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Biomass gasification,catalytic technologies and energy integration for production of circular methanol:New horizons for industry decarbonisation

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Journal of Environmental sciences 2024年第6期140卷 306-318页

作者： luis F.Bobadilla lola Azancot Miriam González-Castañ Estela ruíz-lópez laura pastor-Pérez Francisco J.Durán-Olivencia runping Ye Katie Chong paula HBlanco-sánchez Zenthao Wu Tomás r.reina JoséA.Odriozola Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de sevilla Centro Mixto CSIC-Universidad de SevillaAvda.Américo Vespucio 49Sevilla 41092Spain Departamento de Ingeniería Universidad Loyola AndalucíaAvda.de Las Universidades s/nSevilla 41704Spain Key laboratory of Jiangxi Province for Environment and Energy Catalysis School of Chemistry and Chemical EngineeringNanchang UniversityNanchang330031China Energy and Bioproducts research Institute(EBrI) Aston UniversityBirminghamB47ETUnited Kingdom Department of Chemical and Process Engineering University of SurreyGuildfordGU27XHUnited Kingdom

The Intergovernmental panel on Climate Change(IPCC)recognises the pivotal role of renewable energies in the future energy system and the achievement of the zero-emission *** implementation of renewables should provide major opportunities and enable a more secure and decentralised energy supply *** fuels provide long-term solutions for the transport sector,particularly for applications where fuels with high energy density are *** addition,it helps reducing the carbon footprint of these sectors in the *** on biomass characteristics feedstock is essential for scaling-up gasification from the laboratory to *** review deals with the transformation biogenic residues into a valuable bioenergy carrier like biomethanol as the liquid sunshine based on the combination of modified mature technologies such as gasification with other innovative solutions such as membranes and microchannel *** abatement is a critical process in product gas upgrading since tars compromise downstream processes and equipment,for this,membrane technology for upgrading syngas quality is discussed in this *** reactor technology with the design of state-of-the-art multifunctional catalysts provides a path to develop decentralised biomethanol synthesis from biogenic ***,the development of a process chain for the production of(i)methanol as an intermediate energy carrier,(ii)electricity and(iii)heat for decentralised applications based on biomass feedstock flexible gasification,gas upgrading and methanol synthesis is analysed.

关键词： Biogenic residues Gasification Biomethanol Circular Economy Microreactors

Using proteomics to compare the molecular structures of sulfide and permeate-depilated sheepskins

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Collagen and leather 2024年第1期6卷 70-84页

作者： Yi-Hsuan Tu Trevor s.loo Mark l.patchett Gillian E.Norris school of Natural sciences Massey UniversityPalmerston NorthNew Zealand

An environmentally friendly method using real or artificial bovine milk permeate to both depilate and preserve sheepskins has been reported which completely and cleanly removed the wool from the hair follicle and had no detrimental effects on the skin.A proteomic analysis,assessing the relative abundance of proteins in matched permeate-depilated and chemically depilated(sulfide)sheepskins,showed variations in the levels of specific collagen types in the skin's basement membrane and other proteins associated with the *** findings were corroborated by biochemical analyses of matched permeate depilated and raw skin samples,and provide clues to the mechanism of non-invasiveand complete *** also support the observation that permeate-depilated skins were smoother than their sulfide-depilated counterparts and resulted in leather with a superior surface.

关键词： Collagen Collagen crosslinks Glycosaminoglycan Proteomics relative abundance

Characterization of early maturing elite genotypes based on MTsI and MGIDI indexes:an illustration in upland cotton(Gossypium hirsutum l.)

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Journal of Cotton research 2024年第3期7卷 253-265页

作者： D s rAJ supritha paTIl rajesh s. paTIl Bhuvaneshwara r. NAYAK spurthi N. paWAr Kasu N. Department of Genetics and Plant Breeding College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Agricultural research station Dharwad 580005India Department of Biotechnology College of AgricultureUniversity of Agricultural SciencesDharwad 580005India Department of Crop Physiology College of AgricultureUniversity of Agricultural SciencesDharwad 580005India

Background Globally,the cultivation of cotton is constrained by its tendency for extended periods of *** maturity plays a potential role in rainfed-based multiple cropping system especially in the current era of climate *** the current study,a set of 20 diverse Gossypium hirsutum genotypes were evaluated in two crop seasons with three planting densities and assessed for 11 morphological traits related to early *** study aimed to identify genotype(s)that mature rapidly and accomplish well under diverse environmental conditions based on the two robust multivariate techniques called multi-trait stability index(MTsI)and multi-trait genotype-ideotype distance index(MGIDI).results MTsI analysis revealed that out of the 20 genotypes,three genotypes,viz.,NNDC-30,A-2,and s-32 accomplished well in terms of early maturity traits in two ***,three genotypes were selected using MGIDI method for each planting densities with a selection intensity of 15%.The strengths and weaknesses of the genotypes selected based on MGIDI method highlighted that the breeders could focus on developing early-maturing genotypes with specific traits such as days to first flower and boll *** selected genotypes exhibited positive genetic gains for traits related to earliness and a successful harvest during the first and second ***,there were negative gains for traits related to flowering and boll *** The study identified three genotypes exhibiting early maturity and accomplished well under different planting *** multivariate methods(MTsI and MGIDI)serve as novel approaches for selecting desired genotypes in plant breeding programs,especially across various growing *** methods offer exclusive benefits and can easily construe and minimize multicollinearity issues.

关键词： Cotton MTsI MGIDI Genotype environment interaction Early maturity Multi-trait Multi-environment

system integration analysis of a zeolite 13x thermal energy storage

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Energy and Built Environment 2024年第4期5卷 568-579页

作者： s.De Antonellis l.P.M.Colombo P.Castellazzi A.rossetti l.Marocco Politecnico di Milano Department of Energyvia Lambruschini 4Milan 20156Italy ricerca sul sistema Energetico-rsE s.p.A. Tecnologie di Generazione e Materialivia R.Rubattino 54Milan 20134Italy

Nowadays a major energy transition aimed at cutting CO 2 emissions has begun,with the ambitious goal of drasti-cally reducing the dependence on fossil fuels and promoting the use of renewable energy *** this context,energy storage systems play a key role in ensuring a stable,secure and time-aligned energy *** sorption thermal energy storages(TEss)can contribute to such transition,since they are simple and cheap devices able to provide a hot airflow with a high energy density and to store energy for long *** this work,open sorption TEs systems operated with Zeolite13X are investigated with a focus on the integration in practical ***,the experimental analysis and modelling of the sole TEs system is ***,the integration of the TEs at system level is carried *** analysis evidences that a significant reduction of storage capac-ity occurs if air humidification is necessary before the adsorption process or afterwards to keep adequate indoor comfort conditions for the *** the exemplary case study considered,an energy density of 150 kWhm^(−3) can drop to 40 kWhm−3 in case of complete compensation of the adsorbed water through a *** paper provides useful guidelines for evaluating the performance of a TEs integrated system in terms of specific energy and *** also identifies applications involving high latent loads(e.g.,swimming pools,locker rooms)or for which low relative air humidity is required(*** of vehicles to prevent condensation on windows)as particularly beneficial for using a TEs system.

关键词： Energy storage Adsorption Zeolite system integration Numerical model

sodium nitroprusside as a signal molecule for up-regulating membrane characteristics,antioxidant defense system to improve flax productivity under water stress

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Oil Crop science 2024年第3期9卷 160-169页

作者： N.M.Al-Ashkar B.A.Bakry H.M.s.El-Bassiouny M.M.s.Abdallah M.s.sadak Botany Department Agricultural and Biological Research InstituteNational Research Centre33 El Bohouth Street P.O.12622DokkiGizaEgypt Field Crops research Department Agricultural and Biological Research InstituteNational Research Centre33 El Bohouth Street P.O.12622DokkiGizaEgypt

Water stress is a critical environmental adversity that significantly impacts the growth,development,and yield of flax *** this study,flax seeds were cultivated under different water irrigation requirements(WIr)(100%,75%,and 50%)to investigate the effects of exogenously supplied nitric oxide(NO)donor sodium nitroprusside(sNP)as foliar treatments at concentrations of 0.0 mmol/l,0.5 mmol/l,1.0 mmol/l,and 2.0 mmol/*** stress led to a significant decrease in plant growth,photosynthetic pigments,yield components such as oil and total carbohydrate *** also resulted in an increase in leaf H2O2 production,lipid peroxidation levels and activities of enzymatic antioxidants including polyphenol oxidase,superoxide dismutase,and nitrate reductase ***,foliar application of sNP improved photosynthetic pigments and antioxidant defense system which mitigated the negative impact of water stress on growth and yield productivity by reducing oxidative damage caused by reactive oxygen species *** use of sNP also decreased H_(2)O_(2) accumulation levels,lipid peroxidation levels,and improved membrane *** treatment at concentration of 2 mmol/l showed superior results compared to other concentrations with extremely significant increases observed in yield characteristics such as oil content,total carbohydrate percentages,and unsaturated fatty acids to saturated fatty acids ratio.

关键词： Flax Fatty acid sodium nitroprusside Antioxidant enzymes Yield

Exact solutions for magnetohydrodynamic nanofluids flow and heat transfer over a permeable axisymmetric radially stretching/shrinking sheet

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Chinese Physics B 2024年第2期33卷 108-114页

作者： U.s.Mahabaleshwar G.P.Vanitha l.M.Pérez Emad H.Aly I.Pop Department of studies in Mathematics Davangere UniversityShivagangothriDavangereIndia Departamento de F´ısica FACIUniversidad de Tarapac´aCasilla 7DAricaChile Department of Mathematics Faculty of EducationAin Shams UniversityRoxyCairoEgypt Department of Mathematics Babes-Bolyai University400084 Cluj-NapocaRomania

We report on the magnetohydrodynamic impact on the axisymmetric flow of Al_(2)O_(3)/Cu nanoparticles suspended in H_(2)O past a stretched/shrinked *** the use of partial differential equations and the corresponding thermophysical characteristics of nanoparticles,the physical flow process is *** resultant nonlinear system of partial differential equations is converted into a system of ordinary differential equations using the suitable similarity *** transformed differential equations are solved *** of the magnetic parameter,solid volume fraction and stretching/shrinking parameter on momentum and temperature distribution have been analyzed and interpreted *** skin friction and Nusselt number were also *** addition,existence of dual solution was deduced for the shrinking sheet and unique solution for the stretching ***,Al_(2)O_(3)/H_(2)O nanofluid flow has better thermal conductivity on comparing with Cu/H_(2)O ***,it was found that the first solutions of the stream are stable and physically realizable,whereas those of the second ones are unstable.

关键词： magnetohydrodynamic nanofluid stretching/shrinking sheet axisymmetric flow analytical solution suction/injection

Impact of paenibacillus elgii supernatant on screening bacterial strains with potential for biotechnological applications

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Engineering Microbiology 2024年第3期4卷 1-15页

作者： I.C.Cunha-Ferreira C.s.Vizzotto T.D.Frederico J.Peixoto l.s Carvalho M.r.Tótola r.H.Krüger laboratory of Enzymology Department of Cellular BiologyUniversity of Brasília(UNB)Brasília70910-900Brazil laboratory of Environmental sanitation Department of Civil and Environmental EngineeringUniversity of Brasília(UNB)Brasília70910-900Brazil laboratório de Biotecnologia e Biodiversidade para o Meio Ambiente Universidade Federal de Viçosa(UFV)Viçosa36570-900Brazil

The biotechnological industry faces a crucial demand for novel bioactive compounds,particularly antimicrobial agents,to address the rising challenge of bacterial resistance to current available *** strate-gies for cultivating naturally occurring microorganisms often limit the discovery of novel antimicrobial *** study presents a protocol for targeted selection of bacterial strains using the supernatant of paenibacillus el-gii,which produces abundant signal molecules and antimicrobial *** samples were inoculated in these enriched culture media to selectively cultivate bacteria resistant to the supernatant,indicating their potential to produce similar *** bacterial strains isolated through this method were assessed for their antibac-terial *** addition,the functional annotation of the genome of one of these strains revealed several gene clusters of biotechnological *** study highlights the effectiveness of using this approach for selective cultivation of microorganisms with potential for biotechnological applications.

关键词： Prospecting supernatant Antibacterial activity

Metal-modulated epitaxy of Mg-doped Al_(0.80)In_(0.20)N-based layer for application as the electron blocking layer in deep ultraviolet light-emitting diodes

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Journal of semiconductors 2024年第5期45卷 80-89页

作者： Horacio Irán solís-Cisneros Carlos Alberto Hernández-Gutiérrez Enrique Campos-González Máximo lópez-lópez Optomechatronics Group Tecnológico Nacional de México Campus Tuxtla Gutiérrezcarretera Panamericana 1080C.P.29050Tuxtla GutiérrezChiapasMéxico Departamento de Física Instituto Nacional de Investigaciones NuclearesCarretera México-Toluca s/nC.P.52750La Marquesa OcoyoacacMéxico Departamento de Física Centro de Investigación y estudios Avanzados del Instituto Politécnico NacionalAv.Instituto Politécnico Nacional 2508San Pedro ZacatencoGustavo A.Madero07360 Ciudad de MéxicoCDMXMéxico

This work reports the growth and characterization of p-AlInN layers doped with Mg by plasma-assisted molecular beam epitaxy(paMBE).AlInN was grown with an Al molar fraction of 0.80 by metal-modulated epitaxy(MME)with a thickness of 180 nm on si(111)substrates using AlN as buffer *** substrate temperatures were used to enhance the incorporation of indium atoms into the alloy without clustering,as confirmed by X-ray diffraction(XrD).Cathodoluminescence measurements revealed ultraviolet(UV)range ***,Hall effect measurements indicated a maximum hole mobility of 146 cm^(2)/(V∙s),corresponding to a free hole concentration of 1.23×10^(19)cm^(−3).The samples were analyzed by X-ray photoelectron spectroscopy(XPs)estimating the alloy composition and extracting the Fermi level by valence band ***-doped AlInN layers were studied for use as the electron-blocking layer(EBl)in lED *** varied the Al composition in the EBl from 0.84 to 0.96 molar fraction to assess its theoretical effects on electroluminescence,carrier concentration,and electric field,using sIlVACO *** results from this study highlight the importance and capability of producing high-quality Mg-doped p-AlInN layers through *** simulations suggest that an Al content of 0.86 is optimal for achieving desired outcomes in electroluminescence,carrier concentration,and electric field.

关键词： metal-modulated epitaxy AlInN DUV-lED EBl simulation

The effect of electrical current on lubricant film thickness in boundary and mixed lubrication contacts measured with ultrasound

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Friction 2024年第8期12卷 1882-1896页

作者： Julio A.CAO-rOMErO-GAllEGOs saeid TAGHIZADEH Oscar A.AGUIlAr-rOsAs r.s.DWYEr-JOYCE leonardo I.FArFAN-CABrErA Tecnologico de Monterrey Escuela de Ingeniería y CienciasAve.Eugenio Garza Sada 2501MonterreyN.L.64849México Department of Mechanical Engineering Leonardo Centre for TribologyUniversity of SheffieldSheffield S13JDUK

This work explores experimentally the effects of DC electrical currents on lubricant film thickness alteration in lubricated sliding steel contacts in the boundary and mixed regime as measured by *** experiments were performed in a two-electrode cell-based pin-on-disk tester instrumented with ultrasonic *** and electrified tribological tests were conducted on steel flat-on-flat contacts under various speeds and loads using both a mineral base oil and a gear *** thickness,coefficient of friction(CoF),and electrical contact resistance(ECr)were measured during short experiments(30 s)in unelectrified and electrified(1.5 and 3 A)*** results suggest that film thickness,CoF,and all ECr are altered by passing DC currents through the *** particular,film thickness increased and decreased,respectively,by applying electricity at the different speeds and loads *** alterations were majorly ascribed to oil viscosity decrease by local heat and surface oxidation caused by electrical discharge and break down at the interface.

关键词： electrified sliding ultrasonic measurement electric vehicles pin-on-disk