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低钒和无钒基氧化物类NH_3-SCR催化剂研究进展

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环境工程 2016年第12期34卷 98-102页

作者：庄凤来刘少光林文松陈焱陈成武田军吉上海工程技术大学材料工程学院上海201620 浙江大学材料科学与工程学院杭州310027 上海瀚昱环保材料有限公司上海201611 浙江科得力新材料有限公司浙江温州325029

NH_3-SCR技术是脱硝领域中应用最多和最为成熟的技术。现已工业化应用的V_2O_5-WO_3(MoO_3)-TiO_2催化剂存在低温活性差、操作温度范围窄,活性组分V_2O_5具有生物毒性等缺陷。因此,开发高效、稳定且无毒的新型无钒基NH_3-SCR催化剂成为... 详细信息

NH_3-SCR技术是脱硝领域中应用最多和最为成熟的技术。现已工业化应用的V_2O_5-WO_3(MoO_3)-TiO_2催化剂存在低温活性差、操作温度范围窄,活性组分V_2O_5具有生物毒性等缺陷。因此,开发高效、稳定且无毒的新型无钒基NH_3-SCR催化剂成为脱硝领域的研究热点。以不同活性基的氧化物催化剂为主线,综述了国内外低钒和无钒基氧化物类NH_3-SCR催化剂的研究进展,总结了原料配方和制备工艺对催化剂性能和反应机理的影响,并展望了脱硝领域未来可能的发展方向。

关键词：选择性催化还原低钒基催化剂无钒基催化剂氧化物烟气脱硝

Interannual variability of boreal summer intraseasonal oscillation over the northwestern Pacific influenced by the Pacific Meridional Mode

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 6-11页

作者： Haoyu Zhou Pang-Chi Hsu lin Chen Yitian Qian Key Laboratory of Meteorological Disaster Ministry of Education/Joint International Research Laboratory of Climate and Environmental Change/Collaborative Innovation Center on Forecast and Evaluation of Meteorological DisastersNanjing University of Information Science and TechnologyNanjingChina

During the boreal summer,intraseasonal oscillations exhibit significant interannual variations in intensity over two key regions:the central-western equatorial Pacific(5°S-5°N,150°E-150°W)and the subtropical Northwestern Pacific(10°-20°N,130°E-175°W).The former is well-documented and considered to be influenced by the ENSO,while the latter has received comparatively less attention and is likely influenced by the Pacific Meridional Mode(PMM),as suggested by partial correlation analysis *** elucidate the physical processes responsible for the enhanced(weakened)intraseasonal convection over the subtropical northwestern Pacific during warm(cold)PMM years,the authors employed a moisture budget *** findings reveal that during warm PMM years,there is an increase in summer-mean moisture over the subtropical northwestern *** increase interacts with intensified vertical motion perturbations in the region,leading to greater vertical moisture advection in the lower troposphere and consequently resulting in convective *** a process is pivotal in amplifying intraseasonal convection *** observational findings were further verified by model experiments forced by PMM-like sea surface temperature patterns.

关键词： Boreal summer intraseasonal oscillation Interannual variability Pacific Meridional Mode Moisture budget analysis

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激光熔覆技术的研究进展

热处理技术与装备 2008年第2期29卷 1-3,7页

作者：林文松张光钧王慧萍上海工程技术大学材料工程学院上海201620

综述了激光熔覆技术的原理、工艺特点和熔覆材料的选择,分析了激光熔覆技术的应用范围,对其未来的发展方向作了展望。

关键词：激光熔覆熔覆材料复合涂层纳米表面工程

Dynamical Algebras in the 1+1 Dirac Oscillator and the Jaynes–Cummings Model

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Chinese Physics Letters 2020年第5期37卷 1-4页

作者： wen-Ya song Fu-lin Zhang Department of Physics School of ScienceTianjin UniversityTianjin 300072

We study the algebraic structure of the one-dimensional Dirac oscillator by extending the concept of spin symmetry to a noncommutative *** SO(4)algebra is found connecting the eigenstates of the Dirac oscillator,in wh... 详细信息

关键词： Dirac oscillator Cummings

Studies of Metallic and Trace Minerals of the Tiegelongnan Cu-Au Deposit, Central Tibet, China

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Acta Geologica Sinica(English Edition) 2018年第3期92卷 1123-1138页

作者： HE wen lin Bin YANG Huanhuan song Yingxin China University of Geosicences Beijing 100083 China MLR Key Laboratory of Metallogeny and Mineral Resource Assessment Institute of Mineral ResourcesChinese Academy of Geological Sciences Beijing 100037 China Centre of Excellence in Ore Deposit (CODES) University of Tasmania Hobart 7001 Australia Shandong Geological Sciences Institute Ji 'nan 250013 Shandong China

Electron probe micro-analysis(EPMA) and scanning electron microscopy(SEM) equipped with energy dispersive spectrometry(EDS) have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit, which consists of a high-sulfidation epithermal system(HSES) and a porphyry system(PS). Molybdenite,chalcopyrite, bornite, tennantite, enargite, digenite, anilite, covellite, and tetrahedrite have been identified by EPMA. Intergrowth, cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite ± bornite ± hematite(stage 2),then bornite ± Cu-sulfides ± Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides ±Cu-sulfides(stage 4). Pyrite is developed throughout all the stages. Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite, chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier. The pervasive binary equilibrium phases of calaverite and altaite constrain fin the range from ～-6.5 to ～-8 and f<-*** intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the ***, the dominance of chalcopyrite in the PS, with minor bornite, suggests relatively high temperature conditions. These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems.

关键词： paragenetic sequence Au-Te carriers ore forming conditions EPMA SEM-EDS Tibet China

Boosting bidirectional sulfur conversion enabled by introducing boron-doped atoms and phosphorus vacancies in Ni2P for lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 760-769页

作者： lin Peng Yu Bai Hang Li Meixiu Qu Zhenhua Wang Kening Sun Advanced Research Institute of Multidisciplinary Science Beijing Institute of Technology Beijing Key Laboratory of Chemical Power Source and Green Catalysis School of Chemistry and Chemical Engineering Beijing Institute of Technology

Lithium-sulfur （Li-S） batteries have gained great attention due to the high theoretical energy density and low cost,yet their further commercialization has been obstructed by the notorious shuttle effect and sluggish redox ***,we supply a strategy to optimize the electron structure of Ni2P by concurrently introducing B-doped atoms and P vacancies in Ni2P （Vp-B-Ni2P）,thereby enhancing the bidirectional sulfur *** study indicates that the simultaneous introduction of B-doped atoms and P vacancies in Ni2P causes the redistribution of electron around Ni atoms,bringing about the upward shift of d-band center of Ni atoms and effective d-p orbital hybridization between Ni atoms and sulfur species,thus strengthening the chemical anchoring for lithium polysulfides （LiPSs） as well as expediting the bidirectional conversion kinetics of sulfur ***,theoretical calculations reveal that the incorporation of B-doped atoms and P vacancies in Ni2P selectively promotes Li2S dissolution and nucleation ***,the Li-S batteries with Vp-B-Ni2P-separators present outstanding rate ability of 777 m A h g-1at 5 C and high areal capacity of 8.03 mA h cm-2under E/S of 5μL mg-1and sulfur loading of 7.20 mg *** work elucidates that introducing heteroatom and vacancy in metal phosphide collaboratively regulates the electron structure to accelerate bidirectional sulfur conversion.

关键词： Lithium sulfur batteries

Projective Hilbert modules and sequential approximations

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Science China Mathematics 2025年第1期 137-168页

作者： Lawrence G.Brown Huaxin lin Department of Mathematics Purdue University Department of Mathematics East China Normal University Department of Mathematics University of Oregon Shanghai Institute for Mathematics and Interdisciplinary Sciences

We show that when A is a separable C*-algebra,every countably generated Hilbert A-module is projective（with bounded module maps as morphisms）.We also study the approximate extensions of bounded module *** the case where A is a σ-unital simple C*-algebra with strict comparison,and every strictly positive lower semicontinuous affine function on quasitraces can be realized as the rank of an element in the Cuntz semigroup,we show that the Cuntz semigroup is equivalent to unitarily equivalent classes of countably generated Hilbert A-modules if and only if A has stable rank one.

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Electrocatalytic cleavage of a lignin β-O-4 model compound and coupling with nitrogen-containing aromatics using Prussian blue analogue-derived nickel–cobalt spinel

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Journal of Energy Chemistry 2025年第1期100卷 628-636页

作者： Yi Qi Xueying Chen Bowen Liu Xuliang lin Xueqing Qiu Yanlin Qin Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center Guangdong Basic Research Center of Excellence for Ecological Security and Green Development Guangdong University of Technology

Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great *** demonstrate the targeted synthesis and cation modulation of NiCo2O4spinel nanoboxes,synthesized via cation exchange and calcination *** catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and *** catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as *** porous architecture and polymetallic composition of the NiCo2O4spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for *** innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT *** work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.

关键词： Spinel Biomass valorization Electrocatalysis Lignin oxidation Coupling

Microstructure and mechanical properties of a new high-strength and high-toughness titanium alloy

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Rare Metals 2023年第1期42卷 281-287页

作者： Dong Li song-Xiao Hui wen-Jun Ye Cheng-lin Li State Key Laboratory for Nonferrous Metals and Processes General Research Institute for Nonferrous MetalsBeijing100088China

In order to develop a new titanium alloy with a good combination of strength-ductility-toughness,a nearbeta titanium alloy was designed based on the already widely used Ti-1023 *** avoid beta fleck occurring in the microstructure,the new Ti-Al-Fe-V(Cr,Zr) alloy has been made through decreasing the content of Fe,based on molybdenum equivalency and Bo-Md molecular orbital method(a method for new alloy designing based on the molecular orbital calculating).After primary design computation,Ti-Al-Fe-V(Cr,Zr) alloy was optimized as Ti-3Al-4.5Cr-1Fe-4V-1Zr *** microstructure and tensile properties of this alloy subjected to several commonly used heat treatments were *** results show that the tensile strength of the alloy after solution treated below the β-transus temperature comes between 850 and 1100 MPa,with elongation in the range of 12.5 %-17.0 %.In solution-treated and solution-aged samples,a low-temperature aging at 500 ℃ results in the precipitation of finer α *** the increase in aging temperature,the secondary α phase becomes coarser and decreases in ***,it will lead to the increase in tensile ductility,but reduction in ***,after modulated aging treatment,the alloy can obtain highstrength level with acceptable *** tensile strength of the alloy can achieve 1273 MPa,with an elongation of 11.0 %.At the same time,the fracture toughness(K_(IC)) of the alloy achieves 83.8 MPa·m^(1/2).It is obvious that the newly designed alloy has achieved a good blend of strength-ductility-toughness.

关键词： Beta titanium alloy Microstructure Tensile/toughness property