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Strengthening and toughening styrene-butadiene rubber by mechanically interlocked cross-links

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Science china Chemistry 2024年第10期67卷 3414-3422页

作者： Yuanhao Wang li Yang lin Cheng Jun Zhao Ruixue Bai Wenbin Wang Shaolei Qu Zhaoming zhang Wei Yu xuzhou Yan school of Chemistry and chemical engineering Frontiers Science Center for Transformative MoleculesShanghai Key Laboratory of Electrical Insulation and Thermal AgingShanghai Jiao Tong UniversityShanghai 200240China

Styrene-butadiene rubber(SBR)is an indispensable material in modern society,and the necessity for enhanced mechanical properties in SBR persists,particularly to withstand the rigors of challenging environmental *** surmount the limitations of conventional cross-linking modes,mechanical bonds stabilized by host-guest recognition are incorporated as the cross-linking points of SBR to form mechanically interlocked networks(MINs).Compared with covalently cross-linked network,the representative MIN exhibits superior mechanical performance in terms of elongation(1392%)and breaking strength(4.6 MPa),whose toughness has surged by 17 *** of host-guest recognition and subsequent sliding motion provide an effective energy dissipation mechanism,and the release of hidden length is also beneficial to enhance ***,the introduction of the rotaxane cross-links made the network more pliable and possess damping and elastic properties,which can return to initial state with one minute rest *** aspire that this direct introduction method can serve as a blueprint,offering valuable insights for the enhancement of mechanical properties in conventional commercial polymer materials.

关键词： mechanically interlocked molecules host-guest chemistry styrene-butadiene rubber mechanical properties dynamic materials

Vitrification cryopreservation of ligaments based on zwitterionic betaine

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Chinese Journal of chemical engineering 2024年第8期72卷 1-9页

作者： liming zhang Xinmeng liu Haoyue li Lei zhang Department of Biochemical engineering Frontier Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering(MOE)School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300350China Haihe Laboratory of Sustainable chemical Transformations Tianjin 300192China

ligament cryopreservation enables a prolonged shelf life of allogeneic ligament grafts,which is fundamentally important to ligament ***,conventional cryopreservation techniques fail to eliminate the damage caused by ice crystal growth and the toxicity of cryopreservation agents(CPAs).Here,we report a novel CPA vitrification formulation primarily composed of betaine for ligament *** optimization was conducted on the methods for vitrification and rewarming,as well as the loading and unloading conditions,based on the critical cooling rate(CCR),critical warming rate(CWR),and permeation properties of the *** biomechanical and histological level tests,we demonstrate the superior performance of our method in ligament *** 30 days of vitrification cryopreservation,parameters such as the Young's modulus,tensile stress,denaturation temperature,and glycosaminoglycans content of the ligament remained essentially *** work pioneers the application of ice-free cryopreservation for ligament and holds great potential for improving the long-term storage of ligament,providing valuable insights for future cryopreservation technique development.

关键词： ligament Betaine Vitrification Cryopreservation

engineering single-atom Mn on nitrogen-doped carbon to regulate lithium-peroxide reaction kinetics for rechargeable lithium-oxygen batteries

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Journal of Energy Chemistry 2024年第7期94卷 199-207页

作者： Yaling Huang Yong liu Yang liu Chenyang zhang Wenzhang li Jie li school of Chemistry and chemical engineering Central South UniversityChangsha 410083HunanChina school of Minerals Processing and Bioengineering Central South UniversityChangsha 4003HunanChina

Precision engineering of catalytic sites to guide more favorable pathways for li_(2)O_(2) nucleation and decom-position represents an enticing kinetic strategy for mitigating overpotential,enhancing discharge capac-ity,and improving recycling stability of li-O_(2) *** this work,we employ metal-organic frameworks(MOFs)derivation and ion substitution strategies to construct atomically dispersed Mn-N_(4) moieties on hierarchical porous nitrogen-doped carbon(Mn SAs-NC)with the aim of reducing the over-potential and improving the cycling stability of li-O_(2) *** porous structure provides more chan-nels for mass transfer and exposes more highly active sites for electrocatalytic reactions,thus promoting the formation and decomposition of li_(2)O_(2).The li-O_(2) batteries with Mn SAs-NC cathode achieve lower overpotential,higher specific capacity(14290 mA h g^(-1) at 100 mAg^(-1)),and superior cycle stability(>100 cycles at 200 mA g^(-1))compared with the Mn NPs-NC and *** functional theory(DFT)cal-culations reveal that the construction of Mn-N_(4) moiety tunes the charge distribution of the pyridinic N-rich vacancy and balances the affinity of the intermediates(liO_(2) and li_(2)O_(2)).The initial nucleation of li_(2)O_(2) on Mn SAs-NC favors the O_(2)-→liO_(2)→li_(2)O_(2) surface-adsorption pathway,which mitigates the overpoten-tials of the oxygen reduction(ORR)and oxygen evolution reaction(OER).As a result,Mn SAs-NC with Mn-N_(4) moiety effectively facilitates the li_(2)O_(2) nucleation and enables its reversible *** work establishes a methodology for constructing carbon-based electrocatalysts with high activity and selectivity for li-O_(2)batteries.

关键词： Single-atom Mn MOFs-oriented architecture Rechargeable li-O_(2)battery N-doped carbon Density functional theory calculation

Engineered spidroin-derived high-performance fibers for diverse applications

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Nano Research 2024年第2期17卷 492-502页

作者： Dawen Qin Jingjing li Huanrong li Hongjie zhang Kai liu National-Local Joint engineering Laboratory for Energy Conservation in chemical Process Integration and Resources Utilization Tianjin Key Laboratory of Chemical Process SafetySchool of Chemical Engineering and TechnologyHebei University of TechnologyTianjin 300130China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China engineering Research Center of Advanced Rare Earth Materials Ministry of EducationDepartment of ChemistryTsinghua UniversityBeijing 100084China university of Science and technology of china Hefei 230026China

Spider silks are well known for their exceptional mechanical properties that are tougher than Kevlar and ***,the restricted production amounts from their native sources limit applications of spider *** the decades,there have been significant interests in fabricating man-made silk fibers with comparable performance to natural silks,inspiring many efforts both for biosynthesizing recombinant spider silk proteins(spidroins)in amenable heterologous hosts and biomimetic spinning of artificial spider *** strategies provide promising routes to produce high-performance and functionally optimized fibers with diverse ***,we summarize the hosts that have been applied to produce recombinant *** addition,the fabrication and mechanical properties of recombinant spidroin fibers and their composite fibers are also ***,we demonstrate the applications of recombinant spidroin-based ***,facing the challenges in biosynthesis,scalable production,and hierarchical assembly of high-performance recombinant spidroins,we give a summary and perspective on future development.

关键词： spider silk recombinant spidroin heterologous expression fiber fabrication mechanical property

Increasing(010) active plane of P2-type layered cathodes with hexagonal prism towards improved sodium-storage

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Chinese chemical Letters 2024年第10期35卷 505-509页

作者： Dongmei Dai xiaobing Lai Xiaojuan Wang Yunting Yao Mengmin Jia liang Wang Pengyao Yan Yaru Qiao Zhuangzhuang zhang Bao li Dai-Huo liu Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine chemicals Key Laboratory of Green Chemical Media and Reactions(Ministry of Education)School of Chemistry and Chemical EngineeringHenan Normal UniversityXinxiang 453007China CAS Henan Industrial technology Innovation&Incubation Center Zhengzhou 450016China

Na-ion cathode materials with a fast charge and discharge behavior are needed to develop future high energy sodium-ion batteries(SIBs).However,inevitably complicated phase transitions and sluggish kinet ics during insertion and removal of Na+in P_(2)-type layered transition metal oxides generate structura instability and severe capacity *** get rid of such a dilemma,we report a structural optimization strategy to promote P2-type layered transition metal oxides with more(010)active planes as an efficien cathode for *** a result,as-prepared hexagonal-prism P2-type layered Na_(0.71)Ni_(0.16)li_(0.09)Co_(0.16)Mn0.6O_(2)cathode with more(010)active planes delivers a reversible capacity of 120.1 mAh/g at 0.1 C,impressive rate capability of 52.7 m Ah/g at 10 C,and long-term cycling stability(capacity retention of 95.6%ove200 cycles).The outstanding electrochemical performance benefited from the unique hexagonal-prism with more(010)active facets,which can effectively shorten the diffusion distances of Na+,increase the Na-ion migration dynamics and nanostructural stability during cycling verified by morphology character ization,Rietveld refinement,GITT,density functional theory calculations and operando XRD.

关键词： Layered cathodes Hexagonal-prism shape P2-type structure Sodiumion batteries Enhanced diffusion kinetics

Formation mechanism of Fe-based amorphous powders produced by spark erosion

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Journal of Materials Science & technology 2024年第3期170卷 33-46页

作者： Chekai liu Ran li Jiazi Bi Ding Ma Xiaobin liu Tao zhang school of Materials Science and engineering Key Laboratory of Aerospace Materials and Performance(Ministry of Education)Beihang UniversityBeijing 100191China

Spark erosion is a convenient,flexible,and low-cost method to quickly produce fine powders of metals,alloys,and semiconductors in size ranging from nearly a hundred micrometers to submicrometer by repetitive spark *** to the complexity of the powder-forming journey,normally accompanied by high temperature,high pressure,decomposition,diffusion and rapid quenching caused by discharge plasma,the mechanisms of powder formation and possible contaminant infiltration are still controversial,posing a significant challenge to control particle size and chemical composition of the powder produced by this *** this study,Fe-based amorphous powders in different particle-size distributions with high sphericity were fabricated by spark erosion under different discharge-energy *** max-imum particle size of the resultant powders can be correlated with discharge parameters,crater depth,and crater radius,respectively.A multi-ring-breakup model is proposed to reveal the particle-size distribution of the powder formed from the electrode melt under a single-pulse ***,a dielectric-element infiltration model is provided to quantitatively evaluate the infiltration mass ratio of the contaminant elements,stemming from the decomposed products of dielectric liquid,in the resultant powder with different particle *** models verified through the experimental data are significant for the development of high-performance fine Fe-based amorphous powder with controlled particle size and chemical composition.

关键词： Amorphous alloy Particle Spark erosion Infiltration Modeling

Preparation of sodium molybdate from molybdenum concentrate by microwave roasting and alkali leaching

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 91-105页

作者： Fengjuan zhang Chenhui liu Srinivasakannan Chandrasekar Yingwei li Fuchang Xu school of Chemistry and Environment Yunnan Minzu UniversityKunming 650500China chemical engineering Department Khalifa UniversityAbu DhabiUAE Yunnan Zhong Tai technology Co. Ltd.Kunming 650500China Yunnan Yongchang Silicon Industry Co. Ltd.Baoshan 678000China

The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient development of molybdenum concentrate resources,this paper proposes a new process for efficient recovery of molybdenum from molybdenum concentrate and preparation of sodium molybdate by microwave-enhanced roasting and alkali *** analysis indicated the feasibility of oxidation roasting of molybdenum *** effects of roasting temperature,holding time,and power-to-mass ratio on the oxidation product and leaching product sodium molybdate (Na_(2)MoO_(4)·2H_(2)O) were *** the optimal process conditions:roasting temperature of 700℃,holding time of 110 min,and power-to-mass ratio of 110 W/g,the molybdenum state of existence was converted from MoS_(2) to Mo *** process of preparing sodium molybdate by alkali leaching of molybdenum calcine was investigated,the optimal leaching conditions include a solution concentration of 2.5 mol/L,a liquid-to-solid ratio of 2 mL/g,a leaching temperature of 60℃,and leaching solution termination at pH *** optimum conditions result in a leaching rate of sodium molybdate of 96.24%.Meanwhile,the content of sodium molybdate reaches 94.08wt%after leaching and removing *** and aluminum impurities can be effectively separated by adjusting the pH of the leaching solution with sodium carbonate *** research avoids the shortcomings of the traditional process and utilizes the advantages of microwave metallurgy to prepare high-quality sodium molybdate,which provides a new idea for the highvalue utilization of molybdenum concentrate.

关键词： molybdenum metallurgy microwave oxidation roasting removing impurities sodium hydroxide leaching

Resistance to salt stresses by aerobic granular sludge:sludge property and microbial community

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Frontiers of Environmental Science & engineering 2024年第8期18卷 107-116页

作者： Xiao Wu Hui li Meili Wang Tianying zhang Jiawei li Yongdi liu Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission School of Chemistry and EnvironmentSouthwest Minzu UniversityChengdu 610041China Institute for Environmental Pollution and Health School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444China school of life Sciences Southwest UniversityChongqing 400715China State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on chemical Process School of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai 200237China Institute of Qinghai-Tibetan Plateau Southwest Minzu UniversityChengdu 610041China

Saline wastewater is regarded as a challenge for wastewater treatment plants because high-salinity conditions negatively affect on traditional biological *** granular sludge(AGS)has gained attention as a promising technology for saline wastewater treatment because of its compact structure and the ability to withstand toxic ***,this study investigated the saltresistance performance,sludge properties and microbial community of AGS under low-salinity and high-salinity conditions,with the saline concentrations ranging from 0 to 50 g/*** results showed that AGS could withstand long-term saline stresses,and the maximum salinity reached 50 g/L within 113 *** salinities of 10,30,and 50 g/L,the chemical oxygen demand(COD)removal efficiencies were 90.3%,88.0%and 78.0%,*** also its maintained strength and aggregation at salinities of 10 and 30 g/*** of extracellular polymeric substances(EPS)by non-halophilic bacteria that enhanced sludge *** compact structure that ensured the microorganisms bioactivity helped to remove organic matters under salinities of 10 and 30 g/*** a salinity of 50 g/L,moderately halophilic bacteria,including Salinicola,Thioclava,Idiomarina and Albirhodobacter,prevailed in the *** dominant microbial communities shifted to moderately halophilic bacteria,which could maintain aerobic granular stabilization and remove organic matters under 50 g/L *** results in this study provide a further explanation for the long-term operation of AGS for treating saline wastewater at different *** is hoped that this work could bring some clues for the mystery of salt-resistance mechanisms.

关键词： Aerobic granular sludge Long-term saline stresses Performance Sludge property Microbial community

Multi-objective Design of Blending Fuel by Intelligent Optimization Algorithms

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Transactions of Tianjin university 2024年第3期30卷 221-237页

作者： Ruichen liu Cong li li Wang Xiangwen zhang Guozhu li Key Laboratory for Green chemical technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Collaborative Innovation Center of chemical Science and engineering(Tianjin) Tianjin 300072China Haihe Laboratory of Sustainable chemical Transformations Tianjin 300192China

Fuel design is a complex multi-objective optimization problem in which facile and robust methods are urgently ***,a complete workflow for designing a fuel blending scheme is presented,which is theoretically supported,efficient,and *** on the data distribution of the composition and properties of the blending fuels,a model of polynomial regression with appropriate hypothesis space was *** parameters of the model were further optimized by different intelligence algorithms to achieve high-precision ***,the design of a blending fuel was described as a multi-objective optimization problem,which was solved using a Nelder–Mead algorithm based on the concept of Pareto ***,the design of a target fuel was fully validated by *** study provides new avenues for designing various blending fuels to meet the needs of next-generation engines.

关键词： Multi-objective optimization Machine learning Blending fuel