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A new review of single-ion conducting polymer electrolytes in the light of ion transport mechanisms

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Journal of Energy Chemistry 2024年第2期89卷 543-556,I0012页

作者： Yuqi Luo Lu Gao Weimin kang State Key Laboratory of Separation membranes and membrane Processes/National Center for International Joint Research on Separation membranes School of Textile Science and EngineeringTiangong UniversityTianjin 300387China

With the depletion of fossil fuels and the demand for high-performance energy storage devices,solidstate lithium metal batteries have received widespread attention due to their high energy density and safety *** them,the earliest developed organic solid-state polymer electrolyte has a promising future due to its advantages such as good mechanical flexibility,but its poor ion transport performance dramatically limits its performance ***,single-ion conducting polymer electrolytes(SICPEs)with high lithium-ion transport number,capable of improving the concentration polarization and inhibiting the growth of lithium dendrites,have been proposed,which provide a new direction for the further development of high-performance organic polymer *** view of this,lithium ions transport mechanisms and design principles in SICPEs are summarized and discussed in this *** modification principles currently used can be categorized into the following three types:enhancement of lithium salt anion-polymer interactions,weakening of lithium salt anion-cation interactions,and modulation of lithium ion-polymer *** addition,the advances in single-ion conductors of conventional and novel polymer electrolytes are summarized,and several typical highperformance single-ion conductors are enumerated and analyzed in what way they improve ionic conductivity,lithium ions mobility,and the ability to inhibit lithium ***,the advantages and design methodology of SICPEs are summarized again and the future directions are outlined.

关键词： Lithium metal batteries Single-ion conductor Polymer electrolytes Ion transport mechanism Li-ion transport number

Considerations of advanced aqueous batteries recycling:A perspective

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Journal of Energy Chemistry 2024年第6期93卷 46-54,I0002页

作者： Yun Zhao Yuqiong kang Hao Du Feiyu kang Baohua Li Institute of materials Research Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055GuangdongChina

*** Battery technology,serving as a basis for a rechargeable society,has developed rapidly over a century[1].The progress can be roughly divided into three stages,with the initial two mainly focusing on aqueous battery *** to 1859,research primarily focused on the conceptualization of batteries and the development of primary(non-rechargeable)cells[2].In the subsequent150 years,rechargeable battery technology emerged。

关键词： battery Battery primarily

Confluence of asymmetric catalysis and electrosynthesis in sustainable chemical transformations

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Science China Chemistry 2024年第3期67卷 755-758页

作者： Qinglin Zhang kang Liang Chang Guo Hefei National Research Center for Physical Sciences at the microscale and Department of Chemistry University of Science and Technology of ChinaHefei 230026China

Electrosynthesis has gained widespread recognition for its extraordinary ability to precisely control the redox *** outstanding capability enables the direct conversion of non-functionalized substrates into reactive intermediates by utilizing easily accessible starting materials, eliminating the need for preliminary functionalization procedures and allowing for unconventional bond activations.

关键词： Confluence of asymmetric catalysis and electrosynthesis in sustainable chemical transformations

Novel Perovskite Oxide Hybrid Nanofibers Embedded with Nanocatalysts for Highly Efficient and Durable Electrodes in Direct CO_(2) Electrolysis

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Nano-micro Letters 2024年第5期16卷 214-230页

作者： Akromjon Akhmadjonov Kyung Taek Bae kang Taek Lee Department of mechanical Engineering KAISTDaejeon 34141Republic of Korea KAIST Graduate School of Green Growth and Sustainability Daejeon 34141Republic of Korea

The unique characteristics of nanofibers in rational electrode design enable effec-tive utilization and maximizing material properties for achieving highly efficient and sustainable CO_(2) reduction reactions( CO_(2)RRs)in solid oxide elec-trolysis cells(SOECs).However,practical appli-cation of nanofiber-based electrodes faces chal-lenges in establishing sufficient interfacial contact and adhesion with the dense *** tackle this challenge,a novel hybrid nanofiber electrode,La_(0.6)Sr_(0.4)Co_(0.15)Fe_(0.8)Pd_(0.05)O_(3-δ)(H-LSCFP),is developed by strategically incorporating low aspect ratio crushed LSCFP nanofibers into the excess porous interspace of a high aspect ratio LSCFP nanofiber framework synthesized via electrospinning *** consecutive treatment in 100% H_(2) and CO_(2) at 700°C,LSCFP nanofibers form a perovskite phase with in situ exsolved Co metal nanocatalysts and a high concentration of oxygen species on the surface,enhancing CO_(2) *** SOEC with the H-LSCFP electrode yielded an outstanding current density of 2.2 A cm^(-2) in CO_(2) at 800°C and 1.5 V,setting a new benchmark among reported nanofiber-based *** twinning of the H-LSCFP reveals improved contact adhesion and increased reaction sites for CO_(2)*** present work demonstrates a highly catalytically active and robust nanofiber-based fuel electrode with a hybrid structure,paving the way for further advancements and nanofiber applications in CO_(2)-SOECs.

关键词： Nanofibers Fuel electrodes Digital twinning CO_(2)reduction reaction Solid oxide electrolysis cells

Steel-refractory reactions in lanthanum-,cerium-,and ytrium-added steels

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Journal of Iron and Steel Research(International) 2024年第6期31卷 1473-1485页

作者： Jian kang Hong-po Wang Yu Wang College of materials Science and Engineering Chongqing UniversityChongqing 400044China The State Key Laboratory of mechanical Transmissions Chongqing UniversityChongqing 400044China

A systematic experimental study was conducted on the similarities and differences in the reactions between commonly used rare earth elements(REEs)and frequently used refractories in the steelmaking *** results indicate that the reaction behaviors of La,Ce,and Y with mgO,Al_(2)O_(3),and mgO·Al_(2)O_(3) crucibles differed *** consumption rates of La,Ce,and Y in the molten steel were in descending order of La>Ce>Y for smelting with all three kinds of *** the REEs reacted with the crucible,the contents of mg and Al showed a trend of first increasing and then *** laboratory-scale smelting conditions,the reactions related to REEs were dominated by steel-crucible reactions,and the contact area between the unit mass of molten steel and refractory materials mainly determined the consumption rates of ***-and Ce-crucible reactions generated loose and porous reaction interfaces;however,Y-crucible reactions generated a dense Y_(2)O_(3) layer,dramatically suppressing the consumption rate of *** calculation indicated that the reactions between rare earth and different refractory materials were first-order *** crucible materials significantly affected the product type and morphology of the steel-crucible reaction interfaces,thereby influencing the consumption rate of *** reactions between REEs and refractories must be seriously considered,especially for small-scale smelting.

关键词： Rare earth Inclusion Refractory Thermodynamics Dynamics

Polyoxometalates for continuous power generation by atmospheric humidity

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Nano Research 2024年第3期17卷 1875-1885页

作者： Tuo Ji Weilin Chen Zhenhui kang Liming Zhang Key Laboratory of Polyoxometalate and Reticular material Chemistry of ministry of Education Northeast Normal UniversityChangchun 130024China Institute of Functional Nano&Soft materials(FUNSOm) Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices DepartmentSoochow UniversitySuzhou 215123China macao Institute of materials Science and Engineering Macao University of Science and TechnologyTaipaMacao 999078China Institute of Functional State Key Laboratory of Luminescence and Applications Changchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of SciencesChangchun 130033China

Atmospheric humidity is a sustainable low-value energy widely existing in natural environment,which is a promising candidate to solve the noncontinuous and low efficiency of low-value energy power *** the mono-substituted Dawson-type polyoxometalates are constructed to be highly dispersed organic ammonium-polyoxoanion clusters and are assembled into thin films power generators with micropores,working in atmospheric *** optimal polyoxometalates generator with the thickness of 7.2μm and the area of 0.36 cm^(2) produces a voltage of 0.68 V and a current density of 19.5μA·cm^(-2) under simulated natural environment,and works continuously and stably under almost all-natural environments(humidity 10%–90%).The highly dispersed polyoxometalate nanoclusters can form microporous in polyoxometalate films to effectively absorb atmospheric humidity and spontaneously form distribution gradient of water,which is the structural basis of power *** continuous power generation may be maintained by the effective adsorption and utilization of H_(2)O,the huge electrostatic field of organic ammonium-polyoxoanion clusters,and the reasonably designed polyoxometalates containing inorganic small ions with high *** is the first humidity generator designed with polyoxometalates,which may provide a new research direction for polyoxometalates in sustainable utilization of low-value energy.

关键词： atmospheric humidity continuous power generations nanomaterials polyoxoanions polyoxometalates

Occurrence of microplastics in natural and farmland soil in the Qilian mountains of the Northern Tibetan Plateau

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Journal of mountain Science 2024年第7期21卷 2159-2172页

作者： kang Qiangqiang ZHANG Yulan kang Shichang ZHANG Shengyin LUO Xi LI Longrui WANG Zhaoqing ZHANG Shuncun Key Laboratory of Petroleum Resources Exploration and Evaluation Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China University of Chinese Academy of Sciences Beijing 100049China Key Laboratory of Cryospheric Science and Frozen Soil Engineering Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China College of Earth and Environmental Sciences Lanzhou UniversityLanzhou 730000China

microplastics(mPs)become ubiquitous in soil and are an environmental and public health concern ***,the status of mPs in natural and farmland soils in remote areas remains poorly *** this study,we investigated the characteristics of mPs in natural and farmland soils along two transects in the Qilian mountains of the northern Tibetan *** average abundance of mPs in natural and farmland soils was 29,778 and 56,123 items kg^(-1),respectively,with a detection size range of 10-1000μ*** in the size range of 10-100μm accounted for 84.1%of particles *** the 21 polymers detected,polyethylene dominated in both farmland and natural *** shape of mPs was dominated by fragments(95.8%),followed by fibers(3.8%)and beads(0.4%).The abundance of mPs was positively correlated with increasing altitude in natural *** was no significant correlation between the abundance of mPs and soil physicochemical properties due to the narrow range of values of soil physicochemical *** the growing concern regarding mPs pollution,research on the status of mPs in high altitude and remote areas is critical to understanding their global cycle.

关键词： microplastics pollution Soil Remote areas Tibetan Plateau

Hyperspectral Image Based Interpretable Feature Clustering Algorithm

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Computers, materials & Continua 2024年第5期79卷 2151-2168页

作者： Yaming kang PeishunYe Yuxiu Bai Shi Qiu School of Information Engineering Yulin UniversityYulin719000China Key Laboratory of Spectral Imaging Technology CAS Xi’an Institute of Optics and Precision MechanicsChinese Academy of SciencesXi’an710119China

Hyperspectral imagery encompasses spectral and spatial dimensions,reflecting the material properties of *** application proves crucial in search and rescue,concealed target identification,and crop growth *** is an important method of hyperspectral *** vast data volume of hyperspectral imagery,coupled with redundant information,poses significant challenges in swiftly and accurately extracting features for subsequent *** current hyperspectral feature clustering methods,which are mostly studied from space or spectrum,do not have strong interpretability,resulting in poor comprehensibility of the ***,this research introduces a feature clustering algorithm for hyperspectral imagery from an interpretability *** commences with a simulated perception process,proposing an interpretable band selection algorithm to reduce data *** this,amulti-dimensional clustering algorithm,rooted in fuzzy and kernel clustering,is developed to highlight intra-class similarities and inter-class *** optimized P systemis then introduced to enhance computational *** system coordinates all cells within a mapping space to compute optimal cluster centers,facilitating parallel *** approach diminishes sensitivity to initial cluster centers and augments global search capabilities,thus preventing entrapment in local minima and enhancing clustering *** conducted on 300 datasets,comprising both real and simulated *** results show that the average accuracy(ACC)of the proposed algorithm is 0.86 and the combination measure(Cm)is 0.81.

关键词： Hyperspectral fuzzy clustering tissue P system band selection interpretable

Natural marmatite photocatalyst for treatment of mineral processing wastewater to help zero wastewater discharge

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Journal of Environmental Sciences 2024年第8期142卷 83-91页

作者： meirong Wu Wei Sun Xiangsong meng Jianhua kang Yue Yang School of minerals Processing and Bioengineering Central South UniversityChangsha 410083China Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing mineral Resources Central South UniversityChangsha 410083China

mineral processing wastewater(mPW)with large discharge and high toxicity affects environmental safety,and the realizing zero discharge of mPW is of great significance for reducing environmental pollution,saving water resources,and promoting the sustainable development of the mining *** this study,we reported natural marmatite(Nm)as a low-cost and efficient photocatalyst for the treatment of mPW to help zero wastewater *** photocatalytic activity of Nm was evaluated by the removal of total organic carbon(TOC)from mPW under visible-light illumination,and the optimal degradation conditions were *** showed that superoxide free radicals(^(·)O_(2)^(-))were the dominant active species responsible for organic pollutants degradation,and 74.25%TOC removal was obtained after 120 min reaction under the optimum treatment ***,the wastewater treated by Nm photocatalysis can be reused in the flotation system without adverse impact on the product *** on these findings,a model of zero wastewater discharge for flotation with the help of photocatalytic treatment was established,it indicated that the water of the whole system can be balanced without affecting the ore dressing index,which showed that visible light-driven photocatalyst has a promising application prospect in the treatment and recycling of industrial wastewater.

关键词： Natural mineral Photocatalysis Industrial wastewater Wastewater recycling Water balance