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Chinese Chemical Letters 2024年第9期35卷 169-174页

作者： Chaochao Jin Kai Li Jiongpei zhang Zhihua Wang Jiajing Tan College of Chemistry Beijing University of Chemical Technology(BUCT)Beijing 100029China College of Materials Science and Engineering Shenzhen UniversityShenzhen 518055China

An array of pyridine-ester enolate based organoboron complexes has been designed and synthesized via a one-pot cascade of Pd-catalyzedα-arylation and *** rapid structure-activity relationship(SAR)studies indicated that unsymmetrical N,O-chelated BF2complexes were highly fluorescent in solid state,and exhibited large Stokes shifts,excellent photostability,along with insensitivity to p ***α-aryl group could not only modulate the electronic effect but also inhibit the intermolecularπ-πstacking to promote the aggregation-induced emission(AIE)*** calculations and experiments identified that the intramolecular charge transfer properties of these N,O-chelates could be switched by the modification of substituents,resulting tunable fluorescence ***,post-complexation modification was accomplished,including Suzuki-Miyaura cross-coupling,Buchwald-Hartwig amination,oxidative cleavage,along with a unique triple substitution reaction involving propargyl Grignard *** exemplificative application of dimethylamine substituted boron complex as a reversible acidic vapor sensor was also demonstrated.

关键词： N,O-Bidentate BF2 complexes Aggregation-induced emission Large Stokes shift Post-complexation modification Reversible acidic vapor sensor

An Immune-Inspired Approach with Interval Allocation in Solving Multimodal Multi-Objective Optimization Problems with Local Pareto Sets

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Computers, Materials & Continua 2024年第6期79卷 4237-4257页

作者： Weiwei zhang Jiaqiang Li Chao Wang Meng Li Zhi Rao College of Computer Science and Technology Zhengzhou University of Light IndustryZhengzhou450001China Technology Research and Development Center Jilin Tobacco Industry Company LimitedChangchun130031China College of Tobacco Science and Engineering Zhengzhou University of Light IndustryZhengzhou450001China Raw Material Department Hongyun Honghe Tobacco(Group)CompanyKunming650202China

In practical engineering,multi-objective optimization often encounters situations where multiple Pareto sets(PS)in the decision space correspond to the same Pareto front(PF)in the objective space,known as Multi-Modal Multi-Objective Optimization Problems(MMOP).Locating multiple equivalent global PSs poses a significant challenge in real-world applications,especially considering the existence of local *** identifying and locating both global and local PSs is a major *** tackle this issue,we introduce an immune-inspired reproduction strategy designed to produce more offspring in less crowded,promising regions and regulate the number of offspring in areas that have been thoroughly *** approach achieves a balanced trade-off between exploration and ***,we present an interval allocation strategy that adaptively assigns fitness levels to each *** strategy ensures a broader survival margin for solutions in their initial stages and progressively amplifies the differences in individual fitness values as the population matures,thus fostering better population ***,we incorporate a multi-population mechanism that precisely manages each subpopulation through the interval allocation strategy,ensuring the preservation of both global and local *** results on 21 test problems,encompassing both global and local PSs,are compared with eight state-of-the-art multimodal multi-objective optimization *** results demonstrate the effectiveness of our proposed algorithm in simultaneously identifying global Pareto sets and locally high-quality PSs.

关键词： Multimodal multi-objective optimization problem local PSs immune-inspired reproduction

Finite Difference-Peridynamic Differential Operator for Solving Transient Heat Conduction Problems

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Computer Modeling in Engineering & Sciences 2024年第9期140卷 2707-2728页

作者： Chunlei Ruan Cengceng Dong Zeyue zhang Boyu Chen Zhijun Liu School of Mathematics&Statistics Henan University of Science&TechnologyLuoyang471023China Longmen Laboratory Luoyang471023China

Transient heat conduction problems widely exist in *** previous work on the peridynamic differential operator(PDDO)method for solving such problems,both time and spatial derivatives were discretized using the PDDO method,resulting in increased complexity and programming *** this work,the forward difference formula,the backward difference formula,and the centered difference formula are used to discretize the time derivative,while the PDDO method is used to discretize the spatial *** new schemes for solving transient heat conduction equations have been developed,namely,the forward-in-time and PDDO in space(FT-PDDO)scheme,the backward-in-time and PDDO in space(BT-PDDO)scheme,and the central-in-time and PDDO in space(CT-PDDO)*** stability and convergence of these schemes are analyzed using the Fourier method and Taylor’s *** show that the FT-PDDO scheme is conditionally stable,whereas the BT-PDDO and CT-PDDO schemes are unconditionally *** stability conditions for the FT-PDDO scheme are less stringent than those of the explicit finite element method and explicit finite difference *** convergence rate in space for these three methods is *** constructed schemes are applied to solve one-dimensional and two-dimensional transient heat conduction *** accuracy and validity of the schemes are verified by comparison with analytical solutions.

关键词： Peridynamic differential operator finite difference method stability transient heat conduction problem

Cross-Project Software Defect Prediction Based on SMOTE and Deep Canonical Correlation Analysis

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Computers, Materials & Continua 2024年第2期78卷 1687-1711页

作者： Xin Fan Shuqing zhang Kaisheng Wu Wei Zheng Yu Ge School of Software Nanchang Hangkong UniversityNanchang330063China Software Testing and Evaluation Center Nanchang Hangkong UniversityNanchang330063China

Cross-Project Defect Prediction(CPDP)is a method that utilizes historical data from other source projects to train predictive models for defect prediction in the target ***,existing CPDP methods only consider linear correlations between features(indicators)of the source and target *** models are not capable of evaluating non-linear correlations between features when they exist,for example,when there are differences in data distributions between the source and target *** a result,the performance of such CPDP models is *** this paper,this paper proposes a novel CPDP method based on Synthetic Minority Oversampling Technique(SMOTE)and Deep Canonical Correlation Analysis(DCCA),referred to as *** Correlation Analysis(CCA)is employed to address the issue of non-linear correlations between features of the source and target projects.S-DCCA extends CCA by incorporating the MlpNet model for feature extraction from the *** redundant features are then eliminated by maximizing the correlated feature subset using the CCA loss ***,cross-project defect prediction is achieved through the application of the SMOTE data sampling *** Under Curve(AUC)and F1 scores(F1)are used as evaluation *** paper conducted experiments on 27 projects from four public datasets to validate the proposed *** results demonstrate that,on average,our method outperforms all baseline approaches by at least 1.2%in AUC and 5.5%in F1 *** indicates that the proposed method exhibits favorable performance characteristics.

关键词： Cross-project defect prediction deep canonical correlation analysis feature similarity

Controllable Construction of Vinyl Sulfones and β-keto Selenosulfones via Selective Oxidative Sulfonylation of Alkenes

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Chinese Journal of Chemistry 2024年第12期42卷 1367-1372页

作者： Xiang Liu Yuan zhang Yi Zheng Changfeng Huang Hua Cao School of Chemistry and Chemical Engineering Guangdong Pharmaceutical UniversityZhongshanGuangdong 528458China

Comprehensive Summary The selective oxidative sulfonylation of alkenes with selenium sulfonate depended on the reaction *** electrochemical C—H sulfonylation proceeded smoothly to afford(E)-vinyl sulfones with good selectivity in an undivided cell without external *** aerobic trifunctionalization of alkenes occurred in the presence of KI in the air,which providesβ-keto selenosulfones via the formation of C—O,C—S,and C—Se bonds in *** control experiments,a plausible mechanism is proposed to rationalize the experimental results.

关键词： Synthetic methods Alkenes Difunctionalization Selenylation Sulfonylation

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高盐废水焚烧盐精制提纯研究

化工管理 2024年第2期 127-129,159页

作者：张德仕张珂山东金城晖瑞环保科技有限公司山东淄博255000

高盐废水来源广泛,焚烧法处理高盐废水具有短工艺流程、小型设备等优点,同时可彻底焚烧氧化废水中的污染物。然而,此过程产生大量废盐,其中含有大量有毒有害物质,成分复杂且毒性强,难以降解。文章通过溶解、过滤、重新蒸发结晶等步骤的... 详细信息

高盐废水来源广泛,焚烧法处理高盐废水具有短工艺流程、小型设备等优点,同时可彻底焚烧氧化废水中的污染物。然而,此过程产生大量废盐,其中含有大量有毒有害物质,成分复杂且毒性强,难以降解。文章通过溶解、过滤、重新蒸发结晶等步骤的组合工艺,对高盐废水焚烧盐进行精制提纯,可使硫酸钠纯度提升至95%以上,含水率低于6%,TOC小于30 mg/L,氯化钠纯度提升至93%以上,含水率小于6%,TOC小于30 mg/L,达到日晒盐二级标准。

关键词：高盐废水焚烧盐精制提纯

Research on Evacuation Path Planning Based on Improved Sparrow Search Algorithm

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Computer Modeling in Engineering & Sciences 2024年第5期139卷 1295-1316页

作者： Xiaoge Wei Yuming zhang Huaitao Song Hengjie Qin Guanjun Zhao The School of Building Environment Engineering Zhengzhou University of Light IndustryZhengzhou450001China Zhengzhou key Laboratory of Electric Power Fire Safety Zhengzhou University of Light IndustryZhengzhou450001China Eccom Network System Shanghai201103China

Reducing casualties and property losses through effective evacuation route planning has been a key focus for researchers in recent *** part of this effort,an enhanced sparrow search algorithm(MSSA)was ***,the Golden Sine algorithm and a nonlinear weight factor optimization strategy were added in the discoverer position update stage of the SSA ***,the Cauchy-Gaussian perturbation was applied to the optimal position of the SSA algorithm to improve its ability to jump out of local ***,the local search mechanism based on the mountain climbing method was incorporated into the local search stage of the SSA algorithm,improving its local search *** evaluate the effectiveness of the proposed algorithm,the Whale Algorithm,Gray Wolf Algorithm,Improved Gray Wolf Algorithm,Sparrow Search Algorithm,and MSSA Algorithm were employed to solve various test *** accuracy and convergence speed of each algorithm were then compared and *** results indicate that the MSSA algorithm has superior solving ability and stability compared to other *** further validate the enhanced algorithm’s capabilities for path planning,evacuation experiments were conducted using different maps featuring various obstacle ***,a multi-exit evacuation scenario was constructed according to the actual building environment of a teaching *** the sparrow search algorithm and MSSA algorithm were employed in the simulation experiment for multiexit evacuation path *** findings demonstrate that the MSSA algorithm outperforms the comparison algorithm,showcasing its greater advantages and higher application potential.

关键词： Sparrow search algorithm optimization and improvement function test set evacuation path planning

Rock strength weakening subject to principal stress rotation:Experimental and numerical investigations

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3544-3557页

作者： Huandui Liu Guibin Wang Chunhe Yang Junyue zhang Shiwan Chen State key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China University of Chinese Academy of Sciences Beijing100049China State key Laboratory of Coal Mine Disaster Dynamics and Control College of Resources and Environmental SciencesChongqing UniversityChongqing400044China College of Resources and Environmental Engineering Guizhou UniversityGuiyang50025China

During the construction and operation of gas storage reservoirs,changes in the principal stress direction can induce fracture propagation under conditions of lower differential stress,potentially leading to failure in the surrounding ***,the weakening of strength due to pure stress rotation has not yet been *** on fracture mechanics,an enhanced Mohr-Coulomb strength criterion considering stress rotation is proposed and verified with experimental and numerical *** micro-damage state and the evolution of the rock under the pure stress-rotation condition are *** findings indicate that differential stress exceeding the crack initiation stress is a prerequisite for stress rotation to promote the development of rock *** the differential stress increases,stress rotation is more likely to induce rock damage,leading to a transition from brittle to plastic failure,characterized by wider fractures and a more complex fracture ***,a negative exponential relationship exists between the stress rotation angle required for rock failure and the differential *** feasibility of applying the enhanced criterion to practical engineering is discussed using monitoring data obtained from a mine-by *** study introduces new concepts for understanding the damage evolution of the surrounding rock under complex stress paths and offers a new theoretical basis for predicting the damage of gas storage reservoirs.

关键词： Principal stress rotation(PSR) Fracture mechanics Hollow cylinder torsional apparatus for rock (HCAR) Particle flow method Rock strength

Properties of high cis-1,4 content hydroxyl-terminated polybutadiene and its application in composite solid propellants

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Defence Technology（防务技术） 2024年第10期40卷 199-209页

作者： Deqian Meng Lipeng Sang Pingan zhang Jianru Deng Xiang Guo College of Chemistry and Chemical Engineering Hunan UniversityChangsha410082China Science and Technology on Aerospace Chemical Power Laboratory Xiangyang441003China

In this paper,high cis-1,4 content hydroxyl-terminated polybutadiene(cis-HTPB)with different molecular weights was prepared through the oxidative cracking process using cis-butadiene rubber as raw ***,this article comprehensively compared the differences between cis-HTPB and conventional I-HTPB in terms of molecular weight distribution,functionality,viscosity,molecular polarity,and other physicochemical properties,which provided effective data support for its subsequent *** addition,the reaction kinetics study showed that cis-HTPB with isocyanate curing agent has high reactivity,allowing it to be rapidly cured at low temperatures,and the cured elastomers had excellent mechanical properties,with tensile strength and elongation up to 1.89 MPa and 1100%,*** was also found that cis-HTPB has extremely excellent low-temperature resistance,and the glass transition temperature(T_(g))of its cured elastomer is as low as-101℃.Based on the above studies,cis-HTPB is applied as a binder in composite solid propellants for the first time to investigate its practical performance,and the results indicated that cis-HTPB-based propellants have excellent process and mechanical properties.

关键词： High cis-1,4 content-HTPB(cis-HTPB) Low-temperature resistance Comparison of physicochemical properties cis-HTPB curing process cis-HTPB based propellant

Differentially Private Support Vector Machines with Knowledge Aggregation

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Computers, Materials & Continua 2024年第3期78卷 3891-3907页

作者： Teng Wang Yao zhang Jiangguo Liang Shuai Wang Shuanggen Liu School of Cyberspace Security Xi’an University of Posts and TelecommunicationsXi’an710121China

With the widespread data collection and processing,privacy-preserving machine learning has become increasingly important in addressing privacy risks related to *** vector machine(SVM)is one of the most elementary learning models of machine *** issues surrounding SVM classifier training have attracted increasing *** this paper,we investigate Differential Privacy-compliant Federated Machine Learning with Dimensionality Reduction,called FedDPDR-DPML,which greatly improves data utility while providing strong privacy *** in distributed learning scenarios,multiple participants usually hold unbalanced or small amounts of ***,FedDPDR-DPML enables multiple participants to collaboratively learn a global model based on weighted model averaging and knowledge aggregation and then the server distributes the global model to each participant to improve local data *** at high-dimensional data,we adopt differential privacy in both the principal component analysis(PCA)-based dimensionality reduction phase and SVM classifiers training phase,which improves model accuracy while achieving strict differential privacy ***,we train Differential privacy(DP)-compliant SVM classifiers by adding noise to the objective function itself,thus leading to better data *** experiments on three high-dimensional datasets demonstrate that FedDPDR-DPML can achieve high accuracy while ensuring strong privacy protection.

关键词： Differential privacy support vector machine knowledge aggregation data utility