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Wuhan university Journal of Natural sciences 2009年第4期14卷 369-372页

作者： li xinsheng,ding qianchang,li liangchao, xu dongcheng college of chemistry and life sciences,zhejiang normal university,jinhua 321004,zhejiang,china college of chemistry and life sciences Zhejiang Normal University Jinhua 321004 Zhejiang China

Chiral monodentate phosphoramidite ligands were conveniently prepared from 1,1＇-bi-2-naphthol （BINOL） and （S）-pyrrolidine in good yields, which were effective chiral ligands in the enantioselective rhodium-catalyzed hydrogenation of dehydroamino esters and enamides at low hydrogenation pressure. High conversion rate （up to 99% for dehydroamino esters and enamides） and good enantioselectivity （up to 96.3% ee for dehy- droamino esters and 91.7% ee for enamides） were obtained.

关键词： phosphoramidite chirality hydrogenation dehy- droamino ester enamide

Multiporphyrinic architectures:Advances in structural design for photodynamic therapy

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Aggregate 2024年第1期5卷 67-84页

作者： Yuwei Gao Yan li Zhengwei xu Shuangjiang Yu Junqiu liu Hongcheng Sun college of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhouChina

Rationally designed multiporphyrinic architectures for boosting photodynamic therapy(PDT)have attracted significant attentions recently years due to their great potential for light-mediated generation of reactive oxygen ***,there is still a gap between the structure design and their PDT performance for biomedical *** tutorial review provides a historical overview on(i)the basic concept of PDT for deeply understanding the porphyrin-mediated PDT reactions,(ii)developing strategies for constructing porphyrinic architectures,like nanorings,boxes,metal-organic frameworks(MOFs),covalent-organic frameworks(COFs),vesicles,etc.,where we classified into the following three categories:multiporphyrin arrays,porphyrinic frameworks,and others porphyrin assemblies,(iii)the various application scenarios for clinical cancer therapy and antibacterial ***,the existing challenges and future perspectives on the innovation of porphyrinic architectures for clinical PDT applications are mentioned in the end ***,the porphyrinic nanomaterials with atomically precise architectures provide an ideal platform for investigating the relationship between structures and PDT outputs,design of personalized“all-in-one”theranostic agents,and the popularization and application in wider biomedical fields.

关键词： covalent-organic frameworks(COFs) metal-organic frameworks(MOFs) multiporphyrin arrays photodynamic therapy(PDT) porphyrinic architectures

Aza-BODIPY dye with unexpected bromination and high singlet oxygen quantum yield for photoacoustic imaging-guided synergetic photodynamic/photothermal therapy

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Chinese Chemical Letters 2024年第6期35卷 445-450页

作者： Leichen Wang Anqing Mei Na li Xiaohong Ruan xu Sun Yu Cai Jinjun Shao Xiaochen Dong Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM) Nanjing Tech University(NanjingTech)Nanjing 211800China School of chemistry&Materials Science Jiangsu Normal UniversityXuzhou 221116China Center for Rehabilitation Medicine Rehabilitation&Sports Medicine Research Institute of Zhejiang ProvinceDepartment of Rehabilitation MedicineZhejiang Provincial People’s Hospital(Affiliated People’s HospitalHangzhou Medical College)Hangzhou 310014China

Introducing heavy halogen atoms into organic small molecules is a practical strategy for efficient singlet oxygen(^(1)O_(2))***,bromine or iodine atoms are introduced on the aza-borondipyrromethene(aza-BODIPY)core,rather than on the periphery aryl rings for efficient~1O_(2) ***,an aza-BODIPY dye NBDPBr with unexpected bromination on the periphery aryl rings was synthesized for photoacoustic(PA)imaging-guided synergistic photothermal therapy(PTT)and photodynamic therapy(PDT)in tumor *** to unexcepted bromination at the periphery aryl rings,NBDPBr demonstrated an outstanding singlet oxygen quantum yield(Φ_(Δ))of 66% which was superior to similar brominated photosensitizers previously *** encapsulation with amphiphilic polymer F-127,hydrophilic NBDPBr nanoparticles(NPs)were fabricated and exhibited an excellent photothermal conversion efficiency(η)of 43.0% under 660 nm *** vivo PA imaging results demonstrated that NBDPBr NPs could specifically accumulate at tumor sites and realized the maximum tumor retention at 7 h *** the in vitro and in vivo results indicated the significant potence of NBDPBr with unexpected bis-bromination for PA imaging-guided synergetic PDT/PTT.

关键词： Unexpected bromination Aza-BODIPY Photodynamic therapy Photothermal therapy Synergetic therapy

Nitrite-catalyzed economic and sustainable bromocyclization of tryptamines/tryptophols to access hexahydropyrrolo[2,3-b]indoles/tetrahydrofuroindolines in batch and flow

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Chinese Chemical Letters 2024年第7期35卷 247-252页

作者： Xiao Xiao Biao Chen Jia-Wei li Jun-Bo Zheng xu Wang Hang Zhao Fen-Er Chen Institute of Pharmaceutical Science and Technology Collaborative Innovation Center of Yangtze River Delta Region Green PharmaceuticalsZhejiang University of TechnologyHangzhou 310014China college of chemistry and Chemical Engineering Jiangxi Normal UniversityNanchang 330022China Engineering Center of Catalysis and Synthesis for Chiral Molecules Department of ChemistryFudan UniversityShanghai 200433China Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs Shanghai 200433China

A highly efficient and concise bromocyclization has been successfully achieved,in which tryptamine/tryptophol derivates can be transformed to valuable HPI/TFI scaffolds with economic and green ***,a controllable cascade transformation of bromocyclization and aromatic bromination has also been smoothly achieved to form dibrominated HPIs and *** could be successfully scaled up under both the batch process and a continuous flow *** most remarkable peculiarity of our process over all previous methods is that the generated water is the major ***,successful application of this new protocol has been demonstrated by the pharmaceutical and natural products syntheses.

关键词： Tryptamines and tryptophols Nitrite Economic and sustainable bromocyclization HPI and TFI structures Bath and flow

High-performance wearable bimetallic nanowire-assisted composite foams for efficient electromagnetic interference shielding,infrared stealth,and piezoresistive sensing

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Nano Research 2024年第7期17卷 6757-6765页

作者： Tianyi Hang lijie Zhou Chenhui xu Yiming Chen Jiahui Shen Jiajia Zheng Pingan Yang Xiping li Heng Luo Guoxiu Tong Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology and Equipment of zhejiang Province College of EngineeringZhejiang Normal UniversityJinhua 321004China School of Automation Chongqing University of Posts and TelecommunicationsChongqing 400065China State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials ScienceZhejiang Normal UniversityJinhua 321004China

With the accelerated development of modern detection and communication technology,the multifunctional wearable materials with excellent electromagnetic interference(EMI)shielding,infrared stealth,and human monitoring for improving military combat capability have received extensive *** this work,the lightweight melamine foam(MF)@silver nanowires(AgNWs)-iron nanowires(FeNWs)(AgFe-MF)was fabricated by a vacuum-assisted dip-coating *** to the porous structure and synergistic electrical and magnetic losses,this lightweight(0.115 g/cm^(3))composite foam with an ultra-low filler content(0.62 vol.%)exhibited an ideal EMI shielding efficiency of 38.4 *** the other hand,the AgFe-MF realized a powerful multifunctional *** surface saturation temperature of the AgFe-MF reached 94.2℃under a low applied voltage of 1.8 V and remained extremely fast heating and cooling response and terrific working stability,resulting in excellent infrared stealth and camouflage ***,taking virtues of the elastic porous conductive architecture,the AgFe-MF was utilized as a piezoresistive sensor exhibiting board compressive interval of 0–1.62 kPa(50%strain)with a good sensitivity of 0.57 kPa^(−1).This work will provide new ideas and insights for developing multifunctional wearable devices in the fields of EMI shielding,thermal management,and piezoresistive sensing.

关键词： metal nanowires porous foams electromagnetic interference shielding infrared stealth wearable sensors

Ru-Ni alloy nanosheets as tandem catalysts for electrochemical reduction of nitrate to ammonia

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Nano Research 2024年第6期17卷 4815-4824页

作者： Xingchao You Jiawei xu Zechao Zhuang Junkai Xia Suwen Wang Haiyan Wei Yongfu li Yanjiang Cai Hai Xiang Bing Yu State Key Laboratory of Subtropical Silviculture Zhejiang A&F UniversityHangzhou 311300China Ecological-Environment&Health college(EEHC) Zhejiang A&F UniversityHangzhou 311300China Jiangsu Key Laboratory of Numerical Simulation of Large Scale Complex Systems and School of chemistry and Materials Science Nanjing Normal UniversityNanjing 210023China Department of chemistry Tsinghua UniversityBeijing 100084China Department of Chemical Engineering Columbia UniversityNew YorkNY 10027USA

Developing electrocatalysts that exhibit both high activity and ammonia selectivity for nitrate reduction is a significant and demanding challenge,primarily due to the complex nature of the multiple-electron reduction process *** encouraging approach involves coupling highly active precious metals with transition metals to enhance catalytic performance through ***,we report a ruthenium-nickel alloy catalyst with nanosheets(Ru-Ni NSs)structure that achieves a remarkable ammonia Faradaic efficiency of approximately 95.93%,alongside a yield rate of up to 6.11 g·h^(−1)·cm^(−2).Moreover,the prepared Ru-Ni NSs exhibit exceptional stability during continuous nitrate reduction in a flow reactor for 100 h,maintaining a Faradaic efficiency of approximately 90%and an ammonia yield of 37.4 mg·L^(−1)·h^(−1)using 0.05 M nitrate alkaline *** studies reveal that the catalytic process follows a two-step pathway,in which HONO serves as a migration *** presence of a partially oxidized Ru(002)surface enhances the adsorption of nitrate and facilitates the release of the migration intermediate by adjusting the strength of the electrostatic and covalent interactions between the adsorbate and the surface,*** the other hand,the Ni(111)surface promotes the utilization of the migration intermediate and requires less energy for NH_(3)*** tandem process contributes to a high catalytic activity of Ru-Ni NSs towards nitrate reduction.

关键词： alloy catalyst nitrate reduction ammonia synthesis Faradaic efficiency

New paradigms of water-enabled electrical energy generation

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SusMat 2024年第3期4卷 73-103页

作者： Zhengtong li Tao Yang Jia-Han Zhang Taotao Meng Saad Melhi Jungmok You Miharu Eguchi likun Pan Yusuke Yamauchi Xingtao xu The National Key Laboratory ofWater Disaster Prevention Yangtze Institute for Conservation and DevelopmentState Key Laboratory of Hydrology-Water Resources and Hydraulic EngineeringHohai UniversityNanjingChina School of Electronic Information Engineering Inner Mongolia UniversityHohhotChina Collaborative Innovation Center of Advanced Microstructures School of Electronic Science and EngineeringNanjing UniversityNanjingChina college of Materials Science and Engineering Nanjing Forestry UniversityNanjingChina Department of chemistry College of ScienceUniversity of BishaBishaSaudi Arabia Department of Plant&Environmental New Resources College of Life SciencesKyung Hee UniversityYongin-siGyeonggi-doSouth Korea Department of Applied chemistry School of Advanced Science and EngineeringWaseda UniversityShinjuku-kuTokyoJapan Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic ScienceEast China Normal UniversityShanghaiChina School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQueenslandAustralia Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoyaJapan Marine Science and Technology college Zhejiang Ocean UniversityZhoushanZhejiangChina

Nanotechnology-inspired small-sized water-enabled electricity generation(WEG)has sparked widespread research interest,especially when applied as an electricity source for off-grid low-power electronic equipment and ***,WEG encompasses a wide range of physical phenomena,generator structures,and power generation ***,a systematic framework to clearly describe the connections and differences between these technologies is *** this review,a comprehensive overview of generator technologies and the typical mechanisms for harvesting water energy is *** the different roles of water inWEG processes,the related technologies are presented as two different ***,a detailed analysis of the electrical potential formation in each WEG process is presented,and their similarities and differences are ***,a comprehensive compilation of advanced generator architectures and system designs based on hydrological cycle processes is presented,along with their respective energy *** nanotechnology-inspired small-sized WEG devices show considerable potential for applications in the Internet of Things ecosystem(i.e.,microelectronic devices,integrated circuits,and smart clothing).Finally,the prospects and future challenges of WEG devices are also summarized.

关键词： electricity generation mechanisms Internet of Things multi-angle generator systems smallsized generators water-enabled electricity generation

Multidisciplinary and multiscale nanoscience research roadmap based on large scientific facilities

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Science china chemistry 2024年第8期67卷 2497-2523页

作者： Yuan Zeng Shuhan Zhang Yuecong Guo Yalin Cong xu ding Peihua li Yunxiang lin Wenzhi Ren Hui Su Weigang Sun liuxin xu Guikai Zhang Shihua Chen Yu Chen Weiren Cheng Shengqi Chu Yong Guan Jinru Han Jie lin Hengjie liu Zheyi liu Pan Luo Fanchun Meng Sicong Qiao Zongyin Song Ying Wang Zhao Wu Chenyu Yang Meng Yang Shirui Yang Zi Yin Zhibin Yin Pengjun Zhang Hongyu Zhang Pingping Zheng Jia Zhou Wanlin Zhou Pengfei An He Cheng Chunhai Fan Xingjiu Huang Yong Lei lina li Mu li Qinghua liu Shuming Peng li Song Zhihu Sun Yangchao Tian Fangjun Wang lihua Wang liming Wang Shiqiang Wei Aiguo Wu Chunlei Xiao xueming Yang Panchao Yin Jing Zhang Mingxin Zhang Yaling Wang Chunying Chen CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety New Cornerstone Science LaboratoryNational Center for Nanoscience and TechnologyBeijing 100190China university of Chinese Academy of sciences Beijing 100049China National Synchrotron Radiation Laboratory University of Science and Technology of ChinaHefei 230029China Institute of Solid State Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China Institutes of Physical Science and Information Technology Anhui UniversityHefei 230601China Ningbo Key Laboratory of Biomedical Imaging Probe Materials and Technology Zhejiang International Cooperation Base of Biomedical Materials Technology and ApplicationCAS Key Laboratory of Magnetic Materials and DevicesNingbo Cixi Institute of Biomedical EngineeringZhejiang Engineering Research Center for Biomedical MaterialsNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Advanced Energy Science and Technology Guangdong Laboratory Huizhou 516000China college of chemistry and Chemical Engineering Hunan Normal UniversityChangsha 410081China State Key Laboratory of Luminescent Materials and Devices South China Advanced Institute for Soft Matter Science and TechnologySouth China University of TechnologyGuangzhou 510640China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China CAS Key Laboratory of Separation sciences for Analytical chemistry Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Institute of Advanced Science Facilities Shenzhen 518107China State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China State Key Laboratory of Particle Detection and Electronics Institute of High Energy PhysicsChinese Acade

With the advancement of modern science and technology, large scientific facilities are increasingly oriented toward demand and application, and can be used for basic research as well as serving multiple disciplines. Developing large scientific facilities and related analytical technologies enhances understanding of large scientific facilities and popularizes their application in research across multiple disciplines. The combination of light or neutron sources from large scientific facilities and advanced analytical technologies can be achieved for materials structure information, dynamics study of chemical reactions, high dissociation of biomolecules, 3D visualization of energy materials or biological samples, etc. We first introduce the progress of domestic large scientific facilities of synchrotron radiation(SR) and free electron lasers(FELs) with different wavelengths and neutron *** further discuss the comparison between Chinese and typical foreign facilities in X-ray radiation from X-ray tubes, synchrotrons, X-ray FELs, and neutron sources based on physical parameters of light and neutron sources. In addition, we focus on the technological progress and perspectives combined with advanced X-ray radiation and neutron sources of large scientific facilities in china, especially in the nanoscience fields of energy catalysis and biological science. We hope that this roadmap will provide references on technology and methods to experimental users, as well as prospects for future development of technologies based on large research infrastructure facilities. Comprehensive studies and guidelines for basic research to practical application in various disciplines can be made with the assistance of large scientific facilities.

关键词： large scientific facilities synchrotron radiation FEL light sources neutron sources spectroscopic analysis methods X-ray imaging techniques structural information chemical dynamics

Hollow tubes constructed by carbon nanotubes self-assembly for CO_(2) capture

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Journal of Central South university 2024年第7期31卷 2256-2267页

作者： CHEN xu-rui WU Jun GU li CAO xue-bo college of chemistry and Materials Science Zhejiang Normal UniversityJinhua 321004China college of Biological Chemical Sciences and EngineeringJiaxing UniversityJiaxing 314001China college of Materials and Textile Engineering Jiaxing UniversityJiaxing 314001China college of Advanced Materials Engineering Jiaxing Nanhu UniversityJiaxing 314001China

Carbon nanotubes(CNTs)have garnered significant attention in the fields of science,engineering,and medicine due to their numerous *** initial step towards harnessing the potential of CNTs involves their macroscopic *** present study employed a gentle and direct self-assembly technique,wherein controlled growth of CNT sheaths occurred on the metal wire’s surface,followed by etching of the remaining metal to obtain the hollow tubes composed of *** controlling the growth time and temperature,it is possible to alter the thickness of the CNTs *** immersing in a solution containing 1 g/L of CNTs at 60℃ for 24 h,the resulting CNTs layer achieved a thickness of up to 60μ*** hollow CNTs tubes with varying inner diameters were prepared through surface reinforcement using polymers and sacrificing metal wires,thereby exhibiting exceptional attributes such as robustness,flexibility,air tightness,and high adsorption capacity that effectively capture CO_(2) from the gas mixture.

关键词： carbon nanotubes self-assembly hollow tubes CO_(2) capture

Coordination bonds reinforcing mechanical strength of silicon anode to improve the electrochemical stability

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Rare Metals 2024年第11期 5690-5700页

作者： Jin-Huan li Hong-Qiang xu Min Wu Quan Du Yong-Bo Kuang Bo Yin Hai-Yong He Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of Sciences university of Chinese Academy of sciences chemistry and Chemical Engineering college Gannan Normal University

The severe volumetric expansion and poor conductivity of silicon when used as anode in lithium-ion batteries present challenges in maintaining the stability of electrochemical ***,the binding between silicon nanoparticles and carbon nanotubes（CNTs） is achieved by the utilization of sodium alginate（S A）,which is then strengthened by the coordination between Ca2+and the carboxyl group（-COO-） of SA,resulting in a stable conductive network with ionic transport *** consolidated binding relationship enables silicon-based anode material to possess high mechanical strength and strong deformation resistance,preventing the separation of silicon from CNTs ***,this silicon-based anode material demonstrates a discharge specific capacity of811 mAh·g-1after 100 cycles at a current density of 1 A·g-1,and exhibits high rate performance,with a discharge specific capacity of 1612 mAh·g-1at 2 A·g-1.

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