换及虚拟强度试验进一步校正细观力学参数,开展虚拟疲劳损伤数值模拟,得到重复荷载作用下试件微裂纹扩展路径及疲劳寿命.结果表明:虚拟强度试验能够较好地模拟钢渣透水沥青混合料试件荷载与位移关系曲线,试件裂纹扩展路径符合实际断裂情况,裂纹的分布主要沿着模型内部孔隙处扩展;虚拟疲劳损伤模型能够较好地描绘平行黏结模型的黏结直径随荷载作用次数的增加而减小、随着平行黏结接触颗粒间的拉应力增大而加速减小的趋势,虚拟疲劳损伤模型计算结果和室内疲劳损伤试验结果较为接近,误差不到10%,可有效预测高应力比下钢渣透水沥青混合料的疲劳寿命.

关键词：钢渣透水沥青混合料疲劳损伤离散元方法裂纹扩展

Single-Atom Lithiophilic Sites Confined within Ordered Porous Carbon for Ultrastable Lithium Metal Anodes

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Energy & Environmental Materials 2023年第3期6卷 366-372页

作者： Wenzhong Huang Shanlin liu Ruohan Yu Liang Zhou zhenhui liu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Nanostructure Research Centre Wuhan University of TechnologyWuhan 430070China College of Material Science and Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu hydrogen ValleyFoshan 528200China

Attributing to the high specific capacity and low electrochemical reduction potential,lithium(Li)metal is regarded as the most promising anode for high-energy Li ***,the growth of lithium dendrites and huge volume change seriously limit the development of lithium metal *** overcome these challenges,an ordered mesoporous N-doped carbon with lithiophilic single atoms is proposed to induce uniform nucleation and deposition of Li *** from the synergistic effects of interconnected three-dimensional ordered mesoporous structures and abundant lithiophilic single-atom sites,regulated local current density and rapid mass transfer can be achieved,leading to the uniform Li deposition with inhibition of dendrites and buffered volume *** a result,the as-fabricated anode exhibits a high CE of 99.8%for 200 cycles.A stable voltage hysteresis of 14 mV at 5 mA cm^(−2)could be maintained for more than 1330 h in the symmetric ***,the full cell coupled with commercial LiFePO_(4)exhibits high reversible capacity of 108 mAh g^(−1)and average Coulombic efficiency of 99.8%from 5th to 350th cycles at 1 *** ordered mesoporous carbon host with abundant lithiophilic single-atom sites delivers new inspirations into rational design of high-performance Li metal anodes.

关键词： lithiophilic lithium metal battery ordered mesoporous carbon single atom

A facile method for preparing thiocyanato-functionalized porous silica nanospheres

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Particuology 2016年第1期14卷 183-190页

作者： Jie Li Lianxi Chen Xi Li Chaocan Zhang zhenhui liu School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan 430070 China School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 China

In this study, we present a facile method to prepare thiocyanato-functionalized porous silica nanospheres. Thiocyanato functionalized silica shells were coated on positively charged cetyltrimethylammonium bromide （CTAB） micelles via hydrolysis and condensation of （3-thiocyanatopropyl）triethoxysilane （TCPTES）, the CTAB cores were removed subsequently to form thiocyanato-functionalized porous sil- ica nanospheres. We demonstrate that the contents of the thiocyanato groups within the functionalized porous silica nanosphere frameworks gradually diminished as a function ofhydrothermal treatment time at 100~C until complete removal, confirmed by TGA and FTIR spectra. The data indicate that extended operation at relatively elevated temperatures may lead to the decomposition of the thiocyanato functional groups. In addition, at a lower CTAB concentration （0.0009 M）, non-porous thiocyanato functionalized sil- ica nanospheres were formed. However, increasing the CrAB concentration to 0.01 M resulted in porous nanospheres inferring that a CTAB concentration threshold is needed to form thiocyanato-functionalized porous silica nanospheres.

关键词： Thiocyanato Functionalization Silica nanospheres Porous Micellar template

Expression, purification and polyclonal antibody generation of p23, an Hsp90 cochaperone, in the amphioxus Branchiostoma belcheri

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Acta Oceanologica Sinica 2006年第6期25卷 99-105页

作者： ZHAO Bosheng ZHANG Shicui PANG Qiuxiang liu zhenhui LIANG Yujun Department of Marine Biology Ocean University of China Qingdao 266003 China School of Life Sciences Shandong University of Technology Zibo 255049 China

The cDNA of amphioxus p23, a highly conserved co-chaperone for Hsp90, was cloned into a bacterial expression vector pGEX - 6P - 1 and the GST-tagged fusion protein was produced in Eschherichia coli cells. The recombinant p23 was purified by affinity purification, and its molecular mass was estimated to be approximately 22 kDa by sodium dedecyl sulfate-polyacrylamide gel electrephoresis. The N-terminus of purified p23 was sequenced, and the resulting amino acid sequence matches exactly the predicted residues deduced from the amphioxus p23 gene. Besides, pelyclonal antibodies against the recombinant p23 were generated, and these antibodies not only recognized specifically the fusion protein GST - p23 from induced E. coli cells, purified GST - p23 and p23 protein, but also reacted with the total protein extracted fi＇om the adult amphioxus and formed a single positive band. These results pave the way for identifying its tissue and subcellular localization, and may open the door to clarifying its structure and mechanisms of biological role.

关键词： amphioxus Branchiostoma p23 fusion protein purification antibody

Presence of a long nuclear-localization signal sequence in homeodomain transcription factor Nkx 1.2

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Journal of Oceanology and Limnology 2024年第2期42卷 620-626页

作者： Xinyi LI Lihui CHEN Xinyuan WANG Chen SUN Guangdong JI Guobin HU zhenhui liu College of Marine Life Science and Institute of Evolution&Marine Biodiversity Ocean University of ChinaQingdao 266003China Laoshan Laboratory Qingdao 266237China

Homeodomains,a 60-amino acid sequence encoded by 180 nucleotides,are highly conserved DNA-binding motifs that are present in a variety of transcription factors in species ranging from yeast to *** NKX proteins belong to the homeodomain(HD)-containing transcription factor *** play vital roles in the regulation of ***1-2 is one member of the NKX *** present,information about its nuclear localization signal(NLS)sequence is *** studied the NLS sequence of zebrafish Nkx1.2 by introducing sequence changes such as deletion,mutation,and truncation,and identified an NLS motif(QNRRTKWKKQ)that is localized at the C-terminus of the ***,the deletion of two amino acid residues(RR)in this NLS motif prevents Nkx1.2 from entering the nucleus,indicating that the two amino acids are essential for Nkx1.2 nuclear ***,the NLS motif alone is unable to target cytoplasmic protein glutathione S-transferase(GST)to the *** intact homeodomain is necessary for mediating the complete nuclear transport of cytoplasmic *** most nuclear import proteins with short NLS sequences,a long NLS is present in zebrafish *** also demonstrated that the sequences of homeodomain of NKX1.2 are well conserved among different *** study is informative to verify the function of the NKX1.2 protein.

关键词： NKX1.2 NKX protein homeodomain nuclear localization signal(NLS) nuclear transport

One-step,in situ formation of WN-W_(2)C heterojunctions implanted on N doped carbon nanorods as efficient oxygen reduction catalyst for metal-air battery

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Nano Research 2023年第7期16卷 8773-8781页

作者： Yue Du Wenxue Chen Lina Zhou Rui Hu Shizhu Wang Xueqing Li Yunlong Xie Lun Yang Yisi liu zhenhui liu Institute for Advanced Materials Hubei Normal UniversityHuangshi 435002China College of Material Science and Engineering Jiangsu Key Laboratory of Materials and Technology for Energy ConversionNanjing University of Aeronautics and AstronauticsNanjing 210016China

Transition metal nitrides and carbides have attracted intensive attentions in metal-air battery application due to their metallic electron transport behavior and high chemical stability toward the oxygen reduction reaction(ORR).Herein,the polyoxometalate@polyaniline composite derived WN-W_(2)C heterostructured composite(WN-W_(2)C@pDC)has been fabricated through an in situ nitriding-carbonization strategy,with WN-W_(2)C nanoparticles implanted on N doped carbon *** WN-W_(2)C@pDC demonstrates prominent electrocatalytic performance towards ORR and excellent cycling stability in metal-air battery,which possesses positive half-wave potential and large diffusion limiting current density(0.81 V and 5.8 mA·cm^(-2)).Moreover,it demonstrates high peak power density of 157.4 mW·cm^(-2)as Al-air primary cathode and excellent stability at the discharge-charge test(>500 h)of Zn-air secondary *** excellent activity and durability of WNW_(2)C@pDC catalyst should be attributed to the combined effect of intimate WN-W_(2)C heterointerfaces,unique embedded nanoparticles structure,and excellent electrical media of N doped carbon,confirmed by a series of contrast experiments.

关键词： WN-W_(2)C heterojunctions polyoxometalate@polyaniline composite oxygen reduction reaction metal-air battery

Commercial Application of X-62 Catalyst for Reducing Olefins in Gasoline

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China Petroleum Processing & Petrochemical Technology 2005年第3期7卷 11-18页

作者： Zhao zhenhui liu Jingxiang Xu Wuqing Hou Yubao SINOPEC Luoyang Branch Company Luoyang 471012

In order to reduce the coke yield and increase the economic benefits of FCC unit under the prerequisites of securing the olefin content of gasoline in compliance with the requirement, SINOPEC Luoyang Branch Company applied in the period from July through October 2004 the new generation X-62 catalyst (FlexTec-LOL1) developed by the Engelhard Corporation of USA to improve the heavy oil conversion and to reduce coke make. The result of tests has shown that indicators on reducing the unit catalyst consumption,amplitude on reduction of non-ideal products (coke+oil slurry+dry gas) yield, and amplitude on reduction of coke yield were comparatively satisfactory.

关键词： RFCC gasoline olefin coke heavy oil conversion catalyst

A high-performance electrocatalyst for oxygen reduction derived from copolymer-anchored polyoxometalates

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Nano Research 2024年第6期17卷 5197-5205页

作者： Yue Du Wenxue Chen Zhiyi Zhong Zhixian Shi Yulin Zhang Xuanning Chen Yisi liu Dongbin Xiong Lina Zhou zhenhui liu Mingbo Zheng Hubei Key Laboratory of Photoelectric Materials and Devices&College of Material Science and Engineering Hubei Normal UniversityHuangshi 435002China College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 210016China

The development and synthesis of cathode electrocatalysts with high activity and durable stability for metal-air batteries is an important challenge in the area of ***,we introduce a novel in-situ nitriding and phosphating strategy for producing W_(3)N_(4)and WP from phosphotungstic acid(HPW)-polyaniline-phytic acid-Fe3+organic-inorganic hybrid *** final material has a three-dimensional porous framework with W_(3)N_(4)-WP heterostructures embedded in the carbon matrix(W_(3)N_(4)-WP@NPC).As-made materials exhibit exceptional electrocatalytic performance for the oxygen reduction reaction(ORR),with a diffusion-limiting current density of 6.9 mA·cm^(−2)and a half-wave potential of 0.82 *** a Zn-air primary cathode,the W_(3)N_(4)-WP@NPC assembled battery can provide a relatively high peak power density(194.2 mW·cm^(−2)).As a Zn-air secondary air-cathode,it has great cycling stability over 500 *** work provides a simple and efficient method for rationally designing high-performance air cathodes from copolymer-anchored polyoxometalates.

关键词： W_(3)N_(4)-WP heterojunctions copolymer-anchored polyoxometalates oxygen reduction reaction Zn-air battery

Macroscopic synthesis of ultrafine N–doped carbon nanofibers for superior capacitive energy storage

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Science Bulletin 2019年第21期64卷 1617-1624页

作者： Qiang Yu Jianshuai Lv zhenhui liu Ming Xu Wei Yang Kwadwo Asare Owusu Liqiang Mai Dongyuan Zhao Liang Zhou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Saence and Engineering Wuhan University of TechnologyWuhan 430070China

Carbon nanofibers(CNFs)with excellent electric conductivity and high surface area have attracted immense research interests in ***,the macroscopic production of CNFs still remains a great ***,ultrafine N–doped CNFs(N–CNFs)with a diameter of$20 nm are synthesized through a simple and scalable sol-gel method based on the self-assembly of phenolic resin and cetyltrimethylammonium *** employed in aqueous supercapacitors,the obtained activated N–CNFs manifest a high gravimetric/areal capacitance(380 Fg-1/1.7 Fcm-2)as well as outstanding rate capability and cycling ***,the activated N–CNFs also demonstrate excellent capacitive performance(330 Fg-1)in flexible quasi-solid-state *** remarkable electrochemical performance as well as the easy and scalable synthesis makes the N–CNFs a highly promising electrode material for supercapacitors.

关键词： Macroscopic synthesis Carbon Nanofibers N–doping Supercapacitor