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Facile and effective synthesis strategy for terbium-doped hydroxyapatite toward photoelectric devices and flexible functional fibers

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Rare Metals 2024年第4期43卷 1713-1723页

作者： Xiao-Dong Zhang kun nie Zi-Yao Hu Ran-Ran Zhou Xiu-Qiang Duan Wu-Bin Dai Song-Song nie Song-Jun Yao Luo-Xin Wang Le-Fu Mei Hua Wang Yi-Yi Yao Xiao-Xue Ma Hubei Key Laboratory for New Textile Materials and Applications and State Key Laboratory of New Textile Materials and Advanced Processing Technology School of Materials Science and EngineeringWuhan Textile UniversityWuhan430200China Key Laboratory of Testing and Tracing of Rare Earth Products for State Market Regulation Jiangxi University of Science and TechnologyGanzhou341000China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials and Key Laboratory of Green Chemical Engineering Process of Ministry of Education Wuhan Institute of TechnologyWuhan430205China

As a material with good biocompatibility,hydroxyapatite(HAP)can have optical properties after doping with various rare earth *** a biocompatible fluorescent material,doped HAP could have broad applications in biological probes,drug delivery,optoelectronic materials,fluorescence anti-counterfeiting,and other *** this paper,we put forward the preparation of HAP doped with terbium(Ⅲ)ions(Tb^(3+))by hydrothermal *** controlling the Tb^(3+)doping content in reaction and the reaction time,the changes in HAP's structure,morphology,and luminescence properties under different conditions were *** the doping amount of Tb^(3+)reached an optimal value,the dipole-quadrupole would occur and the concentration would be *** control experiment showed that the optimal Tb3+content was 7.5×10^(-5)mol,which showed the best fluorescence ***,a non-luminous material,was rarely used in the field of fluorescent anti-counterfeiting and photoelectric *** proposed to prepare a luminescent aramid/polyphenylene sulfide(ACFs/PPS)fiber paper and a new light-emitting diode(LED)using the Tb-doped HAP *** composite sample exhibited an excellent stability and fluorescence performance,which also demonstrated a possibility of HAP applications in anticounterfeiting and *** introduction of Tb3+dopant HAP was done to give HAP optical properties and broaden the application range of HAP.

关键词： Hydroxyapatite Rare earth luminescence Photoelectric device Aramid Polyphenylene sulfide fiber paper Luminescent fiber

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CONNECTING INFORMAL NETWORKS TO MANAGEMENT OF TACIT KNOWLEDGE

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Journal of Systems Science and Systems Engineering 2010年第2期19卷 237-253页

作者： kun nie Shufang LIN Tieju MA Yoshiteru NAKAMORI School of Business Administration Zhejiang Gongshang University Hangzhou China Department of Business Administration Yuanpei University Taiwan School of Business East China University of Science and Technology Shanghai China Transition to New Technology International Institute for Applied Systems Analysis Austria Graduate School of Knowledge Sctence Japan Advaneed lnstttute of Science and Technology Japan

The relationship between tacit knowledge and informal networks has not been fully explored. Tacit knowledge cannot be well managed directly, because it is deeply embedded in individual actions and experiences. This study proposes an approach to managing informal networks as a new middle way to facilitate the sharing and transferring of tacit knowledge, owing to the fact that tacit knowledge is mostly shared and transferred through informal networks. To support the idea of the approach, an empirical case study of applying the approach to management of a large scientific project is also included. Our findings suggest that informal networks play essential roles for management of tacit knowledge, and thus good management of informal networks can lead to efficient sharing and transferring of tacit knowledge.

关键词： Informal networks tacit knowledge case study

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Syntheses of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands and their catalytic activity toward the hydrophosphonylation reaction of aldehydes and ketones

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Science China Chemistry 2015年第9期58卷 1451-1460页

作者： kun nie Chengwei Liu Yong Zhang Yingming Yao School of Chemistry and Chemical Engineering Taishan University Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials ScienceSoochow University

A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthesized through the metathesis reactions of {Ln(μ-Cl)[N(Si Me3)2]2(THF)}2(Ln=Sm, Yb, Y) with lithium guanidinate {Li[(RN)2CN(CH2)2]}2(R=iPr, Cy), the latter of which was generated in situ by the reaction of carbodiimides with lithium amides. Complexes 1–5 were well characterized by elemental analyses, IR spectra, and(for Complex 3) NMR spectroscopy. The solid-state molecular structures of all of the complexes were determined by single-crystal X-ray analyses with the exception of Complex 3, which showed similar unsolvated centrosymmetric dinuclear structures. Each of the lanthanide centers is four-coordinated with two nitrogen atoms from a guanidinate ligand and two nitrogen atoms from two amido groups. The piperazidine rings adopt chair conformations in all cases. These organolanthanide complexes were found to be efficient catalysts for the hydrophosphonylation reaction of various aldehydes and unactivated ketones and to afford ?-hydroxyphosphonates in high yields under low catalyst loading(0.1 mol%) in a short reaction time.

关键词： bimetallic lanthanide complex bridged bis(guanidinate) ligand hydrophosphonylation reaction aldehyde ketone

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黔中地区马尾松-甜槠针阔混交林群落结构特征与林木空间分布格局及其关联性

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西北林学院学报 2024年第1期39卷 132-139,176页

作者：金鹏徐明文春玉聂坤杨雪唐雪娅魏珊张健贵州大学生命科学学院贵州贵阳550025

为探究黔中地区天然次生马尾松针阔混交林群落结构及其空间分布格局特征,选取典型的马尾松-甜槠针阔混交林和马尾松纯林为调查对象,采用成对相关函数分析环境异质性对主要树种空间分布的影响、主要树种及径级空间格局和空间关联性研究... 详细信息

为探究黔中地区天然次生马尾松针阔混交林群落结构及其空间分布格局特征,选取典型的马尾松-甜槠针阔混交林和马尾松纯林为调查对象,采用成对相关函数分析环境异质性对主要树种空间分布的影响、主要树种及径级空间格局和空间关联性研究。调查共记录91种植物,其中马尾松-甜槠针阔混交林和马尾松纯林分别为42种和68种。2个森林群落中乔木总径级整体均呈倒“J”形结构,结构稳定,自然更新良好。结果表明,生境异质性对2种群落类型在小距离上空间分布格局的影响作用明显。2块样地幼树、中树及总体分布格局相似,均为点距离在0~10 m内呈聚集分布、在10~25 m内呈随机分布,而大树在整个观察尺度内均为随机分布。马尾松纯林中马尾松-甜槠、甜槠-槲栎的空间关联性均以不相关为主,马尾松-槲栎以负相关为主;而马尾松-甜槠针阔混交林中马尾松与甜槠在10~20 m以负相关为主。2种群落类型不同径级的空间关联性总体为不相关。黔中山地天然次生马尾松-甜槠针阔混交林、马尾松纯林群落结构存在差异,环境异质性、径级结构和空间尺度对两者空间分布格局及其关联性影响明显。

关键词：马尾松针阔混交林群落结构林木空间分布

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Synthesis and luminescence properties of apatite-type red-emitting Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphors

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Journal of Rare Earths 2021年第11期39卷 1320-1326,I0001页

作者： kun nie Xiaoxue Ma Panlong Lin Navnita Kumar Luoxin Wang Lefu Mei State Key Laboratory of New Textile Materials&Advanced Processing Technology and Key Laboratory of Textile Fiber and Products(Ministry of Education) School of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Science and TechnologyChinaUniversity of Geosciences(Beijing)Beijing 100083China Department of Chemistry and Biochemistry University of CaliforniaLos AngelesCA 90095USA

A new kind of apatite-type red-emitting Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphor was prepared by high temperature solid-state *** Rietveld analysis based on the powder diffraction data shows that Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphors possess a pure apatite phase without any *** emission spectrum of Ba_(2)La_(8)(GeO_(4))_(6)O_(2):Eu^(3+)phosphor consists of two bands,an orange emission band from 500 to 600 nm and a red emission band from 600 to 680 *** varying the amount of the doped europium ions from 0.02 to 0.14 mol,it is found that the luminescent properties of this rare earth phosphor are the best when the concentration of europium ion is 0.08 *** optimum concentration is eventually proved to be 0.08 *** Eu^(3+)doping dependent luminescence quenching can be further ascribed to dipole-quadrupole *** quantum yield of Ba_(2)La_(7.92)(GeO_(4))_(6)O_(2):0.08 Eu^(3+)is 37.23%.The CIE analysis confirms a reddish emission in the near ultraviolet(n-UV)*** these above properties of the phosphor can help in contribution of promoting white light-emitting diode.

关键词： Apatite Calcination Phosphor Optical property Luminescence Rare earths

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A convenient method to prepare random LA/CL copolymers from poly(L-lactide) and ε-caprolactone

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Science China Chemistry 2018年第6期61卷 708-714页

作者： Hao Ouyang kun nie Dan Yuan Yong Zhang Dongmei Cui Yingming Yao Key Laboratory of Organic Synthesis of Jiangsu Province Suzhou Key Laboratory of Macromolecular Design and Precision Synthesisand State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials College of Chemistry Chemical Engineering and Materials Science Dushu Lake Campus Soochow University School of Chemistry and Chemical Engineering Taishan University State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences

Sequential addition of L-lactide(LA) followed by ε-caprolactone(CL), and simultaneous addition of both monomers, afforded random LA/CL copolymers in the presence of lanthanide aryloxides under mild conditions. Transesterification was proved to play a predominant role in random copolymer formation. Moreover, treatment of poly(L-lactide) with ε-CL led to random copolymer formation, which provides a new strategy not only to prepare random LA/CL copolymers, but also to directly modify PLLA.

关键词： random copolymers lanthanide complex transesterification lactide ε-caprolactone

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基于GRU门控单元网络的电力负荷预测研究

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粘接 2024年第4期51卷 145-148页

作者：章家义龚圣辉聂堃国网江西省电力有限公司江西南昌330077

准确预测电力负荷,有利于提高电力系统供需平衡,为提高电力负荷预测精度,提出一种基于迁移学习的电力负荷预测模型。该模型以门控循环单元模型(GRU)为基础模型,通过设定最大均值差异算法阈值,从而选择迁移学习的模型,最终实现电力负荷... 详细信息

准确预测电力负荷,有利于提高电力系统供需平衡,为提高电力负荷预测精度,提出一种基于迁移学习的电力负荷预测模型。该模型以门控循环单元模型(GRU)为基础模型,通过设定最大均值差异算法阈值,从而选择迁移学习的模型,最终实现电力负荷雨预测。仿真结果表明,所提模型可准确预测电力负荷数据,相较于BPNN模型和LSTM模型,所提出模型的MAPE值更低,为17.5%,分别降低了15%和7.5%,具有更高的预测准确度,可用于电力负荷预测实际应用中。

关键词：数据分析电力负荷预测迁移学习 GRU模型

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Structure and luminescence properties of color-tunable phosphor Sr_(2)La_(3)(SiO_(4))_(3)F:Tb^(3+),Sm^(3+)

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稀土学报:英文版 2023年第9期41卷 1288-1294,I0001页

作者： Haikun Liu kun nie Yuanyuan Zhang Lefu Mei Dina V.Deyneko Xiaoxue Ma Department of Energy and Chemical Engineering Dongguan University of TechnologyDongguan 523808China State Key Laboratory of New Textile Materials&Advanced Processing Technology and Hubei Key Laboratory for New Textile Materials and Applications School of Materials Science and EngineeringKey Laboratory of Polyphenylene Sulfide Fiber and Application in Textile IndustryWuhan Textile UniversityWuhan430200China Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes National Laboratory of Mineral MaterialsSchool of Materials Sciences and TechnologyChina University of GeosciencesBeijing 100083China School of Materials Sciences and Technology Dongguan University of TechnologyDongguan 523808China School of Materials Science and Engineering Xi'an Jiaotong UniversityXi'an 710049China Department of Chemistry Lomonosov Moscow State UniversityMoscow 119991Russia Laboratory of Arctic Mineralogy and Material Sciences Kola Science CentreRussian Academy of Sciences14 Fersman Str.184209ApatityRussia

A series of single-phase and color-tunable phosphors Sr_(2)La_(3)(SiO_(4))_(3)F:0.15Tb^(3+),xSm^(3+)(SLSOF:0.15Tb^(3+),xSm^(3+)) was prepared using solid-state *** X-ray diffraction(XRD) was used to characterize the phase of the as-prepared *** synthesized phosphors have apatite-type structure without other ***^(3+) and Tb^(3+) ions substitute La^(3+) into the lattice and form a single-phase solid *** elements are evenly distributed in the sample according to the scanning electron microscopy(SEM) *** crystal structure of the host phosphor was refined by the Rietveld *** optical properties were studied in detail by investigation of the luminescence and diffuse spectra,fluorescence decay curves and energy transfer *** phosphor color can be changed from green(0.29,0.48) to yellow/orange and red(0.57,0.42) via adjusting the doping ratio of Sm^(3+).The SLSOF:0.15Tb^(3+),xSm^(3+)phosphors can emit typical multicolor light such as green,yellow,orange and red with gradually increasing Sm^(3+)doping *** results indicate the occurrence of the energy transfer which results in the color-tunable properties of the phosphors.

关键词： Apatite Calcination Phosphor Optical property Luminescence Rare earths

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Cultivation of aerobic granular sludge in a conventional, continuous flow, completely mixed activated sludge system

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Frontiers of Environmental Science & Engineering 2015年第2期9卷 324-333页

作者： Xi CHEN Linjiang YUAN Wenjuan LU Yuyou LI Pei LIU kun nie School of Environmental and Municipal Engineering Xi'an University of Architecture and Technology Xi'an 710055 China Department of Environmental Science Graduate School of Environmental Studies Tohoku University Sendai 980-8579 Japan

Aerobic granules were formed in a conven- tional, continuous flow, completely mixed activated sludge system （CMAS）. The reactor was inoculated with seed sludge containing few filaments and fed with synthetic municipal wastewater. The settling time of the sludge and the average dissolved oxygen （DO） of the reactor were 2 h and 4.2 mg. L 1, respectively. The reactor was agitated by a stirrer, with a speed of 250r·min^-1, to ensure good mixing . The granular sludge had good settleability, and the sludge volume index （SVI） was between 50 and 90 mL ·g ^-1. The laser particle analyzer showed the diameter of the granules to be between 0.18 and 1.25 mm. A scanning electron microscope （SEM） investigation revealed the predominance of sphere-like and rod-like bacteria, and only few filaments grew in the granules. The microbial community structure of the granules was also analyzed by polymerase chain reaction-denaturing gradient gel electro- phoresis （PCR-DGGE）. Sequencing analysis indicated the dominant species were α, β, and γ-Proteobacteria, Bacteroidetes, and Firmicutes. The data from the study suggested that aerobic granules could form, if provided with sufficient number of filaments and high shear force. It was also observed that a high height-to-diameter ratio of the reactor and short settling time were not essential for the formation of aerobic granular sludge.

关键词： aerobic granular sludge completely mixed activated sludge system (CMAS) continuous flow shear force filamentous bacteria polymerase chain reaction- denaturing gradient gel electrophoresis (PCR-DGGE)

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Bimetallic amine-bridged bis(phenolate) lanthanide aryloxides and alkoxides: synthesis, characterization, and application in the ring-opening polymerization of rac-lactide and rac-β-butyrolactone

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Science China Chemistry 2014年第8期57卷 1106-1116页

作者： nie kun FENG Tao SONG FengKui ZHANG Yong SUN HongMei YUAN Dan YAO YingMing SHEN Qi Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials ScienceSoochow University School of Chemistry and Chemical Engineering Taishan University

A series of neutral bimetallic lanthanide aryloxides p-C6H4[OLnL(THF)n]2 [Ln = Y(1), Yb(2), Sm(3)(n = 1) and La(4)(n = 2), L = Me2NCH2CH2N{CH2-(2-O–C6H2–tBu2-3,5)}2] and alkoxides p-C6H4CH2[OLnL(THF)]2 [Ln = Y(5), Yb(6)] supported by an amine-bridged bis(phenolate) ligand have been synthesized through one-pot reactions of Ln(C5H5)3(THF), LH2 with p-benzenediol and 1,4-benzenedimethanol, respectively. All complexes have been fully characterized by elemental analyses, single-crystal X-ray diffraction analysis, and IR and multi-nuclear NMR spectroscopy(in the cases of 1, 4 and 5). Study of their catalytic behavior revealed that, in general, all complexes are efficient initiators for the polymerization of rac-lactide(LA) and rac-β-butyrolactone(BBL), except for 3 and 4 in the case of BBL. The influence imposed by lanthanides of different ionic radii and initiating groups of different structures on the activity, controllability, and stereoselectivity of polymerization were systematically studied and compared. Highly heterotactic PLA(Pr up to 0.99) and syndiotactic PHB(Pr ≈ 0.81) with high molecular weight and narrow polydispersity formed and were automatically capped with hydroxyl functionality at both ends.

关键词： amine-bridged bis(phenolate) ligand bimetallic lanthanide aryloxides and alkoxides ring-opening polymerization,stereoselectivity

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