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A highly sensitive multiple-mode optical thermometer designed in Eu^(2+/3+)and li^(+)co-doped polymorphism compound LaSc_(3)(BO_(3))_(4)

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Journal of Advanced Ceramics 2024年第6期13卷 821-833页

作者： Nan Yang Zhuo li Tingxia Zhou Ziwang Zhang Wen shi Yexiang Tong Jianxin shi School of Chemistry IGCMESun Yat-sen UniversityGuangzhou 510006China MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry IGCMEThe Key Lab of Low-Carbon Chemistry&Energy Conservation of Guangdong ProvinceSun Yat-sen UniversityGuangzhou 510006China

Noncontact optical thermometers have attracted widespread attention,but existing problems such as single-mode and low-sensitivity thermometers still urgently need to be ***,a novel multiple-mode thermometer was designed for the polymorphism LaSc_(3)(BO_(3))_(4):Eu^(2+/3+),li^(+).X-ray diffraction(XRD)patterns revealed a slight transition betweenα-andβ-phases with the concentrations of the dopants,which is further proved by structure refinements and first-principles *** coexistence of Eu^(2+)and Eu^(3+)in the phosphors and their relative percentages were confirmed by X-ray absorption near-edge structure(XANES)*** from appropriate emissions from Eu^(2+)and Eu^(3+)without obvious energy transfer and their opposite changing trends with temperatures under 307 nm excitation,a triple-mode optical thermometer is obtained for this material within the temperature range of 150–450 *** highest sensitivities of 27.65,14.05,and 7.68%·K^(−1)are achieved based on two fluorescence intensity ratio(FIR)modes of Eu^(2+)and Eu^(3+)(5d–4f/^(5)D_(0)–^(7)F_(2,4))and the fluorescence lifetime(FL)mode of Eu^(2+),*** the best of our knowledge,the former is almost the highest in Eu^(2+)and Eu^(3+)co-doped *** results indicate that this material may be used as an excellent multiple-mode optical thermometer.

关键词： phase transition europium(Eu)ions multiple-mode optical thermometer thermal quenching properties fluorescence intensity ratio(FIR) fluorescence lifetime(FL)

Competitive Complexation of Copper and Zinc by Sequentially Extracted Humic Substances from Manure Compost

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Agricultural Sciences in China 2008年第10期7卷 1253-1259页

作者： liU Shuai WANG Xu-dong LU li-lan DIAO shi-rong ZHANG Jun-feng College of Resources and Environment Northwest A ＆ F University Yangling 712100 P.R.China

Chicken manure with similar content of copper and zinc was changes of organic carbon and humus substance complexed chosen to conduct a composting experiment to investigate the copper （HS-Cu） and zinc （HS-Zn）, which were extracted by water （H2O）, sodium hydroxide （NaOH）, and sodium pyrophate-NaOH mixture （Na4P2O7-NaOH）, sequentially. Distributions of copper and zinc in fulvic acids （FA） and humic acids （HA） in the three extracts were studied. During manure composting, the concentrations of copper and zinc increased from about 500 mg kg^-1 in the raw material to 1 100 mg kg^-1 in the final products. HS-Cu in H2O, NaOH, and Na4P2O7-NaOH extracts occupied 6.7, 26.7, and 19% averagely of total copper and HS-Zn represented 2.7, 13.7, and 17% averagely of total zinc in compost, respectively. In water extracts, both HA and FA mainly complexed with Cu and the mole ratio of Cu to Zn was 2.8 in HA fractions and was 2.6 in FA fractions, respectively. HA mainly complexed with copper, so that the ratios of HA-Cu to HA-Zn averaged 3.4 in NaOH extracts. FA had a similar potential to complex with copper and zinc, so that the ratio of FA-Cu to FA-Zn was close to 1. In Na4P2O7-NaOH extracts, HA or FA had a similar potential to complex with copper and zinc. The ratio of HS-Cu to HS-Zn was close to 1. With manure composting, Na4P2O7-NaOH extractable HS-Zn increased to a level as high as HS-Cu. This indicated that more and more stable complexes of HS-Zn were formed in the late decomposition period. The competition between copper and zinc to be complexed with humic substance became weaker and weaker with the decomposition process.

关键词： manure copper and zinc decomposition process humic substance sequential extraction

Enhanced Electrochemical Properties and Optimized li^(+)Transmission Pathways of PEO/LLZTO-Based Composite Electrolytes Modified by Supramolecular Combination

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Energy & Environmental Materials 2024年第1期7卷 238-246页

作者： Zhengyi Lu lin Peng Yi rong Enli Wang Ruhua shi Hongxun Yang Yadong Xu Ruizhi Yang Chao Jin College of Energy Soochow Institute for Energy and Materials InnovationsSoochow UniversitySuzhou 215006China Jiangsu Runchao Energy Storage Technology Co. LtdZhenjiang 212050China

Poly(ethylene oxide)(PEO)and li_(6.75)La_(3)Zr_(1.75)Ta_(0.25)O_(12)(LLZTO)-based composite polymer electrolytes(CPEs)are considered one of the most promising solid electrolyte ***,agglomeration of LLZTO within PEO and lack of li^(+)channels result in poor electrochemical ***,a functional supramolecular combination(CD-TFSI)consisting of activeβ-cyclodextrin(CD)supramolecular with self-assembled liTFSI salt is selected as an interface modifier to coat LLZTO *** from vast H-bonds formed betweenβ-CD and PEO matrix and/or LLZTO,homogeneous dispersion and tight interface contact are ***,^(6)li NMR spectra confirm a new li^(+)transmission pathway from PEO matrix to LLZTO ceramic then to PEO matrix in the as-prepared PEO/LLZTO@CD-TFSI CPEs due to the typical cavity structure ofβ-*** a proof,the conductivity is increased from 5.3×10^(-4)S cm^(-1)to 8.7×10^(-4)S cm^(-1)at 60℃,the li^(+)transference number is enhanced from 0.38 to 0.48,and the electrochemical stability window is extended to 5.1 V versus li/li^(+).li‖liFePO_(4)CR2032 coin full cells and pouch cells prove the practical application of the as-prepared PEO/LLZTO@CD-TFSI *** work offers a new strategy of interface modifying LLZTO fillers with functional supramolecular combination to optimize PEO/LLZTO CPEs for solid lithium batteries.

关键词： conductivity interfacial stability LLZTO fillers modification PEO matrix

THE FLOW PATTERNS OF BUBBLE PLUME IN AN MBBR

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Journal of Hydrodynamics 2011年第4期23卷 510-515页

作者： li shi-rong CHENG Wen WANG Meng CHEN Chen Key Laboratory of Northwest Water Resources and Environmental Ecology of Ministry of Education Xi＇an University of Technology Xi＇an 710048 China Oil Production Plant of No. 4 Changqing Oilfield Company China National Petroleum Corporation Jing Bian 718500 China

The flow patterns of the gas-liquid two-phase flow in a Moving-Bed Biofilm Reactor （MBBR） have a critical effect upon the mass transfer by the convection. Bubble plumes promote unsteadily fluctuating two-phase flows during the aeration. This article studies the unsteady structure of bubble plumes through experiments. The time-serial bubble plume images in various cases of the tank are analyzed. The Recursive Cross Correlation-Particle Image Velocimetry （RCC-PIV） is used to calculate the velocities in those cases, and then the time-serial vortex, the total turbulence intensity, the time-serial streamline are obtained. It is shown that the aspect ratio and the void fraction are the dominant factors influencing the unsteady structure of bubble plumes. When the aspect ratio is unity and the void fraction is high, the bubble plumes see a symmetrical vortex structure with a long residence time, which is beneficial for optimizing the aeration system and enhancing the applied range of bubble plumes.

关键词： bubble plume Recursive Cross Correlation (RCC) Particle Image Velocimetry (PIV) flow pattern

Optimal geometrical configuration and oxidation state of cobalt cations in spinel oxides to promote the performance of li-O_(2) battery

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Nano Research 2024年第1期17卷 221-227页

作者： Yu Zhang Shuting Zhang Mengwei Yuan Yufeng li rong liu Caiyun Nan Chen Chen Engineering Research Center of Advanced Rare Earth Materials Department of ChemistryTsinghua UniversityBeijing 100084China Beijing Key Laboratory of Energy Conversion and Storage Materials Institution College of ChemistryBeijing Normal UniversityBeijing 100875China X-ray diffraction Lab Analytical and Testing CenterBeijing Normal UniversityBeijing 100875China

Co_(3)O_(4) is considered as one of promising cathode catalysts for lithium oxygen(li-O_(2))batteries,which contains both tetrahedral Co^(2+)sites(Co^(2+)Td)and octahedral Co^(3+)sites(Co^(3+)Oh).It is important to reveal the effect of optimal geometric configuration and oxidation state of cobalt ion in Co_(3)O_(4) to improve the performance of li-O_(2) ***,through regulating the synthesis process,Co^(2+)and Co^(3+)sites in Co_(3)O_(4) were replaced with Zn and Al atoms to form materials with a unique Co *** li-O_(2) batteries based on ZnCo_(2)O_(4) showed longer cycle life than that of CoAl_(2)O_(4),suggesting that in Co_(3)O_(4),the Co^(3+)Oh site is a relatively better geometric configuration than Co^(2+)Td site for li-O_(2) *** calculations revealed that Co^(3+)Oh sites provide higher catalysis activity,regulating the adsorption energy of the intermediate liO_(2) and accelerating the kinetics of the reaction in batteries,which further leads to the change of the morphology of the discharge product and ultimately improves the electrochemical performance of the batteries.

关键词： lithium oxygen(li-O_(2))batteries geometrical configuration oxidation state lithium peroxide

Experimental study on performance that carbon dioxide inhibits coal oxidation and spontaneous combustion

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Journal of Coal Science & Engineering(China) 2011年第3期17卷 326-330页

作者： DENG Jun li shi-rong ZHANG Yan-ni MU Ying ZHANG Yang Key Laboratory of Western Mine Exploitation and Hazard Prevention of Ministry of Education School of Energy Engineering Xi＇an University of Science and Technology Xi＇an 710038 China Yangquan Detachment of Shanxi Fire Bureau Yangquan 045000 China College of Humanities and Foreign Languages Xi ＇an University of Science and Technology Xi ＇an 710038 China China Coal Research Institute Beijing 100013 China

Adopting oil-bath temperature programming experiment and gas chromatography, CO2＇s inhibitory performance on spontaneous combustion of Tingnan Coal Mine sample was analyzed. Through temperature rise rate test experiment, the accuracy, stability and reliability of the improved oil-bath temperature programming system applied in this experiment was proved to be superior to the traditional system. Spontaneous combustion characters parameters test of coal sample in pure air was carried out with this system and offered comparison standard for research in next stage. Temperature programming to coal sample was further conducted in oil-bath with different concentration of CO2. Testing results are compared with parameters of concentration of CO, O2, temperature, CO generation rate and O2 consumption rate tested and calculated in previous experiment in pure air. Methods of proportioning between concentration of CO and O2, CO concentration and temperature, CO generation rate and O2 consumption rate were applied to eliminate obstructions from certain external factors such as inlet of CO2; meanwhile influences of CO2 of different concentrations to coal oxidation and spontaneous combustion were investigated. Also CO2 inhibition technique was used in spontaneous combustion prevention in workface No. 106 of Tingnan Coal Mine, data collected from which indicate that CO2 performs well in inhibiting coal oxidation and spontaneous combustion.

关键词： carbon dioxide (CO2) coal spontaneous combustion fire disaster

APC gene mutations in Chinese familial adenomatous polyposis patients

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World Journal of Gastroenterology 2010年第12期16卷 1522-1526页

作者： Sheng, Jian-Qiu Cui, Wei-Jia Fu, Lei Jin, Peng Han, Ying li, Shu-Jun Fan, Ru-Ying li, Ai-Qin Zhang, Ming-Zhi li, shi-rong Gen Hosp Beijing Mil Reg Dept Gastroenterol Beijing 100700 Peoples R China Zhengzhou Univ Affiliated Hosp 1 Dept Oncol Zhengzhou 450052 Henan Province Peoples R China

AIM:To study the characteristics of APC(adenomatous polyposis coli)gene germline mutation in Chinese patients with familial adenomatous polyposis(FAP).METHODS:APC gene from 14 FAP families was amplified by polymerase chain reaction(PCR)and underwent direct sequencing to determine the micromutation *** the samples without micromutation,the large fragment deletion of APC gene was examined by multiplex ligation-dependent probe amplification(MLPA).RESULTS:There were gene micromutations in 9 families with a micromutation detection rate of 64.3%(9/14),including 6 frameshift mutations(66.7%),1 nonsense mutation(11.1%)and 2 splicing mutations(22.2%).Large fragment deletions were detected by MLPA in 2 *** total mutation detection rate of micromutations and large fragment deletions was 78.6%(11/14).CONCLUSION:The detection rate of APC gene germline mutation can be improved by direct sequencing combined with MLPA large fragment deletion detection.

关键词： Adenomatous polyposis coli gene Familial adenomatous polyposis Large fragment deletion Multiplex ligation-dependent probe amplification Mutation

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非对称支承弹性杆的热过屈曲

工程力学 2000年第5期17卷 115-120页

作者：李世荣甘肃工业大学基础科学系兰州730050

本文基于轴线可伸长细杆的几何非线性理论，建立了一端固定夹紧另一端固定简支的均匀加热直杆热弹性过屈曲行为的精确数学模型。这是一个包含杆轴线弧长在内的多未知函数的强非线性一阶常微分方程两点边值问题。采用打靶法和解析延拓法... 详细信息

本文基于轴线可伸长细杆的几何非线性理论，建立了一端固定夹紧另一端固定简支的均匀加热直杆热弹性过屈曲行为的精确数学模型。这是一个包含杆轴线弧长在内的多未知函数的强非线性一阶常微分方程两点边值问题。采用打靶法和解析延拓法直接数值求解上述非线性边值问题，获得了杆的热过屈曲状态解，给出了具有不同长细比杆的热过屈曲平衡路径。

关键词：弹性直杆热过屈曲精确模型打靶法数值解非对称

Management of venous stenosis in living donor liver transplant recipients

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World Journal of Gastroenterology 2009年第39期15卷 4969-4973页

作者： Jie Yang Ming-Qing Xu Lu-Nan Yan Wu-Sheng Lu Xiao li Zheng-rong shi Bo li Tian-Fu Wen Wen-Tao Wang Jia-Ying Yang Department of liver and Vascular Surgery West China Hospital Sichuan University Chengdu 610041 Sichuan Province China

AIM:To retrospectively evaluate the management and outcome of venous obstruction after living donor liver transplantation(LDLT).METHODS:From February 1999 to May 2009,1 intraoperative hepatic vein(HV) tension induced HV obstruction and 5 postoperative HV anastomotic stenosis occurred in 6 adult male LDLT *** portal vein(PV) anastomotic stenosis occurred in 1 pediatric left lobe *** ranged in age from 9 to 56 years(median,44 years).An air balloon was used to correct the intraoperative HV *** surgical reoperation,transjugular HV balloon dilatation with stent placement and transfemoral venous HV balloon dilatation was performed for HV stenosis on days 3,15,50,55,and 270 after LDLT,*** dilatation followed with stent placement via superior mesenteric vein was performed for the pediatric PV stenosis 168 d after ***:The intraoperative HV tension was corrected with an air *** recipient who underwent emergent reoperation for hepatic stenosis died of hemorrhagic shock and renal failure 2 d *** balloon dilatation via the transjugular and transfemoral venous approach was technically successful in all *** patient with early-onset HV stenosis receiving transjugular balloon dilatation and stent placement on the 15th postoperative day left hospital 1 wk later and disappeared,while the patient receiving the same interventional procedures on the 50th postoperative day died of graft failure and renal failure 2 wk *** patients with late-onset HV stenosis receiving balloon dilatation have survived for 8 and 4 mo without recurrent stenosis and ascites,*** dilatation and stent placement via the superior mesenteric venous approach was technically successful in the pediatric left lobe LDLT,and this patient has survived for 9 mo without recurrent PV stenosis and ***:Intraoperative balloon placement,emergent reoperation,proper interventional balloon dilatation and

关键词： living donor liver transplantation Venous obstruction Anastomotic stenosis Venoplasty Stent