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Photochemical reactions as synthetic tool for pharmaceutical industries

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Chinese Chemical Letters 2024年第9期35卷 9-31页

作者： Shehla khalid Muhammad Bilal Nasir Rasool Muhammad Imran Department of Chemistry Government College UniversityFaisalabad 38000Pakistan School of Chemistry and Chemical Engineering Shandong UniversityJi’nan 250100China Department of Chemistry Faculty of ScienceKing Khalid UniversityAbha 61413Saudi Arabia

In the quest for new agrochemicals and pharmaceuticals,chemists seek access to reliable and mild synthetic techniques to allow for the systematic modification of chemical structures,exploration of unexplored chemical space,and facilitation of practical synthesis in their search for novel agrochemicals and *** this regard,photocatalytic reactions enabled the synthesis of intricate and more functionalized *** review overviews the developed synthetic methodologies and their utility in the chemical synthesis of *** review also offers in-depth insights into contemporary photoredox reactions such as allylic additions,cyclization,reductive cross-coupling,C–H activation,ring opening,oxidative cross-coupling,dehydrogenation,desulphonation,and *** provides a positive outlook for the promising future of this field.

关键词： Photocatalyst Photochemical reactions Drugs Natural products Late-stage functionalization

Caching Strategies in NDN Based Wireless Ad Hoc Network:A Survey

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Computers, Materials & Continua 2024年第7期80卷 61-103页

作者： Ahmed khalid Rana Asif Rehman Byung-Seo Kim Department of Computer Science FAST School of ComputingNational University of Computer and Emerging SciencesLahore54000Pakistan Department of Software and Communications Engineering Hongik UniversitySejong City30016Republic of Korea

Wireless Ad Hoc Networks consist of devices that are wirelessly *** Ad Hoc Networks(MANETs),Internet of Things(IoT),and Vehicular Ad Hoc Networks(VANETs)are the main domains of wireless ad hoc *** is used in wireless ad hoc *** is based on Transmission Control Protocol(TCP)/Internet Protocol(IP)network where clients and servers interact with each other with the help of IP in a pre-defined *** fetches data from a fixed *** redundancy,mobility,and location dependency are the main issues of the IP network *** these factors result in poor performance of wireless ad hoc *** main disadvantage of IP is that,it does not provide in-network ***,there is a need to move towards a new network that overcomes these *** Data Network(NDN)is a network that overcomes these *** is a project of Information-centric Network(ICN).NDN provides in-network caching which helps in fast response to user *** NDN in wireless ad hoc network provides many benefits such as caching,mobility,scalability,security,and *** considering the certainty,in this survey paper,we present a comprehensive survey on Caching Strategies in NDN-based Wireless *** cachingmechanism-based results are also *** the last,we also shed light on the challenges and future directions of this promising field to provide a clear understanding of what caching-related problems exist in NDN-based wireless ad hoc networks.

关键词： Content centric network Internet of Things mobile ad hoc network named data network vehicular ad hoc network

Hydrometallurgy two stage process for preparation of (Nd,La,Ce)_(2)O_(3) from end-of-life NiMH batteries

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Journal of Rare Earths 2024年第2期42卷 415-423,I0007页

作者： Karim Tanji khalid Ouzaouit Mohamed Belghiti Isam Lamsayety Hakim Faqir Intissar Benzakour Centre de recherche REMINEX-Groupe MANAGEM MarrakechMorocco

The present work aims to investigate the recovery of light rare earth elements(LREEs) oxides from end-oflife NiMH batteries using a hydro metallurgical process followed by effective *** operational leaching parameters such as phosphoric acid concentration,temperature,and the solid-liquid ratio were first optimized by Box-Behnken *** results reveal that under optimum conditions([H_(3)PO_(4)]=2 mol/L,T=80℃,and S/L=1:10 g/mL) the leaching efficiencies of Ni,Co reach 98.1% and99.3%.While La,Ce,and Nd elements remain in the leaching residue as(La,Ce,Nd)PO_(4) with yields of 98.2%,98.6%,and 99.6% for La,Ce,and Nd,***,the(La,Ce,Nd)PO_(4) is leached with HCl acid,then the rare earth oxalate was precipitated using oxalic acid at a pH of 1.8 and then the product was calcined at 800℃ for 2 h in order to synthesize the(Nd,La,Ce)_(2)O_(3).The analysis using scanning electron microscopy(SEM) coupled with energy dispersive X-ray spectroscopy(EDX) confirms the homogeneity of(Nd,La,Ce)_(2)O_(3) particles that have two morphologies,i.e.,flower and sticks with a particle size between 3and 6 μ*** unit cell parameters of(Nd,La,Ce)_(2)O_(3) were calculated after Rietveld refinement of the XRD patterns,in the space group of Fm-3m are a=b=c=0.57921 nm and the volume equal to 0.194322 nm^(3).

关键词： NiMH batteries Hydrometallurgical process Leaching Phosphoric acid Box-Behnken Light rare earth oxides

An Improved Image Steganography Security and Capacity Using Ant Colony Algorithm Optimization

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Computers, Materials & Continua 2024年第9期80卷 4643-4662页

作者： Zinah khalid Jasim Jasim Sefer Kurnaz Department of Electrical and Computer Engineering Altinbas UniversityIstanbul34000Turkey

This advanced paper presents a new approach to improving image steganography using the Ant Colony Optimization(ACO)*** steganography,a technique of embedding hidden information in digital photographs,should ideally achieve the dual purposes of maximum data hiding and maintenance of the integrity of the cover media so that it is least *** contemporary methods of steganography are at best a compromise between these *** this paper,we present our approach,entitled Ant Colony Optimization(ACO)-Least Significant Bit(LSB),which attempts to optimize the capacity in steganographic *** approach makes use of a grayscale cover image to hide the confidential data with an additional bit pair per byte,both for integrity verification and the file checksumof the secret *** approach encodes confidential information into four pairs of bits and embeds it within uncompressed grayscale *** ACO algorithm uses adaptive exploration to select some pixels,maximizing the capacity of data embedding whileminimizing the degradation of visual *** evaporation is introduced through iterations to avoid stagnation in solution *** levels of pheromone are modified to reinforce successful pixel *** results obtained through the ACO-LSB method reveal that it clearly improves image steganography capabilities by providing an increase of up to 30%in the embedding capacity compared with traditional approaches;the average Peak Signal to Noise Ratio(PSNR)is 40.5 dB with a Structural Index Similarity(SSIM)of *** approach also demonstrates very high resistance to detection,cutting down the rate by 20%.Implemented in MATLAB R2023a,the model was tested against one thousand publicly available grayscale images,thus providing robust evidence of its effectiveness.

关键词： Steganography steganalysis capacity optimization ant colony algorithm

An extensive analytical and numerical study of the generalized q-deformed Sinh-Gordon equation

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Journal of Ocean Engineering and Science 2024年第3期9卷 232-239页

作者： khalid K.Ali Abdel-Haleem Abdel-Aty Mathematics Department Faculty of ScienceAl-Azhar UniversityNasr-CityCairoEgypt Department of Physics College of SciencesUniversity of BishaPO Box 344Bisha 61922Saudi Arabia Physics Department Faculty of ScienceAl-Azhar UniversityAssiut 71524Egypt

In this paper,the q-deformed Sinh-Gordon equation is solved analytically using a new general form based on the extended tanh *** numerical solutions of the equation is obtained using a b-spline finite element ***,we present numerous figures to demonstrate the various solitons propagation *** type of equation has not been previously dealt with in such ways,whether analytical or *** study is very useful in studying several physical systems that have lost their symmetry.

关键词： q-Deformed equation Solitos solutions The extended tanh method Finite element method q-Calculus

Mixed plastics waste valorization to high-added value products via thermally induced phase separation and spin-casting

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Green Energy & Environment 2024年第10期9卷 1627-1640页

作者： Junaid Saleem Moghal Zubair khalid Baig Usman Bin Shahid Rafael Luque Gordon McKay Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa University Center for Advanced Materials Qatar University Department of Chemical and Biological Engineering The Hong Kong University of Science and Technology Universidad ECOTEC

Plastic waste is an underutilized resource that has the potential to be transformed into value-added ***,its chemical diversity leads to cost-intensive sorting techniques,limiting recycling and upcycling ***,we report an open-loop recycling method to produce graded feedstock from mixed polyolefins waste,which makes up 60%of total plastic *** method uses heat flow scanning to quantify the composition of plastic waste and resolves its compatibility through controlled *** resulting feedstock is then used to synthesize blended pellets,porous sorbents,and superhydrophobic coatings via thermally induced phase separation and *** hybrid approach broadens the opportunities for reusing plastic waste,which is a step towards creating a more circular economy and better waste management practices.

关键词： Plastic waste Valorization Superhydrophobic coatings Blended pellets Porous materials Sorbents

Comparative analysis of CO_(2)emissions and economic performance in the United States and China:Navigating sustainable development in the climate change era

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Geoscience Frontiers 2024年第5期15卷 239-255页

作者： khalid Mehmood Syed Tauseef Hassan Xuchun Qiu Shahid Ali Institute of Environmental Health and Ecological Security School of the Environment and Safety EngineeringJiangsu UniversityZhenjiangJiangsu 212013China Department of Trade and Finance Faculty of Economics and ManagementCzech University of Life Sciences PragueKamycka 129PrahaZIP 16500Czechia School of Economics and Management Anhui Polytechnic UniversityWuhu 241000China Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment Suzhou University of Science and TechnologySuzhou 215009China

Economic growth has brought a global climate change into the spotlight,and CO_(2)emissions demonstrate significant challenges in reducing environmental shifts ***,the United States and China contribute the largest amount of CO_(2)*** purpose of this study is to examine the relationship between different types of CO_(2)emissions and economic growth by using a modeling *** analyze total CO_(2)emissions,coal CO_(2)emissions,oil CO_(2)emissions,the global share of coal CO_(2)emissions,the global share of oil CO_(2)emissions,and economic *** study provides unique insights into how to simultaneously reduce CO_(2)emissions and sustain economic growth.A bootstrap autoregressive distributed lag(BARDL)simulation method is utilized to examine the long-and short-run effects of predictors on CO_(2)*** CO_(2)emissions are found to have a significant positive effect on economic growth in the short run but a negative impact on economic growth over the long run in the United *** United States needs to implement stronger measures to balance coal CO_(2)emissions with economic growth for sustainable *** contrast,oil CO_(2)emissions have positive effect for China in both the long run and short ***,China can continue to reduce CO_(2)emissions from oil while maintaining positive economic *** China’s policies promoting cleaner energy alternatives can be adapted and implemented to maintain a balance between economic growth and carbon *** study has valuable insights for policymakers seeking to balance economic growth with carbon reduction *** emphasizes the need to better understand the complex relationship between CO_(2)emissions and economic growth.

关键词： CO_(2)emission Sustainable development Climate change United States China BARDL

Reducing carbon emissions with Geoscience solutions:A look at the contributions of nuclear energy,technology,and green finance

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Geoscience Frontiers 2024年第4期15卷 411-426页

作者： Aifeng Liu Muhammad Imran Abdelmohsen A.Nassani Rima H.Binsaeed khalid Zaman International Business School Shaanxi Normal UniversityXi’anChina Department of Economics The University of HaripurHaripur Khyber Pakhtunkhwa 22620Pakistan Department of Management College of Business AdministrationKing Saud UniversityP.O.Box 71115Riyadh 11587Saudi Arabia

Standards for Low-Carbon Energy Portfolios(LC-EPS)mandate that a certain percentage of a region's electricity generation originate from zero-or low-emissions *** 1995Q1 through 2020Q4,the study used the ARDL-Bounds testing technique to estimate coefficient parameters,Granger causality to draw causal inferences,and variance decomposition analysis to anticipate the factors that will have the greatest impact on carbon emissions in the US *** power significantly impacts carbon emissions,as seen by an inverted U-shaped environmental Kuznets curve,whereas long-term impact of innovation leads to lower *** the other hand,exports of sophisticated technology reduce carbon *** growth has a discernible effect on carbon emissions,nuclear power,innovation,and environmentally friendly ***-tech exports will likely impact carbon emissions most,followed by a demand for nuclear power,innovation,economic expansion,and sustainable finance for the next ten *** results give policymakers helpful insight into how the US economy may reduce carbon emissions and fight climate change via renewable energy and green finance.

关键词： Nuclear energy demand High technology exports Innovation Economic growth Green finance USA

Machine Learning Techniques Using Deep Instinctive Encoder-Based Feature Extraction for Optimized Breast Cancer Detection

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Computers, Materials & Continua 2024年第2期78卷 2441-2468页

作者： Vaishnawi Priyadarshni Sanjay Kumar Sharma Mohammad khalid Imam Rahmani Baijnath Kaushik Rania Almajalid Department of Computer Science Gautam Buddha UniversityGreater NoidaUttar PradeshIndia College of Computing and Informatics Saudi Electronic UniversityRiyadh11673Saudi Arabia School of Computer Science Shri Vaishno Devi UniversityKatraIndia

Breast cancer(BC)is one of the leading causes of death among women worldwide,as it has emerged as the most commonly diagnosed malignancy in *** detection and effective treatment of BC can help save women’s *** an efficient technology-based detection system can lead to non-destructive and preliminary cancer detection *** paper proposes a comprehensive framework that can effectively diagnose cancerous cells from benign cells using the Curated Breast Imaging Subset of the Digital Database for Screening Mammography(CBIS-DDSM)data *** novelty of the proposed framework lies in the integration of various techniques,where the fusion of deep learning(DL),traditional machine learning(ML)techniques,and enhanced classification models have been deployed using the curated *** analysis outcome proves that the proposed enhanced RF(ERF),enhanced DT(EDT)and enhanced LR(ELR)models for BC detection outperformed most of the existing models with impressive results.

关键词： Autoencoder breast cancer deep neural network convolutional neural network image processing machine learning deep learning