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Selective synthesis of carbon monoxide via formates in reverse water–gas shift reaction over alumina-supported gold catalyst

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Journal of Energy Chemistry 2016年第2期25卷 304-308页

作者： Nobuhiro Ishito kenji Hara Kiyotaka Nakajima Atsushi Fukuoka Institute for Catalysis Hokkaido University Graduate School of Chemical Sciences and Engineering Hokkaido University School of Engineering Tokyo University of Technology

Thermal decomposition of formic acid on SiO2, CeO2 and γ-Al2O3 was studied as an elementary step of reverse water–gas shit reaction（RWGS） over supported Au catalysts. γ-Al2O3 showed the highest CO selectivity among the tested oxides in the decomposition of formic acid. Infrared spectroscopy showed the formation of four formate species on γ-Al2O3： three η~1-type and one μ~2-type species, and these formates decomposed to CO at 473 K or higher. Au-loaded γ-Al2O3 samples were prepared by a depositionprecipitation method and used as catalysts for RWGS. The supported Au catalyst gave CO with high selectivity over 99% from CO2 and H2, which is attributed to the formation of formates on Au and subsequent decomposition to CO on γ-Al2O3.

关键词： Reverse water–gas shift reaction Carbon dioxide Hydrogen Formate Carbon monoxide Alumina Gold

Formation of biomimetic hierarchical nanostructure in homopolymers and block copolymer ternary blend particles

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Particuology 2022年第5期20卷 98-109页

作者： Shu Kikuchi Ryoka Shoji Shinji Kanehashi Guanghui Ma kenji Ogino Graduate School of Bio-Applications and Systems Engineering Tokyo University of Agriculture and Technology2-24-16 NakachoKoganei-shiTokyo 184-8588Japan Institute of Global Innovation Research Tokyo University of Agriculture and Technology2-24-16 NakachoKoganei-shiTokyo 184-8588Japan State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100080China

In order to mimic hierarchical nanostructures in nature,particles of polymer blends consisting of poly(4-butyltriphenylamine)(PBTPA),poly(methyl methacrylate)(PMMA)and PBTPA-block-PMMA were fabricated by a solvent evaporation *** of the molecular weight and the chemical composition of PBTPA-b-PMMA,molecular weights of homopolymers,and the composition of the blend on the morphology were *** polymer blend particle consisting of PBTPA and PMMA homopolymers exhibited thermodynamically favored core-shell structure,in which more hydrophilic PMMA-shell surrounded *** addition of 10 wt%of PBTPA-b-PMMA caused the morphological transition from core-shell toJanus or inversed core-shell,in which PBTPA-shell surrounded PMMA-core,depending on the molecular weight of PBTPA segment in *** the molecular weight of PMMA segment was higher than that of PMMA homopolymer,watermelon-like particles in which small PBTPA domain less than 80 nm dispersed in the PMMA domain surrounded by PBTPA shell were *** the ratio of PBTPA-b-PMMA increased,the interface of the macrophase separation became *** 50 wt%of the PBTPA-b-PMMA,only microphase separation was *** measurement of interfacial tension by pendant drop method demonstrated that PBTPA-b-PMMA lower the interfacial tension between PBTPA and the aqueous phase to the value similar to that of PMMA with the aqueous phase.

关键词： Microsphere Hierarchical structure Polymer blend Block copolymer Solvent evaporation Phase separation

A Numerical Sirnulation of Gas-Particle Two-Phase Flow in a Suspension Bed Using DifFusion Flux Model

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Chinese Journal of Chemical Engineering 2003年第5期11卷 497-503页

作者：尚智杨瑞昌 FUKUDA kenji 钟勇巨泽建 State Key Laboratory of Clean Combustion of Coal Tsinghua University Beijing 100084 China Graduate School of Engineering Kyushu University Fukuoka 812-8581 Japan State Key Laboratory of Clean Combustion of Coal. Tsinghua University Beijing 100084China

A mathematical modei of two-dimensional turbulent gas-particle twophase flow based on the modified diffusion flux modei (DFM) and a numerical simulation method to analyze the gas-particle flow structures are developed. The modified diffusion flux modei, in which the acceleration due to various forces is taken into account for the calculation of the diffusion velocity of particles, is applicable to the analysis of multi-dimensional gas-particle two-phase turbulent flow. In order to verify its accuracy and efficiency, the numerical simulation by DFM is compared with experimental studies and the prediction by k-ε-kp two-fluid modei, which shows a reasonable agreement. It is confirmed that the modified diffusion flux modei is suitable for simulating the multi-dimensional gas-particle two-phase flow.

关键词： diffusion flux model gas-solid two-phase flow turbulent flow numerical simulation

Strength evaluation of ultra-high strength steels and spot weld of automotive bodies

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China Welding 2014年第1期23卷 33-39页

作者： kenji Takada Kentaro Sato Ninshu Ma Ninshu Ma JSOL corporation Japan.

Cockcrofi-Latham fracture criterion was applied to predict the fracture of high strength steels. A Marciniak-type biaxial stretching test of the four classes of high strength steels was carried out to measure the material damage limit of Cockcrofi-Latham fracture criterion. Furthermore, in order to improve the simulation accuracy, the local anisotropic parameters depending on the plastic strain （strain dependent model of anisotropy ） were measured by digital image correlation method and incorporated into Hill＇ s anisotropic yield condition by authors. To confirm the validity of Cockcrofi-Latham fracture criterion, the uniaxial tensile tests based on JIS No. 5 tensile specimen were performed. The force-displacement history and fracture happening strokes were predicted with high accuracy. Then, Cockcrofi-Latham fracture criterion was applied to predict the failure of four types of spot welded joints. To simulate the local bending and warping deformations around the heataffected zone, the discrete Kirchhoff triangle element was adapted. FEM results for four classes of high strength steels and four types of spot welded joints had a good correlation with experimental ones.

关键词： strength simulation ultra high strength steels spot weld fracture criterion

Modules for in vitro metabolic engineering:Pathway assembly for biobased production of value-added chemicals

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Synthetic and Systems Biotechnology 2017年第2期2卷 65-74页

作者： Hironori Taniguchi kenji Okano Kohsuke Honda Synthetic Bioengineering Lab Department of BiotechnologyGraduate School of EngineeringOsaka University2-1 YamadaokaSuitaOsaka565-0871Japan

Bio-based chemical production has drawn attention regarding the realization of a sustainable *** vitro metabolic engineering is one of the methods used for the bio-based production of value-added *** method involves the reconstitution of natural or artificial metabolic pathways by assembling purified/semi-purified enzymes in *** from distinct sources can be combined to construct desired reaction cascades with fewer biological constraints in one vessel,enabling easier pathway design with high *** modules have been designed,built,tested,and improved by different groups for different *** this review,we focus on these in vitro metabolic engineering modules,especially focusing on the carbon metabolism,and present an overview of input modules,output modules,and other modules related to cofactor management.

关键词： In vitro metabolic engineering Module Glycolysis Pentose phosphate pathway Cofactor management

Experiment and simulation of turbulent flow in local scour around a spur dyke

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International Journal of Sediment Research 2009年第1期24卷 33-45页

作者： Hajime NAKAGAWA kenji KAWAIKE Yasuyuki BABA Disaster Prevention Research Institute Kyoto University

The turbulent flow in the local scour hole around a single non-submerged spur dyke is investigated with both experimental and numerical methods. The experiments are conducted under clear-water scour regime with an impermeable spur dyke. The scour geometry and flow velocities are measured in details with a high-resolution laser displacement meter,electro-magnetic velocimetries and PIV(Particle image velocimetry). A 3D non-linear k-ε model is developed to simulate the complex local flow field around the scour area. The numerical model is formulated using FVM(Finite volume method) on a collocated unstructured mesh,capable of resolving complex geometries and boundaries. It is found that the simulation results are reasonably consistent with those of the experimental measurements. Based on the study results,the nature of the flow structure around a spur dyke with local scour hole is analyzed.

关键词： Spur dyke Local scour 3D flow Non-linear k-ε model Unstructured mesh

Kaon-Source Size in Relativistic Nucleus-Nucleus Collisions

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Chinese Physics Letters 1997年第7期14卷 510-512页

作者： ZHENG Yu-ming CHU Zi-li Osamu Miyamura kenji Kumagai China Institute of Atomic Energy Beijing 102413 Department of Physics Hiroshima UniversityHigashi-Hiroshima 724Japan

We analyze the two-kaon Bose-Einstein correlation in the reactions of 160A GeV/c Pb+Pb within an event generator *** apparent radius of kaon-source is *** theoretical result agrees quite well with the preliminary data... 详细信息

关键词： radius apparent Collisions

Role of Sphingosine 1-Phosphate Receptor Type 1 in Lymphocyte Egress from Secondary Lymphoid Tissues and Thymus

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Cellular & Molecular Immunology 2006年第1期3卷 11-19页

作者： kenji Chiba Hirofumi Matsuyuki Yasuhiro Maeda Kunio Sugahara Research Laboratory Ⅲ (Immunology) Pharmaceutical Research UnitResearch and Development DivisionMitsubishi Pharma CorporationYokohamaJapan

Circulation of mature lymphocytes between blood and secondary lymphoid tissues plays a central role in the immune system. Homing of lymphocytes from blood into secondary lymphoid tissues beyond high endothelial venules is highly dependent on the interaction between the chemokines CCL19, CCL21, CXCL12, and CXCL13, and their receptors CCR7, CXCR4 and CXCR5. However, the molecular mechanism（s） of lymphocyte egress from secondary lymphoid tissues to lymph remained unclear. We have found a new class of immunomodulator, FTY720 by chemical modification of vegetative wasp-derived natural product, ISP-I （myriocin）. FTY720 has been shown to be highly effective in experimental allograft and autoimmune disease models. A striking feature of FTY720 is the induction of a marked decrease in peripheral blood lymphocytes at doses that show immunomodulating activity in these models. The reduction of circulating lymphocytes by FTY720 is caused by sequestration of lymphocytes into secondary lymphoid tissues and thymus. FTY720 is rapidly converted to （S）-enantiomer of FTY720-phosphate [（S）-FTY720-P] by sphingosine kinase 2 in vivo. （S）-FTY720-P acting as a potent agonist of S1P receptor type 1 （S1P1）, induces long-term down-regulation of S1P1 on lymphocytes, and thereby inhibits the migration of lymphocytes toward S1P. Thus, it is presumed that FTY720-induced lymphocyte sequestration is due to the inhibition of S1P/S1P1-dependent lymphocyte egress from secondary lymphoid tissues and thymus by its active metabolite （S）-FTY720-P. Throughout the analysis of the mechanism of action of FTY720, it is clarified that S1P/S1P1 interaction plays an important role for lymphocyte egress from secondary lymphoid tissues and thymus.

关键词： FTY720 SIP S1P1 immunomodulation lymphocyte egress

An Example of Canal Formation in a Thick Cloud Induced by Massive Seeding Using Liquid Carbon Dioxide

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Journal of Meteorological Research 2015年第4期29卷 682-690页

作者： KIKURO Tomine MASAKI Shimada kenji Wakimizu KOJI Nishiyama Department of Earth and Ocean Sciences National Defense Academy Faculty of Agriculture Kyushu University Hakozaki Faculty of Engineering Kyushu University Motooka

The purpose of this experiment is to show that massive cloud seeding is effective in mitigating the damage caused by heavy snowfall. In order to show its effect, we attempted to form a canal in a thick convective cloud by massive seeding, and left the parts that were not influenced by the seeding as a reference to show that the canal was formed by the massive seeding only. The seeding was carried out by using an aircraft. The seeding rate and air speed of the aircraft were 35 g s-1 and 115 m s 1, respectively. The flight course for seeding was selected to be parallel to the wind direction to ensure that the dispersed liquid carbon dioxide did not influence both sides of the course. The results show that a part of the radar echo observed from onboard beneath the seeding track was weakened and divided the radar echo into two parts 20 minutes after the cloud top and the bottom were seeded, and distribution of rainfall rate on the ground from the target cloud was confirmed to be divided into two parts 24 minutes after the seeding. The target cloud was torn along the seeding track, and we could see the sea surface through the break in the cloud. Canal formation occurred in the cloud along the seeding track. Clouds and snowfall were left on both sides of the canal. The results show that supercooled liquid cloud particles along the seeding track evaporated to form larger precipitable particles which grew and fell rapidly.

关键词： heavy snowfall weather modification aircraft artificial cloud seeding