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Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

Science china Chemistry 2006年第4期49卷 363-370页

作者： li xiaobin1.2. cao hongbin1.& zhang yi1.1. institute of process engineering, Chinese {1. of Sciences,{2., china 2. Graduate School of the Chinese {1. of Sciences, beijing 1.0039, china 1. institute of {1. engineering Chinese Academy of Sciences Beijing 100080 China 2. Graduate School of the Chinese academy of Sciences Beijing 100039 China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3365), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3 to 2..4 kg/m3 with the increase of water level from 3 pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1.μm to 356 μm with the increase of water level from 3 pph to 7 pph, respectively. At the same time, poorer dimen- sional stabi{1.ty was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

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