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Chinese Journal of Structural Chemistry 2020年第8期39卷 1503-1508,1361页

作者： lai heng-dong LIN Qi-Pu State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China

Under solvothermal conditions,two ribbon-shaped chalcogenidometalate coordination compounds(butyl-Sn)4S8M2(TEPA)2(M=Mn(1),Ni(2),TEPA=tetraethylenepentamine),have been synthesized and characterized by elemental analysis,energy dispersive X-ray,infrared/ultraviolet-visible spectroscopy,thermogravimetric analysis,single-crystal and powder X-ray *** 1 and 2 crystallize in the triclinic space group P1 with a=13.999(3),b=14.658(4),c=16.150(4)A,a=68.78(3)°,β=69.12(3)°,γ=72.07(3)°,V=2825.0(14)A3,Z=2,Mr=1448.28,μ=2.503 mm-1,F(000)=1444,GOOF=1.001,R=0.0629 and wR=0.1286 for 12855 observed reflections with I>2σ(I)for 1;and a=11.029(3),b=11.858(2),c=11.888(3)A,a=87.27(2)°,β=69.10(2)°,γ=83.63(2)°,V=1443.6(6)A^3,Z=1,Mr=1455.78,μ=2.660 mm^-1,F(000)=728,GOOF=1.017,R=0.0464 and wR=0.1185 for 9267 observed reflections with I>2σ(I)for 2,*** 1 and 2 are composed of linear hexamer{Sn4M2}(M=Mn for 1,and Ni for 2)with 8μ2-S2-bridges and 2 TEPA terminal *** the quite large inter-paramagnetic-cation spacing(dMn-S-Sn-S-Sn-S-Sn-S-Sn-S-Mn=13.485 A,dNi-S-Sn-S-Sn-S-Sn-S-Sn-S-Ni=14.078 A),two samples exhibit distinct ferromagnetic-like behaviors with the intradimer coupling constant(J)and Weiss(θ)values up to 6.8 cm^-1 and 8.5 K for 1 and 17.2 cm-1 and 21.1 K for 2 calculated from the temperature dependence of the magnetic susceptibility.

关键词： chalcogenidometalates organotin-sulfides linear complexes magnetic properties

Endoscopic treatment of extreme esophageal stenosis complicated with esophagotracheal fistula: A case report

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World Journal of Gastrointestinal Surgery 2024年第1期16卷 239-247页

作者： Jia-heng Fang Wei-Min Li Cheng-Hai He Jian-Liang Wu Yun Guo Zhi-Chao lai Guo-dong Li Department of Gastroenterology Hangzhou Normal University Affiliated HospitalHangzhou 310000Zhejiang ProvinceChina

BACKGROUND At present,there is no unified and effective treatment for extreme corrosive esophageal stenosis(CES)with esophagotracheal fistula(ETF).This case had extreme and severe esophageal stenosis(ES)and ETF after ingesting an enzyme-based chemical detergent,resulting in a serious pulmonary infection and severe *** gastrointestinal imaging showed that he had an ETF,and endoscopy showed that he had extreme and severe esophageal *** case was complex and difficult to *** to the domestic and foreign lite-rature,there is no universal treatment that is *** SUMMARY A patient came to our hospital with extreme ES,an ETF,and severe malnutrition complicated with pulmonary tuberculosis 1 mo after the consumption of an enzy-me-based *** ES was serious,and the endoscope was unable to pass through the *** treated him by endoscopic incision method(EIM),esophageal stent placement(ESP),and endoscopic balloon dilation(EBD)by using the bronchoscope and *** treatment not only closed the ETF,but also expanded the esophagus,with minimal trauma,greatly reducing the pain of the *** to the literature,there are no similar reported *** We report,for the first time,a patient with extreme CES complicated with ETF,where the endoscope could not be passed through his esophagus but he could be examined by bronchoscopy and treated by EIM,ESP,and EBD.

关键词： Extreme corrosive esophageal stenosis Esophagotracheal fistula Endoscopic incision method Esophageal stent placement Endoscopic balloon dilation Case report

Strong-field photoelectron holography in the subcycle limit

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Light(Science & Applications) 2024年第6期13卷 1032-1040页

作者： Tsendsuren Khurelbaatar Jaewuk Heo ShaoGang Yu XuanYang lai XiaoJun Liu dong Eon Kim Center for Attosecond Science and Technology Department of PhysicsPohang University of Science and TechnologyPohangGyeongbuk37673Korea Max Planck POSTECH/KOREA Research Initiative PohangGyeongbuk37673Korea State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Wuhan Institute of Physics and MathematicsInnovation Academy for Precision Measurement Science and TechnologyChinese Academy of Sciences430071WuhanChina Wuhan Institute of Quantum Technology 430206WuhanChina

Strong-field photoelectron holography is promising for the study of electron dynamics and structure in atoms and molecules,with superior spatiotemporal resolution compared to conventional electron and X-ray ***,the application of strong-field photoelectron holography has been hindered by inter-cycle interference from multicycle ***,we address this challenge by employing a near-single-cycle field to suppress the inter-cycle *** observed and separated two distinct holographic patterns for the first *** measurements allow us not only to identify the Gouy phase effect on electron wavepackets and holographic patterns but also to correctly extract the internuclear separation of the target molecule from the holographic *** work leads to a leap jump from theory to application in the field of strong-field photoelectron holography-based ultrafast imaging of molecular structures.

关键词： photoelectron holographic cycle

Regulation role of miR-204 on SIRT1/VEGF in metabolic memory induced by high glucose in human retinal pigment epithelial cells

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International Journal of Ophthalmology(English edition) 2024年第7期17卷 1232-1237页

作者： Qiao-Ling lai Ting Xie Wei-dong Zheng Yan Huang Department of Ophthalmology Renmin Hospital of Wuhan UniversityWuhan 460060Hubei ProvinceChina Department of Ophthalmology The First Affiliated Hospital of Fujian Medical UniversityFuzhou 350004Fujian ProvinceChina Department of Ophthalmology&Optometry Fujian Medical UniversityFuzhou 350004Fujian ProvinceChina

AIM:To examine the regulatory role of microRNA-204(miR-204)on silent information regulator 1(SIRT1)and vascular endothelial growth factor(VEGF)under highglucose-induced metabolic memory in human retinal pigment epithelial(hRPE)***:Cells were cultured with either normal(5 mmol/L)or high D-glucose(25 mmol/L)concentrations for 8d to establish control and high-glucose groups,*** induce metabolic memory,cells were cultured with 25 mmol/L D-glucose for 4d followed by culture with 5 mmol/L D-glucose for *** addition,exposed in 25 mmol/L D-glucose for 4d and then transfected with 100 nmol/L miR-204 control,miR-204 inhibitor or miR-204 mimic in 5 mmol/L D-glucose for *** reverse transcription-polymerase chain reaction(RT-qPCR)was used to detect miR-204 mRNA ***1 and VEGF protein levels were assessed by immunohistochemical and Western *** cytometry was used to investigate apoptosis ***:It was found that high glucose promoted miR-204 and VEGF expression,and inhibited SIRT1 activity,even after the return to normal glucose culture *** of miR-204 promoted apoptosis inhibiting SIRT1 and increasing VEGF ***,downregulation of miR-204 produced the opposite ***:The study identifies that miR-204 is the upstream target of SIRT1and VEGF,and that miR-204 can protect hRPE cells from the damage caused by metabolic memory through increasing SIRT1 and inhibiting VEGF expression.

关键词： human retinal pigment epithelial metabolic memory microRNA-204 silent information regulator 1 vascular endothelial growth factor high-glucose

Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries

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Energy & Environmental Materials 2024年第4期7卷 28-47页

作者： Honggang He Litong Wang Malek Al-Abbasi Chunyan Cao heng Li Zhu Xu Shi Chen Wei Zhang Ruiqing Li Yuekun lai Yuxin Tang Mingzheng Ge School of Textile and Clothing Nantong University School of Science Qingdao University of Technology Department of Biomedical Sciences City University of Hong Kong Institute of Applied Physics and Materials Engineering University of Macau College of Chemical Engineering Fuzhou University

Solid-state lithium batteries (SSLBs) with high safety have emerged to meet the increasing energy density demands of electric vehicles,hybrid electric vehicles,and portable electronic ***,the dendrite formation,high interfacial resistance,and deleterious interfacial reactions caused by solid-solid contact between electrode and electrolyte have hindered the commercialization of SSLBs.

关键词： dendrite formation high energy density interface instability interfacial resistance solid-state electrolyte

Room-temperature phonon-coupled single-photon emission in hexagonal boron nitride

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Science China(Physics,Mechanics & Astronomy) 2024年第5期67卷 109-114页

作者： Jia-Min lai Qing-Hai Tan Feilong Song Haonan Chang Yanpei Lv Xue-Lu Liu Jinghua Teng Weibo Gao Ping-heng Tan Jun Zhang State Key Laboratory of Superlattices and Microstructures Institute of SemiconductorsChinese Academy of SciencesBeijing100083China Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education&Research Institute of Materials Science Shanxi Normal UniversityTaiyuan 030000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Division of Physics and Applied Physics School of Physical and Mathematical SciencesNanyang Technological UniversitySingapore 637371Singapore Institute of Materials Research and Engineering(IMRE) Agency for ScienceTechnology and Research(A*STAR)Singapore 138634Singapore

Photon-lattice(phonon)coupling is fundamental to light-matter interaction,particularly when it reaches the quantum limit of the phonon-coupled single-photon emission,which holds great potential for quantum manipulation and quantum information ***,we report single defect state-phonon coupling in hexagonal boron nitride(h BN)at room *** ultrabroad spectrum of single-photon emissions can be achieved by selecting the excitation *** photoluminescence excitation spectroscopy,we observe single-phonon-assisted resonance-enhanced single-photon emission,along with multiple phonon replicas that herald the creation of phonon Fock *** also develop a transition model to gain insight into the physical process behind the single defect state-phonon *** work sets the stage for manipulating electron-phonon coupling state with single quantum-level precision at room temperature.

关键词： temperature phonon hexagonal

Acidic electroreduction CO_(2)to formic acid via interfacial modification of Bi nanoparticles at industrial-level current

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Nano Research 2024年第7期17卷 5817-5825页

作者： Tian dong Hongdong Li Zhenhui Wang Yanling Geng Rui Chang Xiaofeng Tian Jianping lai Shouhua Feng Lei Wang Key Laboratory of Eco-Chemical Engineering International Science and Technology Cooperation Base of Eco-Chemical Engineering and Green ManufacturingCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

Electrocatalytic CO_(2)reduction reaction(CO_(2)RR)in acidic media is a promising approach to overcome the unavoidable formation of carbonates in alkaline or neutral ***,the proton-rich environment near the catalyst surface favors hydrogen evolution reactions(HER),leading to lower energy efficiency of the desired products,especially in industrial-level current ***,quaternary ammonium cationic surfactant(cetyltrimethylammonium bromide(CTAB))was introduced into acidic electrolyte to modulate the interfacial microenvironment,which greatly enhanced CO_(2)electroreduction to formic acid(HCOOH)at the Bi/C nanoparticles *** a Bi/C nanoparticles electrode with CTAB added,constant production of formic acid was enabled with a cathodic energy efficiency of>40%and maximum FE_(HCOOH)(FE=Faradaic efficiency)of 86.2%at−400 mA·cm^(−2)over 24 *** with in-situ attenuated total reflection Fourier transform infrared spectroscopy,the concentration of*OCHO intermediates significantly increased after CTAB modification,confirming that the hydrophobic interface microenvironment formed by dynamic adsorption of positively charged long alkyl chains on Bi/C nanoparticle electrodes inhibited HER and improved the selectivity of CO_(2)RR to HCOOH.

关键词： acidic media CO_(2)electrolysis electrolyte additive hydrophobic interfacial microenvironment industrial-level current

High-performance ultrathin Ag electrodes by chemical bond anchoring Ag atoms for stretchable organic light-emitting devices

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Nano Research 2024年第8期17卷 7614-7620页

作者： Yue Qin Yawei Wang Xinxin Wang Yaqi Zhang Jiahao Xu Kanchi dong Yuehua Chen Wenyong lai Xinwen Zhang State Key Laboratory of Organic Electronics and Information Displays and Institute of Advanced Materials(IAM) Nanjing University of Posts and TelecommunicationsNanjing 210023China

The progress of stretchable organic light-emitting devices(OLEDs)has brought about new possibilities for highly functional wearable ***,the efficiency and durability of stretchable OLEDs have been limited by the performance of stretchable transparent ***,we proposed an interface engineering strategy that involves anchoring the growth of silver(Ag)atoms with amine-enriched biomaterials for high-quality stretchable transparent *** strong interactions between the Ag atom and the amine group enable the uniform Ag electrodes at an ultralow thickness of 7 nm,and provide remarkable mechanical flexibility and strain endurance to the Ag *** distinct effects of different amino acids were investigated,and a deep understanding of their unique contributions to the film formation process was *** resulting ultrathin Ag electrodes exhibit outstanding optoelectrical properties(transmittance of~98% and sheet resistance of~8.7Ω/sq)and excellent stretchability during 500 stretching cycles at 100%*** green phosphorescent OLEDs based on the Ag electrodes have been demonstrated with a current efficiency of up to~70.4 cd/***,the devices show excellent stretching stability,retaining~89% of the original luminance and~78% of the original current efficiency after 200 stretching cycles at 100%*** work opens up new possibilities for stretchable transparent electrodes,fostering advancements in wearable displays and other innovative flexible devices.

关键词： transparent flexible electrodes ultrathin metal film interface mechanical stability

Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole

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Chinese Chemical Letters 2024年第8期35卷 349-356页

作者： Chunxiu Yu Zelin Wu Hongle Shi Lingyun Gu Kexin Chen Chuan-Shu He Yang Liu heng Zhang Peng Zhou Zhaokun Xiong Bo lai State Key Laboratory of Hydraulics and Mountain River Engineering College of Architecture and EnvironmentSichuan UniversityChengdu 610065China Sichuan Academy of Eco-Environmental Sciences Chengdu 610041China Sino-German Centre for Water and Health Research Sichuan UniversityChengdu 610065China

Herein,a modified metal-free acetylene black(MMF-AB)catalyst was synthesized by a simple solvothermal-calcination method and designed successfully to activate peroxodisulfate(PDS)for the degradation of sulfisoxazole(SIZ).Due to the doping of N,S and O metal-free elements,the modified catalyst showed excellent catalytic performance with 100%SIZ removal within 30 *** first-order reaction rate constants(evaluating catalytic efficiencies and activity)of MMF-AB(kobs=0.105 min^(−1))was 3 times higher than pure-AB(k_(obs)=0.029 min^(−1)).Interestingly,it was demonstrated that the reaction sys-tem is based on the transfer of electrons from SIZ to PDS to realize an electron-transfer-based mechanism by the evidence of premixing,electron paramagnetic resonance(EPR)spectroscopy,salt-bridge experi-ments and electrochemical *** introduction of recyclable filtration device solved the secondary pollution caused by the dispersion of the powdered catalyst in the treated water,which further proved the practicality and superiority of the MMF-AB catalyst.

关键词： Peroxydisulfate Sulfisoxazole Acetylene black Electrochemical Electron transfer

Low-noise and low-power pixel sensor chip for gas pixel detectors

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Nuclear Science and Techniques 2024年第3期35卷 142-152页

作者： Zhuo Zhou Shi-Qiang Zhou dong Wang Xiang-Ming Sun Chao-Song Gao Peng-Zhen Zhu Wei-Ping Ren Jun Liu Mu-Xian Li Chen Lian Chun-lai dong PLAC Key Laboratory of Quark and Lepton Physics(MOE)Central China Normal UniversityWuhan 430079China

Topmetal-M2 is a large-area pixel sensor chip fabricated using the GSMC 130 nm CMOS process in *** pixel array of Topmetal-M2 consists of pixels of 400 rows×512 columns with a pixel pitch of 45μm×45μ*** array is divided into 16 subarrays,with pixels of 400 rows×32 columns per *** pixel incorporates two charge sensors:a diode sensor and a Topmetal *** in-pixel circuit primarily consists of a charge-sensitive amplifier for energy measurements,a discriminator with a peak-holding circuit,and a time-to-amplitude converter for time-of-arrival *** pixel of Topmetal-M2 has a charge input range of~0-3 k e-,a voltage output range of~0-180 mV,and a charge-voltage conversion gain of~59.56μV∕e-.The average equivalent noise charge of Topmetal-M2,which includes the readout electronic system noise,is~43.45 e-.In the scanning mode,the time resolution of Topmetal-M2 is 1 LSB=1.25μs,and the precision is^()7.41μ*** an operating voltage of 1.5 V,Topmetal-M2 has a power consumption of~49 mW∕cm~*** this article,we provide a comprehensive overview of the chip architecture,pixel working principles,and functional behavior of ***,we present the results of preliminary tests conducted on Topmetal-M2,namely,alpha-particle and soft X-ray tests.

关键词： Charge collection Gas detectors Semiconductor detectors X-ray detectors