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Diagnosis of Wastewater Contamination by Metalic Trace Elements (MTE) in the Areas of Yopougon (South Abidjan) and Marcory, Koumassi (North Abidjan) from March to July 2021

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Journal of Materials Science and Chemical Engineering 2023年第10期11卷 19-28页

作者： lydie Nina Amon Aboubakar Sidik Diaby Alfred Niamien Kouamé Kouamé Eric Yao Ali Sanou léon koffi konan Kalpy Julien Coulibaly Mireille Dosso Institut Pasteur of Cô te d’Ivoire Environment and Health Department Abidjan C&#244te d’Ivoire Ivorian Anti-Pollution Center Abidjan C&#244te d’Ivoire laboratory of Composition and Reaction of Matter Félix Houphou&#235t-Boigny University Abidjan C&#244te d’Ivoire laboratory of Hydrobiology Felix Houphouet Boigny University Abidjan C&#244te d’Ivoire Institut National Polytechnique of Félix Houphouë t-Boigny (INP-HB) Laboratory of Industrial Synthesis Processes Environment and New Energies (LAPISEN) Yamoussoukro C&#244te d’Ivoire

Contamination of the aquatic environment by Metallic Trace Elements (MTE) is a major problem encountered in our environment today. In Côte d’Ivoire, in some municipals, residential and industrial areas in the city of Abidjan, waste water of worrying quantity is discharged into the rainwater drainage channels which flow directly into the Ebrié lagoon. In order to identify the origin of the pollution by metallic trace elements (MTE) transported by this water, samples of wastewater were collected and then analyzed. ICP-MS was used for MTE (Cu, Fe, Zn, Al, Pb, Cd) analyses and results were statistically processed in multivariate form using PCA and Excel. The results showed high concentrations of metals, with the exception of Cd. The typological structure represents 85.74% of the total information for the MTE. Plan F1 represents 63.90% of the variance and describes water pollution by copper (0.95), zinc (0.90), iron (0.84) and aluminum (0.84). Plan F2 represents 21.84% and describes the enrichment of water with lead (0.84). It seems more than necessary to make manufacturers aware of the need to install wastewater treatment systems in order to avoid their discharge into the environment.

关键词： MTE Wastewater Typology

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Production of Yam Tubers Using Seed Tubers from Vitroplants Regenerated from Aerial Stems in the Yam Species Dioscorea alata (l.) and Dioscorea cayenensis-rotundata (l. & P.) in Côte d’Ivoire

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Advances in Bioscience and Biotechnology 2024年第3期15卷 184-194页

作者： koffi Honoré Kouamé Kouakou Marius konan Kouadio Ignace Kouassi Kouablan Edmond koffi Assanvo Simon-Pierre N’Guetta Department of des Science and Technology University Alassane Ouattara of Bouaké Bouaké C&#244te d’Ivoire Plant Production Research Unit Department of Natural Sciences University Nangui Abrogoua Abidjan C&#244te d’Ivoire Central Biotechnology laboratory National Center for Agronomic Research (NCAR) Abidjan C&#244te d’Ivoire Genetics laboratory of Bioscience Research Unit University Félix Houphou&#235t Boigny (UFHB) Abidjan C&#244te d’Ivoire

The aim of this study is to produce large quantities of yam tubers in the field from seed tubers derived from vitroplants regenerated from aerial stem cuttings and farmers’ tuber seeds. Seed tubers from ten yam cultivars, including five from Dioscorea alata (cDa083, cDa053, cDa115, cDa150 and cDa266) and five from Dioscorea cayenensis-rotundata (cDr015, cDr027, cDr150, cDr206 and cDr148) with distinct agro-morphological characteristics, were used as material. A completely randomized block design with 3 replications was used. In each block, all cultivars and seed types were represented. When put into cultivation, the tubers produced by the vitroplants all germinated and gave 100% healthy plants, compared with 86% to 100% healthy plants for the seed tubers produced by the farmers. Yields per hectare ranged from 10 to 25 tonnes for seed tubers produced by in vitro plants, and from 4 to 9 tons for seed tubers produced by farmers. Seed tubers from vitroplants can therefore be recommended to farmers as a solution to the problem of seed tuber unavailability.

关键词： Yams Vitroplants Seed Tubers Yields

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Post-Traumatic Palatine Odontogenic Abscess: About 2 Cases

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Open Journal of Stomatology 2024年第7期14卷 336-340页

作者： Aké lucien Jonathan Yapo Bakary Ouattara koffi laurent Boka konan René Kouakou Ahi Morel Mounin Chapo Affoué linda Marie Pierre koffi Kahder Morel Diarra Rokiatou Koné-Kamaté konan Marc koffi Department of Stomatology Maxillofacial and Facial Plastic Surgery University Hospital of Cocody Abidjan Republic of Cote dIvoire

Introduction: Palatal abscess or cellulitis of dental origin is a rare clinical form of circumscribed cellulitis that can sometimes pose a diagnostic problem. It is the consequence of poor or non-treatment of dental caries or trauma. The aim of this study is to describe the clinical and therapeutic aspects of these two cases of palatal cellulitis of post-traumatic dental origin. Observation: The patients consulted for painful palatal swelling secondary to untreated dental trauma of the 21s. The diagnosis of palatal cellulitis was based on the inflammatory and fluctuating nature of the swelling. A probabilistic bi-antibiotic treatment and an incision and drainage associated with treatment of the portal of entry were carried out. Progression was favourable in both cases. Conclusion: Palatal cellulitis is a rare condition and can be prevented by systematic stomatological consultation after dental trauma. Diagnosis is clinical. However, CT scans are sometimes useful. The course is generally favorable with appropriate treatment.

关键词： Abscess Palate Dental Trauma

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A Comparison of Hydrothermal Aging, SO₂ and Propene Poisoning Effects on NH₃-SCR over Cu-ZSM-5 and Cu-SAPO-34 Catalysts

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Journal of Materials Science and Chemical Engineering 2024年第5期12卷 10-28页

作者： Kouadio Brou Albert koffi konan Martin Zran Van Eric-Simon Horo Kone Unité de Formation et de Recherche des Sciences et de Technologies (UFR ST) Universit&#233 Alassane Ouattara Bouak&#233 C&#244te d&#8217Ivoire Unité de Formation et de Recherche Environnement (UFR E) Universit&#233 Jean Lorougnon Gu&#233d&#233 Daloa C&#244te d&#8217Ivoire Unité de Formation et de Recherche des Sciences des Structures de la Mati&#232re et de Technologie (UFR SSMT) Abidjan C&#244te d&#8217Ivoire

This study was aimed to investigate the effects of hydrothermal aging, propene and SO2 poisoning on the ammonia-selective catalytic reduction (NH3-SCR) performance of both Cu-SAPO-34 and Cu-ZSM-5. The catalytic activities of fresh, aged and poisoned samples were tested in ammonia-selective catalytic reduction (NH3-SCR) of NOx conditions. The XRD, TG and N2-desorption results showed that the structures of the Cu-SAPO-34 and Cu-ZSM-5 remained intact after 750˚C hydrothermally aged, SO2 and propene poisoned. After hydrothermal aging at 750˚C for 12 h, the NO reduction performance of Cu-ZSM-5 was significantly reduced at lower temperatures, while that of Cu-SAPO-34 was less affected. Moreover, Cu-SAPO-34 catalyst showed high NO conversion with SO2 or propene compared to Cu-ZSM-5. However, Cu-ZSM-5 showed a larger drop in catalytic activity with SO2 or propene compared to Cu-SAPO-34 catalyst. The H2-TPR results showed that Cu2 ions could be reduced to Cu and Cu0 for Cu-ZSM-5, while no significant transformation of copper species was observed for Cu-SAPO-34. Meanwhile, the UV-vis DRS results showed that CuO species were formed in Cu-ZSM-5, while little changes were observed for the Cu-SAPO-34. Cu-SAPO-34 showed high sulfur and hydrocarbon poison resistance compared to Cu-ZSM-5. In summary, Cu-SAPO-34 with small-pore zeolite showed higher hydrothermal stability and better hydrocarbon and sulfur poison resistant than Cu-ZSM-5 with medium-pore.

关键词： Hydrothermal Aging Propene and SO2Poisoning Ammonia-Selective Catalytic Reduction(NH3-SCR) Cu-SAPO-34 Cu-ZSM-5

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Characterization of Two Clay Raw Materials from Côte d’Ivoire with a View to Enhancing Them in Eco-Construction

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Journal of Minerals and Materials Characterization and Engineering 2022年第2期10卷 198-208页

作者： lébé Prisca M.-S. Kouakou Alfred Niamien Kouamé Bi Irié Hervé Gouré Doubi Namory Méité Jean Thierry Kangah Esmel Privat Zokou léon koffi konan Yao Jonas Andji-Yapi laboratory of Constitution and Reaction of Matter University Felix Houphouet Boigny Abidjan Cote d’Ivoire Unit for Training and Research of Biological Sciences University Peleforo Gon Coulibaly Korhogo Cote d’Ivoire

This study was carried out with a view to appreciate the value of clay, raw materials in eco-construction. To achieve this, we sampled two clay raw materials denoted Aga and Bak and then characterized. The results obtained from geotechnical and mineralogical tests have shown that the clay samples Aga and Bak are fine soils moderately plastic class A soils consisting essentially of quartz with 73.13% and 74.56% respectively for Aga and Bak and clay minerals (kaolinite and illite) with 12.73% kaolinite and 8.55% illite for Aga against 8.31% kaolinite and 13.72% for Bak. Moreover, these samples do not contain swelling clays and contain a sufficient quantity of iron oxides which allows them to be valued in ceramics, in particular in compressed earth bricks (CEB).

关键词： Clays Compressed Earth Bricks Eco-Material Physico-Chemical and Geotechnical Properties

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Management of Mandibular Fractures in Children in Ivory Coast: Experience of the Stomatology and Maxillofacial Surgery Department at the University Hospital of Cocody from 2000 to 2019

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Open Journal of Stomatology 2024年第7期14卷 341-349页

作者： Bakary Ouattara Camille Assouan laurent Boka koffi konan René Kouakou Ake lucien Jonathan Yapo Annick Zoglo-Bro Ahi Morel Mounin Chapo Affoué linda Marie Pierre koffi Kahder Morel Diarra Atse Kobo N’Guessan konan Marc koffi Department of Stomatology Maxillofacial Surgery University Flix Houphout-Boigny Abidjan Republic of Ivory Coast Department of Oral Pathology University Flix Houphout-Boigny Abidjan Republic of Ivory Coast

Introduction: Mandibular fractures in children are becoming increasingly common. Treatment of these fractures is difficult due to their anatomical and physiological complexity. Therefore, there is a need for well-codified management. Our main aim was to develop a decision algorithm for the management of mandibular fractures in children based on our experience. Materials and Methods: This was a retrospective descriptive study carried out in the Department of Stomatology and Maxillofacial Surgery at the University Hospital of Cocody over a period of 20 years (2000-2019). Results: We enrolled 58 patients. The mean age of the patients was 9.35 ± 2.3 years with a sex ratio of 2.22. Traffic accidents were the main cause of mandibular fractures (60.35%). Condylar fractures were the most common (46.87%). Treatment was orthopedic in 45.76% of cases, mixed (orthopedic and surgical) in 24.14% and surgical in 5.17%. Patients were followed up weekly for 1 month, then monthly for 6 months and annually for 3 years, with panoramic radiographs of the maxilla starting at 21 days. We observed 2 cases of complications: temporomandibular ankylosis and gingival stomatitis. Conclusion: Mandibular fractures are common in children. Management is difficult due to anatomical and physiological peculiarities. The choice of treatment depends on several criteria.

关键词： Fractures Mandible Children Treatment Ivory Coast

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Thermal Conductivity of Compressed Earth Bricks Strengthening by Shea Butter Wastes with Cement

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Materials Sciences and Applications 2017年第12期8卷 848-858页

作者： Herve Goure Doubi Alfred Niamien Kouamé léon koffi konan Monique Tognonvi Samuel Oyetola Unité de Formation et de Recherche des Sciences biologiques Université Péléforo Gon Coulibaly de Korhogo Korhogo C&ocirc te d’Ivoire laboratoire de Chimie des Matériaux Inorganiques (lCMI) Université Félix Houphou&euml t-Boigny de Cocody-Abidjan Abidjan C&ocirc te d’Ivoire

Currently, in a context of sustainable development, the economic and environmental challenges incite, to valorize local materials such as clays and agro-industrial waste. It is in this approach that a new category of compressed earth bricks (BTC) stabilized with shea meal (TK) and cement was proposed. The purpose of this paper is to investigate the effect of shea meal rate on the thermal conductivity properties of cement stabilized earth bricks. A lateritic clay (lat) mainly composed of kaolinite (38.44%), quartz (24.94%), goethite (12.28%), hematite (4.44%) and illite (19.9%) was used to make bricks. Different mix designs made up of lateritic clay and 5% cement were studied. The shea meal is added as a partial lateritic clay replacement in different proportions. The thermal conductivity was determined by hot disk method and correlated to both porosity and density of elaborated materials. The results obtained show that the thermal conductivity and density of bricks decrease respectively from 0.72 W·m-1·K-1 to 0.52 W·m-1·K-1 and from 2.77 g·cm-3 to 2.52 g·cm-3. The presence of shea meal within the material generates pore formation, which may partly explain the improvement of the thermal insulation properties. A positive correlation was noted between density and thermal conductivity of these materials.

关键词： lateritic Clay Shea Meal Compressed Earth Brick (CEB) Thermal Conductivity and Eco-Materials

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Reactivity of Recycled Glass Powder in a Cementitious Medium

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New Journal of Glass and Ceramics 2020年第3期10卷 29-44页

作者： Monique Tohoue Tognonvi Arezki Tagnit-Hamou léon koffi konan Ablam Zidol Wilfried Cyrille N’Cho Department of Biological Sciences University of Peleforo-Gbon-Coulibaly Korhogo C&#244 te d’Ivoire Department of Civil Engineering University of Sherbrooke Quebec Canada laboratory of Chemistry of Inorganic Materials University of Felix Houphouet-Boigny Abidjan C&#244 te d’Ivoire

The reactivity of the recycled glass powder (GP) in a cementitious medium has been studied over time by means of X-ray diffraction and thermal gravimetric analysis. Two different mixtures based on cement/glass powder (0 or 20 wt% GP) and lime/glass powder (70 wt% GP) were considered. Analysis revealed the coexistence of both hydration and pozzolanic reaction during the hardening of the mortars. At young age, the cement hydration would prevail over the pozzolanic one resulting in a decrease of physico-chemical le="font-family:"">and mechanical properties of the material due to the dilution effect. The pozzolanic reaction that predominates from 91 days, would induce the formation of supplementary C-S-H leading to improve the material properties.

关键词： Glass Powder Pozzolanic Reaction Calcium Silicate Hydrate Thermal Analysis X-Ray Diffraction

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Structural and Thermomechanical Study of Plastic Films Made from Cassava-Starch Reinforced with Kaolin and Metakaolin

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Materials Sciences and Applications 2018年第1期9卷 41-54页

作者： Namory Meite léon koffi konan Drissa Bamba Bi Irié Hervé Goure-Doubi Samuel Oyetola laboratory of Materials Chemistry Felix Houphouet Boigny University Cocody-Abidjan Ivory Coast laboratory of Water Chemistry Training School of Abidjan (ENS) Abidjan Ivory Coast laboratory of Biological Sciences Péléforo Gon Coulibaly University of Korhogo Korhogo Ivory Coast

The structural and thermomechanical properties of starch-based plastic films reinforced with kaolin and metakaolin have been studied by various techniques (X-ray diffraction, IR-TF spectroscopy, scanning electron microscopy, tensile tests, and thermal resistance). The results obtained showed that kaolin, an inert material, prevents the starch from losing its granular structure and to solubilize during the heating, generating plastic films of low Young’s modulus (7 MPa). On the other hand, metakaolin, an amorphous and dehydroxylated material obtained after heating of kaolin at 700°C for 1 hour, substantially improves the thermomechanical properties of the plastic films. The Young’s modulus increases from 19 MPa to 25 MPa while the thermal resistance increases from 90°C to 120°C. This was attributed to good dispersion of the metakaolin in the polymer matrix after the loss of the granular structure of the starch during heating.

关键词： Cassava Starch Plastic Films Kaolin Metakaolin Stress at Break Young’s Modulus

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Geochemical fingerprints and hydrocarbon potential of Paleocene mudrocks in the Tano Basin, Ghana: insights from biomarkers and stable carbon isotopes

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Acta Geochimica 2024年第2期43卷 255-279页

作者： Kojo Amoako Nancy Pearl Osei-Boakye Ningning Zhong N’Guessan Francois De Sales konan Gordon Foli Prince Opoku Appau Clifford Fenyi Ebenezer Apesegah Research Group for Marine Geochemistry(ICBM-MPI Bridging Group) Institute for Chemistry and Biology of the Marine Environment(ICBM)Carl von Ossietzky University OldenburgAmmerlander Heerstr.26129 OldenburgGermany State Key laboratory of Petroleum Resources and Prospecting College of GeosciencesChina University of PetroleumBeijing 102249China Department of Geological Engineering Faculty of Civil and Geo-EngineeringKwame Nkrumah University of Science and TechnologyKumasiGhana Ghana National Gas Company 225 Osibisa CloseAirport WestAccraGhana Petroleum Corporation GNPCPMBPetroleum HouseTemaGhana

The Paleocene mudrocks in Ghana’s Tano Basin have received limited attention despite ongoing efforts to explore hydrocarbon resources.A thorough geochemical analysis is imperative to assess these mudrocks’petroleum generation potential and formulate effective exploration *** this study,a comprehensive geochemical analysis was carried out on ten Paleocene rock cuttings extracted from TP-1,a discovery well within the Tano *** analytical techniques,including total organic carbon(TOC)analysis,Rock–Eval pyrolysis,gas chromatography-mass spectrometry,and isotope ratio-mass spectrometry,were employed to elucidate their hydrocar-bon potential and organic ***ﬁndings in this study were subsequently compared to existing geochemical data on Paleocene source rocks in the South Atlantic marginal *** results indicated that the Paleocene samples have TOC content ranging from 0.68 to 2.93 wt%.The prevalent kerogen types identiﬁed in these samples were Type Ⅱ and Type Ⅲ.Molecular and isotope data suggest that the organic matter found in the Paleocene mudrocks can be traced back to land plants and lower aquatic *** mudrocks were deposited in a transi-tional environment withﬂuctuating water salinity,charac-terized by sub-oxic redox *** indices,both bulk and molecular,indicated a spectrum of maturity levels within the Paleocene mudrocks,spanning from immature to marginally mature,with increasing maturity observed with greater *** comparison,the organic composition and depositional environments of Paleocene source rocks in the Tano Basin closely resemble those found in the Niger Delta Basin,Douala,and Kribi-Campo Basins,the Kwanza Formation in Angola,and certain Brazilian marginal ***,it is worth noting that Paleocene source rocks in some of the basins,such as the Niger Delta and Brazilian marginal basins,exhibit rela-tively higher thermal maturity levels compared to those observed in the current Paleocene samp

关键词： Paleocene source rocks Source input Depositional environment Thermal maturity Hydrocarbon potential Tano Basin West Africa

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