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Kinetic study on catalytic gasification of a modified sludge fuel

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Particuology 2008年第4期6卷 258-264页

作者： Byungho Song Dookie Kim Seungjae Lee Seokku Jeon Youngtai Choi Yoonseop Byoun Woonsig Moon Joonghee Lee Honggun Kim Hongki Lee Joongpyo shim Department of Chemical Engineering Kunsan National University Department of Civil & Environmental Engineering Kunsan National University Korea Institute of Energy Research Process Plant Group Hyndai Engineering Co. Ltd. Korea Institute of Industrial Technology Micro Science Tech Co. Ltd. Core Technology Research Center for Fuel Cell Department of Mechanical & Auto. Engineering Jeonju University Department of Advanced Material Engineering Woosuk University

A new type of mixture fuel, sludge–oil–coal agglomerate (SOCA), was catalytically gasified with steam in a thermobalance reactor under atmospheric pressure. All the four catalysts studied (K2CO3, CaO, NiO and Fe2O3) were found capable of enhancing the steam gasification rate and significantly increasing the conversion of carbon. The ranking of catalytic activity was found to be K2CO3 CaO > NiO > Fe2O3. A modified volumetric-reaction model in the literature was used to describe the conversion behavior of the steam gasification studied by evaluating the kinetic parameters. Expressions of the apparent gasification rates for SOCA were presented for the design of catalytic gasification processes.

关键词： Sludge Coal Oil Steam gasification Catalyst Thermobalance Kinetics

沉积物中壬基苯酚类雌性激素化合物的加速溶剂提取方法研究

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分析化学 2006年第5期34卷 633-636页

作者：李东浩 shim Wonjoon Oh Jaeryoung 方英玉延边大学分析测试中心 South Sea Institute Korea Ocean Research and Development InstituteKorea 656-834

为了同时提取和检测沉积物中的雌性激素化合物对壬基苯酚(NP)、对壬基苯酚一乙氧醚(NP1EO)和对壬基苯酚二乙氧醚(NP2EO),对加速溶剂提取体系的各种条件和对壬基苯酚类化合物的硅烷基化反应条件等进行了优化。在丙酮和丙酮-二氯甲烷混合... 详细信息

为了同时提取和检测沉积物中的雌性激素化合物对壬基苯酚(NP)、对壬基苯酚一乙氧醚(NP1EO)和对壬基苯酚二乙氧醚(NP2EO),对加速溶剂提取体系的各种条件和对壬基苯酚类化合物的硅烷基化反应条件等进行了优化。在丙酮和丙酮-二氯甲烷混合液(丙酮含量≥60%)介质中,这些化合物的硅烷基化反应很快达到反应终点。加速溶剂提取体系的最佳提取条件是120℃、8.4MPa、两次循环提取;最佳提取溶剂是二氯甲烷。与索氏提取和酸化悬浮液液提取比较,明显提高了提取率、重现性和准确性。平均添标回收率在89.3%95.7%之间,相对标准偏差为2.3%13.4%。本方法对壬基苯酚、对壬基苯酚一乙氧醚和对壬基苯酚二乙氧醚化合物的检出限分别为10、30、35ng/gdw(干重)。

关键词：加速溶剂提取气相色谱-质谱联用分析壬基苯酚内分泌干扰物质

Change in renal function after sodium phosphate preparation for screening colonoscopy

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World Journal of Gastroenterology 2010年第16期16卷 2010-2016页

作者： Dong Choon Seol Sung Noh Hong Jeong Hwan Kim In kyung Sung Hyung Seok Park Jung Hyun Lee Chan Sup shim Department of Internal Medicine Konkuk University School of Medicine Department of Health Promotion Healthcare CenterKonkuk University Medical Center Healthcare Center Konkuk University Medical CenterDepartment of Internal MedicineKonkuk University School of MedicineMedical Immunology CenterInstitute of Biomedical Science and Technology Department of Internal Medicine Konkuk University School of MedicineMedical Immunology CenterInstitute of Biomedical Science and Technology

AIM:To investigate the changes in renal function at 12-24 mo in patients following sodium phosphate(NaP) preparation for screening ***:We carried out a retrospective study on the results from patients who received health check-up services as part of an employer-provided wellness program performed between August 2006 and May 2008 and who were followed up for 12-24 *** to screening colonoscopy,224 patients underwent bowel cleansing with NaP(NaP group) and 113 patients with polyethylene glycol(PEG group).The control group comprised 672 age-matched *** compared the changes in the creatinine levels and the glomerular filtration rates(GFRs) from baseline to 12-24 mo between the NaP,PEG,and control groups using two-way repeated measured analysis of *** addition,multivariate linear regression analysis was performed to assess the risk factors for a decreased ***:The baseline mean serum creatinine level in the NaP,PEG,and control groups was 1.12 ± 0.15,1.12 ± 0.16,and 1.12 ± 0.15 mg/dL,which increased to 1.15 ± 0.15,1.15 ± 0.18,and 1.15 ± 0.15 mg/dL,respectively,after 12-24 *** baseline mean GFR in the NaP,PEG,and control groups was 69.0 ± 7.7,68.9 ± 8.0,and 69.6 ± 6.7 mL/min per 1.73 m2,which decreased to 66.5 ± 7.8,66.5 ± 8.3,and 67.4 ± 6.4 mL/min per 1.73 m2,respectively,after 12-24 *** changes in serum creatinine levels and GFRs were not significantly between the NaP,PEG,and control groups(P = 0.992 and P = 0.233,respectively).Using multivariate linear regression analysis,only the baseline GFR was associated with the change in GFR(P < 0.001).Indeed,the bowel preparations were not associated with the change in GFR(P = 0.297).CONCLUSION:NaP bowel preparation in subjects with normal renal function was not associated with renal injury,and NaP can thus be used safely for screening colonoscopy.

关键词： Sodium phosphate Polyethylene glycol Purgatives Colonoscopy Creatinine Glomerular filtration rate

The Rise and Fall of Social Networking Sites： A Comparative Study of Cyworld and Facebook

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Journalism and Mass Communication 2014年第3期4卷 147-162页

作者： Yongwoon shim Daeho Kim SK Management and Economics Research Institute Seoul South Korea Inha University Incheon South Korea

This study examines why some social networking sites （SNSs） stagnate while other SNSs grow by comparing Cyworld with Facebook. Cyworld was one of the most successful SNSs in the world, but its international expansion efforts failed. Facebook＇s open technology has had considerable influence on various sectors of the economy and society and allowed it to become a dominant SNS at the global level, whereas Cyworld has remained a local SNS. Facebook＇s open platform and application programming interface （API） pose a serious challenge to Cyworld＇s walled-garden approach. Cyworld is based on strong ties fostering close relationships, whereas Facebook expands social networks through its open and weak ties and has more network power than Cyworld. Therefore, openness is the main reason behind the rise of Facebook and the fall of Cyworld.

关键词： social networking site (SNS) Cyworld Facebook socio-technical framework openness

Bimetallic Ni-Co MOF@PAN modified electrospun separator enhances high-performance lithium-sulfur batteries

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Journal of Energy Chemistry 2023年第7期82卷 484-496,I0010页

作者： Xiaolong Leng Jie Zeng Mingdai Yang Changping Li S.V.Prabhakar Vattikuti Jielin Chen Shuang Li Jaesool shim Tong Guo Tae Jo Ko School of Mechanical Engineering Yeungnam UniversityGyeongsangbuk-do 38541Republic of Korea College of Mechanical and Electrical Engineering Hunan University of Science and TechnologyXiangtan 411201HunanChina Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education Nanjing University of Science and TechnologyNanjing 210094JiangsuChina

Lithium-sulfur(Li-S)batteries with high energy density are considered promising energy storage devices for the next ***,the shuttle effect and the passive layer between the separator and the electrodes still seriously affect the cycle stability and ***,a bimetallic Ni-Co metal-organic framework(MOF)with adsorption and catalytic synergism for polysulfides was successfully synthesized as an electrospinning separator sandwich for Li-S *** porous Ni-Co MOF coatings into the separator provides more adsorption catalytic sites for polysulfides,prevents their diffusion to the anode,and enhances sulfur ***,the improved Li-S batteries with a Ni-Co MOF@PAN(NCMP)electrospun separator delivered excellent rate performance and outstanding cycle stability,yielding an ultra-high initial capacity of 1560 mA h g^(-1)at 0.1 ***,remarkable Li-S battery performance with a discharge capacity of 794 mA h g^(-1)(84.1%capacity retention)was obtained after500 cycles,while delivering a low capacity decay rate of 0.032%during long-term cycling(up to 500cycles)at 1 ***,even at the current density of 2 C,the capacity attenuation rate of 2000 cycles is only 0.034%per *** addition,compared with the Celgard separator,the NCMP separator also had high thermal stability(keeping the separator outline at 200℃)that ensured battery safety and excellent electrolyte wettability(73%porosity and 535%electrolyte absorption)and significantly enhanced the ionic conductivity and Li^(+) transfer number,and protected the surface integrity of the anode.

关键词： Li-S batteries Ni-Co MOF Adsorption catalysis Synergistic effect

Rational design ternary platinum based electrocatalysts for effective methanol oxidation reaction

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Journal of Energy Chemistry 2022年第7期31卷 230-235,I0007页

作者： Hao Tian Daoxiong Wu Jing Li Junming Luo Chunman Jia Zhongxin Liu Wei Huang Qi Chen Chong Michael shim Peilin Deng Yijun Shen Xinlong Tian State Key Laboratory of Marine Resource Utilization in South China Sea Hainan Provincial Key Lab of Fine ChemistrySchool of Chemical Engineering and TechnologyHainan UniversityHaikou 570228HainanChina

Exploring effective, durable, and affordable electrocatalysts of methanol oxidation reaction(MOR) is of vital significance for the industrial application of direct methanol fuel cells. Herein, an efficient, general,and expandable method is developed to synthesis two-dimensional(2D) ternary Pt Bi M nanoplates(NPLs), in which various M(Co, Ni, Cu, Zn, Sn) is severed as the third component to the binary Pt Bi system. The MOR performance of Pt Bi M NPLs is entirely investigated, demonstrating that both the MOR activity and durability is enhanced with the introduction of the additional composition. Pt3Bi3Zn NPLs shows much higher MOR activity and stability than that of the Pt Bi counterparts, not to mention the current advanced Pt Ru/C and Pt/C catalysts. The prominent performances are attributed to the modulated electronic structure of the surface Pt in Pt Bi NPLs by the addition of Zn, resulting in a weakened affination between Pt and the adsorbed poisoning species(mainly CO) compared with Pt Bi NPLs, verified by density functional theory(DFT) calculations. In addition, the absorbed OH can be generated on the surface of Zn atom due to its favorable water activation properties, thus the CO removal on the adjacent Pt atoms is accelerated, further leading to a high activity and anti-poisoning performance of the resulting Pt_(3)Bi_(3)Zn catalyst. This work provides new insights and robust strategy for highly efficient MOR electrocatalyst with extraordinary anti-poisoning performance and stability.

关键词： Fuel cells Ternary nanoplates Durability Methanol oxidation reaction Anti-poisoning

Anesthetics management of a renal angiomyolipoma using pulse pressure variation and non-invasive cardiac output monitoring: A case report

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World Journal of Clinical Cases 2022年第24期10卷 8656-8661页

作者： Woo Jae Jeon Woo Jong Shin Young Joon Yoon Chan Woo Park Jae Hang shim Sang Yun Cho Department of Anesthesiolgy and Pain Medicine Hanyang University Guri HospitalGuri-si 471-701Gyeonggi-doSouth Korea

BACKGROUND Hypovolemic shock can lead to life-threatening organ dysfunction,and adequate fluid administration is a fundamental ***,parameters such as vital signs,central venous pressure,and urine output have been used to estimate intravascular ***,pulse pressure variation(PPV)and non-invasive cardiac monitoring devices have been *** this case report,we introduce a patient with massive active bleeding from giant renal angiomyolipoma(AML).During emergent nephrectomy,we used non-invasive cardiac monitoring with CSN-1901(Nihon Kohden,Tokyo,Japan)and PPV to evaluate the patient's intravascular volume status to achieve optimal fluid *** SUMMARY A 30-year-old male patient with giant AML with active bleeding was referred to the emergency room complaining of severe abdominal pain and spontaneous abdominal *** was diagnosed by computed tomography,and emergent nephrectomy was *** bleeding was expected so we decided to use non-invasive cardiac monitoring and PPV to assist fluid therapy because they are relatively easy and fast compared to invasive cardiac *** the surgery,6000 mL of estimated blood loss *** with the patient's vital signs and laboratory results,we monitored cardiac output,cardiac output,stroke volume,stroke volume index with a non-invasive cardiac monitoring device,and PPV using an intra-arterial catheter to evaluate intravascular volume status of the patient to compensate for massive *** In addition to traditional parameters,non-invasive cardiac monitoring and PPV are useful methods to evaluate patient's intravascular volume status and provideguidance for intraoperative management of hypovolemic shock patients.

关键词： Renal angiomyolipoma Pulse pressure variation Cardiac output Case report

Endoscopic ultrasonography does not differentiate neoplastic from non-neoplastic small gallbladder polyps

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World Journal of Gastroenterology 2009年第19期15卷 2361-2366页

作者： Young Koog Cheon Won Young Cho Tae Hee Lee Young Deok Cho Jong Ho Moon Joon Seong Lee Chan Sup shim Institute for Digestive Research and Digestive Disease Center Soon Chun Hyang University College of Medicine657 Hannam-DongYongsan-KuSeoul 140-743South Korea

AIM： To assess the ability of endoscopic ultrasonography （EUS） to differentiate neoplastic from non- neoplastic polypoid lesions of the gallbladder （PLGs）.METHODS： The uses of EUS and transabdominal ultrasonography （US） were retrospectively analyzed in 94 surgical cases of gallbladder polyps less than 20 mm in ***： The prevalence of neoplastic lesions with a diameter of 5-20 mm was 27.2% （10/58）; 22-15 mm, 25.4% （4/26）, and 16-20 mm, 50% （5/20）. The overall diagnostic accuracies of EUS and US for small PLGs were 80.9% and 63.9% （P 〈 0.05）, respectively. EUS correctly distinguished 12 （63.2%） of 19 neoplastic PLGs but was less accurate for polyps less than 1.0 cm （4/10, 40%） than for polyps greater than 1.0 cm （8/9, 88.9%）（P = 0.02）.CONCLUSION： Although EUS was more accurate than US, its accuracy for differentiating neoplastic from non-neoplastic PLGs less than 1.0 cm was low. Thus, EUS alone is not sufficient for determining a treatment strategy for PLGs of less than 1.0 cm.

关键词： Endoscopic ultrasonography Neoplasticlesion Polypoid gallbladder lesion

基于前向道路信息的拖车倒车系统滚动时域控制(英文)

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中国科学技术大学学报 2012年第7期42卷 517-526页

作者：陈娜娜宾洋 shim Taehyun 冯能莲清华大学汽车工程系北京100084 北京科技大学环境与能源工程学院北京100124 密歇根大学迪尔伯恩分校机械工程系密歇根州迪尔伯恩市48128

针对离轴联接形式的拖车倒车系统,阐述了其混合逻辑(mixed logical dynamics,MLD)的建模理论和基于滚动时域控制(receding horizon control,RHC)的方法.首先,采用Lyapunov理论分析了拖车倒车系统的运动学特性.接着,采用MLD建模理论来描... 详细信息

针对离轴联接形式的拖车倒车系统,阐述了其混合逻辑(mixed logical dynamics,MLD)的建模理论和基于滚动时域控制(receding horizon control,RHC)的方法.首先,采用Lyapunov理论分析了拖车倒车系统的运动学特性.接着,采用MLD建模理论来描述拖车倒车系统的运动学模型.针对此MLD运动学模型,提出了一种扩展的二次型代价函数.为了减小拖车的跟踪误差以及平滑牵引车转向角的操控性能,提出将其等效为线性二次型跟踪问题.针对此问题,利用多参数混合整数二次规划(multiparametric mixed-integerquadratic programming,mp-MIQP)技术,设计了一种考虑有限时域前向道路信息的显式RHC控制器.最后,通过仿真对控制器进行验证.结果表明尽管跟踪非平滑的参考路径,控制器均表现出期望的控制效果.

关键词：拖车系统路径跟踪滚动时域控制混合逻辑动力学