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Structure and Bonding in Some Gd(Ⅲ) Metal Complexes Studied by Three-Dimensional X-Ray Analysis and ^(155)Gd Mssbauer Spectroscopy

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Journal of Rare Earths 2007年第6期25卷 647-653页

作者：王军虎 takahashi Masashi Kitazawa Takafumi Takeda Masuo Dalian Institute of Chemical Physics Chinese Academy of Sciences Department of Chemistry Faculty of Science Toho University 2-2-1 Miyama Funabashi Chiba 274-8510 Japan

Some functional lanthanide metal complexes, such as acetylacetonato complexes, ethylenediaminetetraacetato complexes, were successfully applied for diagnostic technique. The authors are interested in investigating the structure and bonding in lanthanide and actinide metal complexes using 166Er, t55Gd, and 237Np Mtissbauer spectroscopies in connection with single-crystal and/or powder X-ray diffraction, making clear the differences on their structures as well as the differences in the participation of 4f and 5f orbitals in the chemical bonds. In this article, the crystal structures of two novel Gd（Ⅲ） acetylacetonato complexes, Gd（pta）3 · 2H2O （pta = 1,1,1 -trifluoro-5,5-dimethy 1-2,4-hexanedione） and Gd（bfa）3 · 2H2O （bfa = 1, 1, 1 -trifluoro-4-phenyl-2-4-butanedione） were reported. Though both of them were dihydrate and had distorted square antiprismatical structure, Gd（pta）3 · 2H2O crystallizes in the P 2 1/n （#14） monoclinic space group and its lattice parameters are a = 1.4141（6） nm, b = 1.0708（3） nm, c =2.2344（4） nm, β =952.4（2）°, and Gd（bfa）3· 2H2O crystallizes in P 212121 orthorhombic space group and its lattice parameters were a = 1.322 （1） nm, b = 2.295 （1） nm, c = 1. 0786（8） nm. In the meantime, the authors had finished a systematic investigation on the ^155Gd Mossbauer isomer shift （δ） of various Gd（Ⅲ） metal complexes having a different coordination number （C.N.） and different ratios coordinating oxygen to nitrogen. A tendency for the 6 value to decrease with an increase in the C.N, and the number of the nitrogen atom coordinating to Gd was confirmed. This indicated that the Gd-O and/or Gd-N bond in the investigated Gd（Ⅲ） metal complexes had a small covalent contribution, which was possible to be deduced from the O and/or N atoms of the lisands donating electrons to 6s, 5d, and 4f orbitals of Gd.

关键词： Gd(Ⅲ) metal complex crystal structure bonding ^155Gd Mossbauer spectroscopy three-dimensional X-ray analysis covalent contribution rare earths

Different effects of grain boundary scattering on charge and heat transport in polycrystalline platinum and gold nanofilms

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Chinese Physics B 2009年第5期18卷 2035-2040页

作者：马维刚王海东张兴 takahashi Koji Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering MechanicsTsinghua University Graduate School of Engineering Kyushu University

The in-plane electrical and thermal conductivities of several polycrystalline platinum and gold nanofilms with different thicknesses are measured in a temperature range between the boiling point of liquid nitrogen （77K） and room temperature by using the direct current heating method. The result shows that both the electrical and thermal conductivities of the nanofilms reduce greatly compared with their corresponding bulk values. However, the electrical conductivity drop is considerably greater than the thermal conductivity drop, which indicates that the influence of the internal grain boundary on heat transport is different from that of charge transport, hence leading to the violation of the Wiedemann-Franz law. We build an electron relaxation model based on Matthiessen＇s rule to analyse the thermal conductivity and employ the Mayadas ＆ Shatzkes theory to analyse the electrical conductivity. Moreover, a modified Wiedemann-Franz law is provided in this paper, the obtained results from which are in good agreement with the experimental data.

关键词： polycrystalline nanofilm grain boundary scattering thermal and electrical conductivities Wiedemann-Franz law

Foreword for the special issue of the 7th China-Japan bilateral symposium on high temperature strength of materials

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Acta Metallurgica Sinica(English Letters) 2011年第2期24卷 I0001-I0002页

作者： Shan-Tung TU Yukio takahashi East China University of Science and Technology Central Research Institute of Electric Power Industry

The 7th China-Japan Bilateral Symposium on High Temperature Strength of Mate- rials was held at Dalian, China, during the period August 23-27, 2010. The symposium was co-organized by the High Temperature Strength and Materials Committee, the So- ciety of Materials, Chinese Mechanical Engineering Society and the Committee on High Temperature Strength of Materials, the Society of Materials Science Japan.

关键词： 7th China-Japan bilateral symposium on high temperature strength of materials lecture Japan friendship

Animal models of nonalcoholic fatty liver disease/nonalcoholic steatohepatitis

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World Journal of Gastroenterology 2012年第19期18卷 2300-2308页

作者： Yoshihisa takahashi Yurie Soejima Toshio Fukusato Department of Pathology Teikyo University School of MedicineTokyo 173-8605Japan

Nonalcoholic fatty liver disease(NAFLD) is a condition in which excess fat accumulates in the liver of a patient without a history of alcohol *** steatohepatitis(NASH),a severe form of NAFLD,can progress to liver cirrhosis and hepatocellular *** is regarded as a hepatic manifestation of metabolic syndrome and incidence has been increasing worldwide in line with the increased prevalence of obesity,type 2 diabetes,and *** models of NAFLD/NASH give crucial information,not only in elucidating pathogenesis of NAFLD/NASH but also in examining therapeutic effects of various *** ideal model of NAFLD/NASH should correctly reflect both hepatic histopathology and pathophysiology of human NAFLD/*** models of NAFLD/NASH are divided into genetic,dietary,and combination *** this paper,we review commonly used animal models of NAFLD/NASH referring to their advantages and disadvantages.

关键词： Animal model Nonalcoholic fatty liver dis-ease Nonalcoholic steatohepatitis Metabolic syndrome Histopathology

Haptic interface using tendon electrical stimulation with consideration of multimodal presentation

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Virtual Reality & Intelligent Hardware 2019年第2期1卷 163-175页

作者： Akifumi takahashi Kenta TANABE Hiroyuki KAJIMOTO Department of Informatics University of Electro-CommunicationsChofuTokyo 182-8585Japan

Background Our previous studies have shown that electrical stimulation from the skin surface to the tendon region(Tendon Electrical Stimulation:TES)can elicit a force sensation,and adjusting the current parameters can control the amount of the *** is thought to present a proprioceptive force sensation by stimulating receptors or sensory nerves responsible for recognizing the magnitude of the muscle contraction existing inside the tendon,so it can be a proprioceptive module of a small-size,low-cost force feedback *** there is also suspect that TES presents only strong,noisy skin *** previous study,it was found that TES has some limitation on varying *** In this study,in addition to characterizing the proprioceptive sensation induced by TES,we constructed a multimodal presentation system reproducing a situation in which force is applied to the hand was offered,so as to investigate whether TES contributed to the reproduction of haptics cooperating with other modalities,rather than disturbing ***,we used vibration to present a cutaneous sensation and a visual head mounted display(HMD)system to present simultaneous *** this system,we also evaluated the efficacy of TES itself and that of the multimodal system involving *** We found that TES,along with visual and vibration stimulation,contributed to the perception of a certain *** Thus,TES appears to be an effective component of multimodal force sense presentation systems.

关键词： Tendon Electrical Stimulation Proprioception Multimodal Force sensation

Direct Simulation Methods for Scalar-Wave Envelopes in Two-Dimensional Layered Random Media Based on the Small-Angle Scattering Approximation

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Communications in Computational Physics 2008年第1期3卷 63-84页

作者： Tatsuhiko Saito Haruo Sato Tsutomu takahashi Earthquake Research Institute The University of TokyoYayoi 1-1-1Bunkyo-kuTokyo113-0032Japan. CREST Japan Science and Technology Agency(JST). Department of Geophysics Graduate School of ScienceTohoku UniversityAramaki-Aza-Aoba 6-3Aoba-kuSendaiMiyagi980-8578Japan. Institute for Research on Earth Evolution Japan Agency for Marine-Earth Science and TechnologyShowa-machi 3173-25Kanazawa-kuYokohamaKanagawa236-0001Japan.

This study presents stochastic methods to simulate wave envelopes in layeredrandom media. High-frequency Seismograms of small earthquakes are so complexdue to lithospheric inhomogeneity that seismologists often analyze wave envelopesrather than wave traces to quantify the subsurface inhomogeneity. Since thestatistical properties of the inhomogeneity vary regionally, it is important to developand examine direct envelope simulation methods for non-uniform random media. Asa simple example, this study supposes planewave propagation through two-layer randommedia in 2-D composed of weak and strong inhomogeneity zones. The characteristicspatial-scale of the inhomogeneity is supposed to be larger than the wavelength,where small-angle scattering around the forward direction dominates large-angle *** envelope simulation methods based on the small-angle scattering approximationare examined. One method is to solve a differential equation for the twofrequencymutual coherence function with the Markov approximation. The other isto solve the stochastic ray bending process by using the Monte Carlo method basedon the Markov approximation for the mutual coherence function. The resultant waveenvelopes of the two methods showed excellent coincidence both for uniform and fortwo-layer random media. Furthermore, we confirmed the validity of the two methodscomparing with the envelopes made from the finite difference simulations of *** two direct envelope simulation methods presented in this study can be a mathematicalbase for the study of high-frequency wave propagation through randomlyinhomogeneous lithosphere in seismology.

关键词： Seismic wave envelope random media.

Plexiform angiomyxoid myofi broblastic tumor of the stomach

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World Journal of Gastroenterology 2010年第23期16卷 2835-2840页

作者： Yoshihisa takahashi Masako Suzuki Toshio Fukusato Department of Pathology Teikyo University School of Medicine Department of Pathology Sekishinkai Sayama Hospital

Plexiform angiomyxoid myofibroblastic tumor of the stomach is a unique mesenchymal tumor that we first described in *** tumor is very rare,and to date,only 18 cases confirmed by immunohistochemistry have been reported in the *** patients' ages ranged from 7 to 75 years(mean,43 years),and the male-to-female ratio was approximately 1:*** clinical symptoms are ulceration,associated upper gastrointestinal bleeding(hematemesis),and *** tumors are located at the antrum in all cases,and grossly,the tumor is whitish to brownish or reddish,and forms a lobulated submucosal or transmural ***,the tumor is characterized by a plexiform growth pattern,the proliferation of cytologically bland spindle cells,and a myxoid stroma that is rich in small vessels and positive for Alcian blue ***,the tumor cells are positive for α-smooth muscle actin and negative for KIT and *** diagnoses include gastrointestinal stromal tumor and other mesenchymal tumors of the gastrointestinal *** authors proposed that this tumor should be designated as "plexiform fibromyxoma",but this designation might cause *** tumor is probably benign and thus far,neither recurrence nor metastasis has been reported.

关键词： Plexiform angiomyxoid myofibroblastic tumor Stomach Gastrointestinal stromal tumor Plexiform fibromyxoma Myofi broblast Fibroblast

Electrocatalytic evolution of oxygen on NiCu particles modifying conductive alumina/nano-carbon network composite electrode

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Science China(Technological Sciences) 2012年第12期55卷 3388-3394页

作者： FUJI Masayoshi SHIRAI Takashi WATANABE Hideo takahashi Minoru Ceramics Research Laboratory Nagoya Institute of Technology

In this paper, a novel electrically conductive alumina/nano-carbon network (NCN) composite material was used as an electro- catalyst carrier. A NiCu/Al2O3 /NCN composite electrode was prepared by electrodepositing NiCu particles onto the surface of the conductive alumina/NCN composite. Morphology, composition, crystalline structure and electrochemical properties of the NiCu/Al2O3 /NCN composite electrode were investigated. The results showed that NiCu particles can be deposited onto the surface of the alumina/NCN composite by a coelectrodeposition method. NiCu particles in the form of solid solution with face-centered cubic (fcc) structure were relatively uniformly distributed over the carbon layer of the conductive ceramic between alumina grains. As-resulted NiCu/Al2O3 /NCN composite electrode had a remarkably enhanced electrochemical activity and high stabilization for oxygen evolution reaction, which indicated its potential application with enhanced performance to oxygen evolution reaction (OER). Moreover, based on the electrochemical measurement, the mechanism of the OER on the NiCu/Al2O3 /NCN composite electrode was discussed.

关键词： conductive aluminafNCN electrodeposition NiCu oxygen evolution electrocatalytic activity

Fabrication of independent nickel microstructures with anodizing of aluminum, laser irradiation, and electrodeposition

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Journal of University of Science and Technology Beijing 2003年第3期10卷 39-42页

作者： T.Kikuchi M.Sakairi H.takahashi Graduate School of Engineering Hokkaido UniversitySapporo 060-8628JapanGraduate School of EngineeringHokkaido UniversitySapporo 060-8628JapanGraduate School of EngineeringHokkaido UniversitySapporo 060-8628Japan

Independent microstructures made of Ni metal were fabricated by fivesequential processes: porous anodic oxide film formation, pore sealing, laser irradiation, Nielectroplating, and removal of the aluminum substrate and anodic oxide films. Aluminum plates androds were anodized in an oxalic acid solution to form porous type anodic oxide films, and thenimmersed in boiling distilled water for pore sealing. The anodized and pore-sealed specimens wereirradiated with a pulsed neodymium-doped yttrium aluminum garnet (Nd-YAG) laser beam in a Ni platingsolution to remove anodic oxide film locally by rotating and moving up I down with anXYZ(theta)-stage. Nickel was deposited at the area where film had been removed by cathodicpolarization in the solution before removing the aluminum substrate and anodic oxide films in NaOHsolutions. Cylindrical or plain network structures were fabricated successfully.

关键词： anodize laser irradiation nickel metal electrodeposition