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Advances of graphdiyne-supported metal catalysts in thermocatalytic reactions

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Nano Research 2024年第4期17卷 2223-2233页

作者： Jia Yu Yida Yang Yuliang li Changyan Cao {2. Song Beijing National Laboratory for Molecular sciences CAS Research/Education Center for Excellence in Molecular SciencesLaboratory of Molecular Nanostructures and NanotechnologyInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical sciences University of Chinese Academy of SciencesBeijing 100049China Beijing National Laboratory for Molecular sciences CAS Research/Education Center for Excellence in Molecular SciencesLaboratory of organic solidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China

Supported metal catalysts are widely used in the modern chemical *** electronic interaction between supports and active components is of great significance for heterogeneous ***(GDY),a new type of carbon allotrope with sp-hybridized carbon atoms,πconjugate structure,and electron transmission capability,is a promising candidate as catalyst *** years have witnessed the rapid progress of GDY-supported metal catalysts for different catalysis *** that most processes in the current chemical industry are thermocatalytic reactions,we herein give an overview about the advances and particular characteristics of GDY-supported catalysts in these *** geometric structure and electronic properties of GDY are first ***,the synthesis methods for GDY-supported metal catalysts and their applications in thermocatalytic reactions are discussed,in which the effect of electronic interaction on catalytic performance is ***,the current challenges and future directions of GDY-supported metal catalysts for thermocatalysis are *** is expected that this review will enrich our understanding of the advances of GDY as a superior support for metal catalysts in thermocatalytic reactions.

关键词： graphdiyne metal catalysts thermocatalytic reactions heterogeneous catalysis

Compression behavior of Zr_(41)Ti_(14)Cu_(12.5)Ni_(10)Be_(2..5) bulk metallic glass up to 2. GPa

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Science china(physics,Mechanics & Astronomy) 2005年第3期48卷 319-324页

作者： li Gong 1, 2., ZHAN Zaiji 2., liU Jing 3 , YUN Jinku 1 , SUN liling 2., liU Riping 1 , ZHANG Jun 2.& WANG Wenkui 1, 2.1. Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, china 2. Center for Condensed Matter physics, institute of physics, chinese academy of sciences, Beijing 100080, china 3. BSRF, institute of {12. energy physics, chinese academy of sciences, Beijing 100039, china 1. Key Laboratory of Metastable Materials Science and Technology Yanshan University 066004 Qinhuangdao China 2. Center for Condensed Matter physics Institute of Physics Chinese Academy of Sciences 100080 Beijing China 3. BSRF Institute of High Energy Physics Chinese Academy of Sciences 100039 Beijing China

The compression of a Zr41Ti14Cu12.5Ni10Be2..5 bulk metallic glass (BMG) is investigated at room temperature up to 2. GPa using in-situ high pressure {2. dispersive X-ray diffraction with a synchrotron radiation source. The pressure-induced structural relaxation is exhibited. It is found that below about 8 GPa, the existence of excess free volume contributes to the rapid structural relaxation, which gives rise to the rapid volumetric change, and the structural relaxation results in the structural stiffness under higher pressure.

关键词： bulk metallic glass, high pressure, structural relaxation, synchrotron radiation.

Geochemical characteristics of rare earth elements in Wuhan section of the Yangtze River

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Journal of Environmental sciences 1995年第1期7卷 44-51页

作者： Wang lijun Zhang Shen Zhang Chaosheng(institute of Geography,{2. academy of sciences,Beijing 100101,china)li Xiuxia(institute of high energy physics,{2. academy of sciences,Beijing 100080,china) Inst of Geog Chinese Academy of Sciences Beijing China China

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关键词： geochemical characteristics rare earth elements Yangtze River

Systematic distortion in cosmic microwave background maps

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Science china(physics,Mechanics & Astronomy) 2009年第5期52卷 804-808页

作者： liU Hao 1,3 &li TiPei 1,2.1Key Laboratory of Particle Astro{2.,institute of high energy {2.,chinese academy of sciences,Beijing 100049,china 2.enter for Astro{2.,Tsinghua University,Beijing 100084,china 3 Graduate University of chinese academy of sciences,Beijing 100049,china Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China Center for Astrophysics Tsinghua University Beijing 100084 China Graduate University of chinese academy of sciences Beijing 100049 China

To minimize instrumentally the induced systematic errors,cosmic microwave background(CMB)anisotropy experiments measure temperature differences across the sky using pairs of horn antennas, temperature map is recovered from temperature difference obtained in sky survey through a map-making *** inspect and calibrate residual systematic errors in the recovered temperature maps is important as most previous studies of cosmology are based on these *** analyzing pixel-ring coupling and latitude dependence of CMB temperatures,we find notable systematic devia- tion from CMB Gaussianity in released Wilkinson Microwave Anisotropy Probe(WMAP)*** detected deviation cannot be explained by the best-fit LCDM cosmological model at a confidence level above 99%and cannot be ignored for a precision cosmology study.

关键词： cosmology cosmic microwave background methods data analysis

Temperature-Dependent Tearing Behavior of Rubber Materials:Characterization and Modeling

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Acta Mechanica Solida Sinica 2024年第2期37卷 316-326页

作者： Qinyuan Yao Feilong Zhang Pan Dong Ziyuan Zhao Yi He weiguo li liming Chen State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing400044China College of Aerospace Engineering Chongqing UniversityChongqing400044China

With the increasingly widespread application of rubber in many fields,there is a growing demand for quantitative characterization of temperature-dependent mechanical properties in high-temperature service *** critical tearing {2. is an important criterion for determining whether rubber materials will experience tearing instability,while tear strength is a key parameter for rubber materials to resist *** is necessary to quantitatively characterize their evolution with *** theoretical research mainly relies on fitting a large amount of experimental data,which is not convenient for engineering ***,in this work,a temperature-dependent critical tearing {2. model is firstly developed based on the force-heat equivalence {2. density *** model considers the equivalent relationship between the critical tearing {2. required for crack instability propagation and the thermal {2. stored in the rubber *** is demonstrated that our model has higher prediction accuracy when compared to other ***,combining with the Griffith fracture theory,temperature-dependent tear strength models applicable to three different crack modes are separately *** models are validated using experimental data for Mode I opening cracks and ModeⅢtearing cracks,and good consistency is ***,a quantitative analysis of the influence of elastic modulus on tear strength at different temperatures is *** work provides a reliable way for predicting temperature-dependent tearing instability behavior and offers beneficial suggestions for improving the tear strength of rubber materials at different temperatures.

关键词： Temperature-dependent Critical tearing energy Tear strength Rubber Theoretical model

energy dissipation mechanism and ballistic characteristic optimization in foam sandwich panels against spherical projectile impact

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Defence Technology（防务技术） 2024年第5期35卷 108-122页

作者： Jianqiang Deng Tao liu liming Chen Xin Pan Jingzhe Wang Shaowei Zhu {2. li College of Aerospace Engineering Chongqing UniversityChongqing 400030China State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing 400030China Chongqing Key Laboratory of Heterogeneous Material Mechanics Chongqing UniversityChongqing 400030China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China

This study systematically examines the energy dissipation mechanisms and ballistic characteristics of foam sandwich panels(FSP)under {2.-velocity impact using the explicit non-linear finite element *** on the geometric topology of the FSP system,three FSP configurations with the same areal density are derived,namely multi-layer,gradient core and asymmetric face sheet,and three key structural parameters are identified:core thickness(t_(c)),face sheet thickness(t_(f))and overlap face/core number(n_(o)).The ballistic performance of the FSP system is comprehensively evaluated in terms of the ballistic limit velocity(BLV),deformation modes,energy dissipation mechanism,and specific penetration energy(SPE).The results show that the FSP system exhibits a significant configuration dependence,whose ballistic performance ranking is:asymmetric face sheet>gradient core>*** mass distribution of the top and bottom face sheets plays a critical role in the ballistic resistance of the FSP *** BLV and SPE increase with tf,while the raising tcor noleads to an increase in BLV but a decrease in ***,a face-core synchronous enhancement mechanism is discovered by the energy dissipation analysis,based on which the ballistic optimization procedure is also conducted and a design chart is *** study shed light on the anti-penetration mechanism of the FSP system and might provide a theoretical basis for its engineering application.

关键词： Sandwich panel Numerical simulation Ballistic resistance Specific penetration energy energy analysis

Formation of super-concentrated hydrochloric acid in the third phase in tertiary amine N2.5-PtCl_6^(2.)-HCl system and its influences on the Pt microemulsion extraction

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Science china Chemistry 2009年第11期52卷 1825-1834页

作者： HUANG Kun1,CHEN Jing1,ZHANG ChengFeng1,2.li ZhiHong3,PAN QingHua1,SUN Yan1,liU ShaoXuan1,liU XueXin2.li WeiHong1,YANG ZhanLan1,WENG ShiFu1,HU TianDou3,XU YiZhuang1 & WU JinGuang1 1 College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,china 2.institute of Chemistry,chinese academy of sciences,Beijing 100190,china 3 institute of high {12. physics,chinese academy of sciences,Beijing 100049,china 1. College of Chemistry and Molecular Engineering Peking University Beijing 100871 China 2. institute of Chemistry Chinese Academy of Sciences Beijing 100190 China 3. institute of high {2. physics Chinese Academy of Sciences Beijing 100049 China

In this paper,we have investigated the formation of the third-phase in tertiary amine(N2.5)-PtCl62.-HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occurrence of the *** third-phase is characterized by various spectroscopic techniques,and the small angle X-ray scattering(SAXS) experiments demonstrate the appearance of nano-aggregates,i.e.,water-in-oil reversed micelles,in the third *** experimental results indicate that(1) formation of the third phase is related to the aggregation behaviors of nano-reversed micelles in which a super-concentrated hydrochloric acid formed with the H+ to H2. molar ratio being much higher than that of the conventional 37 wt% saturated hydrochloric acid.(2. The occurrence of the super-concentrated HCl results in a great amount of H+ and Cl-ions enriched and confined within the nano-water pools of W/O reversed micelles in third ***,the coordination behaviors of platinum complex ions in that super-concentrated hydrochloric acid are very different from their corresponding behaviors in bulk aqueous *** is possible that H+ ions participate in the formation of such complexes as HmPtCl6z+ in the super-concentrated hydrochloric acid.(3) The relative contents of various HmPtCl6z+ complexes are different corresponding to the H+ ion concentrations in confined nanowater *** association ability of the acidified tertiary amine N2.5 molecules(R3NH+) with various HmPtCl6z+ complexes plays an important role in affecting the platinum extraction behaviors.

关键词： solvent extraction third phase super-concentrated hydrochloric acid tertiary amine platinum

Patterns of platinum-group elements in mantle peridotite, granulite xenoliths and basalt in Hannuoba

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chinese Science Bulletin 1999年第18期44卷 1676-1681页

作者： CHU Xuelei, li Xiaolin, XU Jiuhua and liU Jianming1. The Research Center of Mineral Resources Exploration , chinese academy of sciences , Beijing 100101, china 2. institute of Geology , chinese academy of sciences , Beijing 10002., china 3. institute of high energy physics , chinese academy of sciences , Beijing 100817 , china 4. Beijing University of Science and Engineering , Beijing 100083, china Corresponding author The Research Center of Mineral Resources Exploration Chinese Academy of Sciences Beijing China institute of Geology Chinese Academy of Sciences Beijing China institute of high {2. physics Chinese Academy of Sciences Beijing China Beijing University of Science and Engineering Beijing China

Neutron activation analysis after preconcentration of nickel sulfide fire assay was used in measurement of Ru, Ph, Pd, Os, Ir, Pt (i.e. PGE elements) and Au concentrations for basalt, mantle and granulite xenoliths in Hannuoba. The chondrite- and primitive mantle-normalized PGE patterns generally exhibit flat (for Iherzolite), negative slope (for harzburgite),

关键词： mantle xenolith granulite xenolith basalt platinum-group element Hannuoba.

New evidence for lack of CMB power on large scales

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Science china(physics,Mechanics & Astronomy) 2010年第3期53卷 567-570页

作者： liU Hao1 & li TiPei1,2.3 1 Key Laboratory of Particle Astro{2., institute of high energy {2., chinese academy of sciences, Beijing 100049, china 2.Department of {2. & Center for Astro{2., Tsinghua University, Beijing 100084, china 3 Department of Engineering {2. & Center for Astro{2., Tsinghua University, Beijing 100084, china 1. Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China2. Department of Physics & Center for Astrophysics Tsinghua University Beijing 100084 China3. Department of Engineering Physics & Center for Astrophysics Tsinghua University Beijing 100084 China

A digitalized temperature map is recovered from the first light sky survey image published by the Planck team, from which an angular power spectrum of the cosmic microwave background (CMB) is derived. The amplitudes of the low multipoles (low-l) measured from the preliminary Planck power spectrum are significantly lower than those reported by the WMAP team. Possible systematical effects are far from enough to explain the observed low-l differences.

关键词： cosmology cosmic microwave background data analysis