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Refining aquifer heterogeneity and understanding groundwater recharge sources in an intensively exploited agrarian dominated region of the Ganga Plain

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Geoscience Frontiers 2024年第4期15卷 134-147页

作者： Abhinav Patel Shive Prakash Rai Nijesh Puthiyottil Abhinesh Kumar Singh Jacob Noble Rajesh Singh Dharmappa Hagare U.D.Saravana Kumar Nachiketa Rai kossitse venyo akp.taku Department of Geology Institute of ScienceBanaras Hindu UniversityVaranasiUttar Pradesh 221005India Isotope and Radiation Application Division Bhabha Atomic Research CentreTrombayMumbai 400085India Environmental Hydrology Division National Institute of HydrologyRoorkeeUttarakhand 247667India School of Engineering Design and Built EnvironmentWestern Sydney UniversityAustralia Isotope Hydrology Section Division of Physical and Chemical SciencesInternational Atomic Energy Agency(IAEA)ViennaAustria Department of Earth Sciences Indian Institute of TechnologyRoorkeeUttarakhand 247667India Laboratory of Organic Chemistry and Environmental Science Department of ChemistryUniversity of KaraPO Box 404KaraTogo

Densely populated region of Ganga Plain is facing aquifer vulnerability through waterborne pollutants and groundwater stress due to indiscriminate abstraction,causing environmental and socio-economic *** address long-term groundwater resilience,it is crucial to understand aquifer heterogeneity and connectivity,groundwater recharge sources,effects of groundwater abstraction *** this con-text,present study aims to understand factors responsible for vertical and spatial variability of groundwater chemistry and to identify groundwater recharge sources in an intensively exploited agrarian region of the Ganga *** of chemometric,statistical,and isotopic analysis categorises the alluvial aquifer into zone 1(G1;ground surface to 100 m)and zone 2(G2;>100 m-210 m).The group G1 samples are characterized by a wide variation in hydrochemical species,noted with pockets of F-and NO3-rich groundwater,and fresh to more evolved water types,while group G2 groundwater is characterized by a sharp increase in freshwater types and limited variation in their isotopic and hydrochemical *** G1 groundwater chemistry is governed by soil mineralogy,local anthropogenic inputs(SO42-,Cl-,and NO3-),and manifested by multiple recharge sources(local precipitation,river,canal water,pond).The G2 group is dominated by geogenic processes and mainly recharged by the local *** signatures confirm more evolved water type for group G1 in northwestern region,while fresh-water type covers the rest of the study *** rich groundwater is attributed to sodic water under alkaline conditions and enrichedδ18O values emphasizing role of evaporation in F-mobilization from micas and amphiboles abundant in the *** findings provide insight into potential groundwater vulnerability towards inorganic contaminants,and ground water recharge *** outcome of this study will help to develop aquifer resilience towards indiscriminate groundwater extrac

关键词： Stable isotopes Hydrogeochemical attributes Groundwater recharge sources Ganga Plain

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Hydrochemical evolution of groundwater in northwestern part of the Indo-Gangetic Basin,India:A geochemical and isotopic approach

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Geoscience Frontiers 2023年第6期14卷 450-463页

作者： Shive Prakash Rai kossitse venyo akp.taku Jacob Noble Abhinav Patel Suneel Kumar Joshi Department of Geology Institute of ScienceBanaras Hindu UniversityVaranasi 221005India Laboratory of Organic Chemistry and Environmental Sciences Department of ChemistryUniversity of KaraPO Box 404KaraTogo Laboratory of Applied Hydrology and Environment University of LoméP.O.Box 1515LomeTogo Isotope and Radiation Application Division Bhabha Atomic Research CentreMumbai 400085India Hydrological Investigations Division National Institute of HydrologyRoorkee 247667India

The present study aims to understand the hydrochemical evolution of groundwater in the Ghaggar River Basin,representing a zone of excessive abstraction of groundwater in the northwestern Indo-Gangetic *** study comprises a regional scale and high-resolution sampling of groundwater during preand post-monsoon seasons of 2013 and their analyses for major ions,δ^(18)O,δ^(2)H,and 3 *** in hydrochemical and isotopic data is found both in spatial and vertical *** significant vertical variation of TDS,NO_(3)and K^(+)allowed the classification of the aquifer system into two major groups:shallow(depth80 m bgl).The depthwise variations ofδ^(18)O andδ^(2)H support this categorization of the *** Ca-HCO_(3)and Ca-Mg-Na-HCO_(3)water facies with higher values of 3 H in the proximal part of the basin characterize recharge areas under humid *** dominance of Mg-Na-HCO_(3)and Na-HCO_(3)facies in shallow and deep aquifers in central part of the basin,illustrate the intermediate to advanced stages of hydrochemical evolution in the *** of brackish Ca-Mg-Cl-SO_(4)and Na-Cl-SO_(4)water types in the discharge areas is due to the prevailing geological conditions and anthropogenic *** modelling supports the reverse cation exchange and mixing during lateral and vertical flows,weathering of silicate minerals,dissolution of crustal salts,and evaporative enrichment are the natural processes governing the evolution of groundwater chemistry along the *** developed process-based conceptual model will aid in the formulation of a suitable plan for groundwater resource management in the region.

关键词： Hydrogeochemical evolution Groundwater salinity Cation exchange Fluoride Anthropogenic impact Ghaggar River Basin

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Role of Natural and Anthropogenic Influence on the Salinization of Groundwater from Basement Aquifers in the Middle Part of Mono River Basin, Togo

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Journal of Environmental Protection 2020年第12期11卷 1030-1051页

作者： kossitse venyo akp.taku Masamaéya D. T. Gnazou Gbandi Djanéyé-Boundjou Limam Moctar Bawa Serigne Faye Laboratory of Applied Hydrology and Environment Faculty of Science University of Lomé Lomé Togo Department of Geology Faculty of Sciences and Techniques Cheikh Anta Diop University Dakar Senegal Department of Chemistry Faculty of Sciences and Techniques University of Kara Kara Togo

This study aimed to identify the role of natural and anthropogenic influence on geochemical processes controlling groundwater salinization in the middle portion of the Mono River basin, Togo. Multivariate statistical analysis, geochemical masse balance modeling, and conventional graphical methods were applied to the chemical dataset obtained from 110 groundwater samples collected during two campaigns (March-May 2011 and April 2014). The results showed that groundwater is predominantly fresh, acidic to circumneutral and mixed cations-HCO-3 water types. The proportion of ions (Na+, K+, Cl- and SO2-4) occurring ubiquitously in a saline environment increases substantially with TDS. Two factors, defined as natural and anthropogenic, account for 76.5% of the hydrochemical dataset variance. Based on the hierarchical cluster analysis, groundwater samples are classified into four clusters that corroborate the factor analysis results and illustrate different hydrochemical evolution stages along a topographically-driven groundwater flow path. The primary natural process contributing to cations and bicarbonate ions is the weathering of silicate minerals and possibly secondary carbonates by infiltrating water enriched with soil CO2 gas. Groundwater salinization indicators including Cl-, SO2-4 and NO-3, originate from potential sources such as human and animal wastes, agrochemicals, and deforestation. Thermodynamic equilibrium conditions ranged from saturation to oversaturation with respect to quartz, chalcedony, amorphous silica, calcite, dolomite, sepiolite, and talc. In con

关键词： Mono River Basin Groundwater Silicates Weathering Anthropogenic Contamination Salinization Togo

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Physicochemical and Microbiological Quality of Shallow Groundwater in Lomé, Togo

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Journal of Geoscience and Environment Protection 2020年第12期8卷 162-179页

作者： kossitse venyo akp.taku Masamaéya D. T. Gnazou Tse Yawo Agbefu Nomesi Phintè Nambo Komi Doni Limam Moctar Bawa Gbandi Djaneye-Boundjou Laboratory of Applied Hydrology and Environment (Ex Laboratory of Water Chemistry) University of Lomé Lomé Togo Department of Chemistry Faculty of Sciences and Techniques University of Kara Kara Togo Agency of Water and Sanitation for Africa Office of Togo Lomé Togo

The present study aimed to assess the physicochemical and microbiological quality of shallow groundwater tapped by private boreholes for water sale in Togo’s most urbanized coastal areas. Ninety-six (96) groundwater samples were collected at the water sale points for chemical and microbiological analyses using standard methods. The results showed that groundwater is predominantly acidic with fresh and brackish water of Na-Cl type. High concentrations of dissolved inorganic nitrogen (NO3- , NH4+and NO2-) and permanganate indices indicating potential organic matter were found. Among the major ions, Na+ (46.9%), Cl- (51.0%) and NO3- (50.0%) present the highest percentages of unsuitable concentrations compared to WHO guidelines. These findings indicate the control of the natural impact of seawater and lagoon system and anthropogenic pollution from domestic and urban wastes on groundwater’s physicochemical quality. About 65% of groundwater samples did not comply with the drinking water guidelines for microbial indicators, including total mesophilic flora, thermotolerant coliforms, and sulfite-reducing anaerobes. The results showed the failure of sanitation and hygiene conditions around sampling points and fecal contamination from sewage, pit latrines, septic tanks, and refuse and waste disposal. The degradation of physicochemical quality is higher in the old and high-density built-up areas. Simultaneously, microbial contamination represents a high risk of contracting waterborne or hygiene-sanitation-related diseases in the whole study area. This study provides a global view of shallow groundwater’s physicochemical and microbiological quality in the study area. Limitations and suggestions for future research are d

关键词： Shallow Groundwater Saltwater Nitrate Fecal Contamination Lome-Togo

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