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Iron–doped bismuth oxybromides as visible-light-responsive Fenton catalysts for the degradation of atrazine in aqueous phases

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Journal of Environmental Sciences 2024年第3期137卷 321-332页

作者： Yong-li Cai Yu-hang Xu Ji-Zun Xiang Zhi-Qiang zhang Qiu-Xiang he Ya-Feng li Jian lü Fujian Provincial Key laboratory of Soil Environmental health and Regulation College of Resources and EnvironmentFujian Agriculture and Forestry UniversityFuzhou 350002China State Key laboratory of Photocatalysis on Energy and Environment Fuzhou UniversityFuzhou 350116China

Pesticides and its degradation products,being well–known residues in soil,have recently been detected in many water bodies as pollutants of emerging concerns,and thus there is a contemporary demand to develop viable and cost–effective techniques for the removal of related organic pollutants in aqueous ***,a visible-light-responsive Fenton system was constructed with iron–doped bismuth oxybromides(Fe–BiOBr)as the *** the advantage of sustainable Fe(Ⅲ)/Fe(Ⅱ)conversion and optimized h_(2)O_(2)utilization,the optimal Fe–BiOBr–2 catalyst showed an excellent atrazine removal efficiency of 97.61%in 120 min,which is superior than the traditional homogeneous Fenton and the majority of heterogeneous processes documented in the *** this photo–Fenton system,hydroxyl(·Oh)and superoxide(·O_(2)^(-))radicals were dominant active species contributed to the oxidative degradation of *** to the production of various active radicals,five degradation pathways were proposed based on the identification of intermediates and degradation ***,this work not only demonstrates a fundamental insight into creating highly efficient and atom economic photo-Fenton systems,but also provides a complementary strategy for the treatment of organic pollutants in water.

关键词： Bismuth oxybromide Photo–Fenton Atrazine Catalytic degradation

Characterization of local chemical ordering and deformation behavior in high entropy alloys by transmission electron microscopy

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 877-886页

作者： Qiuhong liu Qing Du Xiaobin zhang Yuan Wu Andrey A.Rempel Xiangyang Peng Xiongjun liu hui Wang Wenli Song Zhaoping lü Beijing Advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083China School of Materials Science and Engineering Ocean University of ChinaQingdao 266100China Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences Ekaterinburg 620016Russia China Nuclear Power Technology Research Institute Co.ltd. Shenzhen 518000China Institute of high Energy Physics Chinese Academy of Sciences(CAS)Beijing 100049China Spallation Neutron Source Science Center Dongguan 523803China

Short-range ordering(SRO)is one of the most important structural features of high entropy alloys(hEAs).however,the chemical and structural analyses of SROs are very difficult due to their small size,complexed compositions,and varied *** electron microscopy(TEM)as well as its aberration correction techniques are powerful for characterizing SROs in these compositionally complex *** this short communication,we summarized recent progresses regarding characterization of SROs using TEM in the field of *** using advanced TEM techniques,not only the existence of SROs was confirmed,but also the effect of SROs on the deformation mechanism was ***,the perspective related to application of TEM techniques in hEAs are also discussed.

关键词： high entropy alloys transmission electron microscopy short-range ordering deformation mechanisms

A Possible γ-Ray Pulsation from PSR J1740-5340B in the Globular Cluster NGC 6397

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Research in Astronomy and Astrophysics 2024年第1期24卷 285-291页

作者： Jiao Zheng Pengfei zhang li zhang Department of Astronomy School of Physics and AstronomyKey Laboratory of Astroparticle Physics of Yunnan ProvinceYunnan UniversityKunming 650091China

Recently, a new radio millisecond pulsar(MSP) J1740-5340B, hosted in the globular cluster(GC) NGC 6397,was reported with a 5.78 ms spin period in an eclipsing binary system with a 1.97 days orbital period. Based on a modified radio ephemeris updated by tool tempo2, we analyze the ~15 yr γ-ray data obtained from the large Area Telescope on board the Fermi Gamma-ray Space Telescope and detect PSR J1740-5340B's γ-ray pulsation at a confidence level of ~4σ with a weighted h-test value of ~26. By performing a phase-resolved analysis, the γ-ray luminosity in on-pulse interval of PSR J1740-5340B is l_(γ)~ 3.8 × 10^(33) erg s^(-1) using NGC 6397's distance of 2.48 kpc. And γ-rays from the on-pulse part of PSR J1740-5340B contribute ~90% of the total observed γ-ray emissions from NGC 6397. No significant γ-ray pulsation of another MSP J1740-5340A in the GC is *** that the previous four cases of MSPs in GCs, more data in γ-ray, X-ray, and radio are encouraged to finally confirm the γ-ray emissions from MSP J1740-5340B, especially starving for a precise ephemeris.

关键词： gamma-rays:galaxies (stars:)pulsars:individual(PSR J1740-5340B) (Galaxy:)globular clusters:individual(NGC 6397)

Strategies to achieve effective nitrogen activation

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Carbon Energy 2024年第5期6卷 137-163页

作者： Bin Chang huabin zhang Shuhui Sun Gaixia zhang KAUST Catalysis Center(KCC) King Abdullah University of Science and Technology(KAUST)ThuwalKingdom of Saudi Arabia Institut National de la Recherche Scientifique(INRS) CentreÉnergie Matériaux TélécommunicationsVarennesQuébecCanada Department of Electrical Engineering École de Technologie Supérieure(ÉTS)MontréalQuébecCanada

Ammonia serves as a crucial chemical raw material and hydrogen energy *** electrocatalytic nitrogen reduction reaction(NRR),powered by renewable energy,has attracted tremendous interest during the past few *** some achievements have been revealed in aqueous NRR,significant challenges have also been *** activity and selectivity are fundamentally limited by nitrogen activation and competitive hydrogen *** review focuses on the hurdles of nitrogen activation and delves into complementary strategies,including materials design and system optimization(reactor,electrolyte,and mediator).Then,it introduces advanced interdisciplinary technologies that have recently emerged for nitrogen activation using high-energy physics such as plasma and *** a better understanding of the corresponding reaction mechanisms in the coming years,these technologies have the potential to be extended in further *** review provides further insight into the reaction mechanisms of selectivity and stability of different reaction *** then recommend a rigorous and detailed protocol for investigating NRR performance and also highlight several potential research directions in this exciting field,coupling with advanced interdisciplinary applications,in situ/operando characterizations,and theoretical calculations.

关键词： activation via mediators catalyst optimization electrochemical nitrogen fixation high-energy activation of nitrogen nitrogen

Effect of Shape and Placement of Twisted Pin Fins in a Rectangular Channel on Thermo-hydraulic Performance

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Journal of Thermal Science 2024年第5期33卷 1773-1793页

作者： lI Yong zhang Jin zhang Yingchun zhang Jiajie MA Suxia SUNDEN Bengt XIE Gongnan College of Electrical and Power Engineering Taiyuan University of TechnologyTaiyuan 030024China Key laboratory of Cleaner Intelligent Control on Coal&Electricity Ministry of EducationTaiyuan 030024China Shanxi Provincial Key laboratory of high Efficiency heat Storage and low Carbon heat Supply Taiyuan 030008China School of Energy and Power Engineering North University of ChinaTaiyuan 030051China Department of Energy Sciences Lund UniversityP.O.Box 118Lund SE 22100Sweden School of Marine Science and Technology Northwestern Polytechnical UniversityXi'an 710072China

To enhance the thermo-hydraulic performance of cooling channels,this investigation examines the influence of distinct cross-sectional shapes(i.e.,triangular,rectangular,and hexagonal)of twisted pin fins and their arrangements in straight and cross *** ambient air cooling test platform was established to numerically and experimentally investigate the flow and heat transfer characteristics of 360°twisted pin fins at Re=*** findings reveal that straight rows exhibit higher Nu values than cross rows for triangular and rectangular twisted pin fins,and Nu increases with *** contrast,for hexagonal twisted pin fins,only straight rows at Re=19000 exhibit superior overall thermal performance compared to cross ***,the heat transfer performance of the cooling channel with hexagonal twisted fins surpasses both triangular and rectangular configurations,especially at high Reynolds numbers(Re=22800).Although the heat transfer coefficient of the cooling channel with hexagonal twisted fins is significantly enhanced by 132.71%compared to the flat channel,it also exhibits the highest thermal resistance and relative friction among the three types of twisted fins,the maximum of which are 2.14 and ***,the hydrothermal performance factor(hTPF)of the cooling channels with different types of twisted pin fins depends on the Reynolds number and arrangement *** Re=15200,the highest hTPF achieved for the cross-row hexagonal twisted pin fins is 0.99.

关键词： twisted pin fin cross arrangement heat transfer pressure drop hTPF

Advances in doping strategies for sodium transition metal oxides cathodes:A review

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Frontiers in Energy 2024年第2期18卷 141-159页

作者： Zhijing zhang haoze zhang Yaopeng WU Wei YAN Jiujun zhang Yun ZhENG lanting QIAN Department of Chemical Engineering Waterloo Institute of NanotechnologyUniversity of WaterlooWaterloo ON N2L 3G1Canada School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou 510640China Institute of New Energy Materials Science and Engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

The electrochemistry of cathode materials for sodium-ion batteries differs significantly from lithium-ion batteries and offers distinct ***,the progress of commercializing sodium-ion batteries is currently impeded by the inherent inefficiencies exhibited by these cathode materials,which include insufficient conductivity,slow kinetics,and substantial volume changes throughout the process of intercalation and deintercalation ***,numerous methodologies have been utilized to tackle these challenges,encompassing structural modulation,surface modification,and elemental *** paper aims to highlight fundamental principles and strategies for the development of sodium transition metal oxide ***,it emphasizes the role of various elemental doping techniques in initiating anionic redox reactions,improving cathode stability,and enhancing the operational voltage of these cathodes,aiming to provide readers with novel perspectives on the design of sodium metal oxide cathodes through the doping approach,as well as address the current obstacles that can be overcome/alleviated through these dopant strategies.

关键词： sodium-ion batteries transition metal cathode doping strategy

Surface engineering with ionic polymers on membranes for boron removal

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Frontiers of Chemical Science and Engineering 2024年第5期18卷 61-69页

作者： Xiting zhang Chenyi Fang J Paul Chen Sui zhang Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117576Singapore Department of Civil and Environmental Engineering National University of SingaporeSingapore 119260Singapore College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

Removal of boric acid from seawater and wastewater using reverse osmosis membrane technologies is imperative and yet remains inadequately addressed by current commercial *** research efforts performed post-modification of reverse osmosis membranes to enhance boron rejection,which is usually accompanied by substantial sacrifice in water *** study delves into the surface engineering of low-pressure reverse osmosis membranes,aiming to elevate boron removal efficiency while maintaining optimal salt rejection and water *** were modified by the self-polymerization and co-deposition of dopamine and polystyrene sulfonate at varying ratios and *** surfaces became smoother and more hydrophilic after *** optimum membrane exhibited a water permeability of 9.2±0.1 l·m^(-2)·h^(-1)·bar^(-1),NaCl rejection of 95.8%±0.3%,and boron rejection of 49.7%±0.1% and 99.6%±0.3% at neutral and alkaline ph,*** water permeability is reduced by less than 15%,while the boron rejection is 3.7 times higher compared to the blank *** research provides a promising avenue for enhancing boron removal in reverse osmosis membranes and addressing water quality concerns in the desalination process.

关键词： membrane low-pressure reverse osmosis boron surface engineering

A nanobody-based blocking enzyme-linked immunosorbent assay for detecting antibodies against pseudorabies virus glycoprotein E

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Journal of Integrative Agriculture 2024年第4期23卷 1354-1368页

作者： huanhuan lü Pinpin Ji Siyu liu Ziwei zhang lei Wang Yani Sun Baoyuan liu lizhen Wang Qin Zhao Department of Preventive Veterinary Medicine College of Veterinary MedicineNorthwest A&F University/Shaanxi Scientific Observing and Experimental Station of Veterinary Pharmacology and Diagnostic TechnologyMinistry of Agriculture and Rural AffairsYangling 712100China

Pseudorabies(PR)is an acute infectious disease of pigs caused by the PR virus(PRV)and results in great economic losses to the pig industry *** glycoprotein E(gE)-based enzyme-linked immunosorbent assay(ElISA)has been used to distinguish gE-deleted vaccine-immunized pigs from wild-type virus-infected pigs to eradicate PR in some *** has the advantages of small size and easy genetic engineering and has been a promising diagnostic ***,there were few reports about developing nanobody-based ElISA for detecting anti-PRV-gE *** the present study,the recombinant PRV-gE was expressed with a bacterial system and used to immunize the Bactrian ***,two nanobodies against PRV-gE were screened from the immunized camel by phage display ***,two nanobody-hRP fusion proteins were expressed with hEK293T *** PRV-gE-Nb36-hRP fusion protein was selected as the probe for developing the blocking ElISA(bElISA)to detect anti-PRV-gE *** optimizing the conditions of bElISA,the amount of coated antigen was 200 ng per well,and dilutions of the fusion protein and tested pig sera were separately 1:320 and 1:*** cut-off value of bElISA was 24.20%,and the sensitivity and specificity were 96.43 and 92.63%,*** detecting 233 clinical pig sera with the developed bElISA and a commercial kit,the results showed that the coincidence rate of two assays was 93.99%.Additionallly,epitope mapping showed that PRV-gE-Nb36 recognized a conserved conformational epitope in different reference PRV ***,great stability and low-cost nanobody-based bElISA for detecting anti-PRV-gE antibodies were *** bElISA could be used for monitoring and eradicating PR.

关键词： nanobody nanobody-hRP blocking ElISA PRV-gE antibody

Fjord-Type AIEgens Based on Inherent Through-Space Conjugation

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CCS Chemistry 2024年第7期6卷 1739-1747页

作者： Ye-Qiang han Yuan Xie Jianyu zhang Shiyu Tan haoke zhang Ben Zhong Tang Jonathan l.Sessler Feihe huang Stoddart Institute of Molecular Science Department of ChemistryZhejiang UniversityHangzhou 310058 Zhejiang-Israel Joint laboratory of Self-Assembling Functional Materials ZJU-Hangzhou Global Scientific and Technological Innovation CenterZhejiang UniversityHangzhou 311215 MOE Key laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310058 Center for AIE Research College of Materials Science and EngineeringShenzhen UniversityShenzhen 518061 Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and ReconstructionThe Hong Kong University of Science and TechnologyKowloonHong Kong 999077 School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen(CUHK-Shenzhen)Guangzhou 518172 Department of Chemistry The University of Texas at AustinAustinTexas 78712-1224 Green Catalysis Center and College of Chemistry Zhengzhou UniversityZhengzhou 450001

Through-space conjugation(TSC)is a noncovalently electronic interaction that is emerging as a potential complement to through-bond conjugation(TBC)-based strategies for constructing luminescent ***,the design of efficient luminogens based on TSC is currently challenging due to a lack of established structure-property *** is particularly true in the case of luminogens displaying aggregation-induced emission(AIE)*** this work,three terphenyl derivatives were prepared,and their photophysical properties were systemically *** was found that relative to the corresponding m-and p-linked analogues,the electronic interaction of TBC is weakened while the strength of TSC is commensurately enhanced in the constitutional isomer containing an o-linked fjordtype *** this set of luminogens,the presence of a fjord-type arrangement promotes a transformation from aggregation-caused quenching to *** investigations involving congeneric quaterphenyl and pentphenyl isomers support the universality of the fjord-type unit as a framework for synthesizing AIE-active luminogens(AIEgens)with inherent *** work not only provides a novel set of AIEgens but also establishes the utility of TSC in controlling the photophysical properties of nonconventional and twisted luminogens.

关键词： fjord-type through-space conjugation through-bond conjugation aggregation-induced emission luminescence twisted conformation