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四角切圆锅炉不同燃烧器布置角度结渣特性数值模拟研究

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节能技术 2024年第3期42卷 253-258页

作者：李朝兵赖金平王西伦国能南京电力试验研究有限公司江苏南京210023 烟台龙源电力技术股份有限公司山东烟台264000

为研究燃烧器布置角度对大规模掺烧低灰熔点烟煤锅炉的燃烧特性和结渣倾向,采用CFD方法对一300 MW四角切圆燃煤锅炉进行研究。结果表明,当燃烧器布置角度为38°时,温度分布均匀,火焰充满度高,燃烧稳定,但炉膛壁面易出现结渣;当燃烧器布... 详细信息

为研究燃烧器布置角度对大规模掺烧低灰熔点烟煤锅炉的燃烧特性和结渣倾向,采用CFD方法对一300 MW四角切圆燃煤锅炉进行研究。结果表明,当燃烧器布置角度为38°时,温度分布均匀,火焰充满度高,燃烧稳定,但炉膛壁面易出现结渣;当燃烧器布置角度为42°时,高温火焰集中在炉膛中心,壁面温度降低,结渣倾向较小,但煤粉难以充分燃烧。综合考虑,当燃烧器布置角度为40°时,具有良好的燃烧效果,且结渣风险较低,可实现锅炉稳定运行。

关键词：结渣特性电站锅炉燃烧燃烧器布置角度数值模拟

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燃煤电站锅炉实现点火投运SCR脱硝系统关键技术研究

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电站系统工程 2024年第2期40卷 10-12,16页

作者：陈辉黄林滨李朝兵戴维葆国家能源集团科学技术研究院有限公司江苏南京210031

以某1000 MW超超临界机组锅炉为研究对象,研究抽取邻炉烟气加热点火锅炉烟气,实现锅炉点火时投运SCR脱硝系统关键技术和调整方法。理论计算得到,随着锅炉点火运行时间的增加,抽取邻炉燃煤锅炉的烟气比例呈降低趋势,对邻炉再热汽温、热... 详细信息

以某1000 MW超超临界机组锅炉为研究对象,研究抽取邻炉烟气加热点火锅炉烟气,实现锅炉点火时投运SCR脱硝系统关键技术和调整方法。理论计算得到,随着锅炉点火运行时间的增加,抽取邻炉燃煤锅炉的烟气比例呈降低趋势,对邻炉再热汽温、热一次风温度和热二次风温度影响量呈降低趋势。在锅炉点火2~3 min后,抽取邻炉燃煤锅炉烟气量较大,邻炉再热汽温降低约22℃,降低热一次风温度约36℃,降低热二次风温度约40℃,此时可以通过调整邻炉锅炉负荷至BRL工况,关小邻炉磨煤机冷风门开度,使得烟煤煤粉着火和机组安全性影响可控。优化抽取邻炉烟气加热系统方案设计,基本上可以达到锅炉点火投运SCR脱硝系统的要求。

关键词：燃煤锅炉 SCR脱硝系统深度调峰方案研究

350 MW“W”型火焰锅炉全烧神华烟煤改造技术研究

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电站系统工程 2024年第1期40卷 16-22页

作者：陈辉韩林涛李朝兵赖金平黄林滨国家能源集团科学技术研究院有限公司烟台龙源电力技术股份有限公司

以某电厂W型火焰锅炉为研究对象,针对锅炉燃用煤种由无烟煤变成烟煤进行设备改造技术研究。掺烧烟煤试验结果表明,由于神华烟煤与锅炉设计煤种存在较大的差异,以现有的锅炉及辅机设备全部燃烧神华烟煤存在严重影响机组运行安全性和经济... 详细信息

以某电厂W型火焰锅炉为研究对象,针对锅炉燃用煤种由无烟煤变成烟煤进行设备改造技术研究。掺烧烟煤试验结果表明,由于神华烟煤与锅炉设计煤种存在较大的差异,以现有的锅炉及辅机设备全部燃烧神华烟煤存在严重影响机组运行安全性和经济性的问题。针对全燃神华烟煤存在的问题制定改造方案,包括:制粉系统改造、燃烧系统改造、高温受热面改造、水冷壁改造、一次风机改造等。采用该方案可实现安全、经济、稳定的全燃神华烟煤,且省煤器出口NO_(x)排放浓度控制在360 mg/Nm^(3)(6%O_(2),标态干基)以下,低负荷稳燃达到30%BRL负荷,改造后锅炉效率不低于93.0%。

关键词： W型火焰锅炉烟煤燃烧器改造研究锅炉效率氮氧化物

Syntheses and Crystal Structures of Two Isomeric Au Complexes

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Chinese Journal of Structural Chemistry 2010年第7期29卷 1001-1006页

作者： YUE Cheng-Yang YIN Xiang-Chen li bing-chao JIANG Fei-Long HONG Mao-Chun Department of Chemistry Jining University Qufu Shandong 273155 China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China

Two new isomeric Au complexes, Au（PPh3）（bmt）, have been synthesized via the reaction of Au（PPh3）CI with 2-benzimidazolethiol （Hbmt） in dichloromethane （CH2Cl2） solution. Their crystal structures were determined by elemental analysis and single-crystal X-ray diffraction studies. Complex 1 crystallizes in the monoclinic system, space group C2/c with a = 19.589（2）, b = 21.1368（15）, c = 23.424（2） A, β = 108.346（4）°, V= 9206.1（14） A3, Mr = 1216.85, Dc = 1.756 g/cm3, μ = 6.566 mm^-1, F（000） = 4704, Z = 8, the final R = 0.0563 and wR = 0.1028 for 8125 reflections with I 〉 2σ（I）. Complex 2 crystallizes in the monoclinic system, space group P21/n with a = 9.627（3）, b = 21.384（8）, c = 22.308（8） A, β = 92.068（6）°, V= 4590（3） A3, Mr = 1216.85, Dc = 1.761 g/cms, μ = 6.585 mm^-1, F（000） = 2352, Z = 4, the final R = 0.0500 and wR = 0.0883 for 10477 reflections with I 〉 2σ（i）. X-ray diffraction studies reveal that complexes 1 and 2 both feature a 1D chain along the a axis.

关键词： 2-benzimidazolethiol isomeric gold complex

Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys

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China Foundry 2024年第1期21卷 71-81页

作者： chao Gao bing-rong Zhang Yin-ming li Zhi-ming Wang Xiang-bin Meng Faculty of Mechanical Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Hebei Ounai Machinery Mould Co.Ltd. Xingtai 054500HebeiChina

This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg *** synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were *** show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the *** can improve the strength of the alloy by hindering dislocation movement and crack *** addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain *** addition of Mo greatly improves the heat resistance of the *** extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.

关键词： Al-Si-Cu-Mg alloy high-temperature properties Zr-Mo-rich intermetallics nano-strengthening phases

Asymmetric Zn-N_4 atomic sites embedded hollow fibers as stable Zn anode for high-performance Zn-ion hybrid capacitor

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Journal of Energy Chemistry 2024年第10期97卷 460-469,I0009页

作者： Yukun liu bing li Jin Wang Caiyun li Hongrui Yang Yang Song Sen Zhang chao Deng Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of EducationCollege of Physics and Electronic EngineeringHarbin Normal UniversityHarbin 150025HeilongjiangChina College of Material Science and Chemical Engineering Harbin Engineering UniversityHarbin 150001HeilongjiangChina

Zn based electrochemical energy storage systems(EES)have attracted tremendous interests owing to their low cost and high intrinsic ***,the uncontrolled growth of Zn dendrites and the side reactions of Zn metal anodes(ZMAs)severely restrict their *** address these issues,we design the asymmetric Zn-N_(4) atomic sites embedded hollow fibers(AS-IHF)as the flexible host for stable *** introducing different nitrogen resources in the synthesis,two kinds of coordination,i,***-N(pyridinic)and Zn-N(pyrrolic),are introduced in the Zn-N_(4) atomic module *** asymmetric Zn-N_(4) module with regulated micro-environment facilitates the superior zincophilic features and promotes the Zn ***,the highly porous structure of the hollow fiber effectively reduces local current density,homogenize Zn ion flux,and alleviate structure *** the advantages endow the high efficiency and good stability for Zn plating/*** theoretical and experimental results demonstrate the high reversibility,low nucleation overpotential,and dendritefree behavior of the AS-IHF@Zn anode,which afford the high stability in high-rate and long-term ***,the solid-state Zn-ion hybrid capacitor(ZIHC)based on AS-IHF@Zn anode shows the high flexibility,reliability,and superior long-term cycling capability in a wide-range of temperatures(-20-25℃).Therefore,the present work not only gives a new strategy for modulating local environments of single atomic sites,but also propels the development of flexible power sources for diverse electronics.

关键词： Asymmetric coordination Single atomic sites Zincophilic sites Dendrite free behavior Zn-ion hybrid capacitor

Vinyltrimethylsilane as a novel electrolyte additive for improving interfacial stability of li-rich cathode working in high voltage

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Chinese Chemical Letters 2024年第2期35卷 534-538页

作者： bing Jiang Hao li Bi Luo Lehao liu lihua Chu Qiaobao Zhang Meicheng li State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources School of New EnergyNorth China Electric Power UniversityBeijing 102206China State Key Laboratory of Physical Chemistry of Solid Surfaces College of MaterialsXiamen UniversityXiamen 361005China

Boosting the interfacial stability between electrolyte and li-rich cathode material at high operating voltage is vital important to enhance the cycling stability of li-rich cathode materials for high-performance li-ion *** this work,vinyltrimethylsilane as a new type of organic silicon electrolyte additive is studied to address the interfacial instability of li-rich cathode material at high operating *** cells using vinyltrimethylsilane additive shows the high capacity retention of 73.9%after 300 cycles at 1 C,whereas the cells without this kind of additive only have the capacity retention of 58.9%.The improvement of stability is mainly attributed to the additive helping to form a more stable surface film for li-rich cathode material,thus avoiding direct contact between the electrolyte and the cathode material,slowing down the dissolution of metal ions and the decomposition of the electrolyte under high operating *** findings in this work shed some light on the design of stable cycling performance of li-rich cathode toward advanced li-ion batteries.

关键词： Vinyltrimethylsilane Electrolyte additive li-rich cathode Interfacial stability Capacity retention

Revisiting the Mg isotopic systematics of siliciclastic components of sediments and sedimentary rocks:A new geochemical proxy of continental weathering in Earth's history

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Science China Earth Sciences 2024年第2期67卷 620-633页

作者： Tianzheng HUANG bing SHEN Kangjun HUANG Meng NING chao li Jinzhuang XUE Yuanlin SUN Baoqi HUANG Key Laboratory of Orogenic Belt and Crustal Evolution MOESchool of Earth and Space SciencesPeking UniversityBeijing100871China State Key Laboratory of Continental Dynamics Shaanxi Key Laboratory of Early Life and EnvironmentsDepartment of GeologyNorthwest UniversityXi’an710069China Institute of Sedimentary Geology Chengdu University of TechnologyChengdu610059China Key Laboratory of Rhenium-Osmium Isotopic Geochemistry Chinese Academy of Geological SciencesBeijing100037China

The Mg isotopic compositions of siliciclastic components(δ^(26)Mg_(sili))of sediments and sedimentary rocks have been commonly used to constrain the intensity of continental weathering,based on observations of,(1)an upward enrichment of26Mg in modern weathering profiles,(2)preferential uptake of26Mg in soil clays,and(3)general positive correlations between weathering intensities andδ^(26)Mg_(sili)***,not all weathering profiles display an upward increase ofδ^(26)Mg_(sili),and not all soil clays enrich in26Mg,complicating the interpretations ofδ^(26)Mg_(sili)data of sediments and sedimentary *** further explore the controls ofδ^(26)Mg_(sili)of sediments and sedimentary rocks,here we measuredδ^(26)Mg_(sili),mineralogical compositions and major element compositions of deep sea sediments from South China Sea(SCS)and carbonate rock samples from two late Paleozoic sections in South *** samples show decreasing trends of both normalized Mg concentration(Mgnorm)andδ^(26)Mg_(sili)values with the increase of weathering intensity,while SCS sediments samples do not show any correlation between Mgnormorδ^(26)Mg_(sili)values and weathering intensity.A three-stages weathering model is developed to explain the observed Mgnorm andδ^(26)Mg_(sili)*** the new model,weathering can be divided into three stages,(1)the preliminary weathering stage characterized by dissolution of primary minerals and formation of secondary clay minerals in saprolite,(2)the transitional stage with massive vermiculite and chlorite formation on the bottom of soil,and(3)the advanced stage showing dissolution of vermiculite and chlorite in the top of *** new model explains anδ^(26)Mg_(sili)increase and Mgnormdecrease with an increase weathering intensity in preliminary weathering stage and decrease of Mgnormandδ^(26)Mg_(sili)with increase weathering intensity in advanced weathering *** revised weathering model warrants the application of Mg isotope in the study of contin

关键词： Clay mineral Chemical weathering CIA Soil Weathering model

In Situ-Constructed lixMoS2 with Highly Exposed Interface Boosting High-Loading and Long-life Cathode for All-Solid-State li-S Batteries

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Energy & Environmental Materials 2024年第4期7卷 163-174页

作者： Hao li Rui Wang Jiangping Song Dan liu Hongyang Gao Yimin chao Haolin Tang A State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Department of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory School of Chemistry University of East Anglia

As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes (SSEs) have been incorporated into the cathode to facilitate ion/electron pathways around ***,this has resulted in a reduced capacity and decomposition of SSEs.

关键词： all-solid-state lithium–sulfur batteries conversion/intercalation high-loading and long-life low carbon content mixed ionic/electronic conductivities