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Facile synthesis of W-Mo bimetallic oxides with high adsorption properties from secondary resources

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Tungsten 2024年第4期6卷 806-820页

作者： Jia-li Cheng Yang-Si liu xiao-li xi Zuo-Ren Nie Collaborative Innovation Center of Capital Resource-Recycling Material Technology College of Materials Science and EngineeringBeijing University of TechnologyBeijing100124China National Engineering Laboratory for Industrial Big-Data Application Technology Beijing University of TechnologyBeijing100124China Key Laboratory of Advanced Functional Materials Ministry of EducationBeijing University of TechnologyBeijing100124China

A simple solvothermal method was used to obtain W-Mo bimetallic oxides from W-Mo alloy scrap,and pure metal powders were also used as the raw materials to simulate *** products had a sea urchin-like structure with abundant oxygen vacancies and the products prepared at low temperatures forms a sosoloid resembling orthorhombic W_(0.4)Mo_(0.6)O_(3).The WMo bimetallic oxide prepared at the reaction temperature of 120℃exhibited excellent selective adsorption performance for methylene blue(MB),which the adsorption rate of MB reached 99%in 12 min and the adsorption rate reached 90%after6 adsorption *** the W-Mo molar ratio is 1:3,the maximum adsorption capacity of sample for MB can reach1148 mg·g^(-1).The adsorption process followed the Langmuir and pseudo-second-order models,which is surface-controlled monolayer *** experimental results show the feasibility of preparing W-Mo bimetal oxide products from pure materials and *** process is simple and effective,which offered a potential approach for secondary resource recycling and reusing.

关键词： W-Mo bimetallic oxide Oxygen vacancy Selective adsorption W-Mo alloy scrap Solvothermal

Comprehensive recovery of W,V,and Ti from spent selective reduction catalysts

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Rare Metals 2023年第10期42卷 3518-3531页

作者： li-Wen Ma xiao-li xi Jia-Peng Chen Fan Guo Zi-Jie Yang Zuo-Ren Nie Key Laboratory of Advanced Functional Materials Ministry of EducationFaculty of Materials and ManufacturingBeijing University of TechnologyBeijing100124China Collaborative Innovation Center of Capital Resource-Recycling Material Technology Beijing University of TechnologyBeijing100124China National Engineering Laboratory for Industrial Big-Data Application Technology Beijing University of TechnologyBeijing100124China

In this study,spent WO_(3)/V_(2)O_(5)-TiO_(2) catalysts used for selective catalytic reduction were treated by a hydrometallurgical process to comprehensively recover valuable metallic elements,such as W,V,and *** and Si impurities were preferentially removed by selective micro wave-assisted alkali leaching.W and V were leached by enhanced high-pressure leaching with efficiencies estimated at 95% and 81%.The leaching of W and V followed the nuclear shrinkage model controlled by the combination of product layer diffusion and interfacial chemical reaction.A synergistic extraction was applied to separate W and V using an extractant mixture of di-(2-ethylhexyl)phosphoric acid P204 and the primary amine *** extraction efficiencies of V and W reached 86.5% and 6.3%,respectively,with a separation coefficient(V/W) of *** product was precipitated after extraction to yield ammonium paratung state(APT) and NH_(4)VO_(3).The TiO_(2)catalyst carrier residue meets commercial specifications for *** comprehensive recovery process with the characteristics of high-pressure leaching and synergistic extraction realizes the resourceful utilization of the spent catalysts.

关键词： Spent selective catalytic reduction(SCR)catalysts Microwaveleaching Pressure leaching Synergistic extraction Comprehensive recovery

Applications of molten salt and progress of molten salt electrolysis in secondary metal resource recovery

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International Journal of Minerals,Metallurgy and Materials 2020年第12期27卷 1599-1617页

作者： xiao-li Ming Feng li-wen Zhang Zuo-ren Nie College of Materials Science and Engineering Key Laboratory of Advanced Functional MaterialsEducation Ministry of ChinaBeijing University of TechnologyBeijing 100124China National Engineering Laboratory for Industrial Big-data Application Technology Beijing University of TechnologyBeijing 100124China

Molten salt is an excellent medium for chemical reaction,energy transfer,and *** salt innovative technologies should be developed to recover metals from secondary resources and reserve metals from primary natural *** these technologies,molten salt electrolysis is an economic and environment-friendly method to extract metals from waste *** the perspective of molten salt characteristics,the application of molten salts in chemistry,electrochemistry,energy,and thermal storage should be comprehensively *** review discusses further directions for the research and development of molten salt electrolysis and their use for metal recovery from various metal wastes,such as magnet scrap,nuclear waste,and cemented carbide *** is placed on the development of various electrolysis methods for different metal containing wastes,overcoming some problems in electrolytes,electrodes,and electrolytic *** focus is given to future development directions for current associated processing obstacles.

关键词： molten salt application molten salt electrochemistry resource recycling cemented carbide scrap

Improvement in oxidation resistance of Cantor alloy through microstructure tailoring

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China Foundry 2022年第6期19卷 503-510页

作者： Bao-lin Pang Man Wang Yue-gang Shen xiao-li xi Zuo-ren Nie Collaborative Innovation Center of Capital Resource-Recycling Material Technology Faculty of Materials and ManufacturingBeijing University of TechnologyBeijing 100124China Key Laboratory of Advanced Functional Materials Ministry of EducationBeijing University of TechnologyBeijing 100124China National Engineering Laboratory for Industrial Big-data Application Technology Beijing University of TechnologyBeijing 100124China

A method of improving the oxidation resistance of Cantor alloy through microstructure tailoring was *** with distinctive microstructures were achieved by different annealing treatments on the cold-rolled Cantor *** test was then carried out on the various annealed samples at 800°C for 24 h in *** oxidation behavior was evaluated in terms of oxidation rate,surface and cross-section microstructure *** stratified oxide layers including outer Mn_(2)O_(3) and inner Cr_(2)O_(3) were observed in all the annealed samples,the thickness of Mn_(2)O_(3) and Cr_(2)O_(3) layers was ***,the samples exhibited different oxidation *** results indicate that the oxidation resistance of various annealed samples is closely related with grain size as well as twin density.

关键词： Cantor alloy annealing temperature grain size twins oxidation behavior

The Effects of Space Dimension and Temperature on the Cross Mating of Three Cryptic Species of the Bemisia tabaci Complex in China

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Journal of Integrative Agriculture 2012年第2期11卷 197-205页

作者： li xiao-xi li Shao-jian XUE xia Muhammad Z Ahmed REN Shun-xiang Andrew G S Cuthbertson QIU Bao-li Department of Entomology South China Agricultural University Guangzhou 510640 P.R.China Polytechnic College Hebei University of Science and Technology Shijiazhuang 050018 P.R.China Department of Genetics University of Pretoria Pretoria 0002 South Africa The Food and Environment Research Agency Sand Hutton Y041 1LZ United Kindom

The sweetpotato whitefly Bemisia tabaci（Homoptera：Aleyrodidae）is a destructive pest of agriculture and horticulture *** phylogenetic analysis using mitochondrial cytochrome oxidase 1 sequences indicates that this whitefly is a species complex including at least 24 morphologically indistinguishable but genetically distinct cryptic *** this study,the inter-species crosses of Middle East-Asia Minor 1（MEAM1）,Mediterranean（MED）and Asia II 7 cryptic species,which were referred to as B,Q and Cv biotypes before,were conducted in two different devices,leaf cages（7 cm3）and cylinder cages（280 cm3）,and at three temperatures of 22,30 and 38°*** indicated that no female progeny were produced in the reciprocal cross between MEAM1×Asia II 7,between MED×Asia II 7 cryptic species neither in leaf cage nor in cylinder cages,while 0.81 and 1.37% of females in the offspring were recorded in the reciprocal cross between MEAM1×MED in leaf cage *** 0.95-0.98% female progeny were recorded in the reciprocal cross between MEAM1×MED at 30°C,0.77% female progeny were recorded in the single cross direction between MEAM1 × MED at 22°C,and no female progeny were found in their reciprocal cross at 38°C in leaf *** findings indicated that neither space dimension nor temperature have a significant effect on the hybridization of different *** cryptic species.

关键词： Bemisia tabaci cross mating cryptic species reproductive isolation space dimension temperature

Regulation of morphology and visible light-driven photocatalysis of WO_(3)nanostructures by changing pH

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Rare Metals 2021年第7期40卷 1738-1745页

作者： You-Shu Fan xiao-li xi Yang-Si liu Zuo-Ren Nie lin-Yan Zhao Qing-Hua Zhang College of Materials Science and Engineering Key Laboratory of Advanced Functional MaterialsEducation Ministry of ChinaBeijing University of TechnologyBeijing 100124China National Engineering Laboratory for Industrial Big-data Application Technology Beijing University of TechnologyBeijing 100124China

The controlled preparation of hexagonal tungsten trioxide(h-WO_(3))nanostructures was achieved by adjusting the pH of the precursor *** effect of the pH on the morphology,elemental composition,and photocatalytic performance of the samples was characterized via X-ray diffraction(XRD),scanning electron microscopy,energy dispersive X-ray spectroscopy,and Raman ***-visible(UV-Vis)spectra were used to evaluate the absorbance and the photocatalytic performance of methylene ***(PL),electrochemical impedance spectroscopy,photocurrent response and Brunauer-Emmett-Teller(BET)were used to study the optical properties,electrical performance,and specific surface area of the WO_(3)-nanostructures,*** results indicate that the WO_(3) nanorods prepared at pH=1.0 exhibit the highest photocatalytic performance(87.4%in 1 h),whereas the WO_(3) nanoblocks prepared at p H=3.0 show the *** photocatalytic performance of the one dimensional(1 D)-nanorods can be attributed to their high specific surface area and charge transfer *** h-WO_(3) nanostructures were synthesized via a simple method and without a capping *** show an excellent photocatalytic performance,which is promising for their application in environment purification.

关键词： h-WO_(3) Morphology pH Photocatalysis Charge transfer Optoelectrical properties

肠道菌群在肿瘤免疫治疗耐药中的作用机制研究进展

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中国药理学通报 2025年第1期41卷 1-6页

作者：李慧玲李晓曦冯英楠胡欣张兰董宪喆首都医科大学宣武医院药学部北京100053 遵义医科大学药学院贵州遵义563000

肠道菌群多样性和组成与肿瘤免疫治疗效果相关,但是肠道菌群影响肿瘤免疫治疗耐药的机制鲜少总结和归纳。该文不仅阐述了目前肿瘤免疫治疗耐药的临床现状,还概括分析了肠道菌群的组成和稳态与不同类型肿瘤免疫治疗耐药的相关性及调控机... 详细信息

肠道菌群多样性和组成与肿瘤免疫治疗效果相关,但是肠道菌群影响肿瘤免疫治疗耐药的机制鲜少总结和归纳。该文不仅阐述了目前肿瘤免疫治疗耐药的临床现状,还概括分析了肠道菌群的组成和稳态与不同类型肿瘤免疫治疗耐药的相关性及调控机制,为肠道菌群改善肿瘤免疫治疗耐药的潜在靶点研究提供参考。

关键词：肠道菌群肿瘤免疫治疗耐药性临床现状研究进展调控策略

Comparison of the autofluorescence bronchoscope and the white light bronchoscope in airway examination

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Chinese Journal of Cancer 2010年第12期29卷 1018-1022页

作者： Yun li xiao li xi-Zhao Sui liang Bu Zu-li Zhou Fan Yang Yan-Guo liu Hui Zhao Jian-Feng li Jun liu Guan-Chao Jiang Jun Wang Department of Thoracic Surgery People's Hospital Peking University Beijing 100044 P. R. China

Background and Objective: The sensitivity and accuracy of white light bronchoscopy (WLB) in airway examination are low. Autofluorescence bronchoscope (AFB) can determine early lesions in bronchial mucosa more sensitively, but it has seldom performed in China. To assess the clinical value of the AFB in airway examination, we compared the sensitivity and specificity of the AFB and WLB in detecting cancer of the airway mucosa. Methods: Between September 2009 and May 2010, bronchoscope examinations using both the AFB and WLB were performed on 136 patients, 95 men and 41 women with a median age of 61.5 years (ranged from 25 to 84 years). There were 46 lesions located in the central airway, 84 in the peripheral lung parenchyma, and 6 in the mediastinal region. All patients received local and general anesthesia and were subsequently examined with the WLB and AFB in tandem. All procedures were completed safely. Abnormal visual findings were recorded, and biopsies of the affected regions were collected for pathologic examination. Results: Of 241 regions sampled for biopsy, 76 sites contained malignant lesions, whereas 165 sites contained benign lesions. The AFB detected 72 of the 76 malignant lesions, but the WLB detected only 50. The sensitivities of the AFB and WLB were 94.7% and 65.8%, respectively, and the specificities were 57.0% and 83.6%, respectively. The negative predictive values of the AFB and WLB were 95.9% and 84.1%, respectively. Conclusions: The AFB is more sensitive than the WLB in detecting cancerous lesions in the mucosa, and is an effective airway examination.

关键词：病理检查支气管气道萤光自体检测灵敏度空军基地色光

抗消化淀粉薄膜的结晶结构及消化道靶向性研究

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现代化工 2008年第1期28卷 44-46页

作者：李晓玺陈玲李琳华南理工大学轻化工研究所淀粉与植物蛋白深加工教育部工程中心广东广州510640

研究了抗消化淀粉薄膜的表面形貌和结晶结构。抗消化淀粉薄膜的表面粗糙,在pH为1.2和6.8的模拟缓冲液中分别浸泡2h和6h仍然保持完整;抗消化淀粉在成膜过程中发生结晶取向,其结晶形态为B型。体外模拟实验表明,抗消化淀粉薄膜在人工胃液... 详细信息

研究了抗消化淀粉薄膜的表面形貌和结晶结构。抗消化淀粉薄膜的表面粗糙,在pH为1.2和6.8的模拟缓冲液中分别浸泡2h和6h仍然保持完整;抗消化淀粉在成膜过程中发生结晶取向,其结晶形态为B型。体外模拟实验表明,抗消化淀粉薄膜在人工胃液和人工小肠液中都有良好的抗消化性能,且随着抗消化淀粉含量的增加,抗消化性能越显著。

关键词：抗消化淀粉薄膜结晶结构消化性能消化道靶向性