检索结果-南通市图书馆

A novel fused bi-macrocyclic host for sensitive detection of Cr_(2)O_(7)^(2-)based on enrichment effect

Chinese Chemical Letters 2024年第7期35卷 291-295页

作者： ting-ting Huang Jin-Fa Chen Juan liu Tai-bao Wei Hong Yao Bingbing Shi Qi Lin Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education Key Laboratory of Eco-environmental Polymer Materials of Gansu ProvinceCollege of Chemistry and Chemical EngineeringNorthwest Normal UniversityLanzhou 730070China Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission Gansu Provincial Biomass Function Composites Engineering Research CenterCollege of Chemical EngineeringNorthwest Minzu University(Northwest University for Nationalities)Lanzhou 730000China

Improving the highly selective and sensitive binding of chemosensor to target guest is always very *** order to solve this issue,herein,the enrichment effect was introduced into the design of chemosensor molecule.A novel bi-fused-macrocyclic host molecule BPN1 was synthesized by bridging a pillar[5]arene and a naphthalene diimide(NDI)group through hydrogen-bond-rich *** the BPN1,the naphthalimide side ring is outside the cavity of the pillar[5]*** addition,Cr(VI)greatly threat human health and the environment due to its severe toxicity,and it is very important to develop effective chemosensor for sensitive and selective detection of Cr_(2)O_(7)^(2-)or its ion *** this paper,the novel bi-fused-macrocyclic host molecule BPN1 can recognize Cr_(2)O_(7)^(2-)with high selectivity and *** mechanism of BPN1 recognition of Cr_(2)O_(7)^(2-)was studied through experiments and density functional theory(DFT),the results show that BPN1 could supply enrichment effect to bind Cr_(2)O_(7)^(2-)through multiple weak interactions such as hydrogen bonds and anion-π,and achieve highly sensitive and selective detection of Cr_(2)O_(7)^(2-).It is a significant and feasible strategy for improve high selectivity and sensitivity of host to specific objects by using the enrichment effect of fused bi-macrocyclic.

关键词： Pillararene Bi-macrocyclic Detection of Cr_(2)O_(7)^(2−) DFT The enrichment effect

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Predictability of the upper ocean heat content in a Community Earth System Model ensemble prediction system

引用

Acta Oceanologica Sinica 2024年第1期43卷 1-10页

作者： ting liu Wenxiu Zhong State Key Laboratory of Satellite Ocean Environment Dynamics Second Institute of OceanographyMinistry of Natural ResourcesHangzhou 310012China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519082China School of Atmospheric Sciences Sun Yat-Sen UniversityZhuhai 519082China

Upper ocean heat content(OHC)has been widely recognized as a crucial precursor to high-impact climate variability,especially for that being indispensable to the long-term memory of the *** the predictability of OHC using state-of-the-art climate models is invaluable for improving and advancing climate *** developed retrospective forecast experiments,based on a Community Earth System Model ensemble prediction system,offer a great opportunity to comprehensively explore OHC *** results indicate that the skill of actual OHC predictions varies across different oceans and diminishes as the lead time of prediction *** spatial distribution of the actual prediction skill closely resembles the corresponding persistence skill,indicating that the persistence of OHC serves as the primary predictive signal for its *** decline in actual prediction skill is more pronounced in the Indian and Atlantic oceans than in the Pacific Ocean,particularly within tropical ***,notable seasonal variations in the actual prediction skills across different oceans align well with the phase-locking features of OHC *** potential predictability of OHC generally surpasses the actual prediction skill at all lead times,highlighting significant room for improvement in current OHC predictions,especially for the North Indian Ocean and the Atlantic *** such improvements necessitates a collaborative effort to enhance the quality of ocean observations,develop effective data assimilation methods,and reduce model bias.

关键词： ocean heat content prediction skill retrospective forecast experiment

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

大型干式安全壳消氢系统的初步设计

引用

核动力工程 2008年第1期29卷 30-34页

作者：林继铭刘宝亭中广核工程设计有限公司广东深圳518124

以岭澳核电站为分析对象,利用MELCOR和TONUS(CEA)程序进行分析计算,给出了初步的消氢系统设计方案,对不同核电站的消氢系统设计方案进行了对比和讨论。结果表明:安全壳内安装33个FR750型或者17个左右的FR1500型氢气复合器可以满足氢气... 详细信息

以岭澳核电站为分析对象,利用MELCOR和TONUS(CEA)程序进行分析计算,给出了初步的消氢系统设计方案,对不同核电站的消氢系统设计方案进行了对比和讨论。结果表明:安全壳内安装33个FR750型或者17个左右的FR1500型氢气复合器可以满足氢气控制要求。

关键词：大型干式安全壳非能动催化氢气复合器严重事故自燃反应

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

外延铁酸铋薄膜铁电性和反转特性的研究

引用

人工晶体学报 2015年第4期44卷 1009-1014页

作者：彭增伟刘保亭华北电力大学科技学院保定071051 河北大学物理科学与技术学院保定071002

采用磁控溅射的方法在以SrRuO3(SRO)为底电极的(001)取向的SrTiO3基片上制备了外延BiFeO3(BFO)薄膜,并以氧化铟锡(ITO)和金属Pt为上电极构架了ITO/BFO/SRO和Pt/BFO/SRO两种薄膜电容器,研究上电极对外延BFO薄膜铁电性和反转特性的影响。... 详细信息

采用磁控溅射的方法在以SrRuO3(SRO)为底电极的(001)取向的SrTiO3基片上制备了外延BiFeO3(BFO)薄膜,并以氧化铟锡(ITO)和金属Pt为上电极构架了ITO/BFO/SRO和Pt/BFO/SRO两种薄膜电容器,研究上电极对外延BFO薄膜铁电性和反转特性的影响。结果表明,两种薄膜电容器均体现了良好的饱和电滞回线,当测试电场为333kV/cm时,ITO/BFO/SRO和Pt/BFO/SRO两种电容器的剩余极化强度分别为47.6μC/cm2和56μC/cm2,矫顽场分别为223kV/cm和200kV/cm。此外,两种薄膜电容器都具有良好的保持和抗疲劳特性。通过反转和非反转电流对时间的积分,可以计算出真实的极化强度。当反转电压幅值为17V时,ITO/BFO/SRO和Pt/BFO/SRO两种电容器电流的反转时间分别为0.48μs和0.32μs,真实极化强度的计算值约为41μC/cm2和47μC/cm2,此计算值和铁电净极化强度的测量值符合的很好。

关键词：外延铁酸铋薄膜上电极铁电性反转特性

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Novel Sum-of-Sinusoids Simulation Channel Modeling for 6G Multiple-Input Multiple-Output Vehicle-to-Everything Communications

引用

China Communications 2024年第1期21卷 242-259页

作者： Hao Jiang Hongming Zhang ting liu College of Artificial Intelligence Nanjing University of Information Science and Technology210044China National Mobile Communications Research Laboratory Southeast UniversityNanjing 210096China School of Information and Communication Engineering Beijing University of Posts and TelecommunicationsChina

In this paper,a statistical cluster-based simulation channel model with a finite number of sinusoids is proposed for depicting the multiple-input multiple-output(MIMO)communications in vehicleto-everything(V2X)*** the proposed sum-of-sinusoids(SoS)channel model,the waves that emerge from the transmitter undergo line-of-sight(LoS)and non-line-of-sight(NLoS)propagation to the receiver,which makes the model suitable for describing numerous V2X wireless communication scenarios for sixth-generation(6G).We derive expressions for the real and imaginary parts of the complex channel impulse response(CIR),which characterize the physical propagation characteristics of V2X wireless *** statistical properties of the real and imaginary parts of the complex CIRs,i.e.,autocorrelation functions(ACFs),Doppler power spectral densities(PSDs),cross-correlation functions(CCFs),and variances of ACFs and CCFs,are derived and *** results are generated and match those predicted by the underlying theory,demonstrating the accuracy of our derivation and *** proposed framework and underlying theory arise as an efficient tool to investigate the statistical properties of 6G MIMO V2X communication systems.

关键词： complex CIRs LoS and NLoS propagation components MIMO V2X communication environments SoS simulation channel model statistical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

严重事故下喷淋模式的研究

引用

核动力工程 2005年第2期26卷 114-120页

作者：林继铭贾宝山刘宝亭广东核电集团技术中心广东深圳518124 清华大学工程物理系北京100084

核电厂发生严重事故后,安全壳内有可能堆积大量的氢气,如果此时不适宜地投入喷淋,会破坏安全壳内的惰性环境而引起氢气燃烧或者爆炸,甚至导致安全壳失效。为避免氢燃,本文通过合理的假设,根据相关的实验公式推导出不同氢气产量下安全壳... 详细信息

核电厂发生严重事故后,安全壳内有可能堆积大量的氢气,如果此时不适宜地投入喷淋,会破坏安全壳内的惰性环境而引起氢气燃烧或者爆炸,甚至导致安全壳失效。为避免氢燃,本文通过合理的假设,根据相关的实验公式推导出不同氢气产量下安全壳内压力所需满足的条件,获得了根据安全壳内压力值来指导喷淋开闭的保守的控制模式。本文以大亚湾核电站为分析对象,利用MELCOR来进行分析,验证了此控制模式的可行性,并讨论了堆腔注水、氢气自燃以及安全壳底板成分对制订喷淋模式的影响。

关键词：严重事故喷淋模式堆腔注水氢气自燃底板成分

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Fast and Adaptive Multi-Agent Planning under Collaborative Temporal Logic Tasks via Poset Products

引用

Research 2024年第2期2024卷 81-94页

作者： Zesen liu Meng Guo Weimin bao Zhongkui Li Deparment of Mechanics and Engineering Science College of EngineeringPeking UniversityBejing 0081 China Science and Technology Commission of China Aerospace Science and Technology Corporation Beijing 100048China

Efficient coordination and planning is essential for large-scale multi-agent systems that collaborate in a shared dynamic environment. Heuristic search methods or learning-based approaches often lack the guarantee on correctness and performance. Moreover, when the collaborative tasks contain both spatial and temporal requirements, e.g., as linear temporal logic (LTL) formulas, formal methods provide a verifiable framework for task planning. However, since the planning complexity grows exponentially with the number of agents and the length of the task formula, existing studies are mostly limited to small artificial cases. To address this issue, a new planning paradigm is proposed in this work for system-wide temporal task formulas that are released online and continually. It avoids two common bottlenecks in the traditional methods, i.e., (a) the direct translation of the complete task formula to the associated B點hi automaton and (b) the synchronized product between the B點hi automaton and the transition models of all agents. Instead, an adaptive planning algorithm is proposed, which computes the product of relaxed partially ordered sets (R-posets) on-the-fly and assigns these subtasks to the agents subject to the ordering constraints. It is shown that the first valid plan can be derived with a polynomial time and memory complexity with respect to the system size and the formula length. Our method can take into account task formulas with a length of more than 400 and a fleet with more than 400 agents, while most existing methods fail at the formula length of 25 within a reasonable duration. The proposed method is validated on large fleets of service robots in both simulation and hardware experiments.

关键词： hardware service system

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Asymmetric Partial Hydrosilylation of 2,2-Difluoro-1,3-diketones with Chiral Frustrated Lewis Pairs

引用

Chinese Journal of Chemistry 2024年第8期42卷 853-857页

作者： ting liu Xiangqing Feng Haifeng Du Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and FunctionInstitute of ChemistryChinese Academy of SciencesBeijing100190 China University of Chinese Academy of Sciences Beijing100049 China

Comprehensive Summary,The asymmetric partial reduction of 1,3-diketones stands as a straightforward pathway to access optically active β-hydroxyketones. In this paper, an asymmetric Piers-type hydrosilylation of 2,2-difluoro-1,3-diketones was successfully realized by using a frustrated Lewis pair of chiral borane and tricyclohexylphosphine as a catalyst, delivering a variety of α,α-difluoro-β-hydroxyketones in high yields with up to 99% ee. Significantly, no over-reduced diol products were observed even with an excess amount of silanes. The product can be conveniently converted to α,α-difluoro-β-hydroxyester or 1,3-anti-diol via an oxidation with m-CPBA or a reduction with DIBAL-H without obvious loss of ee.

关键词： Asymmetric catalysis Hydrosilylation Ketones Frustrated Lewis pairs Chiral boranes

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Improvement of Microstructure and Mechanical Properties of Rapid Cooling Friction Stir-welded A1050 Pure Aluminum

引用

Journal of Wuhan University of Technology(Materials Science) 2024年第1期39卷 134-141页

作者：许楠 liu Lutao SONG Qining ZHAO Jianhua bao Yefeng College of Materials Science and Engineering Hohai UniversityChangzhou 213200China

Two-mm thick A1050 pure aluminum plates were successfully joined by conventional and rapid cooling friction stir welding(FSW), respectively. The microstructure and mechanical properties of the welded joints were investigated by electron backscatter diffraction characterization, Vickers hardness measurements, and tensile testing. The results showed that liquid CO_(2) coolant significantly reduced the peak temperature and increased the cooling rate, so the rapidly cooled FSW joint exhibited fine grains with a large number of dislocations. The grain refinement mechanism of the FSW A1050 pure aluminum joint was primarily attributed to the combined effects of continuous dynamic recrystallization, grain subdivision, and geometric dynamic recrystallization. Compared with conventional FSW, the yield strength, ultimate tensile strength, and fracture elongation of rapidly cooled FSW joint were significantly enhanced, and the welding efficiency was increased from 80% to 93%. The enhanced mechanical properties and improved synergy of strength and ductility were obtained due to the increased dislocation density and remarkable grain refinement. The wear of the tool can produce several WC particles retained in the joint, and the contribution of second phase strengthening to the enhanced strength should not be ignored.

关键词： aluminum alloy friction stir welding recrystallization microstructure mechanical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Rapid prediction of damaged ship roll motion responses in beam waves based on stacking algorithm

引用

Journal of Hydrodynamics 2024年第2期36卷 394-405页

作者： Xin-ran liu ting-qiu Li Zi-ping Wang School of Naval Architecture Ocean and Energy Power EngineeringWuhan University of TechnologyWuhan430063China

Accurate modeling for highly non-linear coupling of a damaged ship with liquid sloshing in waves is still of considerable interest within the computational fluid dynamics(CFD)and AI *** paper describes a data-driven Stacking algorithm for fast prediction of roll motion response amplitudes in beam waves by constructing a hydrodynamics model of a damaged ship based on the dynamic overlapping grid CFD *** general idea is to optimize various parameters varying with four types of classical base models like multi-layer perception,support vector regression,random forest,and hist gradient boosting *** offers several attractive properties in terms of accuracy and efficiency by choosing the standard DTMB 5415 model with double damaged compartments for *** is clearly demonstrated that the predicted response amplitude operator(RAO)in the regular beam waves agrees well with the experimental data available,which verifies the accuracy of the established damaged ship hydrodynamics *** high-quality CFD samples,therefore,implementation of the designed Stacking algorithm with its optimal combination can predict the damaged ship roll motion amplitudes effectively and accurately(e.g.,the coefficient of determination 0.9926,the average absolute error 0.0955 and CPU 3s),by comparison of four types of typical base models and their various ***,the established Stacking algorithm provides one potential that can break through problems involving the time-consuming and low efficiency for large-scale lengthy CFD simulations.

关键词： Ship motion damaged ship computational fluid dynamics(CFD) machine learning stacking algorithm

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：