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Carbon dioxide induced degradation of diethanolamine during absorption and desorption processes

Chinese Journal of Chemical Engineering 2018年第2期26卷 293-302页

作者： Md.Sakinul Islam kotaiah naik dhanavath Nhol Kao Pradipto K.Bhattacharjee Brahim Si Ali Rozita Yusoff Department of Chemical Engineering School of EngineeringRMIT UniversityMelbourneVIC 3001Australia Department of Chemical Engineering Faculty of EngineeringUniversity of Malaya50603 Kuala LumpurMalaysia

Alkanolamines are widely used in the purification of the sourgas sweetening process. During the sour gas absorption process, CO_2 significantly degrades the amine solvent and creates enormous problems for plant operation. In this work, CO_2 induced degradation of aqueous diethanolamine(DEA) solution was conducted in a 1.25 L jacketed glass reactor that functioned as an absorber and stripper at atmospheric conditions. Pure CO_2 was bubbled through the reactor until the solution became saturated. In this study, the concentrations of DEA used were in the range of concentrations between 2 mol·L^(-1) and 4 mol·L^(-1). In the degradation experiment, six generic cycles were conducted for each run. Each cycle was configured with the absorption and desorption of carbon dioxide at 55 ℃ and 100 ℃, respectively. Samples were collected after a predetermined experimental time and analyzed by ion chromatography(IC) to identify unknown ionic degradation products(DGPs). In the IC analysis, three different columns were used for anion, cation and ion exclusion systems, which are Metrosep A Supp 5150/4.0, Metrosep C Supp 4 150/4.0 and Metrosep Organic Acids, respectively. The major identified DGPs of D01 DEA2 M, D02 DEA3 M, and D03 DEA4 M are nitrite, acetate and ammonium. Phosphate product was found in the degraded amine samples which might be due to the contamination of water or chromatographic system.

关键词： Degradation Diethanolamine Absorption Stripping Gas sweetening process

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