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Outlier item detection in bundle recommendation via the attention mechanism

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High-Confidence Computing 2024年第3期4卷 51-57页

作者： Yuan liang School of Information Engineering Suqian UniversitySuqian 223800China Guangxi Key Laboratory of Trusted Software Guilin University of Electronic TechnologyGuilin 541004China

Bundle recommendation offers users more holistic insights by recommending multiple compatible items at ***,the intricate correlations between items,varied user preferences,and the pronounced data sparsity in combinations present significant challenges for bundle recommendation ***,current bundle recommendation methods fail to identify mismatched items within a given set,a process termed as‘‘outlier item detection’’.These outlier items are those with the weakest correlations within a *** them can aid users in refining their item *** the correlation among items can predict the detection of such outliers,the adaptability of combinations might not be adequately responsive to shifts in individual items during the learning *** limitation can hinder the algorithm’s *** tackle these challenges,we introduce an encoder–decoder architecture tailored for outlier item *** encoder learns potential item correlations through a self-attention ***,the decoder garners efficient inference frameworks by directly assessing item *** have validated the efficacy and efficiency of our proposed algorithm using real-world datasets.

关键词： Bundle recommendation Outlier item detection Attention mechanism Decoder encoder

Screening of transition metal oxides for electrocatalytic nitrate reduction to ammonia at large currents

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Nano Research 2024年第5期17卷 3902-3910页

作者： Qiongfei Wu Weijie Zhu Dongxu Ma Chao liang Zhoucheng Wang Hanfeng liang State Key Laboratory of Physical Chemistry of Solid Surfaces Tan Kah Kee Innovation LaboratoryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China College of Chemical Engineering Tianjin UniversityTianjin 300072China

Electrochemical nitrate reduction reaction(NO_(3)RR)towards ammonia,as an emerging and appealing technology alternative to the energy-intensive Haber-Bosch process and inefficient nitrogen reduction reaction,has recently aroused wide concern and ***,the current research of the NO_(3)RR towards ammonia lacks the overall performance comparison of various *** this,we here make a comparison of 12 common transition metal oxide catalysts for the NO_(3)RR under a high cathodic current density of 0.25 A·cm^(-2),wherein Co_(3)O_(4) catalyst displays the highest ammonia Faradaic efficiency(85.15%)and moderate activity(ca.-0.25 V *** hydrogen electrode).Other external factors,such as nitrate concentrations in the electrolyte and applied potential ranges,have also been specifically investigated for the NO_(3)RR.

关键词： nitrate reduction reaction ammonia production transition metal oxides Co_(3)O_(4)

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基于FMCW雷达的多目标生命体征信号检测

计量学报 2024年第1期45卷 112-120页

作者：潘良刘康张远辉中国计量大学机电工程学院浙江杭州310018

应用雷达在复杂场景下检测生命体征时,为了解决现有的多人体目标检测和干扰滤除以及心跳信号干扰滤除的问题,提出了一种应用调频连续波(FMCW)雷达检测多目标生命体征信号的方法。首先,介绍了雷达检测原理与信号模型,阐述了整个雷达信号... 详细信息

应用雷达在复杂场景下检测生命体征时,为了解决现有的多人体目标检测和干扰滤除以及心跳信号干扰滤除的问题,提出了一种应用调频连续波(FMCW)雷达检测多目标生命体征信号的方法。首先,介绍了雷达检测原理与信号模型,阐述了整个雷达信号的处理流程,即多目标距离单元检测、相位提取、生命体征信号提取。其中在多目标距离检测过程中,提出1种改进的单元平均恒虚警率(CA-CFAR)算法,该方法具有自适应检测门限特点的同时,解决了传统CA-CFAR算法目标附近距离门重复检测的问题,实现多目标检测;在生命体征信号提取过程中,运用自动多尺度峰值检测(AMPD)算法估计呼吸率与心率,过滤无效的波峰干扰,提高对心跳检测的鲁棒性。最后,通过多组测试,相较于常用的频谱分析估算方法,呼吸速率和心率检测的平均误差率分别降低了3.67%和3.31%,验证了所提方法的可行性和准确性。

关键词：生命体征检测非接触测量调频连续波雷达自动多尺度峰值检测心率呼吸速率

AFM probe for measuring~10^(−5)ultra-low friction coefficient:Design and application

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Friction 2024年第1期12卷 64-73页

作者： Yushan CHEN liang JIANG Linmao QIAN Tribology Research Institute State Key Laboratory of Traction PowerSouthwest Jiaotong UniversityChengdu 610031China

Superlubricity provides a novel approach to addressing friction and wear issues in mechanical ***,little is known regarding improving the atomic force microscope(AFM)friction coefficient measurement ***,this study established the theoretical formula for the AFM friction coefficient measurement and deduced the measurement ***,the formula was applied to the AFM probe with a rectangular cross-section *** measurement resolution is associated with the dimensional properties of the AFM probe,the mechanical properties of the cantilever material,the properties of the position-sensitive detector(PSD),and probably the anti-vibration performance of the *** is feasible to make the cantilever as short as possible and the tip as high as possible to improve the measurement *** AFM probe for measuring an ultra-low friction coefficient was designed and *** cantilever’s length,width,and thickness are 50,35,and 0.6μm,*** tip height is 23μ*** measurement resolution can reach 7.1×10^(−6) under the maximum normal ***,the AFM probe was applied to measure the superlubricity between graphene *** friction coefficient is 0.00139 under 853.08 *** work provides a promising method for measuring a~10^(−5) friction coefficient of superlubricity.

关键词： atomic force microscope(AFM) superlubricity friction coefficientμ probe

Polyelectrolyte Complexes and Coacervates Formed by De novo-Designed Peptides and Oligonucleotide

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Chinese Journal of Polymer Science 2024年第9期42卷 1333-1340,I0007页

作者： Tian-Hao Ren De-Hai liang Beijing National Laboratory for Molecular Sciences Department of Polymer Science and Engineering and the Key Laboratory of Polymer Chemistry and Physics of the Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

The liquid-liquid phase separation of biopolymers in living cells contains multiple interactions and occurs in a dynamic *** the regulation mechanism is still a *** this work,we designed a series of peptides(XXLY)_(6)SSSGSS and studied their complexation and coacervation behavior with single-stranded ***“X”and“Y”are varied to combine known amounts of charged and non-charged amino acids,together with the introduction of secondary structures and pH *** show that the electrostatic interaction,which is described as charge density,controls both the strength of complexation and the degree of chain relaxation,and thus determines the growth and size of the *** hydrophobic interaction is prominent when the charges are ***,the secondary structures of peptides exhibit profound effect on the morphology of the phases,such as solid phase to liquid phase *** study gains insight into the phase separation under physiological *** is also helpful to create coacervates with desirable structures and functions.

关键词： Polyelectrolyte complex Coacervate Peptides Secondary structure Electrostatic interaction

Forming process chain for manufacturing complex conical-section profiled rings:On a co-design method

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Chinese Journal of Aeronautics 2024年第6期37卷 485-503页

作者： Lei liang Chaojiang ZOU lianggang GUO State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Guizhou Aviation Technology Development Co.Ltd Guiyang 550081China

The final quality of complex conical-section rings depends on co-design of multiple processes in forming process *** this study,for a complex aeroengine casing ring with a large slope and a flange on its end,a co-design method of the forming process chain is put forward towards the objective of precision forming,which not only proposes a standard process route composed of multiple processes of upsetting,punching,rectangular ring rolling,loose tooling forging and profiled ring rolling,but also presents co-design methods of dies and blanks for all the *** profiled ring rolling,a design method of preformed blank that makes the blank and the target conical-section ring have the same axial volume distribution is *** the method,the axial metal redistribution during the process can be alleviated greatly thus improving the forming stability and precision of the *** on the geometric features of designed preformed blank,design methods of blanks and dies for loose tolling forging,rectangular ring rolling,punching and upsetting are proposed *** view of the key roles of loose tooling forging(manufacturing the preformed blank)and profiled ring rolling on the final quality of the conical ring parts,inherited FE simulations for these two processes are performed to verify the proposed design methods and determine appropriate design *** is demonstrated that the proposed design method has significant advantages in improving forming ***,a suggestive value 1.5 of the rolling ratio for profiled ring rolling(a key design parameter)is given based on comprehensive consideration of multiple indicators such as ring roundness,deformation uniformity and forming *** corresponding industrial experiments performed illustrate that a high forming precision of the conical-section aeroengine casing ring is achieved.

关键词： Complex conical-section ring Co-design of forming process chain Profiled ringrolling Preformed blank Loose tooling forging

AFM probe with the U-shaped cross-sectional cantilever for measuring the ultra-low coefficient of friction of 10^(–6)

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Friction 2024年第8期12卷 1707-1715,F0004页

作者： Yushan CHEN liang JIANG Linmao QIAN Tribology Research Institute State Key Laboratory of Traction PowerSouthwest Jiaotong UniversityChengdu 610031China

Accurately measuring the coefficient of friction(COF)is the fundamental prerequisite of superlubricity *** study aimed to reduce the COF measurement resolutionΔμof atomic force microscopy(AFM).Based on the theoretical model,a distinctive strategy was adopted to reduceΔμby optimizing the cantilever’s cross-section of the AFM probe,inspired by civil engineering.Δμcan be reduced by decreasing the width of the horizontal side wR and the wall thickness t and increasing the width of the vertical side ***,the I-shape demonstrates the highest reduction inΔμ,followed by the *** the processability,the AFM probe with the U-shaped cross-sectional cantilever was investigated further,and the dimensions are 35μm wR,3.5μm wH,0.5μm t,50μm l(cantilever length),and 23μm htip(tip height).The finite element analysis results confirm its *** being fabricated and calibrated,the AFM probe achieves the minimalΔμof 1.9×10^(–6)under the maximum normal force so ***,the friction detection capability of the fabricated AFM probe improves by 78 times compared to the commercial tipless-force modulation mode(TL-FM)AFM probe with the conventional solid rectangular cross-sectional *** study provides a powerful tool for measuring 10^(–6)COF.

关键词： atomic force microscopy superlubricity coefficient of friction probe cantilever

Research on Credit Default Swaps Pricing Considering Moral Hazard Incentive under Reduce-Form Model

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Journal of Systems Science and Systems Engineering 2024年第3期33卷 311-329页

作者： liang Wu Kangjie He Zhe Guo School of Mathematical Science Henan Institute of Science and TechnologyXinxiang453003China Public Front Office Department Industrial and Commercial Bank of ChinaZhengzhou450000China

Equilibrium pricing of credit default swaps(CDS)promotes efficient identification of credit risk in the market,which in turn leads to efficient allocation of ***,even when CDS have been priced in equilibrium,i.e.,when premiums are equal to anticipated payments,the moral hazard incentives of CDS buyers increase with CDS ***,it becomes an interesting research direction to study the impact of moral hazard incentives on the trading mechanism or pricing of derivatives(CDS).Most of the existing literature on the impact of moral hazard incentives in CDS pricing on derivatives trading mechanisms takes a macro perspective and focuses on the agreement risk *** literature exploring the analysis of the impact of moral hazard on the probability of agreement default from a micro perspective is not yet *** this in mind,this paper focuses on the mechanisms by which“fraud”,an extreme manifestation of micro-moral hazard incentives,affects the probability of *** paper introduces for the first time the concept of“claiming fraud”by credit protection buyers,which is different from the macro perspective of moral hazard incentives,and thus defines a specific extreme form of moral hazard ***,to address the intrinsic feature of the lack of economic explanatory power of the reduce-form model,this paper introduces a moral hazard incentive factor into the reduce-form model,and proposes a moral hazard state variable as a function of the asset value of the reference entity,which gives the reduce-form model strong economic explanatory power,and the default predictability is reduced by the description of the reduce-form *** terms of the object of study,this paper considers the issue of moral hazard incentives in the presence of claiming fraud in two reference entities to further explore the impact of moral hazard incentives on default protection at the micro level in terms of cyclic ***,based on the

关键词： Financial engineering moral hazard incentive claiming fraud reduce-form model probability of default calculation CDS pricing

Stereoselective synthesis of substituted 1,3-dienes from propargylic esters: electrophilic-metal or redox catalysis?

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Science China Chemistry 2024年第5期67卷 1384-1396页

作者： Mengfu Dai liangliang Song liang-An Chen Jiangsu Collaborative Innovation Center of Biomedical Functional Materials Jiangsu Key Laboratory of New Power BatteriesSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023China Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Chemical EngineeringNanjing Forestry UniversityNanjing 210037China

1,3-Diene architectures are not only widely present in natural products, pharmaceuticals, and functional organic materials but also serve as versatile building blocks to furnish important functionalized molecules in synthetic chemistry due to conjugated repeating C=C units. Accordingly, various strategies to access substituted 1,3-dienes in a stereoselective manner have been developed. However, chemo-, regio-and stereoselective synthesis of highly substituted 1,3-dienes still remains elusive and challenging. Readily available propargylic esters have emerged as an appealing class of synthetic intermediates for accessing functionalized 1,3-dienes, especially challenging tri-or tetrasubstituted variants, via transition-metal catalysis, including electrophilic metal and redox neutral catalysis. This review, for the first time, systematically highlights recent advances in transitionmetal catalyzed synthesis of substituted 1,3-dienes from propargylic esters, discusses the mechanisms and synthetic utilities, and gives the remaining challenges and potential opportunities in this field.

关键词： 1 3-diene propargylic ester Lewis acid redox catalysis transition metal