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Chinese Journal of Polymer Science 2004年第4期22卷 343-348页

作者： khalil faghihi Organic Polymer Chemistry Research Laboratory Department of Chemistry Faculty of Science Arak University Arak 38156 Iran

Facile and rapid polycondensation reactions of N,N'-(pyromellitoyl)-bis-L-leucine diacid chloride 1 with eight different derivatives of hydantoin compounds 2a-h were developed by using a domestic microwave oven in the presence of a small amount of polar organic medium such as o-cresol. The polycondensation reactions proceeded rapidly, compared with the conventional solution polycondensation, and was completed within 7-10 min, producing a series of novel optically active poly(amide-imide)s 3a-h with high yield and inherent viscosity of 0.35-0.65 dL/g. All of the above polymers were fully characterized by FT-IR, elemental analyses, inherent viscosity (η inh ), solubility test and specific rotation. Some structural characterization and physical properties of these optically active poly(amide-imide)s are reported.

关键词： Microwave-assisted rapid polycondensation Optically active polymers Poly(amide-imide)s Hydantoin derivatives N,N'-(Pyromellitoyl)-bis-L-leucine diacid chloride

SYNTHESIS AND CHARACTERIZATION OF OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S CONTAINING PHOTOSENSITIVE CHALCONE UNITS IN THE MAIN CHAIN

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Chinese Journal of Polymer Science 2010年第5期28卷 695-704页

作者： khalil faghihi Hassan Moghanian Organic Polymer Chemistry Research Laboratory Department of ChemistryFaculty of ScienceArak UniversityArak 38156Iran

A series of new optically active poly（amide-imide）s were synthesized by direct polycondensation reaction of 4,4＇-diaminochalcone with several N-trimellitylimido-L-amino acids using a tosyl chloride （TsCl）, pyridine （Py） and dimethylformamide （DMF） system as condensing agent. The resulting thermally stable poly（amide-imide）s were obtained in good to high yields and inherent viscosities ranging between 0.35 dL/g and 0.58 dL/g and were characterized with FTIR, IH-NMR, CHN, Ultraviolet, TGA and DTG techniques.

关键词： Poly(amide-imide)s Chalcone moeity Polycondensation Optically active polymers.

New optically active poly(amide-imide)s derived from N,N'-(4,4-diphthaloyl)-bis-L-leucine and hydantoin derivatives:Synthesis and properties

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Chinese Chemical Letters 2009年第10期20卷 1153-1156页

作者： khalil faghihi Polymer Chemistry Research Laboratory Department of ChemistryFaculty of ScienceIslamic Azad UniversityArak BranchArakIran

Six new optically active poly（amide-imide）s （5a-f） were synthesized through the direct polycondensation reaction of N,N′-（4,4′- diphthaloyl）-bis-L-leucine （3） with six hydantoin derivatives （4a-f）. Tripbenyl phosphite （TPP）/pyridine in the presence of calcium chloride （CaCl2） and N-methyl-2-pyrrolidone （NMP） were successfully applied for direct polycondensation. The polycondensation reactions produce a series of new poly（amide-imide）s （5a-f） in high yields, and inherent viscosity between 0.42 and 0,55 dL/g. The resulting poly（amide-imide）s （5a-f） were characterized by elemental analysis, viscosity measurements, thermal gravimetric analysis （TGA and DTG）, solubility test and FT-IR spectroscopy.

关键词： High performance polymers Poly(amide-imide)s Direct polycondensation Hydantoin derivatives

Synthesis and characterization of new polyesters based on 2,5-bis[(4-chloro carboxyanilino)carbonyl]pyridine and aromatic diols

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Chinese Chemical Letters 2010年第1期21卷 13-17页

作者： khalil faghihi Polymer Research Laboratory Department of ChemistryFaculty of ScienceIslamic Azad UniversityBranch ArakArakIran

Six new polyesters 7a-f were synthesized through the solution polycondensation reaction of diacid chloride 5 with six aromatic diols 6a-f in N,N-dimethyl acetamide(DMAc) as solvent in the presence of pyridine as *** polycondensation reaction produced a series of novel polyester containing pyridyl moiety in the main chain in high yields with inherent viscosities between 0.35 and 0.54 dL/*** resulted polymers were fully characterized by means of FT-IR spectroscopy,elemental analyses,inherent viscosity ...

关键词： High-performance polymers Polyesters Pyridyl moiety Aromatic diols

RAPID SYNTHESIS OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S DERIVED FROM N,N'-(PYROMELLITOYL)-BIS-L-ALANINE DIACID CHLORIDE AND HYDANTOIN DERIVATIVES UNDER MICROWAVE IRRADIATION

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Chinese Journal of Polymer Science 2005年第1期23卷 63-69页

作者： khalil faghihi Azizollah Mirsamie Organic Polymer Chemistry Research Laboratory Department of ChemistryFaculty of ScienceArak UniversityArak38156Iran Chemical Engineering DeptFaculty of EngineeringAzad Univertsity of ArakArakIran Organic Polymer Chemistry Research LaboratoryDepartment of ChemistryFaculty of ScienceArak UniversityArak38156Iran

Eight novel poly(amide-imide)s were synthesized under microwave irradiation by using a domestic microwaveoven from the polycondensation reactions of N.N'-(pyromellitoyl)-bis-L-alanine diacid chloride(1)with eight differentderivatives of hydantoin compounds(2a-h)in the presence of a small amount of a polar organic medium such as *** polycondensation proceeded rapidly,compared with the conventional solution polycondensation and was completedwithin 8-10 min,producing a series of new poly(amide-imide)s(3a-h)with inherent viscosities about 0.35-0.68 dL/g inhigh *** obtained PAIs(3a-h)were fully characterized by means of FT-IR spectroscopy,elemental analyses,inherentviscosity(ηinh),solubility and specific rotation *** of the resulting polymers show optical rotation and areoptically *** properties of the poly(amide-imide)s were investigated by using thermal gravimetric analysis(TGA).

关键词： Microwave-assisted polycondensation Optically active polymers 5,5-Disubstituted hydantoin derivatives.

OPTICALLY ACTIVE AND FLAME-RETARDANT POLY(AMIDE-IMIDE)S BASED ON PHOSPHINE OXIDE MOIETY AND N,N′-(PYROMELLITOYL)BIS-L-AMINO ACID IN THE MAIN CHAIN:SYNTHESIS AND CHARACTERIZATION

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Chinese Journal of Polymer Science 2010年第4期28卷 517-525页

作者： khalil faghihi Mohsen Hajibeygi Organic Polymer Chemistry Research Laboratory Department of ChemistryFaculty of ScienceArak UniversityArak 38156Iran

Six new optically active and flame-retardant poly（amide-imide）s PAls 5a-5f containing phosphine oxide moiety as a flame-retardant unit in the main chain were synthesized from direct polycondensation reaction of six chiral N,N＇-（pyromellitoyl）-bis-L-amino acid 3a-3f with bis（3-aminophenyl）phenyl phosphine oxide 4 in a medium consisting of N-methyl-2-pyrrolidone （NMP）, triphenyl phosphite （TPP）, calcium chloride （CaCl2） and pyridine. The polymerization reactions produced a series of optically active poly（amide-imide）s with good yield and good inherent viscosity of 0.34-0.70 dLg^-1. The resulted polymers were fully characterized by means of FTIR and ^1H-NMR spectroscopy, gel permeation chromatography （GPC）, elemental analyses, inherent viscosity and solubility tests. Thermal properties and flameretardant behavior of the PAIs 5a-5f were investigated using thermal gravimetric analysis （TGA and DTG） and limiting oxygen index （LOI）. Data obtained by thermal analysis （TGA and DTG） revealed that these polymers showed good thermal stability. Furthermore, high char yield in TGA and good LOI values indicated that the resulting polymers were capable of exhibiting good flame retardant properties. N,N＇-（pyromellitoyl）-bis-L-amino acids 3a-3f were prepared in quantitative yields by the condensation reaction of pyromellitic dianhydride （1,2,4,5-benzenetetracarboxylicacid-1,2,4,5-dianhydride） 1 with L-alanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e and L-2-aminobutyric acid 2f in acetic acid solution.

关键词： Optically active Flame-retardant polymers Poly(amide-imide)s Limiting oxygen index

SYNTHESIS AND CHARACTERIZATION OF OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S BASED ON[N,N'-(4,4'-CARBONYLDIPHTALOYL)-BIS-LAMINO DIACID]S AND l,5-BIS(4-AMINOPHENYL)PENTA-l,4-DIEN-3-ONE

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Chinese Journal of Polymer Science 2012年第6期30卷 777-785页

作者： khalil faghihi Akram Feyzi Organic Polymer Chemistry Research Laboratory Department of ChemistryFaculty of ScienceArak UniversityArak38156Iran

Six dicarboxylic acids 3a-3f were synthesized dianhydride 1 with L-aminoacids 2a-2f in a solution of glacial new poly（amide-imide）s PAIs were synthesized from by the reaction of 3,3＇,4,4＇-benzophenonetetracarboxylic acetic acid/pyridine （Py） at refluxing temperature. Then six the direct polycondensation reaction of [N,N＇-（4,4＇- carbonyldiphtaloyl）-bis-L-amino diacid]s with 1,5-bis（4-aminophenyl）penta-l,4-dien-3-one （APPD）. The polymerization reactions produced a series of new optically active PAls with high yield and good inherent viscosity. Also these PAls are optically active and soluble in various organic solvents chromatography for the separation of enantiomeric mixtures. FTIR and 1H-NMR spectroscopy, elemental analyses, thermogravimetric analysis （TGA）. These resulting new polymers can be used in column The resulted polymers were fully characterized by means of inherent viscosity measurements, solubility tests and

关键词： Organosoluble polymers Thermal properties Glass transition.

Synthesis and characterization of optically active and organosoluble poly(amide-imide)s containing imidazole rings as pendent groups by direct polycondensation

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Science China Chemistry 2010年第3期53卷 580-586页

作者： khalil faghihi MEISAM Shabanian Polymer Research Laboratory Department of ChemistryFaculty of ScienceIslamic Azad University Yang Researchers Club Islamic Azad University

Six new optically active poly(amide-imide)s(PAIs) 6a-f were prepared by direct polycondensation reaction of N-trimelli-tylimido-L-histidine 4 as a chiral diacid with various aromatic diamines *** phosphite(TPP)/pyridine(Py) in the presence of calcium chloride(CaCl2) and N-methyl-2-pyrrolidone(NMP) were successfully applied to direct polycondensation *** resulting new polymers were in good yields,and had inherent viscosities ranging between 0.29 and 0.41 dL g-1 and were detected with elemental analysis,FTIR,1H-NMR spectroscopy,specific rotation and differential scanning calorimeter(DSC),thermogravimetric analysis(TGA),and derivative of thermaogravimetry(DTG).Imidazole pendent groups of the polymer chains disturb interchain and intrachain interactions and make these PAIs readily soluble in polar aprotic solvents such as N,N-dimethylacetamide(DMAc),N,N-dimethylformamide(DMF),dimethylsulfoxide(DMSO),NMP and solvents such as sulfuric *** analysis indicated that the residual weight percents of polymers at 600 °C were between 56.47% and 68.76%,which show their thermal stability.

关键词： poly(amide-imide)s direct polycondensation optically active polymers imidazole histidine

Synthesis and characterization of new optically active copoly(amid-imide)s based on N-phthalimido-L-aspartic acid and aromatic diamines

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Chinese Chemical Letters 2010年第4期21卷 407-411页

作者： khalil faghihi Hamidreza Alimohammadi Polymer Research Laboratory Department of ChemistryFaculty of ScienceIslamic Azad UniversityBranch ArakIran Yaung Research Club Islamic Azad UniversityBranch ArakIran

In this article,six new optically active copoly(amide-imide)s(10a-f) were synthesized through the direct polycondensation reaction of N-phthalimido-L-aspartic acid(4) with 1,5-diamino naphthalene(8),3,4-diamino benzophenone(9) in the presence of therphthahc acid(7),fumaric acid(6) and adipic acid(5) as a second diacid in a medium consisting of N-methyl-2-pyrrolidone,triphenyl phosphite, calcium chloride and *** resulting copolymers were fully characterized by means of FT-IR spectroscopy,elemental a...

关键词： High-performance polymers Copoly(amide-imide)s Direct polycondensation

SYNTHESIS AND CHARACTERIZATION OF ORGANO-SOLUBLE POLY(AMIDE-IMIDE)S BASED ON 1,2-BIS[4-(TRIMELLITIMIDO)PHENOXY]ETHANE AND AROMATIC DIAMINES

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Chinese Journal of Polymer Science 2010年第6期28卷 941-949页

作者： khalil faghihi Mehdi Nourbakhsh Mohsen Hajibeygi Organic Polymer Chemistry Research Laboratory Department of ChemistryFaculty of Science Arak University

New organo-soluble poly（amide-imide）s（PAIs） 8a-8f were prepared from newly synthesized 1,2-bis[4,4＇-（trimellitimido） phenoxy]ethane 6 via direct polycondensation with various aromatic *** diacid 6 was synthesized by the condensation reaction of 12-bis[4-atninophenoxy]ethane 4 with trimellitic anhydride 5 in acetic *** polymers were obtained in quantitative high yields with inherent viscosities of 0.48-0.61 dL/*** of these polymers were highly soluble in organic solvents such as,N-methyl-2-pyrrolidone（NMP）,dimethylformamide（DMF）,N,N＇-dimethylacetamide （DMAc） and dimethylsulfoxide（DMSO） at room temperature and were fully characterized by means of NMR spectroscopy, FTIR spectroscopy,elemental analyses,inherent viscosity,solubility test,specific rotation,differential scanning calorimetry （DSC） and thermogravimetric analysis（TGA）.

关键词： Poly(amide-imide) Polycondensation Organo-soluble