检索结果-南通市图书馆

Chemical Research in Chinese Universities 2024年第3期40卷 521-528页

作者： SHAO Chen GUO ru li Hui WANG Xiaozhong YANG Qingfeng LAI Xiaoyong State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering School of Chemistry and Chemical EngineeringNingxia UniversityYinchuan 750021P.R.China

Acetone is a tracer for monitoring air quality and a potential breath maker for diabetes. It remains a great challenge for current portable sensors to sensitively and selectively detect acetone at low-ppb (part per billion) level. Herein, we present an ordered mesoporous nickel oxide (NiO) with both large mesopores and ultrathin crystalline frameworks for the detection of low-ppb acetone. The ordered mesoporous NiO replicas with predominant large mesopores of 11 nm, high specific surface areas of 121–128 m2/g and ultrathin crystalline frameworks of 5 nm were synthesized by the nanocasting method and the crystalline properties of NiO frameworks were adjusted by changing the annealing temperature from 300℃ to 750℃, which resulted in different contents of oxygen deficient on the surface of ultrathin frameworks. The gas-sensing properties for all the NiO samples were investigated and the ordered large-pore mesoporous NiO (NiO-600) with maximum oxygen deficient obtained at 600℃ exhibited the highest response (R_(gas)/R_(air)−1=2.9) toward acetone (1 ppm, ppm: part per million), which is 3.4 and 30 times larger than those for common mesoporous NiO obtained at 300℃ and bulk NiO. Notably, a low detection limit (2 ppb), good selectivity and cycling stability were also observed in NiO-600.

关键词： Mesoporous semiconductor NiO Gas sensing Acetone

Effect of Mn content on microstructure and properties of AlCrCuFeMnx high-entropy alloy

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

China Foundry 2024年第2期21卷 147-158页

作者： Ning Wang Kai Ma Qiu-da li Yu-dong Yuan Yan-chun Zhao li Feng School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Reuse of Nonferrous Metals Lanzhou 730050China CNNC Nuclear Power Operation and Management Co. Ltd.Haiyan 314300ZhejiangChina

AlCrCuFeMnx(x=0,0.5,1,1.5,and 2)high-entropy alloys were prepared using the vacuum arc melting *** microstructure and mechanical properties of AlCrCuFeMnxwere analyzed and tested by XRD,SEM,TEM,nanoindentation,and electronic universal *** results indicate that the AlCrCuFeMnxhigh-entropy alloy exhibits a dendritic structure,consisting of dendrites with a BCC structure,interdendrite regions with an FCC structure,and precipitates with an ordered BCC structure that form within the ***(Mn)has a strong affinity for dendritic,interdendritic,and precipitate structures,allowing it to easily enter these *** an increase in Mn content,the size of the precipitated nanoparticles in the dendritic region initially increases and then ***,the area fraction initially decreases and then ***,the alloy’s strength and wear resistance decrease,while its plasticity *** Al Cr Cu Fe Mn1.5alloy boasts excellent mechanical properties,including a hardness of 360 HV and a wear rate of 2.4×10^(-5)mm^(3)·N^(-1)·mm^(-1).It also exhibits impressive yield strength,compressive strength,and deformation rates of 960 MPa,1,700 MPa,and 27.5%,respectively.

关键词： high-entropy alloys microstructure mechanical properties wear resistance strengthening mechanisms

Synthesis of crystalline g-C_(3)N_(4) with rock/molten salts for efficient photocatalysis and piezocatalysis

在线全文

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第5期9卷 890-898页

作者： Tingting Xu Jung Hur Ping Niu Shulan Wang Sangwook Lee Sang-Eun chun li li Department of Chemistry College of ScienceNortheastern UniversityShenyang110819China State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819China School of Metallurgy Northeastern UniversityShenyang110819China School of Materials Science and Engineering Kyungpook National UniversityDaegu41566Republic of Korea School of Industrial Technology Advances Kyungpook National UniversityDaegu41566Republic of Korea

Graphitic carbon nitride(g-C_(3)N_(4))is emerging as a promising visible-light photocatalyst while the low crystallinity with sluggish charge separation/migration dynamics signiﬁcantly restricts its practical ***,synthesizing highly crystalline g-C_(3)N_(4) with sufﬁcient surface activities still remains ***,different from using alkali molten salts which is commonly reported,we propose an approach for synthesis of highly crystalline g-C_(3)N_(4) with FeCl3/KCl rock/molten mixed *** rock salt can serve as the structure-directing template while molten salt provides the required liquid medium for ***,the synthesized photocatalyst showed further enhanced crystallinity and improved surface area along with high p/p*excitation compared with crystalline C_(3)N_(4) prepared from conventional molten-salt *** catalytically advantageous features lead to its superior photocatalytic and piezocatalytic activities with a high reactivity for overall water splitting that is not commonly reported for C_(3)N_(4).This work provides an effective strategy for structural optimization of organic semiconductor based materials and may inspire new ideas for the design of advanced photocatalysts.

关键词： High crystallinity Carbon nitride Photocatalysis Piezocatalysis Overall water splitting

Impact wear properties of dissimilar joints between bainitic frogs and pearlite rails

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2024年第1期31卷 275-287页

作者： Pin-yong Zeng chun-guang Zuo Xiao-yu Zhang Wei li Tribology Research Institute Southwest Jiaotong UniversityChengdu610031SichuanChina

The impact wear behavior and damage mechanism of dissimilar welded joints between U26Mn frog and U75 V rail before and after normalizing treatment were studied by cyclic impact *** experiment indicated that the impact wear volume of the joints increased with the increasing number of impact *** main wear mechanisms include pitting wear,mild fatigue wear,delamination wear,and fatigue wear,and plastic deformation was the primary impact wear *** them,fatigue wear had the greatest influence on wear volume,while other wear mechanisms had limited *** impact wear resistance of the base material was better than that of the heat-affected *** treatment was beneficial to improving the impact wear resistance of welded joints owing to its effect to promote pearlite recovery,grain refinement,and uniform distribution of *** martensite generated in the rail welded joints aggravated the impact wear damage to the materials,which should be avoided.

关键词： Dissimilar welded joint Impact wear Bainitic steel Damage mechanism Wear rate

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

轻烧高铝矾土制备超细粉料的工艺

矿产综合利用 2001年第2期 15-18页

作者：李如椿河北理工学院河北唐山063009

在不同温度、不同保温时间对特级高铝矾土的轻烧过程进行了研究 ,基于强度与活性的最佳结合点 ,用机械粉碎的方法制备高活性陶瓷耐火材料用超细粉 ,并且对此法制得的轻烧料的易磨性和烧结性进行了检验。此方法最大优点是成本低、性能好。

关键词：高铝矾土轻烧超细粉强度活性陶瓷耐火材料烧结温度抗折强度

Integration of urchin-like MnCo_(2)O_(4)@C core–shell nanowire arrays within porous copper current collector for superior performance li-ion battery anodes

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第2期43卷 599-611页

作者： Xue-ru Zhang Qiong Wu Yong Zhang Xi-Fei li Ting Xie Yu-Cheng Wu Instrumental Analysis Center Hefei University of TechnologyHefei230009China Key Laboratory of Advanced Functional Materials and Devices of Anhui Province Hefei230009China School of Materials Science and Engineering Hefei University of TechnologyHefei230009China Institute of Advanced Electrochemical Energy Xi’an University of TechnologyXi’an710048China

Spinel MnCo_(2)O_(4) is a promising energy storage candidate as anode materials in lithium-ion batteries owing to synergistic effects of two intrinsic solid-state redox ***,low conductivity,poor rate capacity and rapid capacity fading have seriously impaired its practical *** overcome the inferiorities,urchin-like MnCo_(2)O_(4)@C core–shell nanowire arrays have been fabricated directly within a porous copper current collector via a facile hydrothermal method followed by a chemical vapor deposition carbonization *** a typical nanowire,the core is composed of interconnected MnCo_(2)O_(4)nanoparticles and the shell shows as a thin amorphous carbon *** integrated MnCo_(2)O_(4)@C/Cu structure could act as working anodes without using additives or polymer *** MnCo_(2)O_(4)@C/Cu possesses slightly longer li-ion insertion/desertion pathway than that of MnCo_(2)O_(4)/Cu,the carbon shell could effectively prevent the pulverization of MnCo_(2)O_(4) and lower down charge transfer resistance and actively participate in li-ion *** rearrangement of carbon atoms during lithiation/delithiation cycling could inhibit the formation of passive solid electrolyte interphase *** a result,the MnCo_(2)O_(4)@C/Cu electrode presents superior rate capacity(600 mAh·g^(−1) at 1 A·g^(−1)) and better stability(797 mAh·g^(−1) after 200 cycles at 100 mA·g^(−1)).The excellent reversible li ion storage capacity,cycling stability and rate capacity endow MnCo_(2)O_(4)@C/Cu great potential as stable and high output integrated anode materials in li-ion batteries.

关键词： MnCo_(2)O_(4)@C Urchin-like nanowire arrays Core-shell Integrated anode materials lithium-ion batteries

Conditioning treatments mitigate the levels of fecal pollution indicators in soil during land-application of sewage sludge

在线全文

学校读者我要写书评

暂无评论

Science China Technological Sciences 2024年第10期67卷 3091-3102页

作者： WANG YuHang li Hua FANG WenHao WANG ru WANG XinXin ZHENG GuanYu ZHOU liXiang Department of Environmental Engineering College of Resources and Environmental SciencesNanjing Agricultural University College of Materials and Chemical Engineering Pingxiang University Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization

Sewage sludge is a major source of fecal pathogens in the environment, and its application to land can result in a significant release of these pathogens into the soil. While conditioning treatments are crucial for improving the dewatering process of sludge, their impact on the presence and behavior of fecal pathogens in soil remains unclear. This study aims to assess four extraction methods for recovering fecal pollution indicators from soil amended with unconditioned and conditioned sludge. The indicators include Escherichia coli(EC), human-specific HF183 Bacteroides(HF183), human adenovirus(HAdV), human BK polyomavirus(BKPyV), human JC polyomavirus(JCPyV), and cross-assembly phage(crAssphage). This study also examines how soil moisture content affects the decay of these fecal pollution indicators in soil amended with raw sludge and investigates the influence of conditioning treatments with cationic polyacrylamide(PAM), Fenton's reagents, Fe[Ⅲ]/CaO on their persistence in soil. The results indicated that the direct extraction method was the most effective and unbiased for recovering fecal pollution indicators from sludge-amended soil compared with the three elution-concentration methods. All fecal pollution indicators, except HAdV, remained stable under dry soil conditions, while high soil moisture content(48.39%-53.14%) slowed the decay rates of these indicators. During the application of sludge to soil, effective control of fecal pollution indicators was observed, with JCPyVand HAdV becoming undetectable within a short period. The log reduction values of HF183, BKPyV, and crAssphage ranged from 0.1 to 2.8 logs after 30 d of cultivation. The application of conditioned sludge, especially Fenton's reagent-conditioned sludge, resulted in a reduction in human fecal contamination in the receiving soil. Therefore, implementing appropriate conditioning methods, such as using Fenton's reagent, can effectively mitigate the health risks associated with fecal pathogens.

关键词： fecal pollution indicators sewage sludge conditioning treatment land application soil

同方期刊数据库

Synergistic effects of multiscale TiC and dual-phase structure on tensile properties of particle-reinforced steel

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2024年第5期31卷 1232-1245页

作者： Ye Jia Xiang-tao Deng Qi Wang Cheng-ru li Hao Wu Zhao-dong Wang State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819LiaoningChina

The conventional melting methods were used to obtain in situ TiC particle-reinforced dual-phase steel,followed by hot rolling and heat treatment *** aim was to investigate the effect of TiC particles on the fracture behavior of dual-phase steel at different annealing temperatures,by analyzing the microstructure and tensile behavior of the multiscale TiC particle-reinforced dual-phase *** results showed that TiC particles precipitated in the as-cast microstructure of dual-phase steel were distributed along the grain *** hot rolling,the grain boundary-like morphology of the micron-sized TiC particles was disrupted,and the particles became more refined and evenly distributed in the *** tensile tests revealed that the strength of the TiC particle-reinforced dual-phase steel increased with increasing martensite content,while the elongation *** results were similar to those of conventional *** addition of 1 vol.%multiscale TiC particles improved the strength of the dual-phase steel but did not affect elongation of the *** and holes were primarily concentrated around the TiC particles rather than at the interface of martensite and *** main causes of crack sprouting were TiC particle interface cracking and TiC particle internal ***,the study demonstrated the potential of multiscale TiC particle-reinforced dual-phase steel as a strong and tough *** refined distribution of TiC particles in the matrix improved the strength of the material without compromising its *** results also highlighted the importance of careful selection of reinforcement particles to avoid detrimental effects on the fracture behavior of the material.

关键词： TiC particle Dual-phase structure TiC-reinforced dual-phase steel Tension Fracture behavior

Modulation on electrostatic potential to build a firm bridge at NiO_(x)/perovskite interface for efficient and stable perovskite solar cells

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第9期96卷 249-258页

作者： Xiangbao Yuan Xufeng ling Hongyu Wang Chengxia Shen ru li Yehao Deng Shijian Chen Chongqing Key Laboratory of Interface Physics in Energy Conversion College of PhysicsChongqing UniversityChongqing 401331China Key Laboratory of Optoelectronic Technology&Systems(Ministry of Education) College of Optoelectronic EngineeringChongqing UniversityChongqing 400044China Center of Modern Physics Institute for Smart City of Chongqing University in LiyangLiyang 213300JiangsuChina

The NiO_(x)/perovskite interface in NiO_(x)-based inverted perovskite solar cells(PSCs)is one of the main issues that restrict device performance and long-term stability,as the unwanted interfacial defects and undesirable redox reactions cause severe interfacial non-radiative recombination and open-circuit voltage(Voc)***,a series of self-assembled molecules(SAMs)are employed to bind,bridge,and stabilize the NiO_(x)/perovskite interface by regulating the electrostatic *** on systematically theoretical and experimental studies,4-pyrazolecarboxylic acid(4-PCA)is proven as an efficient molecule to simultaneously passivate the NiO_(x)and perovskite surface traps,release the interfacial tensile stress as well as quench the detrimental interface redox reactions,thus effectively suppressing the interfacial non-radiative recombination and enhancing the quality of perovskite ***,the PSCs with 4-PCA treatment exhibited an eminently increased Voc,leading to a significant increase in power conversion efficiency from 21.28%to 23.77%.Furthermore,the unencapsulated devices maintain 92.6%and 81.3%of their initial PCEs after storing in air with a relative humidity of 20%–30%for 1000 h and heating at 65℃for 500 h in a N_(2)-filled glovebox,respectively.

关键词： Perovskite solar cells Nickel oxide Interface defects passivation Redox reaction Nonradiative recombination

Incidence and Mortality of Cancers in Female Genital Organs—China,2022

在线全文

学校读者我要写书评

暂无评论

China CDC weekly 2024年第10期6卷 195-202,I0003,I0004页

作者： Kexin Sun Bingfeng Han Hongmei Zeng Shaoming Wang li li ru Chen Rongshou Zheng Wenqiang Wei National Central Cancer Registry National Cancer Center/National Clinical Research Center for Cancer/Cancer HospitalChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijingChina

Introduction:This study presented the incidence and mortality rates of cancers affecting the female genital organs in China,along with their trends spanning from 2010 to ***:700 population-based cancer registries provided relevant cancer incidence and mortality data for the year *** these,106 registries had continuous monitoring data suitable for trend analysis from 2010 to *** focused specifically on cancers affecting female genital organs(ICD10=C51-C54,C56)and projected their incidences and mortalities in China for 2022 based on data from 2018 and the trends observed from 2010 to ***-standardized incidence rate(ASIR)and mortality rate(ASMR)were calculated using Segi’s world standard ***:In 2022,there were an estimated 296,300 new cases and 104,900 deaths from female cancers in *** for vulva(C51),vagina(C52),cervix uteri(C53),corpus uteri(C54),and ovary(C56)were 0.32,0.23,13.83,6.84,and 5.68 per 100,000 *** for corpus uteri and ovary cancers were higher in urban *** for vulva,vagina,cervix,corpus uteri,and ovary cancers were 0.14,0.08,4.54,1.05,and 2.64 per 100,000 population,*** for ovarian cancer was higher in urban *** and ASMRs for most female genital organ cancers increased from 2010 to 2018,although the rate of increase for vulvar and cervical cancers in rural areas has slowed ***:Tailored cancer prevention and control programs specific to each region are necessary to address the growing disease burden.

关键词： ICD10 mortality organs