检索结果-南通市图书馆

Construction of Pd-doped RuO_(2) nanosheets for efficient and stable acidic water oxidation

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第6期9卷 937-948页

作者： Yibo liu xing Hu Chenxi liu Shan Zhu Kezhu Jiang Feng liu Shijian Zheng Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology College of Materials Science and EngineeringHebei University of TechnologyTianjin300401China Yunnan Precious Metals Lab Co. LTDKunming650100China

RuO_(2) has been considered a potential alternative to commercial IrO_(2) for the oxygen evolution reaction(OER)due to its superior intrinsic ***,its inherent structure dissolution in acidic environments restricts its commercial *** this study,we report a novel Pd-doped ruthenium oxide(Pd–RuO_(2))nanosheet catalyst that exhibits improved activity and stability through a synergistic effect of Pd modulation of Ru electronic structure and the two-dimensional *** catalyst exhibits excellent performance,achieving an overpotential of only 204 mVat a current density of 10 mA cm^(-2).Impressively,after undergoing 8000 cycles of cyclic voltammetry testing,the overpotential merely decreased by 5 *** PEM electrolyzer with Pd0.08Ru0.92O_(2) as an anode catalyst survived an almost 130 h operation at 200 mA cm^(-2).To elucidate the underlying mechanisms responsible for the enhanced stability,we conducted an X-ray photoelectron spectroscopy(XPS)analysis,which reveals that the electron transfer from Pd to Ru effectively circumvents the over-oxidation of Ru,thus playing a crucial role in enhancing the catalyst's ***,density functional theory(DFT)calculations provide compelling evidence that the introduction of Pd into RuO_(2) effectively modulates electron correlations and facilitates the electron transfer from Pd to Ru,thereby preventing the overoxidation of ***,the application of the two-dimensional structure effectively inhibited the aggregation and growth of nanoparticles,further bolstering the structural integrity of the catalyst.

关键词： Oxygen evolution reaction Pd-doped ruthenium oxide Two-dimensional structure Electron transfer Stability

Modulation of charge in C_(9)N_(4) monolayer for a highcapacity hydrogen storage as a switchable strategy

在线全文

学校读者我要写书评

暂无评论

Frontiers of physics 2024年第4期19卷 47-55页

作者： Lin ju junxian liu Minghui Wang Shenbo Yang Shuli liu School of Physics and Electric Engineering Anyang Normal UniversityAnyang 455000China School of Mechanical Medical and Process EngineeringQueensland University of TechnologyBrisbane QLD 4001Australia Hongzhiwei Technology(Shanghai)Co.Ltd. 1599 Xinjinqiao RoadPudongShanghai 201206China

Developing advanced hydrogen storage materials with high capacity and efficient reversibility is a crucial aspect for utilizing hydrogen source as a promising alternate to fossil *** this paper,we have systematically investigated the hydrogen storage properties of neutral and negatively charged C_(9)N_(4) monolayer based on density functional theory(DFT).Our foundings indicate that injecting additional electrons into the adsorbent significantly boosts the adsorption capacity of C_(9)N_(4) monolayer to H2 *** gravimetric density of negatively charged C_(9)N_(4) monolayer can reach up to 10.80 wt% when fully covered with *** other hydrogen storage methods,the storage and release processes happen automatically upon introducing or removing extra ***,these operations can be easily adjusted through activating or deactivating the charging *** a result,the method is easily reversible and has tunable kinetics without requiring particular ***,C_(9)N_(4) is proved to be a suitable candidate for efficient electron injection/release due to its well electrical *** work can serve as a valuable guide in the quest for a novel category of materials for hydrogen storage with high capacity.

关键词： hydrogen storage C_(9)N_(4)monolayer charge modulation density functional theory

Oxidation behavior of low-grade vanadiferous titanomagnetite concentrate with high titanium

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2024年第2期31卷 329-341页

作者： Jin-sheng liu Zhen-xing xing Gong-jin Cheng Xue-yong Ding Xiang-xin Xue School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina Liaoning Key Laboratory of Recycling Science for Metallurgical Resources Shenyang110819LiaoningChina Innovation Research Institute of Vanadium and Titanium Resource Industry Technology Northeastern UniversityShenyang110819LiaoningChina

In order to clarify the oxidation mechanisms and make better use of the low-grade vanadiferous titanomagnetite concentrate with high titanium(LVTC),the oxidation behavior of LVTC was *** results showed that oxidation degree was achieved within 90 min when temperature was not lower than 700°C,and the main phases of the oxidized LVTC consisted of Fe9TiO15,Fe2O3,CaSiTiO5 and a small amount of *** temperature is favorable to the formation of *** surface of LVTC gradually becomes rough,with fine particles of needle-like and granular shape appearing on the surface,which finally turn from laminar to creamy,spread out,and are interspersed with many tiny *** phase oxidation paths in LVTC were as follows:(1)Fe2.75Ti0.25O4→Fe9TiO15+Fe2O3;(2)Fe2.75Ti0.25O4→Fe2O3+FeTiO3→Fe2TiO5;(3)FeTiO3→Fe2O3+Fe2Ti3O9→*** is predominantly mesoporous whether oxidized or not,with the pores mainly distributed in the range of 2–40 nm,and the specific surface area of LVTC decreases significantly with increasing temperature.

关键词： Low-grade vanadiferous titanomagnetite concentrate Oxidation degree Phase transformation Micromorphology Oxidation path Pore structure

In-situ embedded ultrafine Bi_(12)O_(17)Br_(2)nanotubes in MOF-derived hierarchical porous carbon for enhanced photocatalytic CO_(2)conversion to CO

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2024年第4期171卷 47-53页

作者： xing Sun Mengxia Ji Yi Zhang Qingzeng xing Zihan liu Nianhua liu Emmanuel Nkudede Huaming Li Sheng Yin Jiexiang Xia School of Chemistry and Chemical Engineering Institute for Energy ResearchJiangsu UniversityZhenjiang 212013China Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Provincial Key Laboratory of Resources Chemistry of Salt LakesQinghai Institute of Salt LakesChinese Academy of SciencesXining 81008China

Increasing the utilization efficiency of photogenerated electrons is highly recognized as one of the ef-ficient approaches to boost the photocatalytic CO_(2)conversion ***,ZIF-67-derived porous carbon(PC)material was employed for the construction of PC@ultrafine Bi_(12)O_(17)Br_(2)nanotubes(PC@BOB NTs)composites through a facile solvothermal synthesis in order to optimize the use of excited elec-trons in the BOB *** characterization results revealed that the introduction of PC material achieved a faster charge separation rate in the PC@BOB composites,ensuring more photogener-ated electrons participate in the CO_(2)adsorption and activation ***,the pore structures of ZIF-67-derived PC material provided abundant confined spaces for the enrichment of CO_(2)***-ter 5 h of Xenon lamp irradiation,PC@BOB composites exhibited obviously increased photocatalytic CO_(2)reduction activity in the pure *** the addition amount of PC was 5 wt%,the PC@BOB-2 com-posite showed the highest CO evolution rate of 359.70μmol/g,which was 2.95 times higher than that of the pure BOB *** work provides some independent insights into the applications of Metal-Organic Framework(MOF)-derived hierarchical porous structures to strengthen the CO_(2)enrichment,as well as the excited charge utilization efficiency,thus achieving a high solar-to-fuel conversion efficiency.

关键词： Bi_(12)O_(17)Br_(2)nanotubes Hierarchical porous structure CO_(2)enrichment Charge separation CO_(2)photoreduction

MCR-YOLO model for underwater target detection based on multi-color spatial features

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Optoelectronics Letters 2024年第5期20卷 313-320页

作者： liu Peiyu xing Weiwei MA Yixuan School of Software Engineering Beijing Jiaotong UniversityBeijing 100044China

Within the fields of underwater robotics and ocean information processing, computer vision-based underwater target detection is an important area of research. Underwater target detection is made more difficult by a number of problems with underwater imagery, such as low contrast, color distortion, fuzzy texture features, and noise interference, which are caused by the limitations of the unique underwater imaging environment. In order to solve the above challenges, this paper proposes a multi-color space residual you only look once(MCR-YOLO) model for underwater target detection. First, the RGB image is converted into YCb Cr space, and the brightness channel Y is used to extract the non-color features of color-biased images based on improved Res Net50. Then, the output features of three scales are combined between adjacent scales to exchange information. At the same time, the image features integrated with low-frequency information are obtained via the low-frequency feature extraction branch and the three-channel RGB image, and the features from the three scales of the two branches are fused at the corresponding scales. Finally, multi-scale fusion and target detection are accomplished utilizing the path aggregation network(PANet) framework. Experiments on relevant datasets demonstrate that the method can improve feature extraction of critical targets in underwater environments and achieve good detection accuracy.

关键词： underwater image utilizing

Auto-Detection Method Using Convolution Neural Network for Bottom-Simulating Reflectors

在线全文

学校读者我要写书评

暂无评论

Journal of Ocean University of China 2024年第3期23卷 683-694页

作者： XU Haowei xing junhui YANG Boxue liu Chuang Key Laboratory of Submarine Geosciences and Prospecting Techniques MOE and College of Marine GeosciencesOcean University of ChinaQingdao 266100China Laboratory for Marine Mineral Resources Qingdao National Laboratory for Marine Science and TechnologyQingdao 266071China

In studies on gas hydrate,bottom-simulating reflectors(BSR)are used to determine the potential hydrate-bearing sedimentary ***,BSR detection is performed manually by experienced ***,a method for implementing an auto-matic BSR detection process should be *** this study,we develop a novel architecture for BSR characterization using the convolutional neural network(CNN)*** propose the use of Stokes’transform(ST)to obtain a time-frequency spectrum for the input of *** fully uses the frequency content of the seismic data,and a part of the 3D seismic data collected from the Blake Ridge is utilized to train the *** seismic records with variable signal-to-noise ratios(SNR),as well as Blake Ridge seismic data,were used to validate the detection effect of the *** show that the CNN trained by this method exhibits excellent performance in noise-resistant testing and achieves an accuracy of more than 89% in field seismic data detection.

关键词： BSR CNN Stocks’transform gas hydrate Blake Ridge

Impact of Mo/Ni alloying on microstructural modulation and low-temperature toughness of high-strength low-alloy steel

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2024年第7期31卷 1746-1762页

作者： Wei liu Hong-li Zhao Bing-xing Wang Yong Tian State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819LiaoningChina

The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control *** investigation was conducted to explore the effect of Ni/Mo microalloying on microstructure evolution and mechanical properties of the *** results revealed that the increase in Ni content from 1 to 2 wt.%reduced the transition temperature of ferrite and the growth range of ferritic grain was narrowed,which promoted grain *** optimized combination of grain size,high-angle grain boundaries(HAGBs),and martensite-austenite(M-A)islands parameter contributed to the excellent impact toughness of S1 steel at-100℃(impact absorbed energy of 218.2 J at-100℃).As the Mo increases from 0 to 2 wt.%,the matrix structure changes from multiphase structure to granular bainite,which increases the average effective grain size to~4.62 pm and reduces HAGBs proportion to~36.22%.With these changes,the low-temperature impact toughness of S3 steel is *** addition,based on the analysis of the characteristics of crack propagation path,it was found that M-A islands with low content(~2.21%)and small size(~1.76 pm)significantly retarded crack propagation,and the fracture model of M-A islands with different morphologies was further ***,correlation between behaviour of delamination and toughness was further analysed by observing delamination size and impact energy parameters.

关键词： High-strength low-alloy steel Microstructural regulation Ni addition Mo addition Crack propagation Low-temperature toughness

Link Prediction Method Fusion with Local Structural Entropy for Directed Network

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Electronics 2024年第1期33卷 204-216页

作者： Shuxin liu Hongchang CHEN Lan WU Kai WANG xing LI People’s Liberation Army Strategic Support Force Information Engineering University

Link prediction utilizes accessible network information to complement or predict the network *** is an important prerequisite for link prediction which means links more likely occurs between two similar nodes. Existing methods utilize the similarity of nodes but neglect of network structure. However the link direction leads to a far more complex structure and contains more information useful than the undirected networks. Most classic methods are difficult to depict the distribution of the network structure with incidental direction so the similarity characteristics of the network structure itself are lost. In this respect, a new method of local structure entropy is proposed to depict the directed structural distribution characteristics, which can be used to evaluate the degree of local structural similarity of nodes and then applied to link prediction methods. Experimental results on 8 real directed networks show that this method is effective for both area under the receiver operating characteristic curve(AUC)and ranking-score measures, and improved predictive capacity of the baseline methodology.

关键词： Correlation Current measurement Area measurement Prediction methods Receivers Benchmark testing Entropy

Drug delivery with Mn-doped MoO_(2) for photothermalenhanced chemotherapy in fighting cancers

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第5期43卷 2230-2240页

作者： Ping Zhao Hai-Fa Zheng ju Peng xing-Long Li Fazal Raziq Xiao-jun liu Hao-Quan Yu Jin-Lu Tang Yi-Fan Kang Wen-Huan Huang School of Chemistry and Chemical Engineering Guangdong Pharmaceutical UniversityGuangzhou 510006China KAUST Catalysis Center King Abdullah University of Science and Technology23955-6900 ThuwalKingdom of Saudi Arabia Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical EngineeringShaanxi University of Science and TechnologyXi'an 710021China

Although chemotherapy has been intensively applied in cancer treatments,its inadequate therapeutic efficacy and severe side effects are still under constant *** used as anti-tumor drug delivery system(DDS)have attracted tremendous attentions owing to their various intriguing ***,Mn-doped MoO_(2)nanoparticles coated with ZrO_(2)and capped with Bi_(2)O_(3)have been designed as a DDS,namely *** possesses good magnetic properties,great photothermal conversion ability,sensitive tumor microenvironment(TME)responsiveness,and good biocompatibility in hemocompatibility in ***,MMZB has been utilized to load the chemotherapeutic agent daunomycin(DNM)(MMZB@DNM)for chemo-photothermal combined ***@DNM demonstrates a more impressive anti-cancer effect than the individual photothermal or chemotherapy both in vitro and in ***,the analysis of tumor specimen sections and serum levels after the treatment indicates negligible side effects for MMZB@DNM in *** contribution provides a valuable concept in designing therapeutic agents for achieving significantly enhanced tumor treatments,which benefits from the synergistic combination of chemotherapy and photothermal therapy in one single nanoagent.

关键词： Mn-doped MoO_(2) Bi_(2)O_(3) Nanocarrier Photothermal Chemotherapy