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A general synthetic strategy for N, P co-doped graphene supported metal-rich noble metal phosphides for hydrogen generation

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Green Energy & Environment 2024年第1期9卷 152-162页

作者： Jingwen ma Xiang li Guangyu Lei Jun Wang Juan Wang Jian liu ming Ke Yang li Chunwen Sun School of Chemical and Environmental Engineering China University of Mining and Technology(Beijing)Beijing100083China State Key laboratory of Heavy Oil Processing China University of PetroleumBeijing102249China Lab of Advanced Nano-structures&Transfer Processes Department of Chemical EngineeringTianjin UniversityTianjin300354China Petrochina Planning and Engineering Institute Beijing100083China

The exploitation of electrocatalysts with high activity and durability for HER is desirable for future energy systems,but it is still a *** have attracted increasing attentions,but the preparation process often needs toxic regents or dangerous reaction ***,we develop a general green method to fabricate metal-rich NMPs anchored on NPG through pyrolyzing DNA cross-linked *** obtained Ru_(2) P-NPG exhibits an ultrasmall overpotential of 7 mV at 10 ma cm^(2) and ultralow Tafel slope of 33 mV dec^(-1) in 1.0 mol L?1 KOH,even better than that of commercial Pt/*** addition,Ru 2 P-NPG also shows low overpotentials of 29 and 78 mV in 0.5 mol L^(-1) H_(2)SO_(4) and 1.0 mol L^(-1) PBS,*** superior activity can be attributed to the ultrafine dispersion of Ru 2 P nanoparticles for more accessible sites,more defects formed for abundant active sites,the two-dimensional plane structure for accelerated electron transfer and mass transport,as well as the regulation of electron distribution of the ***,the synthetic method can also be applied to prepare other metal-rich noble metal phosphides(Pd_(3)P-NPG and Rh_(2)P-NPG),which also exhibits high activity for *** work provides an effective strategy for designing NMP-based electrocatalysts.

关键词： Noble metal phosphides Electrocatalyst Deoxyribonucleic acid Hydrogen evolution pH universal

The crystal structure of (Fe_(4)Cr_(4)Ni)_(9)C_(4)

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Science china Earth Sciences 2005年第3期48卷 338-345页

作者： shi nicheng1, ma zhesheng1, xiong ming1, DAI mingquan1, BAI Wenji2, FANG Qingsong2, YAN Binggang2 & YANG Jingsui2 1. X-ray Diffraction laboratory, china university of geosciences, beijing 100083, china 2. Institute of Geology, Chinese Academy of Geological Sciences, beijing 100037, china 1. X-ray Diffraction laboratory China University of Geosciences 100083 Beijing China 2. Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determina- tion of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, space group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some me- tallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525— 0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893—0.2169 nm. The coordina- tion number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonal-prismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.

关键词： Luobusha of Tibet, metal carbide, crystal structure.

Hierarchically structured Nb_(2)O_5 Microflowers with Enhanced Capacity and Fast-Charging Capability for Flexible Planar Sodium Ion Micro-Supercapacitors

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Nano-Micro Letters 2024年第4期16卷 97-109页

作者： Jiaxin ma Jieqiong Qin Shuanghao Zheng Yinghua Fu liping Chi Yaguang li Cong Dong Bin li Feifei Xing Haodong shi Zhong‑Shuai Wu State Key laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of Sciences457 Zhongshan RoadDalian 116023People’s Republic of China School of materials Science and Engineering Zhengzhou UniversityZhengzhou 450001People’s Republic of China College of Science Henan Agricultural UniversityNo.63 Agricultural RoadZhengzhou 450002People’s Republic of China Dalian national laboratory for Clean Energy Chinese Academy of Sciences457 Zhongshan RoadDalian 116023People’s Republic of China university of Chinese Academy of Sciences 19A Yuquan RoadShijingshan DistrictBeijing 100049People’s Republic of China Hebei Key Lab of Optic‑Electronic Information and materials The College of Physics Science and TechnologyInstitute of Life Science and Green DevelopmentHebei UniversityBaoding 071002People’s Republic of China

Planar Na ion micro-supercapacitors(NIMSCs) that offer both high energy density and power density are deemed to a promising class of miniaturized power sources for wearable and portable microelectron-ics. Nevertheless, the development of NIMSCs are hugely impeded by the low capacity and sluggish Na ion kinetics in the negative ***, we demonstrate a novel carbon-coated Nb_(2)O_5 microflower with a hierarchical structure composed of vertically intercrossed and porous nanosheets, boosting Na ion storage performance. The unique structural merits, including uniform carbon coating, ultrathin nanosheets and abun-dant pores, endow the Nb_(2)O_5 microflower with highly reversible Na ion storage capacity of 245 mah g^(-1) at 0.25 C and excellent rate *** from high capacity and fast charging of Nb_(2)O_5 microflower, the planar NIMSCs consisted of Nb_(2)O_5 negative electrode and activated car-bon positive electrode deliver high areal energy density of 60.7 μWh cm^(-2),considerable voltage window of 3.5 V and extraordinary cyclability. Therefore, this work exploits a structural design strategy towards electrode materials for application in NIMSCs, holding great promise for flexible microelectronics.

关键词： Nb_(2)O_5 nanosheets Microflowers Sodium ion micro-supercapacitors Flexibility Energy storage

A review of ultrafast laser micro/nano fabrication:material processing,surface/interface controlling,and devices fabrication

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Nano Research 2024年第7期17卷 6212-6230页

作者： Heng Guo Jiawang Xie Guangzhi He Dezhi Zhu ming Qiao Jianfeng Yan Jiachen Yu Jiaqun li Yuzhi Zhao ma Luo Haoze Han State Key laboratory of Tribology in Advanced Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China

Ultrafast laser processing technology has offered a wide range of opportunities in micro/nano fabrication and other fields such as nanotechnology,biotechnology,energy science,and photonics due to its controllable processing precision,diverse processing capabilities,and broad material *** processing abilities and applications of the ultrafast laser still need more *** the field of material processing,controlling the atomic scale structure in nanomaterials is *** effects exist in ultrafast laser surface/interface processing,making it difficult to modulate the nanostructure and properties of the surface/interface as *** the ultrafast laser fabrication of micro functional devices,the processing ability needs to be ***,we review the research progress of ultrafast laser micro/nano fabrication in the areas of material processing,surface/interface controlling,and micro functional devices *** useful ultrafast laser processing methods and applications in these areas are *** various processing effects and abilities,the ultrafast laser processing technology has demonstrated application values in multiple fields from science to industry.

关键词： ultrafast laser micro/nano fabrication material processing surface/interface controlling devices fabrication

Fast source mask co-optimization method for high-NA EUV lithography

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Opto-Electronic Advances 2024年第4期7卷 44-54页

作者： Ziqi li lisong Dong Xu ma Yayi Wei EDA Center Institute of Microelectronics of Chinese Academy of SciencesBeijing 100029China Key laboratory of Photoelectronic Imaging Technology and System of Ministry of Education of china School of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China university of Chinese Academy of Sciences Beijing 100049China Guangdong Greater Bay Area Applied Research Institute of Integrated Circuit and Systems Guangzhou 510700China

Extreme ultraviolet(EUV)lithography with high numerical aperture(NA)is a future technology to manufacture the integrated circuit in sub-nanometer ***,source mask co-optimization(SMO)is an extensively used approach for advanced lithography process beyond 28 nm technology *** work proposes a novel SMO method to improve the image fidelity of high-NA EUV lithography system.A fast high-NA EUV lithography imaging model is established first,which includes the effects of mask three-dimensional structure and anamorphic ***,this paper develops an efficient SMO method that combines the gradient-based mask optimization algorithm and the compressivesensing-based source optimization algorithm.A mask rule check(MRC)process is further proposed to simplify the optimized mask *** illustrate that the proposed SMO method can significantly reduce the lithography patterning error,and maintain high computational efficiency.

关键词： computational lithography high-NA EUV lithography source-mask co-optimization lithography imaging model

Mechanical and damping performances of TPMS lattice metamaterials fabricated by laser powder bed fusion

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china Foundry 2024年第4期21卷 327-333页

作者： Yan-peng Wei Huai-qian li Jing-jing Han Ying-chun ma Hao-ran Zhou Jing-chang Cheng Jian shi Zhi-quan Miao Bo Yu Feng lin national Key laboratory of Advanced Casting Technologies Shenyang Research Institute of Foundry Co.Ltd.CAMShenyang 110022China Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China Key laboratory of Space Physics Beijing 100076China

Lattice metamaterials based on three-period minimum surface(TPMS)are an effective means to achieve lightweight and high-strength materials which are widely used in various fields such as aerospace and ***,its vibration and noise reduction,and damping properties have not been fully ***,in this study,the TPMS structures with parameterization were designed by the method of surface migration,and the TPMS structures with high forming quality was manufactured by laser powder bed fusion(LPBF).The mechanical properties and energy absorption characteristics of the beam and TPMS structures were studied and compared by quasi-static *** modal shapes of the beam lattice structures and TPMS structures were obtained by the free modal analysis,and the damping properties of two structures were obtained by modal *** the two structures after heat treatment with the same porosity of 70%,the yield strength of the beam lattice structure reaches 40.76 MPa,elastic modulus is 20.38 GPa,the energy absorption value is 32.23 MJ·m^(-3),the damping ratio is 0.52%.The yield strength,elastic modulus,energy absorption value,and damping ratio of the TPMS structure are 50.74 MPa,25.37 GPa,47.34 MJ·m^(-3),and 0.99%,*** results show that TPMS structures exhibit more excellent mechanical properties and energy absorption,better damping performance,and obvious advantages in structural load and vibration and noise reduction compared with the beam lattice structures under the same porosity.

关键词： lattice metamaterials TPMS energy absorption damping laser powder bed fusion

Portable fluorogenic probe for monitoring of volatile amine vapour and food spoilage

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Chinese Chemical Letters 2024年第3期35卷 257-261页

作者： Jian-Hao Zhao Wen-Xing Xu Bin li Wei Xu Wu-Kun Zhang ming-Shuai Yuan Hui-Zi li Qing-Guo He Xiang ma Jian-Gong Cheng Yan-Yan Fu State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China Center of materials Science and Optoelectronics Engineering University of the Chinese Academy of SciencesBeijing 100039China School of Physical Science and Technology ShanghaiTech UniversityShanghai 201210China Key laboratory for Advanced materials and Feringa Nobel Prize Scientist Joint Research Center Frontiers Science Center for materiobiology and Dynamic Chemistry School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

There are urgent needs of volatile amine gas sensors with high-performance in food quality control,disease monitoring and environmental ***-film fluorescent probe is suitable for amine vapour sensing due to its high sensitivity,high selectivity,and no polluting ***,a novel fluorescent probe based on indacenodithiophene structure withπconjugated system was designed and *** experimental results show that the films prepared by this material exhibit rapid and distinct fluorescence quenching after being exposed to saturated vapours of primary amine,secondary amine and tertiary amine represented by n-propylamine,diethylamine and trimethylamine,*** quenching of fluorescence is 84%,87%and 96%,respectively,within 10 *** detection mechanism of probe for primary amine is based on specific chemical reaction,while the detection mechanism for secondary amine and tertiary amine is intramolecular charge *** experiments show that the detection limit of the fluorescent probe for trimethylamine,an important marker of food spoilage,could reach 4.610 ***-site detection based on spoilage of small yellow croaker suggests the material possesses the potential for food freshness *** simple fluorogenic probe is an original approach to simplify real-time visual monitoring of volatile amine vapour.

关键词： Fluorescent probe Volatile amine Gas sensing Trimethylamine Food spoilage

Synthesis of LaFeO_3 catalytic materials and their sensing properties

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Science china Chemistry 2009年第12期52卷 2106-2113页

作者： BAI Shouli,shi BingJie,ma liJing,YANG PengCheng,liU ZhiYong,li DianQing & CHEN AiFan State Key laboratory of Chemical Resource Engineering,College of Science,beijing university of Chemical Technology,beijing 100029,china 1. State Key laboratory of Chemical Resource Engineering College of Science Beijing University of Chemical Technology Beijing 100029 China

LaFeO3 is a p-type semiconductor catalytic material of perovskite structure (ABO3). Its magnetic and photocatalytic properties have been widely investigated,but the gas sensing properties are seldom reported,especially for toxic and noxious gases of NO2 and CO. The nanocomposites of LaFeO3 and LaFe1-xMgxO3 (x = 0.02,0.04,0.06) were prepared by various methods of the wet chemical process and their exact composition,crystal structures,grain sizes,specific surfaces,morphology and the electronic interaction between components were characterized by EDX,XRD,BET,SEM and XPS analysis. The sensors based on these nanocomposites have been fabricated to examine the sensing responses to gases,and the results show that these sensors exhibited high response to both oxidizing gas (NO2) and reducing gas (CO),and the response was greatly enhanced by the surface modification of MgO. The additive method,amount of additives,and their effects on the LaFeO3 structure and gas response have been analyzed and discussed by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopic (XPS) analysis.

关键词： LaFeO3 NO2 CO sensing properties MgO-modified

crystal structure of Natural Non-metamict Ti- and Fe2+-rich Chevkinite-（Ce）

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Acta Geologica Sinica(English Edition) 2005年第3期 325-331页

作者： li guowu~*1,YANG Guangming2,ma Zhengsheng1,shi nicheng1,xiong ming1,FAN Haifu3 and SHENG Ganfu4 1 china university of geosciences(beijing),beijing 100083 2 china university of geosciences(Wuhan),Wuhan,Hubei 430074 3 Institute of Physics,Chinese Academy of Sciences,beijing 100080 4 Chengdu Institute of Geology and mineral Resources,Chengdu,Sichuan 610082

The crystal structure of non-metamict Ti- and Fe2+-rich chevkinite-(Ce) has been redetermined with the single -crystal sample collected from Bayan Obo, Inner Mongolia, china. The chemical formula of the sample is Ce4Fe2Ti3Si4O22. The crystals are monoclinic with the unit cell parameters a = 13.4656(15) ?, b = 5.7356(6) ?, c = 11.0977(12) ?, β= 100.636(2)o, V = 842.39 (16) ?3 and Z = 2. The structures of Ti- and Fe2+-rich chevkinite-(Ce) were refined with space groups P21/a and C2/m. Least-squares refinement results show that both structural models of Ti- and Fe2+-rich chevkinite-(Ce) are very good, R[F2>2σ(F2)] =0.027 with P21/a and R[F2>2σ(F2)] =0.021 with C2/m. In order to illustrate the relationship between the two space groups P21/a and C2/m, the distribution of diffraction intensities was inspected. Pseudo extinction was found, i.e., reflections with h+k=2n are systematically strong, while those with h+k=2n+1 are weak. By neglecting the systematically weak (h+k=2n+1) reflections the space group becomes C2/m. There is a mirror plane in the C2/m perpendicular to the b axis. However, oxygen atoms in the P21/a model are of a symmetrical relationship with the corresponding pseudo mirror plane. It is concluded that the crystal structure of non-metamict Ti- and Fe2+-rich chevkinite-(Ce) is a superstructure with the space group of P21/a, which is of pseudo symmetry corresponding to the space group C2/m.

关键词： non-metamict Ti- and Fe2+-rich chevkinite-(Ce) crystal structure space group superstructure