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Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate li metal batteries

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Chinese Chemical Letters 2024年第6期35卷 239-243页

作者： Long li Kang Yang Chenpeng Xi Mengchao li Borong li Gui Xu Yuanbin Xiao Xiancai Cui Zhiliang liu lingyun li Yan Yu Chengkai Yang Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesSchool of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China College of Material Sciences and Chemical Engineering Harbin Engineering UniversityHarbin 150001China

Side reactions and dendrite growth triggered by the unstable interface and inhomogeneous deposition have become the biggest obstacle to the commercialization for lithium metal *** this study,a highly-chlorinated organic-inorganic hybrid interfacial protective layer is developed by rationally tuning the interfacial passivation and robustness to achieve the convenient and efficient li metal *** polyvinyl chloride(PVC)can effectively resist water and oxygen,which is confirmed by density functional *** organic-dominant solid electrolyte interphases(SEI)with lithium chloride are investigated by the X-ray photoelectron spectroscopy(XPS)with little mineralization of oxide,such as li_(2)O and li_(2)CO_(3).With such artificial SEI,a uniform and dense lithium deposition morphology are formed and an ultra-long stable cycle of over 500 h are achieved even at an ultra-high current density of 10 m A/cm^(2).Moreover,the simple and convenient protected anode also exhibits excellent battery stability when paired with the liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)and liFePO_(4)(LFP)cathode,showing great potential for the commercial application of lithium metal batteries.

关键词： Highly-chlorinated Water/oxygen resistance Stable interphase Dendrite-free lithium metal batteries High-rate

不同滴灌施肥策略对棉花氮素吸收和氮肥利用率的影响

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土壤学报 2007年第4期44卷 702-708页

作者：侯振安李品芳龚江王艳娜中国农业大学资源与环境学院北京100094 石河子大学农学院资源与环境科学系新疆石河子832003

在温室条件下应用15N标记尿素进行了不同滴灌施肥策略对棉花氮素吸收和氮肥利用率影响的盆栽试验。根据滴灌灌水施肥时段的分配,设置四种不同氮肥滴灌施肥策略。研究结果表明,不同滴灌施肥策略显著影响棉花的干物质重和氮素吸收量,棉花... 详细信息

在温室条件下应用15N标记尿素进行了不同滴灌施肥策略对棉花氮素吸收和氮肥利用率影响的盆栽试验。根据滴灌灌水施肥时段的分配,设置四种不同氮肥滴灌施肥策略。研究结果表明,不同滴灌施肥策略显著影响棉花的干物质重和氮素吸收量,棉花的氮素吸收量明显受到根系生长的影响,整株氮素吸收量与根干物质重之间呈显著的正相关关系。在一次灌溉过程中先滴1/2时间的肥液,然后再滴1/2时间清水的施肥策略可显著促进棉花根系的生长,增加棉花的氮素吸收量,减少氮肥在土壤中的残留,提高氮肥利用率。因此,在膜下滴灌条件下采用合适的施肥策略有助于提高肥料的利用效率。

关键词：膜下滴灌棉花 ^15 N 滴灌施肥氮肥利用率

Accelerating lithium-sulfur battery reaction kinetics and inducing 3D deposition of li_(2)S using interactions between Fe_(3)Se_(4)and lithium polysulfides

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Journal of Energy Chemistry 2024年第8期95卷 540-553,I0012页

作者： Yihan lin liheng li Longjie Tan Yongliang li Xiangzhong Ren Peixin Zhang Chuanxin He lingna Sun College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060GuangdongChina

Although lithium-sulfur batteries(LSBs)exhibit high theoretical energy density,their practical application is hindered by poor conductivity of the sulfur cathode,the shuttle effect,and the irreversible deposition of li_(2)*** address these issues,a novel composite,using electrospinning technology,consisting of Fe_(3)Se_(4)and porous nitrogen-doped carbon nanofibers was designed for the interlayer of *** porous carbon nanofiber structure facilitates the transport of ions and electrons,while the Fe_(3)Se_(4)material adsorbs lithium polysulfides(liPSs)and accelerates its catalytic conversion ***,the Fe_(3)Se_(4)material interacts with soluble liPSs to generate a new polysulfide intermediate,li_(x)FeS_(y)complex,which changes the electrochemical reaction pathway and facilitates the three-dimensional deposition of li_(2)S,enhancing the reversibility of *** designed LSB demonstrates a high specific capacity of1529.6 mA h g^(-1)in the first cycle at 0.2 *** rate performance is also excellent,maintaining an ultra-high specific capacity of 779.7 mA h g^(-1)at a high rate of 8 *** investigation explores the mechanism of the interaction between the interlayer and liPSs,and provides a new strategy to regulate the reaction kinetics and li_(2)S deposition in LSBs.

关键词： lithium-sulfur batteries Polysulfide intermediates li_(2)S electrodeposition Interlayers Electrostatic spinning Adsorption Catalysis

EEMD能量熵和奇异值熵与SVM融合的船用空压机故障诊断

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上海海事大学学报 2020年第4期41卷 95-102页

作者：王永坚胡欢欢李品芳集美大学轮机工程学院福建厦门361021

针对船用往复式二级空压机振动信号非线性、非平稳性问题,利用振动信号辨识故障,综合集成经验模态分解(ensemble empirical mode decomposition,EEMD)和支持向量机(support vector machine,SVM)的信号处理优势,提出一种将EEMD能量熵和... 详细信息

针对船用往复式二级空压机振动信号非线性、非平稳性问题,利用振动信号辨识故障,综合集成经验模态分解(ensemble empirical mode decomposition,EEMD)和支持向量机(support vector machine,SVM)的信号处理优势,提出一种将EEMD能量熵和奇异值熵与SVM融合的船用空压机故障诊断方法。模拟正常状态和4种故障状态进行故障诊断实验。采集的振动信号用小波降噪法进行处理。为模拟船用空压机实际工作环境,在EEMD处理过程中加入加性高斯白噪声(信噪比7.5 dB)。以相关性为评价指标选取各状态下本征模态函数(intrinsic mode function,IMF),并以每个IMF的能量熵和奇异值熵作为特征值,采用SVM分类器识别故障。实验表明:与基于经验模态分解(empirical mode decomposition,EMD)和SVM等故障诊断方法相比,该方法能更有效地识别故障。该方法在实船应用中获得较好的诊断效果,可为现代船舶智能故障诊断研究提供参考。

关键词：船用往复式二级空压机集成经验模态分解(EEMD) EEMD能量熵和奇异值熵支持向量机(SVM) 故障诊断

Boosting the performance of liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) electrode by uniform li_(3)PO_(4) coating via atomic layer deposition

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Chinese Chemical Letters 2024年第5期35卷 499-503页

作者： Mingjiao Lu Zhixing Wang Gui Luo Huajun Guo Xinhai li Guochun Yan Qihou li Xianglin li Ding Wang Jiexi Wang School of Metallurgy and Environment Central South UniversityChangsha 410083China BASF ShanShan Battery Materials Co. Ltd.Changsha 410006China Engineering Research Center of the Ministry of Education for Advanced Battery Materials Central South UniversityChangsha 410083China Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy Central South UniversityChangsha 410083China School of Physics and Chemistry Hunan First Normal UniversityChangsha 410205China National and Local Joint Engineering Laboratory for lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China

Ultra-high nickel material is considered to be a promising cathode ***,with the increase of nickel content,the interfacial side reactions between the cathode and electrolyte become increasingly ***,an atomically controllable ionic conductor li_(3)PO_(4)(LPO)coating is deposited on the liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2)(NCM9064)based electrode by the atomic layer deposition *** results shows that the LPO coating is uniformly and densely covered on the surface of secondary particles of NCM9064,helping to prevent the direct contact between the electrolyte and cathode during the chargingdischarging *** addition,the coating layer is electrochemically *** a result,the interfacial side reactions during the long cycle are effectively suppressed,and the solid electrolyte interphase layer at the interface is *** electrode with 20 layers of LPO deposition(ALD-LPO-20)exhibits an excellent capacity retention of 81%after 200 cycles in 2.8-4.3 V at 25℃,which is 18%higher than the unmodified material(ALD-LPO-0).Besides,the moderate LPO coating improves the rate capability and high temperature cycling performance of *** study provides a method for the modification of ultra-high nickel cathode materials and corresponding electrodes.

关键词： Ultra-high nickel material liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) Atomic layer deposition li_(3)PO_(4) Ionic conductor

2017年全英羽毛球公开赛女单创造和限制杀球进攻途径的研究

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体育科技文献通报 2019年第9期27卷 56-57,66页

作者：李品芳钟剑腾广州体育学院

采用文献资料法、录像分析法、数理统计法对2017年全英羽毛球公开赛8强后的7场比赛进行研究,对高水平羽毛球女子单打创造和限制杀球进攻途径进行分析。研究结果显示:1)创造普通杀球进攻的最主要途径是"正手发高远球-杀球";2)创造突击杀... 详细信息

采用文献资料法、录像分析法、数理统计法对2017年全英羽毛球公开赛8强后的7场比赛进行研究,对高水平羽毛球女子单打创造和限制杀球进攻途径进行分析。研究结果显示:1)创造普通杀球进攻的最主要途径是"正手发高远球-杀球";2)创造突击杀球进攻的主要途径是"正手发高远球-平高-杀球"、"放网-推球-杀球"、"推球-平高球-杀球"、"吊球-推球-杀球"等;3)在限制普通杀球进攻时,接杀挡网是相对稳健的限制途径,接杀抽底线是相对激进的限制途径;4)在限制突击杀球进攻时,接杀挡网是更加有风险限制途径,接杀抽底线则是更加稳健的限制途径。

关键词：羽毛球女子单打杀球进攻效果

Layered niobium carbide enabling excellent kinetics and cycling stability of li-Mg-B-H hydrogen storage material Layered niobium carbide enabling excellent kinetics

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Rare Metals 2024年第3期43卷 1153-1166页

作者： li-Wen Lu Hui Luo Guang-Xu li Yun li Xin-Hua Wang Cun-Ke Huang Zhi-QiangLan Wen-Zheng Zhou Jin Guo Mohammad Ismail Hai-Zhen liu Guangxi Novel Battery Materials Research Center of Engineering Technology Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science and TechnologyGuangxi UniversityNanning530004China State Key Laboratory of Featured Metal Materials and life-Cycle Safety for Composite Structures Nanning530004China School of Mechanical and Electrical Engineering Quzhou College of TechnologyQuzhou324000China Department of Materials Science and Engineering Zhejiang UniversityHangzhou310027China Faculty of Ocean Engineering Technology and Informatics Universiti Malaysia Terengganu21030Kuala NerusTerengganuMalaysia Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin300071China

The li-Mg-B-H composite(2liBH_(4)+MgH_(2))has a high capacity of 11.4 wt%as a hydrogen storage ***,the slow kinetics and poor cycling stability severely restrict its practical *** this work,a layered Nb_(2)C MXene was first synthesized and then introduced to tailor the kinetics and cycling stability of the li-Mg-B-H *** milled 2liH+MgB_(2)composites were initially hydrogenated to obtain the 2liBH_(4)+MgH_(2)*** 2liBH_(4)+MgH_(2)+5wt%Nb_(2)C can release 9.0 wt%H_(2)in 30 min at 400℃,while it is only 2.7 wt%for the undoped 2liBH_(4)+MgH_(2).The dehydrogenation activation energies of MgH_(2)and liBH_(4)are 123 and 154 kJ·mol^(-1)respectively for the 5 wt%Nb_(2)C-doped composite,lower than the undoped composite(164 and 165 kJ·mol^(-1)).The 2liBH_(4)+MgH_(2)+5 wt%Nb_(2)C possesses excellent cycling stability,with the reversible capacity only slightly reduced from 9.4 wt%for the 1st cycle to 9.3 wt%for the 20th ***_(2)C keeps stable in the composite and acts as an efficient catalyst for the li-Mg-B-H *** is believed that both the layered structure and the active Nb element contribu te to the enhanced hydrogen storage performances of the li-Mg-B-H *** work confirms that the Nb_(2)C MXene with layered stru cture has a significant enhancing impact on the li-Mg-B-H hydrogen storage materials,which is different from the bulk NbC.

关键词： Hydrogen storage lithium borohydride Magnesium hydride Nb_(2)C MXene

Hard-carbon hybrid li-ion/metal anode enabled by preferred mesoporous uniform lithium growth mechanism

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Journal of Energy Chemistry 2024年第1期88卷 252-259,I0006页

作者： Fang Yan Yan liu Yuan li Yan Wang Zicen Deng Meng li Zhenwei Zhu Aohan Zhou Ting li Jingyi Qiu Gaoping Cao Shaobo Huang Biyan Wang Hao Zhang School of Chemistry and Biological Engineering University of Science and TechnologyBeijing 100083China Research Institute of Chemical Defense Beijing 100191China College of Physics and Engineering Henan University of Science and TechnologyLuoyang 471023HenanChina National Base for International Science&Technology Cooperation School of ChemistryXiangtan UniversityXiangtan 411105HunanChina Materials and Manufacturing Department Beijing University of TechnologyBeijing 100124China

To achieve high energy density in lithium batteries,the construction of lithium-ion/metal hybrid anodes is a promising *** particular,because of the anisotropy of graphite,hybrid anode formed by graphite/li metal has low transport kinetics and is easy to causes the growth of lithium dendrites and accumulation of dead li,which seriously affects the cycle life of batteries and even causes safety ***,by comparing graphite with two types of hard carbon,it was found that hybrid anode formed by hard carbon and lithium metal,possessing more disordered mesoporous structure and lithophilic groups,presents better *** indicate that the mesoporous structure provides abundant active site and storage space for dead *** the synergistic effect of this structure and lithophilic functional groups(–COOH),the reversibility of hard carbon/lithium metal hybrid anode is maintained,promoting uniform deposition of lithium metal and alleviating formation of lithium *** hybrid anode maintains a 99.5%Coulombic efficiency(CE)after 260 cycles at a specific capacity of 500 m Ah/*** work provides new insights into the hybrid anodes formed by carbon-based materials and lithium metal with high specific energy and fast charging ability.

关键词： Hard carbon/li metal hybrid anode Mesoporous structure Surface oxygen functional group Fast charging lithium batteries

玛纳斯河流域不同地貌单元弃耕地土壤盐分差异研究

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土壤学报 2012年第6期49卷 1241-1246页

作者：杨学涛李品芳侯振安范远中国农业大学资源与环境学院北京100193 石河子大学农学院资源与环境科学系新疆石河子832003

玛纳斯河流域位于天山北麓经济带的中心，其内部开垦了新疆面积最大的人工绿洲，同时还是我国第四大灌溉农业区。由于特殊的地理环境及水土开发利用不当，灌区土壤盐渍化发展，大面积耕地被迫弃耕。盐渍化问题成为除水之外制约绿洲农业... 详细信息

玛纳斯河流域位于天山北麓经济带的中心，其内部开垦了新疆面积最大的人工绿洲，同时还是我国第四大灌溉农业区。由于特殊的地理环境及水土开发利用不当，灌区土壤盐渍化发展，大面积耕地被迫弃耕。盐渍化问题成为除水之外制约绿洲农业发展的主要因素，严重影响着区域的生态环境和农业可持续发展。

关键词：玛纳斯河流域地貌类型弃耕地土壤盐分盐渍化类型空间分布