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Journal of Iron and Steel Research International 2024年第7期31卷 1746-1762页

作者： Wei liu Hong-li zhao bing-xing Wang Yong Tian State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819LiaoningChina

The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control *** investigation was conducted to explore the effect of Ni/Mo microalloying on microstructure evolution and mechanical properties of the *** results revealed that the increase in Ni content from 1 to 2 wt.%reduced the transition temperature of ferrite and the growth range of ferritic grain was narrowed,which promoted grain *** optimized combination of grain size,high-angle grain boundaries(HAGBs),and martensite-austenite(M-A)islands parameter contributed to the excellent impact toughness of S1 steel at-100℃(impact absorbed energy of 218.2 J at-100℃).As the Mo increases from 0 to 2 wt.%,the matrix structure changes from multiphase structure to granular bainite,which increases the average effective grain size to~4.62 pm and reduces HAGBs proportion to~36.22%.With these changes,the low-temperature impact toughness of S3 steel is *** addition,based on the analysis of the characteristics of crack propagation path,it was found that M-A islands with low content(~2.21%)and small size(~1.76 pm)significantly retarded crack propagation,and the fracture model of M-A islands with different morphologies was further ***,correlation between behaviour of delamination and toughness was further analysed by observing delamination size and impact energy parameters.

关键词： High-strength low-alloy steel Microstructural regulation Ni addition Mo addition Crack propagation Low-temperature toughness

Cobalt-catalyzed deoxygenative borylation of diaryl ketones

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Chinese Chemical Letters 2024年第3期35卷 277-281页

作者： Longqing liu bing Zhang Yu liu Jinbo zhao Tao Li Wanxiang zhao College of Chemistry and Life Science Changchun University of TechnologyChangchun 130012China State Key Laboratory of Chemo/Biosensing and Chemometrics College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China

Geminal diboronates and diarylmethyl boronates are versatile building blocks in synthetic *** here reported a highly efficient approach for the synthesis of gem-bisborylalkanes and diarylmethyl boronates via cobalt-catalyzed deoxygenative borylation of diaryl *** borylation protocol is compatible with a broad range of functionalized aryl groups,providing access to a wide array of boronic *** resulting boronic esters can be further transformed to various cross-coupling products and TPEs that represent important structural motifs in organic chemistry and materials science.

关键词： Bisborylalkanes Cobalt Deoxygenative borylation Ketones

Synthesis and characterization of BiFeO_3 nanotube arrays and Y-junction BiFeO_3 nanotubes

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Chinese Science Bulletin 2009年第5期54卷 719-722页

作者： LI ChunYang liu bing zhao JianPo WANG JiangFeng HU BinBin DU ZuLiang Key Laboratory for Special Functional Materials Henan University Kaifeng 475004 China

Multiferroic BiFeO3 (BFO) nanotube arrays (～100 nm in diameter and ～50 μm in length) were synthesized by the sol-gel method utilizing the anodic aluminum oxide (AAO) membrane technique. The micro-structure and chemical components of the BFO nanotubes were investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectrometer (XPS). The BFO nanotubes exhibited polycrystalline microstructures. The novel Y-junction BFO nano-tubes were simultaneously fabricated.

关键词：氧化铝模板技术铁酸铋纳米管阵列溶胶-凝胶法

Modeling urban scale human mobility through big data analysis and machinelearning

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Building Simulation 2024年第1期17卷 3-21页

作者： Yapan liu bing Dong Department of Mechanical&Aerospace Engineering Syracuse University263 Link HallSyracuseNY 13244USA

In the United States,the buildings sector consumes about 76%of electricity use and 40% of all primary energy use and associated greenhouse gas *** behavior has drawn increasing research interests due to its impacts on the building energy ***,occupant behavior study at urban scale remains a challenge,and very limited studies have been *** an effort to couple big data analysis with human mobility modeling,this study has explored urban scale human mobility utilizing three months Global Positioning System(GPS)data of 93,o00 users at Phoenix Metropolitan *** research extracted stay points from raw data,and identified users'home,work,and other locations by Density-Based Spatial Clustering ***,daily mobility patterns were constructed using different types of *** propose a novel approach to predict urban scale daily human mobility patterns with 12-hour prediction horizon,using Long Short-Term Memory(LSTM)neural network *** shows the developed models achieved around 85%average accuracy and about 86%mean *** developed models can be further applied to analyze urban scale occupant behavior,building energy demand and flexibility,and contributed to urban planning.

关键词： urban human mobility big data analysis urban scale occupant behavior recurrent neural networks

Insight into the selective separation of CO_(2)from biomass pyrolysis gas over metal-incorporated nitrogen-doped carbon materials:a first-principles study

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Frontiers of Chemical Science and Engineering 2024年第3期18卷 1-12页

作者： Li zhao Xinru liu Zihao Ye Bin Hu Haoyu Wang Ji liu bing Zhang Qiang Lu National Engineering Research Center of New Energy Power Generation North China Electric Power UniversityBeijing102206China

The composition of biomass pyrolysis gas is complex,and the selective separation of its components is crucial for its further ***-incorporated nitrogen-doped materials exhibit enormous potential,whereas the relevant adsorption mechanism is still ***,16 metal-incorporated nitrogen-doped carbon materials were designed based on the density functional theory calculation,and the adsorption mechanism of pyrolysis gas components H2,CO,CO_(2),CH_(4),and C2H6 was *** results indicate that metal-incorporated nitrogen-doped carbon materials generally have better adsorption effects on CO and CO_(2)than on H_(2),CH_(4),and C_(2)H_(6).Transition metal Mo-and alkaline earth metal Mg-and Ca-incorporated nitrogen-doped carbon materials show the potential to separate CO and CO_(2).The mixed adsorption results of CO_(2)and CO further indicate that when the CO_(2)ratio is significantly higher than that of CO,the saturated adsorption of CO_(2)will precede that of ***,the three metal-incorporated nitrogen-doped carbon materials can selectively separate CO_(2),and the alkaline earth metal Mg-incorporated nitrogen-doped carbon material has the best *** study provides theoretical guidance for the design of carbon capture materials and lays the foundation for the efficient utilization of biomass pyrolysis gas.

关键词： CO_(2)capture biomass pyrolysis gas selective adsorption carbon materials first-principles

Concept, configuration, and application of on-board nanogrids for use in electric vehicles

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Science China(Technological Sciences) 2024年第7期67卷 2053-2073页

作者： zhao bing LI Yong WU Fang WAN JiangHu CAI JiuQing YANG HaiTao liu Fang College of Electrical and Information Engineering Hunan UniversityChangsha 410082China Wuhan Second Ship Design and Research Institute Wuhan 430000China School of Automation Central South UniversityChangsha 410083China

Against the backdrop of increasingly serious climate change, researchers are attempting to extend macroscale carbon reduction research to smaller scales. With the rapid development and widespread application of electric vehicles(EVs), an effective approach for carbon reduction based on EVs has the potential to be developed. To coordinate and manage the EV platform in diverse application scenarios, the concept of an on-board nanogrid(OBNG), in which a nanogrid is combined with the EV, is proposed and defined, and the characteristics summarized. A configuration that includes a physical layer with the on-board hardware system;an information layer for logical control, energy management, and communication coordination;and an application layer that can cope with different working environments is proposed. A detailed introduction to the basic architecture and management mode of each layer is provided along with information concerning the relevant technologies for coordinated operation. New ideas and approaches to improve the existing performance are proposed, and finally, combined with a background of smart and low-carbon cities, major application scenarios are envisioned.

关键词： electric vehicle nanogrid energy management hybrid energy storage power electronics converter

Experimental investigation for temperature and emissivity by flame emission spectrum in a cavity of rocket based combined cycle combustor chamber

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Defence Technology（防务技术） 2024年第9期39卷 114-122页

作者： Weiguang Cai Shu Zheng Yan Wang bing liu Shaohua Zhu Li zhao Qiang Lu National Engineering Research Center of New Energy Power Generation North China Electric Power UniversityBeijing 102206China Science and Technology on Combustion Internal Flow and Thermal-structure LaboratoryNorthwestern Polytechnical UniversityXi'an 710072China

Flame temperature and spectral emissivity were the important parameters characterizing the sufficient degree of fuel combustion and the particle radiative characteristics in the Rocket Based Combined Cycle(RBCC)*** investigate the combustion characteristics of the complex supersonic flame in the RBCC combustor,a new radiation thermometry combined with Levenberg-Marquardt(LM)algorithm and the least squares method was proposed to measure the temperature,emissivity and spectral radiative properties based on the flame emission ***-situ measurements of the flame temperature,emissivity and spectral radiative properties were carried out in the RBCC direct-connected test bench with laser-induced plasma combustion enhancement(LIPCE)and without *** flame average temperatures at fuel global equivalence ratio(a)of 1.0b and 0.6 with LIPCE were 4.51%and 2.08%higher than those without *** flame combustion oscillation of kerosene tended to be stable in the recirculation zone of cavity with the thermal and chemical effects of laser induced *** differences of flame temperature at a=1.0b and 0.6 were 503 K and 523 K with LIPCE,which were 20.07%and42.64%lower than those without *** flame emissivity with methane assisted ignition was 80.46%lower than that without methane assisted ignition,due to the carbon-hydrogen ratio of kerosene was higher than that of *** spectral emissivities at 600 nm with LIPCE were 1.25%,22.2%,and 4.22%lower than those without LIPCE at a=1.0a(with methane assisted ignition),1.0b(without methane assisted ignition)and *** effect of concentration in the emissivity was removed by normalization to analyze the flame radiative properties in the RBCC combustor *** maximum differences of flame normalized emissivity were 50.91%without LIPCE and 27.53%with *** flame radiative properties were stabilized under the thermal and chemical effects of laser induced plasma at a=0.6.

关键词： Rocket-based combined-cycle Supersonic combustion Flame temperature measurement Emissivity Laser induced plasma combustion enhancement

Dual‑functional application of Ca_(2)Ta_(2)O_(7):Bi^(3+)/Eu^(3+)phosphors in multicolor tunable optical thermometry and WLED

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Frontiers of Optoelectronics 2024年第3期17卷 133-149页

作者： Jingjing Ru bing zhao Fan Zeng Feiyun Guo Jinhua liu Jianzhong Chen College of New Energy and Materials Fujian Province University Key Laboratory of Green Energy and Environment CatalysisNingde Normal UniversityNingde 352100China College of Mechanical and Electrical Engineering Ningde Normal UniversityNingde 352100China School of Environment and Resources School of Carbon Neutral and Modern IndustryFujian Normal UniversityFuzhou 350007China College of Chemistry Fuzhou UniversityFuzhou 350108China School of Pharmacy and Medical Technology Key Laboratory of Pharmaceutical Analysis and Laboratory Medicine of Fujian ProvincePutian UniversityPutian 351100China

A series of Bi^(3+)/Eu^(3+)co-doped Ca_(2)Ta_(2)O_(7)(CTO:Bi^(3+)/Eu^(3+))phosphors were prepared by high-temperature solid-state method for dual-emission center optical thermometers and white light-emitting diode(WLED)*** modulating the doping ratio of Bi^(3+)/Eu^(3+)and utilizing the energy transfer from Bi^(3+)to Eu^(3+),the tunable color emission ranging from green to reddish-orange was *** designed CTO:0.04Bi^(3+)/Eu^(3+)optical thermometers exhibit signifcant thermochromism,superior stability,and repeatability,with maximum sensitivities of Sa=0.055 K^(−1)(at 510 K)and Sr=1.298%K^(−1)(at 480 K)within the temperature range of 300−510 K,owing to the diferent thermal quenching behaviors between Bi^(3+)and Eu^(3+)*** features indicate the potential application prospects of the prepared samples in visualized thermometer or hightemperature safety ***,leveraging the excellent zero-thermal-quenching performance,outstanding acid/alkali resistance,and color stability of CTO:0.04Bi^(3+)/0.16Eu^(3+)phosphor,a WLED device with a high Ra value of 95.3 has been realized through its combination with commercially available blue and green phosphors,thereby demonstrating the potential application of CTO:0.04Bi^(3+)/0.16Eu^(3+)in near-UV pumped WLED devices.

关键词： WLED devices.Keywords Phosphor Energy transfer Zero-thermal-quenching Optical thermometry WLEDs

Systematic Studies of Nitrogen Loss from Paddy Soils Through Leaching in the Dongting Lake Area of China

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Pedosphere 2011年第6期21卷 753-762页

作者： JI Xiong-Hui ZHENG Sheng-Xian SHI Li-Hong liu zhao-bing Soil and Fertilizer Institute of Hunan Province Changsha 410125 （China） Hunan Agricultural Environment Research Center Changsha 410125 （China）

A two-year lysimeter study was conducted to study the effects of different fertilizers and soils on nitrogen leaching loss in a double rice cropping system by considering three major types of paddy soils from the Dongting Lake area. The results showed that N concentration in the leachate did not differ significantly among the treatments of urea, controlled release N fertilizer and pig manure and that all these fertilizers produced higher total nitrogen （TN） concentrations in the leachate compared to the case where no fertilizer was applied. The TN leaching loss following urea treatment accounted for 2.28%, 0.66%, and 1.50% of the amount of N applied in the alluvial sandy loamy paddy soil （ASL）, purple calcareous clayey paddy soil （PCC）, and reddish-yellow loamy paddy soil （RYL）, respectively. Higher TN loss was found to be correlated with the increased leachate volume in ASL compared with RYL, and the lowest TN loss was observed in the PCC, in which the lowest leachate volume and TN concentration were observed. Organic N and NH＋-N were the major forms of N depleted through leachate, accounting for 56.8% and 39.7% of TN losses, respectively. Accordingly, soil-specific fertilization regimens are recommended; in particular, the maximum amount of fertilizer should be optimized for sandy soils with a high infiltration rate. To avoid a high N leaching loss from rice fields, organic N fertilizers such as urea or coated urea should primarily be used for surface topdressing or shallow-layer application and not for deep-layer application.

关键词： double rice cropping fertilizer application leachate nitrogen concentration

Microstructural characterization and mechanical properties of(TiC+TiB)/TA15 composites prepared by an in-situ synthesis method

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China Foundry 2024年第2期21卷 168-174页

作者： Zhi-yong Zhang Jiao-jiao Cheng Jia-qi Xie Shi-bing liu Kun Shi Jun zhao Shenyang Research Institute of Foundry Co. Ltd.CAMShenyang 110022China National Key Laboratory of Advanced Casting Technologies Shenyang 110022China

Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high *** this study,the TA15-based composites reinforced with a volume fraction of 10% to 25%(TiB+TiC)were prepared using powder metallurgy and casting *** characterization and phase constitution were examined using optical microscopy(OM),scanning electron microscopy(SEM),and X-ray diffraction(XRD).In addition,the microhardness,room temperature(RT)and high temperature(HT)tensile properties of the composites were *** revealed that the reinforcements are distributed uniformly even in the composites with a high volume of TiB and ***,as the volume fraction exceeds 15%,TiB and TiC particles become coarsening and exhibit rod-like and dendritic-like *** increases gradually from 321.2 HV for the base alloy to a maximum of 473.3 HV as the reinforcement increases to 25vol.%.Tensile test results indicate that a reinforcement volume fraction above 20% is beneficial for enhancing tensile strength and yield strength at high temperatures,but it has an adverse effect on room temperature ***,if the reinforcement volume fraction is below 20%,it can improve high-temperature elongation when the temperature exceeds 600℃.

关键词： titanium matrix composites microstucture microhardness tensile properties in-situ synthesis