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Surface structural transformation of Ni2P@C electrocatalysts for overall alkaline water splitting

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Progress in Natural Science:Materials International 2024年第1期34卷 102-107页

作者： kun Yang Xinjuan liu Jun Xu Yun Gong Shuling Shen Jinchen Fan Xiaojie Zhang Yuhua Xue School of Materials and Chemistry University of Shanghai for Science and Technology National&Local Joint Engineering Research Center for Mineral Salt Deep Utilization Huaiyin Institute of Technology

Understanding the surface restructuring, including atomic rearrangement and chemical composition adjustments,is urgent to accelerate electrocatalytic reactions. Herein, we focus on the surface restructuring and active species for phosphide especially Ni2P during the water splitting process by combination of in-situ Raman and ex-situ X-ray photoelectron spectroscopy. Results confirm that NiOOH and NiOO* are formed during OER, while Niδ+-Hadactive sites are formed during HER. In situ-formed NiOOH/Ni2P@C and Niδ+/Ni2P@C show enhanced water splitting（1.514 V at 10 mA/cm2） and NO3RR(86% and 668 μmol h-1cm-2for NH3Faraday efficiency and yield)activities. In-depth investigation of the surface dynamic changes can provide guidance for establishing the relation of structure-electrocatalytic activity.

关键词： Dynamic surface restructuring Phase structural transition In-situ Raman spectra Ni_2P@C Overall water splitting

Vibration Analysis of a 51-Story Tower from the Recorded Data of the Earthquake, Typhoon and Ambient Vibration

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World Journal of Engineering and Technology 2018年第1期6卷 161-175页

作者： kun-sung liu Department of Civil Engineering & Hazard Mitigation Research Center Kao Yuan University Taiwan

This study uses the in-structure recordings to investigate the vibration characteristics of a 51-story steel high-rise building in response to a major earthquake, typhoon and ambient vibrations. This presents an opportunity for us to compare the building behaviors, especially their modal properties under different types of excitation. First, we use a two-stage regression procedure to obtain the relations of the building response, including peak floor acceleration and velocity as a function of the wind speed and floor height of the building. Secondly, the structural dynamic characteristics of the high rise building, including the transfer functions and natural frequencies, excited by the Chi-Chi earthquake, Typhoon Aere, and ambient vibrations are also determined and compared. As a result, from the formulas for building response, the predicted peak floor acceleration is higher in the lateral (EW) component than in the longitudinal (NS) component. This is probably due to the greater stiffness of the building in the longitudinal direction than in the lateral direction. In addition, after having identified the 1st, 2nd, and 3rd natural frequencies using the recorded data from the earthquake, typhoon and ambient vibrations, the ranking of the fundamental natural frequencies from low to high is the Chi-Chi earthquake, Typhoon Aere and the ambient vibrations. This means that greater excitation forces of the earthquake have resulted in lower natural frequencies than that produced by the typhoon and ambient vibrations.

关键词： Earthquake Typhoon Peak Floor Acceleration Peak Floor Velocity Vibration Analysis

Effects of rare earth elements on inclusions, microstructure and impact toughness of spring steel

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Journal of Iron and Steel Research(International) 2024年第4期31卷 933-944页

作者： Chun-lei Hao Chao-yun Yang Peng liu Yi-kun Luan Bao-guang Sang Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016LiaoningChina School of Mechanical Engineering and Automation Dalian Polytechnic UniversityDalian 116034LiaoningChina

Spring steel is an indispensable basic part manufacturing material in mechanical equipment,which is widely used in transportation tools such as automobiles,railways,construction machinery and other *** effects of rare earth(RE)on inclusions,microstructure,carbides and impact toughness of 50CrV spring steel were studied by means of optical microscope,scanning electron microscope,transmission electron microscope and impact *** results show that the addition of rare earth can modify the main MnS and Al_(2)O_(3) inclusions in steel to form spherical or near-spherical rare earth inclusions,and the size of inclusions is significantly *** the quenched structure,the size of martensite slab becomes smaller and the structure is *** tempering,the carbide changes from sheet to ellipse,which makes it easier for spring steel to form stress concentration cracks under *** becomes finer and more dispersed,which leads to better pinning of grain boundaries and smaller grain *** impact toughness of 50CrV-RE spring steel increased from 21 to 41 J by 95%due to the improvement of inclusions,microstructure and carbides by rare *** is possible to improve the strength and toughness of spring steel for the improvement of railway running speed and the development of vehicle lightweight in China.

关键词： Rare earth-Spring steel Inclusion Microstructure Impact toughness

A Two-Layer Active Power Optimization and Coordinated Control for Regional Power Grid Partitioning to Promote Distributed Renewable Energy Consumption

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Energy Engineering 2024年第9期121卷 2479-2503页

作者： Wentao Li Jiantao liu Yudun Li GuoxinMing Kaifeng Zhang kun Yuan Key Laboratory of Measurement and Control of CSE Southeast UniversityNanjing210096China China Electric Power Research Institute Nanjing210003China State Grid Shandong Electric Power Research Institute Jinan250003China

With the large-scale development and utilization of renewable energy,industrial flexible loads,as a kind of loadside resource with strong regulation ability,provide new opportunities for the research on renewable energy consumption problem in power *** paper proposes a two-layer active power optimization model based on industrial flexible loads for power grid partitioning,aiming at improving the line over-limit problem caused by renewable energy consumption in power grids with high proportion of renewable energy,and achieving the safe,stable and economical operation of power ***,according to the evaluation index of renewable energy consumption characteristics of line active power,the power grid is divided into several partitions,and the interzone tie lines are taken as the optimization ***,on the basis of partitioning,a two-layer active power optimization model considering the power constraints of industrial flexible loads is *** upper-layer model optimizes the planned power of the inter-zone tie lines under the constraint of the minimum peak-valley difference within a day;the lower-layer model optimizes the regional source-load dispatching plan of each resource in each partition under the constraint of theminimumoperation cost of the partition,so as to reduce the line overlimit phenomenon caused by renewable energy consumption and save the electricity cost of industrial flexible ***,through simulation experiments,it is verified that the proposed model can effectively mobilize industrial flexible loads to participate in power grid operation and improve the economic stability of power grid.

关键词： Renewable energy consumption active power optimization power grid partitioning industrial flexible loads line over-limit

Evaluation of erastin synergized cisplatin anti-nasopharyngeal carcinoma effect with a glutathione-activated near-infrared fluorescent probe

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Chinese Chemical Letters 2024年第2期35卷 311-316页

作者： Rong He Dandan Tang Ningge Xu Heng liu kun Dou Xuejun Zhou Fabiao Yu Department of Otolaryngology Head and Neck SurgeryThe First Affiliated Hospital of Hainan Medical UniversityHaikou 570102China Key Laboratory of Hainan Trauma and Disaster Rescue Key Laboratory of Emergency and TraumaMinistry of EducationEngineering Research Center for Hainan Bio-Smart Materials and Bio-Medical DevicesCollege of Emergency and TraumaHainan Medical UniversityHaikou 571199China Sichuan Provincial General Hospital of Judicial Police Chengdu 610225China

Nasopharyngeal carcinoma(NPC),a malignant tumor originating from the nasopharynx,is one of the common malignant tumors of the head and *** are significant geographical differences in the incidence of nasopharyngeal carcinoma,with a high incidence in China and Southeast Asian ***,we designed and synthesized a novel near-infrared fluorescent(NIRF)probe to detect glutathione(GSH)in cellular and tumor environments using semi-naphthofluorescein(SNAFL)as the fluorescent molecular backbone and 2-fluoro-4-nitrobenzenesulfonate as the recognition *** reaction with GSH,SNAFL-GSH emitted a fluorescence signal,and its emission wavelength at 650 nm was remarkably *** results of selectivity experiments indicated that SNAFL-GSH was able to discriminate GSH from Cys,Hcy,and H_(2) ***,SNAFL-GSH could image both endogenous and exogenous GSH and distinguish normal and cancer cells by fluorescence signal *** the cellular level,cisplatin(DDP)-induced ferroptosis and inhibition of proliferation of various NPC cell lines(CNE2,CNE1,5-8F cells)by erastin combined with DDP were visualized with the help of *** a mouse tumor xenograft model,we successfully employed SNAFL-GSH for the evaluation of the efficacy of erastin combined with DDP in the treatment of *** importantly,the probe could image cancerous tissue sections from NPC patients with an imaging depth of approximately 80µ*** was foreseen that SNAFL-GSH offered great potential for application in the diagnosis and evaluation of the therapeutic efficacy of NPC,and these results would also provide new ideas for the clinical treatment of NPC.

关键词： Glutathione NIRF probe Ferroptosis Anti-tumor therapy evaluation Bioimaging

An effective strategy for dendrite free Li metal anodes:Nickel foam decorated with high lattice-matching CoN and CoF_(2) nanosheets for dense deposition

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Nano Research 2024年第5期17卷 4069-4078页

作者： Wenlong liu Jianzong Man Xiaodong Sun Ning Zhang Yehong Du kun liu Zhongsheng Wen Song Li Juncai Sun Institute of Materials and Technology Dalian Maritime UniversityDalian 116026China Shandong Provinvial Key Laboratory of Chemical Energy Storage and Novel Cell Technology and School of Chemistry and Chemical enginneringLiaocheng UniversityLiaocheng 252000China Department of Public Security Management Liaoning Police CollegeDalian 116036China

The notorious dendrite and infinite volume change seriously restrict the advancement of lithium metal anodes(LMAs),during the long-term process of stripping/***,the nanosheets of metal fluoride(CoF_(2))and metal nitride(CoN)with magnificent lithiophilicity on the nickel(Ni)foam are designed as the“regulator”to uniform the Li plating and build stronger solid electrolyte interface(SEI)layer for dendrite free *** Ni foam offers abundant space to receive deposited Li *** CoN nanosheets can guarantee the fast transfer of electrons,which provides a stable interface of Li^(+)***,the nanosheet structure with lithiophilicity would accelerate the move of Li+and decrease the nucleation barrier,due to the high lattice-matching of Li and ***,the CoF_(2) could increase the content of F(LiF)in the SEI layer,which enhances the strength and avoids the destruction of SEI *** the cooperation of CoN and CoF_(2),the composited anode(Li/NF@CNCF)exhibits ultra-long cycle performance(more than 1200 h)and fantastic structure stability at 1 mA·cm^(-2) with 1 mAh·cm^(-2).Based on the LiFePO_(4) and Li/NF@CNCF,the full cells deliver excellent specifical capacity and steady coulombic *** strategy contributes an effective approach to alleviate the issues of lithium metal anodes in the field of LMAs.

关键词： CoN and CoF_(2) lattice-matching nanosheet lithiophilicity lithium metal anodes

The cooperative migration dynamics of particles correlates to the nature of hexatic-isotropic phase transition in 2D systems of corner-rounded hexagons

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Fundamental Research 2024年第2期4卷 284-290页

作者： Zhanglin Hou Mingwei liu Yiwu Zong Fangfu Ye kun Zhao Wenzhou Institute University of Chinese Academy of SciencesWenzhouZhejiang 325001China Frontiers Science Center for Synthetic Biology and Key Laboratory of Systems Bioengineering(Ministry of Education) School of Chemical Engineering and TechnologyTianjin 300072China School of Physical Science University of Chinese Academy of SciencesBeijing 100049China Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China Oujiang Laboratory(Zhejiang Lab for Regenerative Medicine Vision and Brain Health)WenzhouZhejiang 325001China Sichuan Provincial People’s Hospital University of Electronic Science and Technology of ChinaChengduSichuan 610054China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengduSichuan 610054China

In the two-dimensional(2D)melting transition of colloidal systems,the hexatic-isotropic(H-I)transition can be either first-order or ***,how particle dynamics differs at the single-particle level during these two different melting transitions remains to be *** this work,by Brownian dynamics(BD)simulations,we have systematically studied the dynamic behavior of corner-rounded hexagons during the H-I transition,for a range of corner-roundness𝜁=0.40 to 0.99 that covers the crossover from the continuous to first-order nature of H-I *** results show that hexagons with𝜁≤0.5 display a continuous H-I transition,whereas those with𝜁≥0.6 demonstrate a first-order H-I *** analysis shows different evolution pathways of the dominant cluster formed by migrating particles,which results in a droplet-like cluster structure for𝜁=0.40 hexagons and a tree-like cluster structure for𝜁=0.99 *** investigations on the hopping activities of particles suggest a cooperative origin of migrating *** work provides a new aspect to understand the dependence of the nature of H-I transition on the roundness of hexagons through particle dynamic behavior.

关键词： Melting transition Colloids Hexatic phase Cooperative migration Hexagons

Immunoglobulin superfamily containing leucine-rich repeat(ISLR)negatively regulates osteogenic differentiation through the BMP-Smad signaling pathway

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Genes & Diseases 2024年第4期11卷 138-140页

作者： Lei Xiong Miaomiao Lan Chang liu Lei Li YingYing Yu Tongtong Wang Fan liu kun Wang Jin liu Qingyong Meng State Key Laboratory of Agrobiotechnology College of Biological SciencesChina Agricultural UniversityBeijing 100094China

Osteoporosis(OP)is an aging-associated condition that significantly affects the quality of life in aging humans and has few treatment *** an important marker,recombinant immunoglobulin superfamily containing leucinerich repeat(ISLR)could be used as a gene therapy for *** herein used alkaline phosphatase(ALP)and alizarin red S(ARS)staining to evaluate osteogenic differentiation potential.

关键词： Immunoglobulin alkaline herein

New perspectives on the genetic structure of dotted gizzard shad(Konosirus punctatus)based on RAD-seq

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Marine Life Science & Technology 2024年第1期6卷 50-67页

作者： Ying Peng Yifan liu Jiasheng Li kun Zhang Xun Jin Sixu Zheng Yunpeng Wang Zhenming Lu Liqin liu Li Gong Bingjian liu National Engineering Laboratory of Marine Germplasm Resources Exploration and Utilization Zhejiang Ocean UniversityZhoushan 316022China National Engineering Research Center for Facilitated Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316022China

To maintain,develop and rationally utilize marine organisms,understanding their genetic structure and habitat adaptation pattern is *** punctatus,which is a commercial fish species inhabiting the Indo-west Pacific Ocean,has shown an obvious annual global capture and aquaculture production decline due to climate changes and human *** the present study,restriction-site associated DNA sequencing(RAD-seq)was used to describe its genome-wide single nucleotide polymorphisms panel(SNPs).Among 146 individuals collected at nine locations scattered in China,Korea and Japan,a set of 632,090 SNPs were *** genetic analysis showed that *** individuals were divided into two significant genetic ***,potential genetic differentiation between northern and southern population of *** was *** results indicated that gene flow existed among sampling locations of ***,especially from southern Japan to ***,candidate genes associated with habitat adaptations of *** were identified,which are involved in diverse physiological processes of *** including growth and development(e.g.,KIDINS220,PAN3),substance metabolism(e.g.,PGM5)and immune response(e.g.,VAV3,CCT7,HSPA12B).Our findings may aid in understanding the possible mechanisms for the population genetic structure and local adaptation of ***,which is beneficial to establish the management and conservation units of ***,guiding the rational use of resources,with reference significance for a profound understanding of the adaptative mechanisms of other marine organisms to the environment.

关键词： Population structure Konosirus punctatus SNP RAD-seq Local adaptation