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Simultaneous removal of trihalomethanes by bimetallic Ag/Zn:kinetics study

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Frontiers of Chemical Science and Engineering 2010年第3期4卷 322-327页

作者： Ahmed H A DABWAN Satoshi KANECO Hideyuki katsumata Tohru SUZUKI Kiyoyuki EGUSA Kiyohisa OHTA Faculty of Chemical Engineering Technology Tati University CollegeJalan PanchorTeluk Kalong24000 KemamanTerengganuMalaysia Department of Chemistry for Materials Graduate School of EngineeringMie UniversityMie 514-8507Japan Environmental Preservation Center Mie UniversityMie 514-8507Japan

In the present work,bimetallic silver/zinc was applied into the degradation of trihalomethanes,THMs:CHCl_(3),CHBrCl_(2),CHBr_(2)Cl,and CHBr_(3).The kinetics reaction rates and removal efficiencies of the THM compound mixtures,in the aqueous solutions,were *** experiments were conducted under mild conditions,ambient temperature,and *** primary degradation reaction followed a pseudo-first-order kinetic *** first-order rate constants and the degradation efficiencies followed the decreasing order of CHBr_(3)>CHBr_(2)Cl>CHBrCl_(2)>CHCl_(3).The bond dissociation energy and hydrophilic/hydrophobic characteristics of the THM compounds may become the most important parameters affecting the degradation kinetics and efficiency by bimetallic Ag/Zn.

关键词： degradation trihalomethanes bimetallic silver/zinc halogenated pollutants kinetics

An Algorithm for Connected-Component Labeling, Hole Labeling and Euler Number Computing

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Journal of Computer Science & Technology 2013年第3期28卷 468-478页

作者：何立风巢宇燕 kenji Suzuki Artificial Intelligence Institute College of Electrical and Information Engineering Shaanxi University of Science and Technology Faculty of Information Science and Technology Aichi Prefectural University Faculty of Environment Information and Business Nagoya Sangyo University Department of Radiology The University of Chicago

Labeling connected components and holes and computing the Euler number in a binary image are necessary for image analysis, pattern recognition, and computer （robot） vision, and are usually made independently of each other in conventional methods. This paper proposes a two-scan algorithm for labeling connected components and holes simultaneously in a binary image by use of the same data structure. With our algorithm, besides labeling, we can also easily calculate the number and the area of connected components and holes, as well as the Euler number. Our method is very simple in principle, and experimental results demonstrate that our method is much more efficient than conventional methods for various kinds of images in cases where both labeling and Euler number computing are necessary.

关键词： computer vision connected-component labeling Euler number hole pattern recognition

Study of Interaction between Supersonic Flow and Rods Surrounded by Porous Cavity

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Journal of Thermal Science 2006年第4期15卷 324-330页

作者： Minoru YAGA kenji YAMAMOTO Piotr DOERFFER Kenyu OYAKAWA Dept.of Mech.Systems Eng. Univ.of the RyukyusSenbaru 1NishiharaOkinawa903-0213 Graduate student Faculty of Eng.Univ.of the RyukyusSenbaru 1NishiharaOkinawa903-0213 Institute of Fluid Flow Machinery Polish Academy of ScienceFiszera 14PL-80 952 GdanskPoland

In this paper, some preliminary calculations and the experiments were performed to figure out the flow field, in which some rods were normally inserted into the main flow surrounded by a porous cavity. As a result, it is found that the starting shock wave severely interacts with the rods, the bow shock wave, its reflections, and the porous wall, which are numerically well predicted at some conditions. Moreover, inserting the rods makes the pressure on the upper wall in the porous region increase when the main flow in the porous region is completely supersonic. The calculations also suggest that three rods cause the widest suction area.

关键词： shock wave compressible flow porous cavity bow shock wave rod

Si nanowire FET and its modeling

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Science China(Information Sciences) 2011年第5期54卷 1004-1010+1012页

作者： IWAI Hiroshi NATORI kenji SHIRAISHI kenji IWATA Jun-ichi OSHIYAMA Atsushi YAMADA Keisaku OHMORI kenji KAKUSHIMA Kuniyuki AHMET Parhat Frontier Research Center Tokyo Institute of Technology Yokohama Japan Interdisciplinary Graduate School of Science and Engineering Tokyo Institute of Technology Yokohama Japan Graduate School of Pure and Applied Sciences University of Tsukuba Tsukuba Japan Center for Computational Sciences University of Tsukuba Tsukuba Japan School of Engineering The University of Tokyo Tokyo Japan

Because of its ability to effectively suppress off-leakage current with its gate-around conffguration, the Si nanowire FET is considered to be the ultimate structure for ultra-small CMOS devices to the extent that the devices would be approaching their downsized limits. Recently, several experimental studies of Si nanowire FETs with on-currents much larger than those of planar MOSFETs have been published. Consequently, Si nanowire FETs are now gaining significant attention as the most promising candidate for mainstream CMOS devices in the 2020s. To enable the introduction of the Si nanowire FETs into integrated circuits, good compact models, which circuit designers can easily handle, are essential. However, it is a very challenging task to establish such a compact model, because the ID - VD characteristics of Si nanowire FETs are affected by the band structure of the nanowire, which is very sensitive to the nanowire diameter, cross-sectional shape, crystal orientation, mechanical stress and interface states. In this paper, the recent status of research on Si nanowire FETs in experimental and theoretical studies is described.

关键词： Si nanowire MOSFET modeling

Microstructures and mechanical properties of a cast Al-Cu-Li alloy during heat treatment procedure

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Rare Metals 2021年第7期40卷 1897-1906页

作者： Shu-Wei Duan kenji Matsuda Tao Wang Yong Zou MOE Key Laboratory for Liquid-Solid Structure Evolution and Materials Processing Institute of Materials JoiningShandong UniversityJinan 250061China Department of Materials Science and Technology Faculty of EngineeringUniversity of ToyamaToyama 930-8555Japan

Al-Cu-Li alloy is a huge potential alloy for aerospace industry due to its low density and excellent comprehensive *** this study,the microstructures and mechanical properties of a novel cast Al-Cu-Li alloy during the heat treatment were *** showed that most of the secondary phases along grain boundaries in as-cast state were dissolved into the Al matrix after homogenization and solution treatment,while the Cu-rich phases were slightly segregated once again on grain boundaries after aging.A relatively good combination of strength and ductility(average ultimate tensile strength of 430 MPa and elongation of 8.9%)was obtained after natural *** electron microscopy(TEM)results revealed that there was a complicated precipitate distribution in this cast alloy after natural *** with the similar alloys which introduced dislocations before aging,the density of T1(Al_(2)CuLi)phases was decreased but the size was *** low volume fraction of d0 phase,medium density of needle-shaped precipitates and relativity narrow precipitates-free zone with varying widths near grain boundary are the reasons accounting for the improvement of performances.

关键词： Al-Cu-Li alloy Heat treatment Microstructure Mechanical property Precipitate

Impulse Turbine with 3D Guide Vanes for Wave Energy Conversion

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Journal of Thermal Science 2006年第1期15卷 27-30页

作者： Manabu TAKAO Toshiaki SETOGUCHI kenji KANEKO Shuichi NAGATA Department of Mechanical Engineering Matsue National College of Technology 14-4 Nishiikuma-cho Matsue-shi Shimane 690-8518 Japan Department of Mechanical Engineering Saga University 1 Honjo-machi Saga-shi Saga 840-8502 Japan Institute of Ocean Energy Saga University 1 Honjo-machi Saga-shi Saga 840-8502 Japan

In this study, in order to achieve further improvement of the performance of an impulse turbine with fixed guide vanes for wave energy conversion, the effect of guide vane shape on the performance was investigated by experiment. The investigation was performed by model testing under steady flow condition. As a result, it was found that the efficiency of the turbine with 3D guide vanes are slightly superior to that of the turbine with 2D guide vanes because of the increase of torque by means of 3D guide vane, though pressure drop across the turbine for the 3D case is slightly higher than that for the 2D case.

关键词： fluid machinery impulse turbine guide vane wave energy conversion.

Heavy metal removal from aqueous solution using carbonaceous K_2S-impregnated adsorbent

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Journal of Environmental Sciences 2009年第12期21卷 1730-1734页

作者： Takaaki Wajima kenji Murakami Takahiro Kato Katsuyasu Sugawara Faculty of Engineering and Resource Science Akita University

A novel carbonaceous adsorbent for heavy metal removal was prepared from raw coal by one-step simple sulfur impregnation using K2S. Raw coal was mixed with K2S powder and then heated at 800℃ for 30 min in nitrogen to produce K2S char. The sulfur content and form in K2S char were determined, and the ability of K2S char to adsorb Zn^2＋, Cd^2＋ and Pb^2＋ was examined. The K2S impregnation was effective at impregnating sulfur into coal, especially in the form of elemental, thiophenic and sulfatic sulfur. The sulfur content of K2S char was higher than those of raw coal and pyrolysis char. The Zn^2＋ removal in 2.4 mmol/L of Zn^2＋ solution by K2S char was higher than raw coal with the removal rate of 100%. K2S char adsorbed Pb^2＋ and Cd^2＋ in 24 mmol/L of Pb^2＋ and Cd^2＋ solution with the removal rate of 97% and 35%, respectively. The elution extents of adsorbed Pb^2＋ and Cd^2＋ were zero in distilled water and 27% in 0.1 mol/L HCl solution. These results indicated that an effective adsorbent for heavy metal ions was prepared from coal using K2S sulfur impregnation, and that the adsorbed metals were strongly retained in K2S char.

关键词： sulfur impregnation carbonaceous adsorbent K2S heavy metal adsorption

Selective synthesis of carbon monoxide via formates in reverse water–gas shift reaction over alumina-supported gold catalyst

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Journal of Energy Chemistry 2016年第2期25卷 304-308页

作者： Nobuhiro Ishito kenji Hara Kiyotaka Nakajima Atsushi Fukuoka Institute for Catalysis Hokkaido University Graduate School of Chemical Sciences and Engineering Hokkaido University School of Engineering Tokyo University of Technology

Thermal decomposition of formic acid on SiO2, CeO2 and γ-Al2O3 was studied as an elementary step of reverse water–gas shit reaction（RWGS） over supported Au catalysts. γ-Al2O3 showed the highest CO selectivity among the tested oxides in the decomposition of formic acid. Infrared spectroscopy showed the formation of four formate species on γ-Al2O3： three η~1-type and one μ~2-type species, and these formates decomposed to CO at 473 K or higher. Au-loaded γ-Al2O3 samples were prepared by a depositionprecipitation method and used as catalysts for RWGS. The supported Au catalyst gave CO with high selectivity over 99% from CO2 and H2, which is attributed to the formation of formates on Au and subsequent decomposition to CO on γ-Al2O3.

关键词： Reverse water–gas shift reaction Carbon dioxide Hydrogen Formate Carbon monoxide Alumina Gold

Formation of biomimetic hierarchical nanostructure in homopolymers and block copolymer ternary blend particles

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Particuology 2022年第5期20卷 98-109页

作者： Shu Kikuchi Ryoka Shoji Shinji Kanehashi Guanghui Ma kenji Ogino Graduate School of Bio-Applications and Systems Engineering Tokyo University of Agriculture and Technology2-24-16 NakachoKoganei-shiTokyo 184-8588Japan Institute of Global Innovation Research Tokyo University of Agriculture and Technology2-24-16 NakachoKoganei-shiTokyo 184-8588Japan State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100080China

In order to mimic hierarchical nanostructures in nature,particles of polymer blends consisting of poly(4-butyltriphenylamine)(PBTPA),poly(methyl methacrylate)(PMMA)and PBTPA-block-PMMA were fabricated by a solvent evaporation *** of the molecular weight and the chemical composition of PBTPA-b-PMMA,molecular weights of homopolymers,and the composition of the blend on the morphology were *** polymer blend particle consisting of PBTPA and PMMA homopolymers exhibited thermodynamically favored core-shell structure,in which more hydrophilic PMMA-shell surrounded *** addition of 10 wt%of PBTPA-b-PMMA caused the morphological transition from core-shell toJanus or inversed core-shell,in which PBTPA-shell surrounded PMMA-core,depending on the molecular weight of PBTPA segment in *** the molecular weight of PMMA segment was higher than that of PMMA homopolymer,watermelon-like particles in which small PBTPA domain less than 80 nm dispersed in the PMMA domain surrounded by PBTPA shell were *** the ratio of PBTPA-b-PMMA increased,the interface of the macrophase separation became *** 50 wt%of the PBTPA-b-PMMA,only microphase separation was *** measurement of interfacial tension by pendant drop method demonstrated that PBTPA-b-PMMA lower the interfacial tension between PBTPA and the aqueous phase to the value similar to that of PMMA with the aqueous phase.

关键词： Microsphere Hierarchical structure Polymer blend Block copolymer Solvent evaporation Phase separation