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Molecular-scale co-assembly membranes derived from keplerate cluster:carbonic anhydrase-mimicking nanocapsules for enhanced CO_(2)/N_(2)separation

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Science China Chemistry 2024年第10期67卷 3271-3282页

作者： Wan-Lei zhao Hongqiang li Ruoxuan zheng Yixin yang Wei chen Yu-Fei song State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Quzhou Institute for Innovation in Resource Chemical Engineering Quzhou 324000China

The development of CO_(2)separation membranes with high permeability and high selectivity,as well as ultra-thin selective layers,has always been ***,a molecular-scaled co-assembly strategy is employed to fabricate the Pebax-Mo_(132)(Pebax=polyether-block-amide copolymer;Mo_(132)=(NH_(4))_(42)[Mo_(72)^(Ⅵ)Mo_(60)^(Ⅴ)O_(372)(CH_(3)COO)_(30)(H_(2)O)_(72)])*** optimal selfstanding membrane,Pebax-Mo_(132)-5%,shows a CO_(2)permeability of~384 Barrer and an ultra-high ideal CO_(2)/N_(2)selectivity of~244,outperforming most membranes reported in the *** CO_(2)permeability and ideal CO_(2)/N_(2)selectivity are increased by 70%and 367%,respectively,compared with the pristine Pebax membrane.A thin-film composite membrane prepared by spin-coating technique on a support membrane with gutter layers also exhibits a CO_(2)permeance of 838 GPU and a CO_(2)/N_(2)selectivity of *** excellent performance can be attributed to the following reasons:(1)strong hydrogen bonding interactions between{Mo_(132)}clusters and Pebax confer excellent interfacial compatibility to the mixed matrix membranes;(2)incorporation of hollow{Mo_(132)}clusters into the Pebax molecular chain decreases the crystallinity of Pebax,and thereby accelerates the chain dynamics and increases the free volume of the membrane;(3)in situ diffuse reflectance infrared Fouriertransform spectroscopy demonstrates that the{Mo_(132)}clusters can effectively catalyze the hydration reaction of CO_(2)and promote the transport of CO_(2);(4)furthermore,the 0.35 nm pores of the crown ether-type{Mo_(9)O_(9)}allow the accurate size sieving of CO_(2)(0.33 nm)and N_(2)(0.36 nm)molecules.

关键词： polyoxometalates molecular-scale assembly CO_(2)capture mixed matrix membranes

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Improving the detecting efficiency of suspected gastrointestinal tumors with dual-time-point 18F-FDG PET/CT

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Nuclear Science and Techniques 2017年第10期28卷 23-30页

作者： Jian-Hua song Jin-Hua zhao Xue-Qian Xie Yan Xing Xiang chen wen-li Qiao Chang-Cun liu Tai-song wang department of Nuclear Medicine Shanghai General HospitalShanghai Jiao Tong University School of Medicine100 Haining Rd.Shanghai 200080China department of Radiology Shanghai General HospitalShanghai Jiao Tong University School of Medicine100 Haining Rd.Shanghai 200080China

We conducted a retrospective analysis of 221 subjects with 256 suspected gastrointestinal lesions from2007 to 2015 to explore the detecting efficiency of dualtime-point fluorine-18 fludeoxyglucose(^(18)F-FDG) positron emission tomography/computed tomography(PET/CT)and pathology examination. The abdominal delayed PET/CT was performed within 45 min of the conventional *** change in maximum standardized uptake value(ASUV_(max)) and morphological features of the suspected lesions between the conventional and dual-time-point PET/CT were compared. The sensitivity, specificity, positive predictive value, and negative predictive value(NPV) of conventional PET/CT were 81.6%(84/103), 56.2%(86/153), 55.6%(84/151), and 81.9%(86/105), *** of dual-time-point PET/CT were 94.1%(97/103),78.4%(120/153), 74.6%(97/130), and 95.2%(120/126),respectively. There was a significant difference between the conventional and dual-time-point PET/CT(P delay accounted for 79.6%(82/103) and more than that of nonneoplastic lesions(15.5%, 29/187)(x^2= 115.5, P detect gastrointestinal *** constant morphology and increased SUV_(delay) help to detect the tumors and adding delayed imaging on the locality will be an effective method when we accidentally find a suspected gastrointestinal tumor on the conventional PET/CT images.

关键词：胃肠道肿瘤 CT检测检测效率 PET 肠肿瘤计算机断层扫描正电子发射断层扫描形态特征

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A bio-based epoxy resin derived from p-hydroxycinnamic acid with high mechanical properties and flame retardancy

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Chinese Chemical Letters 2022年第11期33卷 4912-4917页

作者： Xin song Ze-Peng deng Chun-Bo li Fei song xiu-li wang li chen de-Ming Guo Yu-Zhong wang The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)State Key Laboratory of Polymer Materials EngineeringCollege of ChemistrySichuan UniversityChengdu 610064China

Recent advances in epoxy resins have been forward to achieving high mechanical performance,thermal stability,and flame ***,seeking sustainable bio-based epoxy precursors and avoiding introduction of additional flame-retardant agents are still of increasing *** we report the synthesis of p-hydroxycinnamic acid-derived epoxy monomer(HCA-EP)via a simple one-step reaction,and the HCA-EP can be cured with 4,4′-diaminodiphenylmethane(DDM)to prepare epoxy *** with the typical petroleum-based epoxy resin,bisphenol A epoxy resin,the HCA-EP-DDM shows a relatively high glass transition temperature(192.9℃)and impressive mechanical properties(tensile strength of 98.3 MPa and flexural strength of 158.9 MPa).Furthermore,the HCA-EP-DDM passes the V-1 flammability rating in UL-94 test and presents the limiting oxygen index of 32.6%.Notably,its char yield is as high as 31.6%under N_(2),and the peak heat rate release is 60%lower than that of bisphenol A epoxy *** findings provide a simple way of using p-hydroxycinnamic acid instead of bisphenol A to construct high-performance bio-based thermosets.

关键词： Epoxy resin Bio-based p-Hydroxycinnamic acid Mechanical performance Intrinsic flame retardancy

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Purification efficiency of ecological spur dikes for river pollutants in different geometric arrangements:Experiments and numerical modeling

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Journal of Hydrodynamics 2022年第5期34卷 934-947页

作者： Yi-tian chen xiao-ling wang song-min li Ya-zhi zheng Guang-yao Dong College of Environmental Science and Engineering Tianjin UniversityTianji300350China State Key Laboratory of Hydraulic Engineering Simulation and Safety Tianjin UniversityTianjin300072China College of Hydraulic Engineering Tianjin Agricultural CollegeTianjin300392China

The traditional ecological spur dike is improved,by using the biological fillers such as the plant materials,combined with microorganisms,to obtain a larger water purification *** of the researches on spur dikes focused on the hydrodynamic force and the migration and the diffusion of the pollutants,but not so much on the effects of the spur dike materials and the arrangement parameters on the water purification *** this paper the biological zeolite is used to make ecological spur *** laboratory flume experiment shows that compared with the natural zeolite spur dike,the purification effect of the biological zeolite spur dike is significantly improved,and the average removal rate of the NH3-N is kept at 6.8%after 24 h compared with 3.5%of the natural zeolite spur *** NH3-N removal rates of a single spur dike,the counterpart spur dikes and the staggered spur dikes decrease with the increase of the inlet flow,and the staggered spur dikes have the best purification ***,a numerical model based on the MIKE21 is verified by the experimental results and applied for the Tangjiali Section of the Xutangqiao River in Xinwu District,Wuxi City,Jiangsu *** orthogonal test shows that the length of the spur dike has the most important effect on the interception of pollutants and the purification,followed by the angle of the spur dike and the spacing of the spur dikes has the least important *** geometric arrangement parameters of the ecological spur dike group with the highest efficiency on the pollutant interception and the purification are:60°(angle),6.7 m(length)and 20 m(spacing).

关键词： Ecological spur dike spur dike group numerical simulation biological zeolite interception purification geometric arrangement parameters

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Experimental Study of Mooring Type Effect on the Hydrodynamic Characteristics of VLFS

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China Ocean Engineering 2022年第1期36卷 155-166页

作者： FENG Ming-wei SUN zhao-chen liANG Shu-xiu li Zhi LV Xuan JIA song-lin HUXin-yue State Key Laboratory of Coastal and Offshore Engineering Dalian University of TechnologyDalian 116024China

Mooring system is a significant part of very large offshore floating structures(VLFS).In this paper,a single module pontoon type VLFS model considering four mooring types is studied through physical model tests to determine the effects of mooring conditions on the hydroelastic response,mooring force,incident coefficient,reflection coefficient and energy dissipation *** mooring cables are symmetrically arranged on both sides of the *** floating body model satisfies the similarity of stiffness and gravity,while the cable satisfies the similarity of elasticity and *** results show that the effect of mooring type on mooring force is greater than that on hydroelastic *** the initial tension of the mooring cable will reduce the amplitude of the leeward of the VLFS *** mooring angle of the mooring cable will affect the maximum mooring force and the initial tension of the mooring line will affect the wave period in which the maximum mooring force *** transmission coefficient and wave energy dissipation coefficient will change regularly with different mooring *** results may provide a reference to facilitate the mooring design of VLFS.

关键词： VLFS hydroelastic response mooring system 3D experimental test mooring force wave reflection coefficient wave transmission coefficient wave dissipation coefficient

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Efficacy and toxicity of capecitabine combined with intensitymodulated radiotherapy after D1/D2 lymph node dissection in patients with gastric cancer

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World Journal of Gastrointestinal Oncology 2021年第10期13卷 1532-1543页

作者： Xin wang Wei-Hu wang Shu-lian wang Yong-wen song yue-Ping liu Yuan Tang Ning li wen-yang liu hui Fang Ye-xiong li Dong-Bing zhao Yihebali Chi lin yang Jing Jin department of Radiation Oncology National Cancer Center/National Clinical Research Center for Cancer/Cancer HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100021China department of Radiation Oncology Peking University Cancer Hospital and InstituteBeijing 100001China department of Radiation Oncology National Cancer Center/National Clinical Research Center for Cancer/Cancer Hospital&Shenzhen HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeShenzhen 518116Guangdong ProvinceChina department of Pancreatic and Gastric Surgery National Cancer Center/National Clinical Research Center for Cancer/Cancer HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100021China department of Medical Oncology National Cancer Center/National Clinical Research Center for Cancer/Cancer HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100021China

BACKGROUND Adjuvant chemoradiotherapy(ACRT)with oral capecitabine and intensitymodulated radiotherapy(IMRT)were well tolerated in a phase I study in patients who had undergone partial or total gastrectomy for locally advanced gastric cancer(GC).This phase II study aimed to further determine the efficacy and toxicity of this combination after radical resection and D1/D2 lymph node dissection(LND)for patients with locally advanced *** To further determine the efficacy and toxicity of this combination after radical resection and D1/D2 LND for patients with locally advanced *** Forty patients(median age,53 years;range,24-71 years)with pathologically confirmed adenocarcinoma who underwent D1/D2 LND were included in this *** patients received ACRT comprising IMRT(total irradiation dose:45 Gy delivered in daily 1.8-Gy fractions on 5 d a week over 5 wk)and capecitabine chemotherapy(dose:800 mg/m²twice daily throughout the duration of radiotherapy).The primary study endpoint was disease-free survival(DFS),and the secondary endpoints were overall survival(OS),toxic effects,and treatment *** The 3-year DFS and OS were 66.2%and 75%,*** median time to recurrence was 19.5 mo(range,6.1-68 mo).Peritoneal implantation(n=10)was the most common recurrence pattern,and the lung was the most common site of extra-abdominal metastases(n=5).Nine patients developed grade 3 or 4 toxicities during *** patients discontinued ACRT,while eleven underwent ACRT without receiving the entire course of *** were no treatmentrelated *** The ACRT protocol described herein showed acceptable safety and efficacy for patients with locally advanced GC who received radical gastrectomy and D1/2 LND.

关键词： Gastric cancer Radiotherapy Chemoradiotherapy Clinical trial Phase II

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Advances of manganese-oxides-based catalysts for indoor formaldehyde removal

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Green Energy & Environment 2023年第3期8卷 626-653页

作者： Jiayu zheng wenkang zhao liyun song Hao wang hui Yan Ge chen Changbao Han Jiujun Zhang Faculty of Materials and Manufacturing Beijing University of TechnologyBeijing100124China Key Laboratory of Beijing on Regional Air Pollution Control and Beijing Key Laboratory for Green Catalysis and Separation Beijing University of TechnologyBeijing100124China College of Sciences&Institute for Sustainable Energy Shanghai UniversityShanghai200444China

Formaldehyde(HCHO)has been identified as one of the most common indoor pollutions *** oxides(MnO_(x))are considered to be a promising catalytic material used in indoor HCHO oxidation removal due to their high catalytic activity,low-cost,and environmentally *** this paper,the progress in developing MnO_(x)-based catalysts for HCHO removal is comprehensively reviewed for exploring the mechanisms of catalytic oxidation and catalytic *** catalytic oxidation mechanisms based on three typical theory models(Mars-van-Krevelen,Eley-Rideal and Langmuir-Hinshelwood)are discussed and ***,the research status of catalytic deactivation,catalysts’regeneration and integrated application of MnO_(x)-based catalysts for indoor HCHO removal are detailed in the ***,the technical challenges in developing MnO_(x)-based catalysts for indoor HCHO removal are analyzed and the possible research direction is also proposed for overcoming the challenges toward practical application of such catalysts.

关键词： Manganese dioxide(MnOx) Formaldehyde(HCHO) Catalytic oxidation Room temperature Indoors

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Ambiently fostering solid electrolyte interphase for low-temperature lithium metal batteries

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Journal of Energy Chemistry 2023年第12期87卷 473-478,I0012页

作者： Jia-yue Duan Jin-xiu chen Fang-Fang wang Jin-Hao Zhang xiao-Zhong Fan liping wang Yingze song Wei Xia Yusheng zhao Long Kong Frontiers Science Center for Flexible Electronics and Xi’an Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710129ShaanxiChina department of Physics Academy for Advanced Interdisciplinary StudiesSouthern University of Science and TechnologyShenzhen 518055GuangdongChina State Key Laboratory of Environment-Friendly Energy Materials School of Materials Science and EngineeringGraphene Joint Innovation CentreSouthwest University of Science and TechnologyMianyang 621010SichuanChina Eastern Institute for Advanced Study Eastern Institute of TechnologyNingbo 315201ZhejiangChina

despite being a leading candidate to meet stringent energy targets,lithium(li) metal batteries(LMBs)face severe challenges at low temperatures such as dramatic increase in impedance,capacity loss and dendrite *** fingerprinting rate-limited factors of low-temperature LMBs would encourage targeted approaches to promote ***,the charge transfer impedance across solid electrolyte interphase(SEI) is identified to restrict battery operation under low temperature,and we propose a facile approach on the basis of ambiently fostering SEI(af-SEI) to facilitate charge *** concept of af-SEI stems from kinetic benefits and structural merits to construct SEI at ambient temperature over low temperature developed SEI that is temporally consuming to achieve steady state and that is structurally defective to incur dendrite *** af-SEI allows ionically conductive and morphologically uniform layer on the anode surface,which exhibits a lower resistance and induces an even deposition of li in the subsequent low temperature battery *** with af-SEI,the LMBs deliver the improved rate performance and prolonged cycle life when subjected to low temperature *** work unveils the underlying causes that limit low temperature LMB performances,and enlightens the facile test protocols to build up favorable SEI,beyond scope of material and morphology design.

关键词： li matel batteries Ambiently fostering SEI Charge transfer impedance Low temperature kinetics

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顶空固相微萃取/气相色谱法快速萃取-解吸土壤中7种芳香族化合物

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分析测试学报 2025年第1期44卷 172-179页

作者：李丙阳王钊陈佳邱洪灯新疆师范大学化学化工学院新疆乌鲁木齐830000 中国科学院兰州化学物理研究所甘肃省天然药物重点实验室甘肃兰州730000

利用氧化石墨烯功能化修饰固相微萃取(GO@SPME)针,结合气相色谱(GC)-氢火焰离子化检测器(FID)建立了检测土壤中7种挥发性芳香烃及其衍生物(包括甲苯、氯苯、乙苯、对二甲苯、邻二甲苯、硝基苯和萘)的快速萃取和解吸策略。考察了萃取液... 详细信息

利用氧化石墨烯功能化修饰固相微萃取(GO@SPME)针,结合气相色谱(GC)-氢火焰离子化检测器(FID)建立了检测土壤中7种挥发性芳香烃及其衍生物(包括甲苯、氯苯、乙苯、对二甲苯、邻二甲苯、硝基苯和萘)的快速萃取和解吸策略。考察了萃取液体积、搅拌速率、萃取温度、加盐量、解吸温度、萃取时间和解吸时间对目标物萃取效果的影响,确定在土壤样品中加入内标物质(氘代甲苯),经甲醇提取,顶空固相微萃取快速富集,再结合GC-FID进行检测,基质匹配内标法定量分析。在优化的实验条件下,该方法在15 s内可实现对目标物的快速萃取与解吸(萃取时间12 s,解吸时间3 s)。土壤样品中7种挥发性芳香烃及其衍生物的线性关系良好,相关系数(r^(2))均不小于0.9989,方法检出限(LOD,S/N=3)为1.71~11.60μg/g,定量下限(LOQ,S/N=10)为5.70~38.67μg/g;在3个不同加标水平(60、120、180μg/g)下的平均回收率为87.3%~109%,相对标准偏差(RSD)不大于12%。该方法前处理简单快速,成本较低,数据稳定可靠,适用于土壤样品中芳香族类化合物的快速检测。

关键词：芳香烃及其衍生物氧化石墨烯顶空固相微萃取气相色谱法快速萃取-解吸策略土壤

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Stability analysis of complex terrain slope based on multi-source point cloud fusion

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Journal of Mountain Science 2022年第9期19卷 2703-2714页

作者： ZAN wen-bo ZHANG wen-jie wang Ning zhao Chun-chen yang Qian li Hao School of Highway Chang’an UniversityXi’an 710064China Research and development Center for Loess Mechanics and Engineering Test Technology Shaanxi Polytechnic InstituteXianyang 712000China School of Automobile Chang’an UniversityXi’an 710064China

Numerical modelling is a common routine for slope stability analysis in the complex terrain,and the accuracy of topographic survey has a great impact on the *** this study,a combination of unmanned aerial vehicle(UAV)photogrammetry and 3D laser scanning technique was first proposed to establish a high-precision digital elevation model(deM),which could be accurate to 0.2 m,fulfilling the engineering ***,a series of 3D/2D finite element models(FEM)were constituted on the basis of deM to investigate the slope stability in the complex *** results indicate that the deformation of complex terrain slope is chiefly triggered by compression-shear failure and the failure zones are mostly distributed on the middle-upper part and the ***,the complex terrain slope is divided into concave,convex,concave-convex and convex-concave slope according to the topographical curvature,and the factor of safety(FOS)is as follows:the maximum value 1.8504 for the concave-convex slope,the minimum value 1.1129 for the convexconcave slope,and the median for either concave or convex *** inflection points and curvature of the slope jointly determine the shape of nonlinear slope,dominating the morphological effect on the slope stability,so the rational use of section morphological effect will be conducive to the overall stability of the *** four representative slopes,the plastic deformation first emerges into the middle,then progressively develops to the upper,and finally forms the connected failure zones.

关键词： Slope stability Complex terrain deM Numerical simulation Plastic zone Factor of Safety

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