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Enhancing postoperative pain control by surgically-initiated rectus sheath block in abdominal aortic aneurysm open repair: A case report

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World Journal of Clinical Cases 2025年第6期13卷 41-47页

作者： kuan-hua Chen Ming-Yuan Kang Yi-Ting Chang Sheng-Yang huang Yung-Szu Wu Center for Cardiovascular Disease Taichung Veterans General HospitalTaichung 407219TaiwanChina Department of Anesthesiology Taichung Veterans General HospitalTaichung 407219TaiwanChina Division of Pediatric Surgery Department of SurgeryTaichung Veterans General HospitalTaichung 407219TaiwanChina School of Medicine National Yang Ming Chiao Tung UniversityTaipei 112304TaiwanChina Department of Post-Baccalaureate Medicine National Chung Hsing UniversityTaichung 402202TaiwanChina

BACKGROUND Abdominal aortic aneurysm(AAA)repair often involves significant postoperative pain,traditionally managed with systemic opioids,which can cause undesirable side *** case report explores the novel use of a surgically-initiated rectus sheath block with a catheter-over-needle assembly for pain management in AAA *** SUMMARY A 67-year-old female with hypertension and previous aortic dissection underwent elective open repair of an infrarenal AAA,which had grown from 3.4 cm to 4.3 cm over 14 months.A rectus sheath block was initiated surgically for postoperative pain *** patient reported low pain scores and did not require systemic intravenous opioids,enabling early ambulation and discharge on postoperative day seven without *** preventing complications of systemic opi-oids,the method indicating a promising direction for postoperative pain management in major vascular *** Surgically-initiated rectus sheath block as a valuable tool for managing postoperative pain in AAA repair.

关键词： Abdominal aortic aneurysm Postoperative pain management Rectus sheath block Surgical anesthesia Opioid-sparing techniques Case report

Synthesis and Crystal Structure of 1-(N,N-Di-(p-toluenesulfonyl))-amino-2-(N'-p-toluenesulfonyl)-amino-3,5-dinitrobenzene

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Chinese Journal of Structural Chemistry 2007年第3期26卷 309-313页

作者： CHEN hua-Mei LIN Hai LIN hua-kuan Department of Chemistry Nankai University Tianjin 300071 China State Key Laboratory of Functional Polymer Materials for Absorption and Separation Nankai University Tianjin 300071 China

The title compound, 1-（N,N-di-（p-toluenesulfonyl））-amino-2-（N＇-p-toluenesulfonyl）- amino-3,5-dinitrobenzene, was synthesized and structurally determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Pna21 with a = 13.723（2）, b = 25.354（4）, c = 8.6565（12） A, V= 3011.9（8） A^3, Z = 4, Mr = 660.68, F（000） = 1368, Dc = 1.457 g/cm^3, μ = 0.309, the final R = 0.0609 and wR = 0.1042. The H atom of N2-H group, which is the unique recognition site to anion, is enveloped by two oxygen atoms and one benzene from two and one p-toluenesulfonyl moieties, respectively.

关键词： sulfonylamide anion recognition receptor crystal structure

Applications of Extended Mapping Deformation Method in Two （3＋1）-Dimensional Nonlinear Models

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Communications in Theoretical Physics 2005年第5期43卷 775-780页

作者： huaNGWen-hua ZHANGJie-Fang GEWei-kuan CollegeofScience HuzhouUniversityHuzhou313000China／／ShanghaiInstituteofAppliedMathematicsandMechanicsShanghaiUniversityShanghai200072China ShanghaiInstituteofAppliedMathematicsandMechanics ShanghaiUniversityShanghai200072China／／InstituteofNonlinearPhysicsZhejiangNormalUniversityJinhua321004China CollegeofScience HuzhouUniversityHuzhou313000China

Based on the extended mapping deformation method and symbolic computation, many exact travelling wave solutions are found for the (3+1)-dimensional JM equation and the (3+1)-dimensional KP equation. The obtained solutions include solitary solution, periodic wave solution, rational travelling wave solution, and Jacobian and Weierstrass function solution, etc.

关键词： (3+1)-dimensional JM equation (3+1)-dimensional KP equation travelling wavesolution

Synthesis and Crystal Structure of N-(1′-H-Pyrrol-2′-ylcarbonyl)-5-amino-1,10-phenanthroline

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Chinese Journal of Structural Chemistry 2008年第2期27卷 163-166页

作者： WANG Yue-Hong LIN Hai LIN hua-kuan Department of Chemistry Nankai University Tianjin 300071 China Key Laboratory of Functional Polymer Materials of the Ministry of Education Nankai University Tianjin 300071 China

The title compound, N-（1′-H-pyrrol-2′-ylcarbonyl）-5-amino-1,10-phenanthroline, was synthesized by the reaction of a-pyrrolyl carbonyl chloride and 5-amino-1,10-phenanthroline in pyridine. Determined by X-ray structure analysis, it crystallizes in triclinic system, space group P1 with the following crystallographic data： C20H21N5O3, Mr = 379.42, a = 7.8559（4）, b = 9.1681（6）, c = 14.6818（9） A, α= 73.254（10）,β= 88.938（15）, γ= 68.080（10）°, V= 934.66（10） A3, Z = 2, F（000） = 400, Dc = 1.348 g/cm^3 and p = 0.094 mm-1. The final R = 0.0680 and wR = 0.1419 for 2142 observed reflections with I 〉 2σ（/）, and R = 0.1084 and wR = 0.1643 for all reflections. Two aromatic ring planes （pyrrole and phenanthroline rings） are connected by the amide plane. Two different types of intermolecular hydrogen bonds, O-H…N and N-H…O, exist in the crystal. The title complex molecules are connected through hydrogen bonds and weak π-π stacking interactions to generate a 3-D supramolecule.

关键词： 1,10-phenanthroline pyrrole amide crystal structure

Trinuclear Metal Complexes Based on 1,10-Phenanthroline Derivates as Catalysts for Cleavage of a RNA-Model Substrate

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Chemical Research in Chinese Universities 2007年第5期23卷 493-499页

作者： XU Xin-he LIN Hai LIN hua-kuan　 Department of Chemistry Key Laboratory of Functional Polymer Materials of Ministry of Education Nankai University Tianjin 300071 P. R. China

Two multidentate ligands 2,9-di[6＇-（2″-hydroxyl-3″-methoxyphenyl）-n-2＇,5＇-diazahexyl]-1,10-phenanthroline（LA）and 2,9-di（6＇-α-phenol-n-2＇,5＇-diazahexyl）-1,10-phenanthroline（LB）were synthesized and fully *** of the ligands and the stability of the complexes of the ligands with divalent metal ions were *** trinuclear metal complexes [Cu（Ⅱ）and Zn（Ⅱ）] of the ligands were studied,as catalysts,for the transphosphorylation of the RNA-model substrate 2-hydroxypropyl-p-nitrophenyl phosphate（HPNP）.The second-order rate constants of HPNP-hydrolysis catalyzed by M3L and M3LH-1 were obtained,which indicated that Zn3LBH-1 was the most efficient catalyst among *** proposed mechanisms included the activation of the substrate via binding to the metal ions and intramolecular nucleophilic attack by the deprotonated C2-hydroxyl of HPNP.

关键词： (:eywords Trinuclear metal complex 1, 10-Phenanthroine derivate Catalyst Cleavage of RNA-model substrate

Synthesis and Crystal Structure of Cu(II) Complex with 2,9-Bis(n-2',5'-diazaheptanyl)-1,10-phenanthroline

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Chinese Journal of Structural Chemistry 2004年第7期23卷 778-782页

作者： LIFeng-hua LIUTian-Fu LINhua-kuan ZHUShou-Rong WANGZhong-Ming DepartmentofChemistry NankaiUniversityTianjin300071China

The Cu(II) complex with the ligand 2,9-bis(n-2?5?diazaheptanyl)-1,10-phenan- throline (L) has been synthesized and characterized by single-crystal X-ray diffraction. It crys- tallizes in the monoclinic system, space group P21/n with a = 12.549(4), b = 13.544(4), c = 16.767(5) ? = 107.179(5), C22H32Cl2N6CuO8, Mr = 642.98, V = 2722.5(13) 3, Z = 4, Dc = 1.569 g/cm3, ?= 1.056 mm-1, F(000) =1332, the final R = 0.0733 and wR = 0.1581. The X-ray analysis revealed that the Cu(II) ion is coordinated by six nitrogen atoms of the ligand, in which two nitrogen from phenanthroline and another two from the imine groups near phenanthroline are in the equatorial plane while the two from imine groups at the end of both arms in the axial positions. The coordination geometry can be described as a compressed octahedron.

关键词： phenanthroline Cu(II) complex crystal structure compressed octahedron

Design,Synthesis and Recognition Properties of a New Acetate Ion Receptor Based on Shiff-base Derivative

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Chemical Research in Chinese Universities 2011年第4期27卷 574-577页

作者： QIAO Yan-hong LIN Hai LIN hua-kuan Department of Chemistry Tianjin Normal University Tianjin 300387 P. R. China Department of Chemistry Nankai University Tianjin 300071 P. R. China Key Laboratory of Functional Polymer Materials Ministry of Education Nankai University Tianjin 300070 P. R. China

A simple colorimetric acetate ion receptor based on 3-methoxysalicylaldehyde-4＇-nitrophenyl-hydrazone was synthesized in an ethanol solution through one step,and characterized by 1H NMR and elemental *** anion-binding ability was examined by UV-Vis absorption spectroscopy in DMSO（dimethyl sulfoxide）.The result shows that the compound has a high affinity for and a high selectivity toward acetate ions,and also an advantage of ＇naked-eye＇ recognition of color changing from yellow to purple.

关键词： Anion recognition Colorimetric 'Naked-eye' recognition Schiff base

Synthesis and Crystal Structure of a New Mononuclear Cu(Ⅱ) Complex with 4,4'-Dimethyl-2,2'-bipyridine

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Chinese Journal of Structural Chemistry 2004年第7期23卷 765-767页

作者： LI Feng-hua GAO Dong-Zhao WU Hong-Xing LIN hua-kuan ZHU Shou-Rong Department of Chemistry Nankai UniversityTianjin 300071China

A new mononuclear copper (II) complex, [Cu(dbpy)2Cl]OH0.5CH3OH2H2O (dbpy = 4,4?dimethyl-2,2?bipyridine) (C24.50H31ClCuN4O3.50, Mr = 536.52) has been synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in monoclinic, space group P2/c with a = 13.383(6), b = 7.653(3), c = 14.164(6) ? b = 105.395(8), V = 1398.7(10) 3, Z = 2, Dc = 1.274 g/cm3, m = 0.908 mm-1, F(000) = 560 and R = 0.0773 for 1467 observed reflections with I>2s(I). Each copper(II) ion is coordinated by two dbpy and one Cl- ion and the coordination geometry can be described as a distorted trigonal bipyramidal arrange- ment.

关键词： copper complex 4,4′-dimethyl-2,2′-bipyridine crystal structure

Design strategy of phase and microstructure of Si_(3)N_(4) ceramics with simultaneously high hardness and toughness

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Journal of Advanced Ceramics 2023年第1期12卷 122-131页

作者： Shao-Jun TANG Wei-Ming GUO Shi-kuan SUN hua-Tay LIN School of Electromechanical Engineering Guangdong University of TechnologyGuangzhou 510006China School of Material Science and Energy Engineering Foshan UniversityFoshan 528000China

Aiming to achieve silicon nitride( Si_(3)N_(4))ceramics with high hardness and high toughness,the relationships among phase composition,microstructure,and mechanical properties of Si_(3)N_(4) ceramics prepared by spark plasma sintering(SPS)at temperatures ranging from 1500 to 1800℃were investigated in this *** stages with different phase and microstructure features were observed and ***α-βphase transformation occurs first,and the development and growth of grains lag *** the first stage,the average grain size remains basically unchanged,and the hardness maintains at a value of~20.18±0.26 GPa,despite theβ- Si_(3)N_(4) phase fraction increases from 7.67 to 57.34 wt%.Subsequently,the equiaxed grains transform into rod-like grains with a high aspect ratio via the reprecipitation process,resulting in a significant increase in the fracture toughness from 3.36±0.62 to 7.11±0.15 MPa·m^(1/2).In the second stage of sintering process,the fraction ofβ- Si_(3)N_(4) phase increases to 100.00 wt%,and the grain growth also rapidly ***,the fracture toughness increases slightly to 7.61±0.42 MPa·m^(1/2),but the hardness reduces to 16.80±0.20 *** current results demonstrate that the phase contents ofβ- Si_(3)N_(4) and the microstructure shall be carefully tailored to achieve high-performance Si_(3)N_(4) ceramics. Si_(3)N_(4) ceramics with a finegrained bimodal microstructure,consisting of the mainα-andβ-phases,can exhibit the optimized combination of hardness and toughness.

关键词： silicon nitride(Si_(3)N_(4)) phase composition microstructure hardness toughness