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Mechanism of high li-ion conductivity in poly(vinylene carbonate)-poly(ethylene oxide)cross-linked network based electrolyte revealed by solid-state NMR

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Journal of Energy Chemistry 2024年第6期93卷 377-383,I0010页

作者： Fan li Tiantian dong Yi Ji lixin liang Kuizhi Chen Huanrui Zhang Guanglei Cui Guangjin Hou State Key Laboratory of Catalysis Dalian National Laboratory for Clean EnergyCollaborative Innovation Center of Chemistry for Energy MaterialsDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of Sciences Beijing 100049China Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101ShandongChina

Solid polymer electrolytes(SPEs)have become increasingly important in advanced lithium-ion batteries(liBs)due to their improved safety and mechanical properties compared to organic liquid ***-linked polymers have the potential to further improve the mechanical property without trading off li-ion *** this study,focusing on a recently developed cross-linked SPE,i.e.,the one based on poly(vinylene carbonate)-poly(ethylene oxide)cross-linked network(PVCN),we used solid-state nuclear magnetic resonance(NMR)techniques to investigate the fundamental interaction between the chain segments and li ions,as well as the lithium-ion *** utilizing homonuclear/heteronuclear correlation,CP(cross-polarization)kinetics,and spin-lattice relaxation experiments,etc.,we revealed the structural characteristics and their relations to lithium-ion *** is found that the network formation prevents poly(ethylene oxide)chains from crystallization,which could create sufficient space for segmental tumbling and li-ion co nductio *** such,the mechanical property is greatly improved with even higher li-ion mobilities compared to the poly(vinylene carbonate)or poly(ethylene oxide)based SPE analogues.

关键词： ssNMR lithium-ion mobility Cross-link Solid polymer electrolyte

鸭源鸡杆菌tolC无痕敲除株的构建及生物学特性分析

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农业生物技术学报 2024年第4期32卷 974-982页

作者：马立静史姿聪王新卫陈陆彭泽宇李栋梁杨霞河南农业大学动物医学院南阳农业职业学院牧医工程学院动物病原与生物安全教育部重点实验室

TolC家族蛋白是一种广泛存在于革兰氏阴性菌中的外膜通道蛋白，介导多种底物胞外转运过程，在细菌的生物学功能中发挥着重要作用。解析鸭源鸡杆菌(Gallibacterium anatis) TolC蛋白在该菌致病过程中发挥的功能，对于该病防控具有重要意... 详细信息

TolC家族蛋白是一种广泛存在于革兰氏阴性菌中的外膜通道蛋白，介导多种底物胞外转运过程，在细菌的生物学功能中发挥着重要作用。解析鸭源鸡杆菌(Gallibacterium anatis) TolC蛋白在该菌致病过程中发挥的功能，对于该病防控具有重要意义。本研究以临床分离株Yu-PDS-RZ-1-SLG(野生型)为研究对象，采用自然转化法构建tolC无痕敲除株ΔtolC，初步研究其生物学特性。结果显示，与野生型比较，ΔtolC的菌落及溶血环变小，对数生长期滞后2 h，整体生长速度减慢；生物被膜形成能力显著减弱(P<0.001)；对高温、氧化应激及渗透压力的拮抗能力均降低(P<0.01)；在浮游态及被膜态对部分抗菌药物的敏感性升高：浮游状态下ΔtolC对SDS、磷霉素和多西环素的敏感性分别增强至32、8和4倍，被膜态下ΔtolC对SDS、磷霉素和多西环素的敏感性分别增强至16、8和8倍，对硫酸新霉素和卡那霉素的敏感性没有变化；对人(Homo sapiens)宫颈癌细胞系(Hela)的黏附能力减弱。tolC无痕敲除株的构建及生物学特性分析为TolC蛋白在鸭源鸡杆菌中的生物学功能、致病机理及耐药机制等研究提供了基础资料。

关键词：鸭源鸡杆菌外膜通道蛋白TolC 缺失

An unprecedented synthesis of axially chiral biaryls by rearrangement and aromatization of carbocations with central-to-axial conversion of chirality

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Science China Chemistry 2024年第9期67卷 2998-3003页

作者： Qi liu Xue-dong li liang Cheng li liu Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Molecular Recognition and Function CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences University of Chinese Academy of Sciences

The central-to-axial chirality conversion represents a fascinating class of chemical processes consisting of the destruction of stereogenic centers and the simultaneous installation of axial chiral elements, which provides efficient methods for the preparation of axially chiral compounds. However, developing catalytic asymmetric approaches for constructing these central chirality precursors and the efficient central-to-axial chirality conversion remains a challenge due to the requirement of aromatization or elimination process. In this work, we have developed an unprecedented enantioselective intramolecular FriedelCrafts alkylation with unactivated-ketone carbonyls from which a chiral tertiary alcohol was generated with high efficiency and excellent enantioselectivity. In addition, the central-to-axial chirality conversion strategy has been successfully applied to the synthesis of enantioenriched biaryls via a less-explored carbocation-initiated rearrangement and aromatization under the promotion of Lewis acid. This methodology provided a straightforward and sustainable access to a broad range of biaryl-2-carboxylic acid and in excellent yields(up to 92%) and excellent central-to-axial chirality conversion(up to 99% conversion percentage). This work could be a great model for developing new methods for synthesizing axially chiral biaryls and a general protocol for the rearrangement and aromatization of carbocations for further functionalization.

关键词： brønsted acid catalysis desymmetrization phosphoric acid axially chiral biaryls central-to-axial conversion

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A Hybrid Level Set Optimization Design Method of Functionally Graded Cellular Structures Considering Connectivity

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Computers, Materials & Continua 2024年第4期79卷 1-18页

作者： Yan dong Kang Zhao liang Gao Hao li The State Key Lab of Digital Manufacturing Equipment and Technology Huazhong University of Science and TechnologyWuhan430074China Institute of Systems Engineering China Academy of Engineering PhysicsMianyang621900China

With the continuous advancement in topology optimization and additive manufacturing(AM)technology,the capability to fabricate functionally graded materials and intricate cellular structures with spatially varying microstructures has grown ***,a critical challenge is encountered in the design of these structures–the absence of robust interface connections between adjacent microstructures,potentially resulting in diminished efficiency or macroscopic failure.A Hybrid Level Set Method(HLSM)is proposed,specifically designed to enhance connectivity among non-uniform microstructures,contributing to the design of functionally graded cellular *** HLSM introduces a pioneering algorithm for effectively blending heterogeneous microstructure ***,an interpolation algorithm is presented to construct transition microstructures seamlessly connected on both ***,the algorithm enables the morphing of non-uniform unit cells to seamlessly adapt to interconnected adjacent *** method,seamlessly integrated into a multi-scale topology optimization framework using the level set method,exhibits its efficacy through numerical examples,showcasing its prowess in optimizing 2D and 3D functionally graded materials(FGM)and multi-scale topology *** essence,the pressing issue of interface connections in complex structure design is not only addressed but also a robust methodology is introduced,substantiated by numerical evidence,advancing optimization capabilities in the realm of functionally graded materials and cellular structures.

关键词： Hybrid level set method functionally graded cellular structure connectivity interpolated transition optimization design

Considering individual game behavior and time delay in the multi-channel rumor propagation model

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Communications in Theoretical Physics 2024年第7期76卷 11-31页

作者： Yafang dong liang'an Huo Xiaoxiao Xie Ming li Business School University of Shanghai for Science and Technology School of Intelligent Emergency Management University of Shanghai for Science and Technology

The rapid development of the Internet has accelerated the spread of rumors, posing challenges to social cohesion and stability. To address this, a multi-channel rumor propagation model incorporating individual game behavior and time delay is proposed. It depicts individuals strategically choosing propagation channels in the rumor spread process, capturing real-world intricacies more faithfully. Specifically, the model allowing spreaders to choose between text and video information base channels. Strategy adoption hinges on benefits versus costs, with payoffs dictating strategy and the propagation process determining an individual's state. By theoretical analysis of the model, the propagation threshold and equilibrium points are obtained. Then the stability of the model is further demonstrated based on Routh–Hurwitz judgment and Descartes' Rule of Signs. Numerical simulations are conducted to verify the correctness of the theoretical results and the sensitivity of the model to key parameters. The outcomes reveal that increasing the propagation cost of spreaders can significantly curb the spread of rumors. In contrast to the classical ISR model, rumors spread faster and more widely in the improved multi-channel rumor propagation model in this paper, which is a feature more aligned with real-world ***, the validity and predictive ability of the model are verified by using real rumor propagation data sets, indicating that the improved multi-channel rumor propagation model has good practical application and predictive value.

关键词： game behavior multi-channel rumor propagation time delay

Generation and Suppression of Pendant Droplet Oscillation in Electron Beam Directed Energy Deposition

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Engineering 2024年第6期37卷 215-229页

作者： Zhiyue liang Zhenyu liao Haoyu Zhang Zixiang li li Wang Baohua Chang dong Du Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationTsinghua UniversityBeijing 100084China

Electron beam–directed energy deposition(EB–DED)has emerged as a promising wire-based metal additive manufacturing ***,the effects of EBs on pendant droplets at wire tips have not yet been *** aim of this study is to enhance the understanding of this action by analyzing the mechanism of droplet *** pendant droplet oscillation phenomenon hinders the stable transfer of droplets to the molten pool and limits the feasibility of manufacturing complex lattice structures by EB–***,another aim of this study is to create an oscillation suppression *** escalating asymmetric amplitude is the main characteristic of droplet *** primary oscillationinducing force is the recoil force generated from the EB-acted local surface of the *** physical mechanism of this force is the rapid increase and uneven distribution of the local surface temperature caused by the partial action of the *** prerequisites for droplet oscillation include vacuum conditions,high power densities,and bypass wire feeding *** proposed EB–dynamic surrounding melting(DSM)method can be applied to conveniently and effectively suppress oscillations,enable the accurate transfer of droplets to the molten pool,and achieve stable processes for preparing the strut elements of lattice *** the temperature and improving the uniformity of its distribution are the mechanisms of oscillation suppression in EB–*** this study,the physical basis for interpreting the mechanism by which EBs act on droplets and the technical basis for using EB–DED to prepare complex lattice structure parts are provided.

关键词： Additive manufacturing Electron beam freeform fabrication In situ monitoring Pendant droplet

Three-dimensional stability calculation method for high and large composite slopes formed by mining stope and inner dump in adjacent open pits

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International Journal of Mining Science and Technology 2024年第4期34卷 507-520页

作者： Zuchao liang dong Wang Guanghe li Guangyu Sun Mingyu Yu dong Xia Chunjian Ding College of Mining Engineering Liaoning Technical UniversityFuxin 123000China Inner Mongolia Pingxi Baiyinhua Coal Industry Co. Ltd.Xilingol League 026000China Guoneng Baorixile Energy Co. Ltd.Hulunbuir 021008China

The 2D limit equilibrium method is widely used for slope stability ***,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical ***,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope *** the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding *** integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is ***,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is *** analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear *** spatial form equation of the sliding mass comprises an ellipsoid and weak plane *** analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite ***,the3D stability coefficient of the composite slope exhibits an exponential co

关键词： Composite slope Destabilization mechanism 3D mechanical effect Three-dimensional stability Coordinated development distance

Engineering FeOOH/Ni(OH)_(2) heterostructures on Ni_(3)S_(2)surface to enhance seawater splitting

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Rare Metals 2024年第5期43卷 1989-1998页

作者： Chen Yang Ya-dong li li-Juan Cao Xi-Long Wang Han-Pu liang Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of SciencesQingdao 266101China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Sino-Danish College University of Chinese Academy of SciencesBeijing 100049China

The construction of highly stable and efficient electrocatalysts is desirable for seawater splitting but remains challenging due to the high concentration of Cl-in ***,FeOOH/Ni(OH)_(2)heterostructure supported on Ni_(3)S_(2)-covered nickel foam(Fe–Ni/Ni_(3)S_(2)/NF)was fabricated by hydrothermal and etching methods,as well as anodic oxidation *** electronic structure of FeOOH and Ni(OH)_(2)could be modulated after depositing FeOOH nanoparticles on Ni(OH)_(2)nanosheet,which greatly boosted the catalytic *** the catalyst used as an electrode for oxygen evolution reaction(OER),it needed low overpotentials of 266 and 368 m V to achieve current densities of 100 and 800 m A·cm^(-2),respectively,in 1 mol·L^(-1)KOH+seawater *** can operate continuously at 100 m A·cm^(-2)for 400 h without obvious ***,in situ generated SO_(4)^(2-)from inner Ni_(3)S_(2)during electrolysis process would accumulate on the surface of active sites to form passivation layers to repel Cl^(-),which seemed to be responsible for superior *** study not only synthesizes an OER catalyst for highly selective and stable seawater splitting,but also gives a novel approach for industrial hydrogen production.

关键词： Anodic oxidation Heterostructure Oxygen evolution reaction Seawater splitting

A semi-analytical model for coupled flow in stress-sensitive multi-scale shale reservoirs with fractal characteristics

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Petroleum Science 2024年第1期21卷 327-342页

作者： Qian Zhang Wen-dong Wang Yu-liang Su Wei Chen Zheng-dong Lei Lei li Yong-Mao Hao Key Laboratory of Unconventional Oil&Gas Development(China University of Petroleum(East China)) Ministry of EducationQingdao266580ShandongChina School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580ShandongChina Shale Oil Development Branch Changqing Oilfield CompanyPetroChinaQingyang745708GansuChina PetroChina Research Institute of Petroleum Exploration&Development Beijing100083China

A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes due to stress sensitivity, which plays a crucial role in controlling pressure propagation and oil flow. This paper proposes a multi-scale coupled flow mathematical model of matrix nanopores, induced fractures, and hydraulic fractures. In this model, the micro-scale effects of shale oil flow in fractal nanopores, fractal induced fracture network, and stress sensitivity of multi-scale media are considered. We solved the model iteratively using Pedrosa transform, semi-analytic Segmented Bessel function, Laplace transform. The results of this model exhibit good agreement with the numerical solution and field production data, confirming the high accuracy of the model. As well, the influence of stress sensitivity on permeability, pressure and production is analyzed. It is shown that the permeability and production decrease significantly when induced fractures are weakly supported. Closed induced fractures can inhibit interporosity flow in the stimulated reservoir volume (SRV). It has been shown in sensitivity analysis that hydraulic fractures are beneficial to early production, and induced fractures in SRV are beneficial to middle production. The model can characterize multi-scale flow characteristics of shale oil, providing theoretical guidance for rapid productivity evaluation.

关键词： Multi-scale coupled flow Stress sensitivity Shale oil Micro-scale effect Fractal theory