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Formation of super-concentrated hydrochloric acid in the third phase in tertiary amine N235-PtCl_6^(2-)-HCl system and its influences on the Pt microemulsion extraction

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Science china Chemistry 2009年第11期52卷 1825-1834页

作者： HUANG Kun1,CHEN Jing1,ZHANG ChengFeng1,2,li ZhiHong3,PAN QingHua1,SUN Yan1,liU ShaoXuan1,liU XueXin2,li WeiHong1,YANG ZhanLan1,WENG ShiFu1,HU TianDou3,XU YiZhuang1 & WU JinGuang1 1 College of Chemistry and Molecular Engineering,Peking University,beijing 100871,china 2 institute of Chemistry,chinese academy of sciences,beijing 100190,china 3 institute of high energy physics,chinese academy of sciences,beijing 100049,china College of Chemistry and Molecular Engineering Peking University Beijing China institute of Chemistry Chinese Academy of Sciences Beijing China institute of high energy physics Chinese Academy of Sciences Beijing China

In this paper,we have investigated the formation of the third-phase in tertiary amine(N235)-PtCl62--HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occurrence of the *** third-phase is characterized by various spectroscopic techniques,and the small angle X-ray scattering(SAXS) experiments demonstrate the appearance of nano-aggregates,i.e.,water-in-oil reversed micelles,in the third *** experimental results indicate that(1) formation of the third phase is related to the aggregation behaviors of nano-reversed micelles in which a super-concentrated hydrochloric acid formed with the H+ to H2O molar ratio being much higher than that of the conventional 37 wt% saturated hydrochloric acid.(2) The occurrence of the super-concentrated HCl results in a great amount of H+ and Cl-ions enriched and confined within the nano-water pools of W/O reversed micelles in third ***,the coordination behaviors of platinum complex ions in that super-concentrated hydrochloric acid are very different from their corresponding behaviors in bulk aqueous *** is possible that H+ ions participate in the formation of such complexes as HmPtCl6z+ in the super-concentrated hydrochloric acid.(3) The relative contents of various HmPtCl6z+ complexes are different corresponding to the H+ ion concentrations in confined nanowater *** association ability of the acidified tertiary amine N235 molecules(R3NH+) with various HmPtCl6z+ complexes plays an important role in affecting the platinum extraction behaviors.

关键词： solvent extraction third phase super-concentrated hydrochloric acid tertiary amine platinum

Patterns of platinum-group elements in mantle peridotite, granulite xenoliths and basalt in Hannuoba

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chinese Science Bulletin 1999年第18期44卷 1676-1681页

作者： CHU Xuelei, li Xiaolin, XU Jiuhua and liU Jianming1. The Research Center of Mineral Resources Exploration , chinese academy of sciences , beijing 100101, china 2. institute of Geology , chinese academy of sciences , beijing 100029, china 3. institute of high energy physics , chinese academy of sciences , beijing 100817 , china 4. beijing University of Science and Engineering , beijing 100083, china Corresponding author The Research Center of Mineral Resources Exploration Chinese Academy of Sciences Beijing China institute of Geology Chinese Academy of Sciences Beijing China institute of high energy physics Chinese Academy of Sciences Beijing China beijing University of Science and Engineering Beijing China

Neutron activation analysis after preconcentration of nickel sulfide fire assay was used in measurement of Ru, Ph, Pd, Os, Ir, Pt (i.e. PGE elements) and Au concentrations for basalt, mantle and granulite xenoliths in Hannuoba. The chondrite- and primitive mantle-normalized PGE patterns generally exhibit flat (for Iherzolite), negative slope (for harzburgite),

关键词： mantle xenolith granulite xenolith basalt platinum-group element Hannuoba.

IMAGING IN high energy ASTRONOMY

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空间科学学报 1998年第S1期18卷 12-20页

作者： li Ti-pei (institute of high Enerpy physics, The chinese academy of sciences, beijing 100039)

Space research is usually costly, and this restricts participation of developing countries. With traditional techniques one must construct high resolution instrument,more and more complicated and expensive, to obtain high resolution results from space observations. It is a difficult task to make observations with both high sensitivity and high resolution. Applying advanced inversion technique, one can subtract more information from old data in public domain,and, furthermore, conduct high sensitive and high-resolution experiments with low-cost low-resolution instruments. So developing and applying data analysis technique is of great importance for developing countries to do basic space *** this paper we summarize efforts of chinese scientists in recent years along this direction on imaging in space high energy astronomy.

关键词： Space astronomy Astronomical satellite Imaging

The rms-flux relation of Cyg X-2 in the horizontal branch

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中国科学：物理学、力学、天文学英文版 2010年第S1期53卷 86-90页

作者： li ZhiBing,LEI YaJuan,QU JinLu,ZHANG Shu & SONG liMing Key Laboratory for Particle Astrophysics,institute of high energy physics,chinese academy of sciences(CAS),beijing 100049,china Key Laboratory for Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences (CAS) Beijing China

We have investigated the relation between the root mean square(rms) variability and the X-ray flux(rms-flux relation) of the Z source Cyg X-2,and as well the energy dependence based on the Rossi X-ray Timing Explorer(RXTE) *** currently focus on the horizontal branch(HB),due to the negative correlation in flux of the soft and the hard *** rms-flux correlation has energy dependence as follows:positive at hard X-rays(above 10 keV) but negative at soft X-rays(below 10 keV).This provides a feature different from the previous one,and may be suggestive of different origins of X-rays below and above 10 ***,the overall spectrum can be well fitted with a model consisting of a blackbody and Comptonization components,but the fitting results do not reveal any features around 10 keV that could account for such a change in the rms-flux relation.

关键词： accretion accretion disk—binaries:close-stars:individual(Cygnus X-2)-X-rays:binaries

Electrochemical properties and interfacial reactions of liNi0.5Mn1.5O4-δ nanorods

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Progress in Natural Science:Materials International 2012年第3期22卷 207-212页

作者： liping Wang, Hong li, Xuejie Huang institute of physics, chinese academy of sciences, beijing 100190, china institute of physics Chinese Academy of Sciences Beijing 100190 China

liNi0.5Mn1.5O4-δ which possesses a high voltage of 4.7 V vs. lit/li and stable structure has been considered as a promising cathode material for high energy li-ion batteries. In this study, well-crystallized liNi0.5Mn1.5O4-δ nanorods with diameter of ～50 nm and length of ～500 nm were synthesized by a hydrothermal-solid state process followed by a lithiation reaction. It delivers ～120 mA h-g 1 discharge capacity under 30 mA g-1 at 3.5-4.9 V, and 90 mA h g-1 at 150 mA g-1. An unstable solid electrolyte interphase (SEI) film with thickness 2-10 nm was observed by transmission electron microscopy. The thick and unstable SEI layers are responsible for its low rate performance and low coulombic efficiency during cycling.

关键词： lithium ion battery high voltage spinel Nanorods Surface reaction

Bifurcation timescales in power spectra of black hole binaries and ultraluminous X-ray sources

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Science china(physics,Mechanics & Astronomy) 2010年第S1期53卷 177-182页

作者： WANG TaiShan1 & li TiPei1,2 1 Department of physics & Center for Astrophysics,Tsinghua University,beijing 100084,china 2 Key Laboratory of Particle Astrophysics,institute of high energy physics,chinese academy of sciences,beijing 100049,china Department of physics & Center for Astrophysics Tsinghua University Beijing China Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing China

For black hole binaries(BHBs) and active galactic nuclei(AGNs),bifurcation timescales(BTs) Δtb exist,below which time-domain power is significantly higher than the corresponding Fourier ***-periodic oscillations(QPOs) are removed from the Fourier spectra of BHBs.A relationship between BT,black hole mass and bolometric luminosity is *** anti-correlation between BT and luminosity of Cyg X-1 is *** removing the QPOs,BTs are also obtained for two ultraluminous X-ray sources(ULXs),M82 X-1 and NGC5408 *** results support that they harbor intermediate mass black holes(IMBHs).

关键词： black hole binary ultraluminous X-ray source power spectral density data analysis

Timing in the Time Domain: Cygnus X-1

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chinese Journal of Astronomy and Astrophysics 2001年第4期1卷 313-332页

作者： Ti-Pei li (Department of physics and Center for Astrophysics, Tsinghua University, beijing 100084 high energy Astrophysics Lab., institute of high energy physics, chinese academy of sciences, beijing 100039)E-mail:litp@*** Department of physics and Center for Astrophysics Tsinghua University Beijing 100084 High Energy Astrophysics Lab. Institute of High Energy Physics Chinese Academy of Sciences Beijing 100039

Quantities characterizing temporal property, e.g., power density, coherence, and time lag, can be defined and calculated directly in the time domain without using the Fourier transformation. Spectral hardness, variability duration, and correlation between different characteristic quamtities on different time scale can be studied in the time domain as well. The temporal analysis technique in the time domain is a powerful tool, particularly in studying rapid variability on short time scales (or in high frequencies). Results of studying variabilities of X-rays from Cyg X-1 with the analysis technique in the time domain and RXTE data reveal valuable clues to understanding production and propagation processes of X-rays and structure of accretion disk in the black hole system.

关键词： methods: data analysis - stars: individual (Cygnus X-1) - X-rays: stars

Inconsistency between WMAP data and released map

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chinese Science Bulletin 2010年第10期55卷 907-909页

作者： liU Hao1 & li TiPei1,2,3 1 Key Laboratory of Particle Astrophysics,institute of high energy physics,chinese academy of sciences,beijing 100049,china 2 Department of physics & Center for Astrophysics,Tsinghua University,beijing 100084,china 3 Department of Engineering physics & Center for Astrophysics,Tsinghua University,beijing 100084,china Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Beijing China Department of physics & Center for Astrophysics Tsinghua University Beijing China Department of Engineering physics & Center for Astrophysics Tsinghua University Beijing China

A remarkable inconsistency between the calibrated differential time-ordered data (TOD) of the Wilkinson Microwave Anisotropy Probe (WMAP) mission,which is the input for map-making,and the cosmic microwave background (CMB) temperature maps published by the WMAP team is revealed,indicating that there must exist a serious problem in the map making routine of the WMAP *** inconsistency is easy to be confirmed without the use of WMAP map-making *** view of the importance of this issue for cosmology study,we invite readers to check it by themselves.

关键词：威尔金森微波各向异性探测器 WMAP 地图制作宇宙微波背景有序数据制作软件 TOD CMB

Synthesis of spherical nano-ZSM-5 zeolite with intergranular mesoporous for alkylation of ethylbenzene with ethanol to produce m-diethylbenzene

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chinese Journal of Chemical Engineering 2024年第3期67卷 298-309页

作者： Siyue Wang Jinhong li Qingxin Xu Shengjie Song Yu'ni Jiang lidong Chen Xin Shi weiguo Cheng Faculty of Chemistry and Chemical Engineering Liaoning Normal UniversityDalian 110629China beijing Key Laboratory of Ionic liquids Clean Process Key Laboratory of Green Process and EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Catalytic synthesis of m-diethylbenzene(m-DEB)through alkylation of ethylbenzene(EB)may be a promising alternative route in comparison with traditional rectification of mixed DEB,for which the top priority is to develop efficient and stable heterogeneous ***,the spherical nano-ZSM-5 zeolite with abundant intergranular mesoporous is synthesized by the seed-mediated growth method for alkylation of EB with ethanol to produce *** results show that the spherical nano-ZSM-5 zeolite exhibits better stability and higher alkylation activity at a lower temperature than those of commercial micropore *** then,the spherical nano-ZSM-5 is further modified by La_(2)O_(3) through acid treatment followed by immersion *** acid treatment causes nano-ZSM-5 to exhibit the increased pore size but decreased the acid sites,and subsequent La_(2)O_(3) loading reintroduces the weak acid *** a result,the HNO_(3)-La_(2)O_(3)-modified catalyst exhibits a slight increase in EB conversion and DEB yield in comparison with unmodified one,and meanwhile,it still maintains high m-DEB *** catalyst after acid treatment achieves higher catalytic stability besides maintaining the high alkylation activity of EB with *** present study on the spherical nano-HZSM-5 zeolite and its modification catalyst with excellent alkylation ability provides new insights into the production of mDEB.

关键词： Zeolite Modification Alkylation reaction m-diethylbenzene Catalyst Fixed-bed