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Unleashing the Power of Bio-based Thermotropic Liquid Crystal Modifiers:Toughening and Reinforcing Petroleum-based Epoxy Resin without Compromising Other Properties

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Chinese Journal of Polymer Science 2024年第8期42卷 1093-1102页

作者： Qing-Yun Lu Hong-Wei Gu Jia-Hui Li Qian-Qian Fan Bei-Tao liu Yan Kou Xi-Gao Jian Zhi-Huan Weng State Key Laboratory of Fine Chemicals Frontiers Science Center for Smart MaterialsLiaoning Technology Innovation Center of High Performance Resin MaterialsDepartment of Polymer Science&EngineeringDalian University of TechnologyDalian 116024China Thermochemistry Laboratory Liaoning Province Key Laboratory of Thermochemistry for Energy and MaterialsDalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China

Toughening the petroleum-based epoxy resin blends with bio-based modifiers without compromising their modulus,mechanical strength,and other properties is still a big challenge in view of the *** this study,a bio-based liquid crystal epoxy resin(THMT-E P)with an s-triazine ring structure was utilized to modify a petroleum-based bisphenol A epoxy resin(E51)with 4,4'-diaminodiphenylsulfone(DDS)as a curing agent,and the blended systems were evaluated for their thermal stability,mechanical properties,and flame *** results showed that the impact strength of the blended system initially increased and then decreased with the increase in THMT-EP content,and it reached the a maximum value of 26.5 kJ/m^(2)when the THMT-EP content was 5%,which was 31.2%higher than that of E51/***,the flexural strength,modulus,and glass transition tem perature of the blended system were all simultaneously improved with the addition of *** the same time,the addition of THMT-EP enhanced the flame retardancy of the system by increasing the char yield at 700℃and decreasing the peak heat release rate and total heat release *** work paves the way for a more sustainable improvement in the comprehensive performance of epoxy resin.

关键词： Epoxy resin Toughening Bio-based Thermotropic liquid crystal

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Assessment of hydraulic performance changes of Dongting Lake after the Three Gorges Reservoir impoundment by a novel semi-empirical approach

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Journal of Geographical Sciences 2024年第8期34卷 1537-1557页

作者： SUN Zhaohua LI Zhiqing CHEN Li FAN Jiewei liu Ya State Key Laboratory of Water Resources Engineering and Management Wuhan UniversityWuhan 430072China Yellow River Water&Hydropower Development Group Co. Ltd.Jiyuan 459017HenanChina Changjiang River Scientific Research Institute Wuhan 430010China

Floodplain lakes are important water storage areas in lowland regions that often undergo geomorphologic evolution,and timely topographic data are generally *** this study,to assess the impacts of lakebed deformation on hydraulic performance in Dongting Lake,a set of semi-empirical methods was proposed to establish performance graphs(PGs)using only hydrological *** methods were used to evaluate the changes in water level,storage capacity,and flood detention ability in Dongting Lake caused by topographic adjustment after the Three Gorges Reservoir *** methods showed that PGs can effectively simulate the water level and outflow processes of Dongting Lake with Nash-Sutcliffe efficiency coefficients(NSEs)above 0.9.A comparison of the estimated water level and discharge using PGs from different periods suggested that bed erosion in Dongting Lake caused water level decreases of 0.18 m and 0.32 m during the flood and dry seasons,*** the magnitude of erosion at high elevations in the lake is small,the impacts of bed adjustment on the storage capacity and flood detention ability are not currently *** study showed that the hydraulic performance of a floodplain lake can be evaluated independently of topographic data under the condition of no reverse flows or negative watersurface slopes.

关键词： Dongting Lake hydraulic performance graph bed adjustment semi-empirical approach backwater effect

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Subsurface multi-physical characterization of mountain excavation and city construction in loess plateau with a fiber-optic sensing system

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第8期16卷 2935-2946页

作者： Jie liu Bin Shi Kai Gu Meng-Ya Sun Jun-Cheng Yao He-Ming Han School of Earth Sciences and Engineering Nanjing UniversityNanjingJiangsu210023China Frontiers Science Center for Critical Earth Material Cycling Nanjing UniversityNanjing210023China School of Earth Sciences and Engineering Hohai UniversityNanjing210098China

Mountain excavation and city construction(MECC)projects being launched in the Loess Plateau in China involve the creation of large-scale artificial *** the subsurface evolution characteristics of the artificial land is essential,yet ***,we use an improved fiber-optic monitoring system for its subsurface multi-physical *** system enables us to gather spatiotemporal distribution of various parameters,including strata deformation,temperature,and ***’an New District was selected as a case study to conduct refined in-situ monitoring through a 77 m-deep borehole and a 30 m-long *** reveal that the ground settlement involves both the deformation of the filling loess and the underlying intact ***,the filling loess exhibits a stronger creep capability compared to underlying intact *** deformation along the profile is unevenly distributed,with a positive correlation with soil *** accumulation has been observed at the interface between the filling loess and the underlying intact loess,leading to a significant ***,the temperature and moisture in the filling loess have reached a new equilibrium state,with their depths influenced by atmospheric conditions measuring at 31 m and 26 m,*** refined investigation allows us to identify critical layers that matter the sustainable development of newly created urban areas,and provide improved insights into the evolution mechanisms of land creation.

关键词： Mountain excavation and city construction Fiber-optic monitoring Multi-physical characterization Compacted loess

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Moyamoya syndrome may result from psoriasis: Four case reports

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World Journal of Clinical Cases 2024年第10期12卷 1830-1836页

作者： Zhi-Ying Chen Xiao-Qin Yu Yuan-Yuan Xiang Ling-Hua liu Xiao-Ping Yin Department of Neurology The Affiliated Hospital of Jiujiang UniversityJiujiang 332000Jiangxi ProvinceChina Department of Dermatology The Affiliated Hospital of Jiujiang UniversityJiujiang 332000Jiangxi ProvinceChina

BACKGROUND Moyamoya syndrome(MMS)is a group of diseases that involves more than one underlying disease and is accompanied by moyamoya vascular *** is a chronic immune skin disease closely linked to high blood pressure and heart ***,psoriasis-related MMS has not been *** SUMMARY We collected data on patients with stroke due to MMS between January 2017 and December 2019 and identified four cases of *** histories,imaging,and hematological data were *** average age of the initial stroke onset was 58.25±11.52 years;three cases of hemorrhagic and one case of ischemic stroke were *** average duration from psoriasis confirmation to the initial MMS-mediated stroke onset was 17±3.56 *** MMS-related stenoses involved the bilateral cerebral arteries:Suzuki grade III in one case,grade IV in two cases,and grade V in one *** elevated plasma interleukin-6 levels were observed in four *** patients had abnormally elevated immunoglobulin E levels,and two had *** four patients received medication instead of *** an average follow-up time of 2 years,two causing transient ischemic attacks occurred in two patients,and no hemorrhagic events *** Psoriasis may be a potential risk factor for *** with psoriasis should be screened for MMS when they present with neurological symptoms.

关键词： Moyamoya syndrome Psoriasis Stroke Interleukin-6 Immune Hypertension Case report

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Cross section determination of^(27)Al(n,2n)^(26)Al reaction induced by 14-MeV neutrons uniting with D-T neutron activation and AMS techniques

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Nuclear Science and Techniques 2024年第6期35卷 78-89页

作者： Xian-Lin Yang Chang-Lin Lan Yu-Ting Wei Yi Zhang Gong Jiang Bo Xie Yu liu Hong-Tao Shen Xiao-Jun Sun School of Nuclear Science and Technology Lanzhou UniversityLanzhou 730000China MOE Frontiers Science Center for Rare Isotopes Lanzhou UniversityLanzhou 730000China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China Guangxi Key Laboratory of Nuclear Physics and Nuclear Technology Guangxi Normal UniversityGuilin 541004China

Aluminum is the primary structural material in nuclear engineering,and its cross section induced by 14-MeV neutrons is of great *** address the issue of insufficient accuracy for the^(27)Al(n,2n)^(26)Al reaction cross section,the activation method and accelerator mass spectrometry(AMS)technique were used to determine the^(27)Al(n,2n)^(26)Al cross section,which could be used as a D-T plasma ion temperature monitor in fusion *** the China Academy of Engineering Physics,neutron activation was performed using a K-400 neutron generator produced by the T(d,n)4He ***^(26)Al∕^(27)Al isotope ratios were measured using the newly installed GYIG 1 MV AMS at the Institute of Geochemistry,Chinese Academy of *** neutron flux was monitored by measuring the activity of 92mNb produced by the 93Nb(n,2n)92mNb *** measured results were compared with available data in the experimental nuclear reaction database,and the measured values showed a reasonable degree of consistency with partially available literature *** newly acquired cross-sectional data at 12 neutron energy points through systematic measurements clarified the divergence,which has two different growth trends from the existing experimental *** obtained results are also compared with the corresponding evaluated database,and the newly calculated excitation functions with TALYS−1.95 and EMPIRE−3.2 codes,the agreement with CENDL−3.2,TENDL-2021 and EMPIRE−3.2 results are generally acceptable.A substantial improvement in the knowledge of the^(27)Al(n,2n)^(26)Al reaction excitation function was obtained in the present work,which will lay the foundation for the diagnosis of the fusion ion temperature,testing of the nuclear physics model,evaluation of nuclear data,etc.

关键词： 14-MeV neutron ^(27)Al(n,2n)^(26)Al Cross section AMS

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中国区域人口收缩对经济增长的影响及形成机理

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地理研究 2024年第4期43卷 949-965页

作者：刘振李伟刘盛和中国科学院地理科学与资源研究所中国科学院区域可持续发展分析与模拟重点实验室北京100101 中国科学院大学资源与环境学院北京100049 南京师范大学地理科学学院南京210023 江苏省地理信息资源开发与利用协同创新中心南京210023 可持续发展大数据国际研究中心北京100094

近年来中国区域尺度的人口收缩不断蔓延,然而区域人口收缩对经济发展会产生怎样的影响尚缺乏探讨。利用1990—2020年4个普查时点地级尺度的人口普查数据,分析地级单元常住人口变化,识别人口收缩区,建立人口收缩经济效应测度模型,分析人... 详细信息

近年来中国区域尺度的人口收缩不断蔓延,然而区域人口收缩对经济发展会产生怎样的影响尚缺乏探讨。利用1990—2020年4个普查时点地级尺度的人口普查数据,分析地级单元常住人口变化,识别人口收缩区,建立人口收缩经济效应测度模型,分析人口收缩对经济增长的影响及其空间分异特征,并探讨人口收缩经济效应的形成机理。研究发现:(1) 1990—2020年,人口收缩区呈快速扩张趋势,2020年人口收缩的地级单元占比已超过40%。(2)研究时期内,人口收缩并未对区域经济增长产生负向影响,反而能够促进区域人均产出水平的提高。(3)人口收缩对区域经济增长的影响存在一定的空间分异,东部和中西部地区人口收缩能够促进经济增长,但东北地区不显著。(4)在解释机理上,这主要与现阶段绝大多数人口收缩区以农村人口外流引起的收缩为主,而城镇人口仍保持增长这一特征密切相关;东北地区城镇人口收缩持续蔓延,是东北地区与其它地区人口收缩经济效应存在差异的重要原因。建议避免单纯从负面角度看待区域常住人口收缩现象,但必须重视城镇人口收缩区域的经济可持续发展问题。

关键词：人口收缩人口迁移经济效应城镇化中国

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Boron-doped high-entropy oxide toward high-rate and long-cycle layered cathodes for wide-temperature sodium-ion batteries

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Journal of Energy Chemistry 2024年第8期95卷 577-587,I0012页

作者： Yuzhen Dang Zhe Xu Yurong Wu Runguo Zheng Zhiyuan Wang Xiaopin Lin Yanguo liu Zheng-Yao Li Kai Sun Dongfeng Chen Dan Wang School of Materials Science and Engineering Northeastern UniversityShenyang 110819LiaoningChina School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004HebeiChina Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004HebeiChina Neutron Scattering Laboratory Department of Nuclear PhysicsChina Institute of Atomic EnergyBeijing 102413China

03-type layered metal oxides hold great promise for sodium-ion batteries cathodes owing to their energy density ***,the severe irreversible phase transition and sluggish Na^(+)diffusion kinetics pose significant challenges to achieve high-performance layered ***,a boron-doped03-type high entropy oxide Na(Fe_(0.2)Co_(0.15)Cu_(0.05)Ni_(0.2)Mn_(0.2)Ti_(0.2))B_(0.02)O_(2)(NFCCNMT-B_(0.02))is designed and the covalent B-O bonds with high entropy configuration ensure a robust layered *** obtained cathode NFCCNMT-B_(0.02)exhibits impressive cycling performance(capacity retention of 95%and 82%after100 cycles and 300 cycles at 1 and 10 C,respectively)and outstanding rate capability(capacity of 83 mAh g^(-1)at 10 C).Furthermore,the NFCCNMT-B_(0.02)demonstrates a superior wide-temperature performance,maintaining the same capacity level(113,4 mAh g^(-1)@-20℃,121 mAh g^(-1)@25℃,and 119 mAh g^(-1)@60℃)and superior cycle stability(90%capacity retention after 100 cycles at 1 C at-20℃).The high-entropy configuration design with boron doping strategy contributes to the excellent sodium-ion storage *** high-entropy configuration design effectively suppresses irreversible phase transitions accompanied by small volume changes(ΔV=0.65 A3).B ions doping expands the Na layer distance and enlarges the P3 phase region,thereby enhancing Na^(+)diffusion *** work offers valuable insights into design of high-performance layered cathodes for sodium-ion batteries operating across a wide temperature.

关键词： High entropy oxide Born substitution Phase transition Na~+diffusion kinetics Sodium-ion batteries

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Solid-state non-volatile memories based on vdW heterostructure-based vertical-transport ferroelectric field-effect transistors

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Science China(Information Sciences) 2024年第6期67卷 198-206页

作者： Qiyu YANG Zheng-Dong LUO Fei XIAO Junpeng ZHANG Dawei ZHANG Dongxin TAN Xuetao GAN Yan liu Zhufei CHU Yinshui XIA Genquan HAN Hangzhou Institute of Technology Xidian University State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology School of MicroelectronicsXidian University School of Artificial Intelligence Xidian University School of Materials Science and Engineering University of New South Wales (UNSW) Sydney ARC Centre of Excellence in Future Low-Energy Electronics Technologies (FLEET) University of New South Wales (UNSW) Sydney Key Laboratory of Light Field Manipulation and Information Acquisition Ministry of Industry and Information Technologyand Shaanxi Key Laboratory of Optical Information TechnologySchool of Physical Science and TechnologyNorthwestern Polytechnical University Faculty of Electrical Engineering and Computer Science Ningbo University

Driven by the explosive development of data-centric computation applications, it is becoming urgent to develop in-memory computing devices that are beyond the von Neumann architecture with an arrangement of separated logic and memory components. The transistor-type solid-state non-volatile memories,such as ferroelectric field-effect transistors(Fe FETs), have long been regarded as a competitive candidate for future in-memory computing architectures. However, the density scaling towards high-density arrays would require advanced Fe FETs with reduced footprints, which remains a great challenge so far. Here, a vertical-transport(VT) Fe FET that flips the charge transport channel perpendicular to the substrate plane is proposed, in which a ferroelectric gate and a van der Waals(vd W) heterojunction channel are vertically integrated, effectively reducing the device footprints. The proposed VT-Fe FET shows not only the robust binary non-volatile memory states but also several key synaptic functionalities at the device level. An artificial neural network with supervised learning was simulated based on the device conductance switching properties,showing excellent classification accuracy for the MNIST handwritten digits. These findings suggest that the proposed VT-Fe FET could offer a new solution for future non-volatile memories as well as more advanced neuromorphic systems.

关键词： vdW heterostructure non-volatile memory vertical-transport transistor ferroelectric field-effect transistor memristive devices

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Reflection on methodology of the correlation between electromagnetic interference and safety in high-speed railway

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Railway Sciences 2024年第1期3卷 84-96页

作者： Chang liu Shiwu Yang Yixuan Yang Hefei Cao Shanghe liu Department of Electromagnetic Environmental Effects Technology Studio CRSC Research and Design Institute Group Co.Ltd.BeijingChina School of Traffic and Transportation Shijiazhuang Tiedao UniversityShijiazhuangChina School of Automation and Intelligence Beijing Jiaotong UniversityBeijingChina Infrastructure Technology Research Institute CRSC Research and Design Institute Group Co.Ltd.BeijingChina Research Center for Electromagnetic Environmental Effects Shijiazhuang Tiedao UniversityShijiazhuangChina

Purpose – In the continuous development of high-speed railways, ensuring the safety of the operation controlsystem is crucial. Electromagnetic interference (EMI) faults in signaling equipment may cause transportationinterruptions, delays and even threaten the safety of train operations. Exploring the impact of disturbances onsignaling equipment and establishing evaluation methods for the correlation between EMI and safety isurgently ***/methodology/approach – This paper elaborates on the necessity and significance of studying theimpact of EMI as an unavoidable and widespread risk factor in the external environment of high-speed railwayoperations and continuous development. The current status of research methods and achievements from theperspectives of standard systems, reliability analysis and safety assessment are examined layer by ***, it provides prospects for innovative ideas for exploring the quantitative correlation between EMIand signaling *** – Despite certain innovative achievements in both domestic and international standard systems andrelated research for ensuring and evaluating railway signaling safety, there’s a lack of quantitative and strategic research on the degradation of safety performance in signaling equipment due to EMI. A quantitativecorrelation between EMI and safety has yet to be established. On this basis, this paper proposes considerationsfor research methods pertaining to the correlation between EMI and ***/value – This paper overviews a series of methods and outcomes derived from domestic andinternational studies regarding railway signaling safety, encompassing standard systems, reliability analysisand safety assessment. Recognizing the necessity for quantitatively describing and predicting the impact ofEMI on high-speed railway signaling safety, an innovative approach using risk assessment techniques as abridge to establish the correlation between EMI and signaling safety is proposed.

关键词： Electromagnetic interference Reliability Safety Risk assessment Signaling system High-speed railway

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心脏移植患者术前肺动脉高压对术后早期并发症及存活的影响

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中华实验外科杂志 2015年第9期32卷 2276-2278页

作者：方泽民陈军胡敏刘立刚郑萍魏翔华中科技大学同济医学院附属同济医院心胸外科心肺移植中心武汉430030

目的观察心脏移植患者术前肺动脉高压对术后早期并发症及存活的影响.方法分析76例心脏移植患者住院资料.根据术前肺动脉收缩压（sPAP）是否≥45 mmHg（1 mmHg=0 133 kPa）分为肺动脉高压组（n=22）和对照组（n=54）.分析比较两组受者... 详细信息

目的观察心脏移植患者术前肺动脉高压对术后早期并发症及存活的影响.方法分析76例心脏移植患者住院资料.根据术前肺动脉收缩压（sPAP）是否≥45 mmHg（1 mmHg=0 133 kPa）分为肺动脉高压组（n=22）和对照组（n=54）.分析比较两组受者术前一般资料、术后并发症发生率及术后早期存活率.结果肺动脉高压组与对照组受者术前sPAP分别为（52.0±4.6） mmHg和（28.0±5.2） mmHg,两组患者术前的吸烟史百分率、原发病中心肌病百分率、氨基末端B型利钠肽前体（NT-proBNP）、中心静脉压（CVP）和移植前心力衰竭时间的差异有统计学意义（P＜0.05）.两组术后机械通气时间、右心衰竭发生率、二次插管/气管切开率、需持续肾脏替代治疗（CRRT）或体外膜肺氧合（ECMO）支持治疗应用率以及ICU住院时间的差异也有统计学意义（P＜0.05）.两组术后早期存活率分别为95.5％和96.3％,差异无统计学意义（P＞0.05）.结论术前肺动脉高压的心脏移植患者术后并发症发生率高于对照组,经有效降低肺动脉高压治疗后术后早期存活率未受影响.

关键词：肺动脉高压心脏移植并发症存活率

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