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Oxide ancillary ligand-based europium β-diketonate complexes and their enhanced luminosity

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Rare Metals 2021年第10期40卷 2873-2881页

作者： Devender singh Shri Bhagwan Anuj Dalal Kapeesha Nehra Raman Kumar Saini kapoor singh Anura Priyajith Simantilleke Sumit Kumar Ishwar singh Department of Chemistry Maharshi Dayanand UniversityRohtak 124001India Centre de Fisica Universidade of MinhoBraga 4710057Portugal Department of Chemistry DCR University of Science and TechnologyMurthal 131039India

Ternary materials of europium complex with2,2,6,6-tetramethyl-3,5-heptanedione(tmhd) ligand and aqua ligand as ancillary ligands have been prepared and characterized for various optoelectronic *** of hydrated complex [Eu(tmhd)_(3)(H_(2)O)_(2)] proceeded with triphenylphosphine oxide(TPPO) and pyridine-N-oxide(PNO) ancillary ligands were studied to develop novel complexes. The prepared complexes show good thermal stability. A comparative investigation of preparedmaterials[Eu(tmhd)_(3)(H_(2)O)_(2)],[Eu(tmhd)_(3)(TPPO)_(2)] and [Eu(tmhd)_(3)(PNO)_(2)] was conducted for their luminescent behaviors in order to obtain the role of ancillary ligand in the enhancement of illumination amount generated from europium(Eu^(3+)) ion. Color coordinates of prepared ternary complexes such as[Eu(tmhd)_(3)(H_(2)O)_(2)]with(x = 0.54,y = 0.32),[Eu(tmhd)_(3)(TPPO)_(2)] with(x = 0.56, y = 0.32) and[Eu(tmhd)_(3)(PNO)_(2)] with(x = 0.57, y = 0.33) indicated that these materials exhibited bright red emission in visible region spectrum. The complexes show a proficient energy transport pathway from the ligands to the innermost Eu^(3+)by means of an ancillary ligand-sensitized luminescence process. Interaction between the metal and ligand results in a distinguished effect on quantum efficiency(η) as well as on Judd–Ofelt intensity factor(Ω_(2)) of the prepared materials.

关键词： Ternary Eu^(3+)complexes Red emissive materials Photoluminescence Quantum efficiency Judd-Ofelt intensity Optoelectronic devices

Exploration of IoT Nodes Communication Using LoRaWAN in Forest Environment

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Computers, Materials & Continua 2022年第6期71卷 6239-6256页

作者： Anshul Sharma Divneet singh kapoor Anand Nayyar Basit Qureshi Kiran Jot singh Khushal Thakur Embedded Systems&Robotics Research Group Chandigarh UniversityMohali140413PunjabIndia Graduate School Duy Tan UniversityDa Nang550000Vietnam Faculty of Information Technology Duy Tan UniversityDa Nang550000Vietnam Department of Computer Science Prince Sultan UniversityRiyadh11586Saudi Arabia

The simultaneous advances in the Internet of Things(IoT),Artificial intelligence(AI)and Robotics is going to revolutionize our world in the near *** recent years,LoRa(Long Range)wireless powered by LoRaWAN(LoRa Wide Area Network)protocol has attracted the attention of researchers for numerous applications in the IoT *** is a low power,unlicensed Industrial,Scientific,and Medical(ISM)bandequipped wireless technology that utilizes a wide area network protocol,i.e.,LoRaWAN,to incorporate itself into the network *** this paper,we have evaluated the LoRaWAN communication protocol for the implementation of the IoT(Internet of Things)nodes’communication in a forest *** outdoor performance of LoRa wireless in LoRaWAN,i.e.,the physical layer,has been evaluated in the forest area of Kashirampur Uttarakhand,***,the present paper aims towards analyzing the performance level of the LoRaWAN technology by observing the changes in Signal to Noise Ratio(SNR),Packet Reception Ratio(PRR)and Received Signal Strength Indicator(RSSI),with respect to the distance between IoT *** article focuses on estimating network lifetime for a specific set of LoRa configuration parameters,hardware selection and power *** the experimental results,it has been observed that transmissions can propagate to a distance of 300 m in the forest environment,while consuming approx.63%less energy for spreading factor 7 at 2 dBm,without incurring significant packet loss with PRR greater than 80%.

关键词： LoRa LoRaWAN IoT communication protocol wireless sensor networks packet reception ratio

Gallbladder and cystic duct agenesis diagnosed laparoscopically

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Hepatobiliary & Pancreatic Diseases International 2010年第1期9卷 107-108页

作者： Nikhil Gupta Sandeep K Gupta Harmeet singh kapoor Department of Surgery Maulana Azad Medical College Department of Surgery Sri Balaji Action Medical Institute

To the Editor:Anatomical variations of the biliary tree are not un-common but isolated agenesis of the gallbladder is rare,[1]with a reported incidence of 0.013%-0.075%.[2]Thisvariation remains undiagnosed since the p... 详细信息

关键词： Gallbladder and cystic duct agenesis diagnosed laparoscopically

Behavior of Delivery Robot in Human-Robot Collaborative Spaces During Navigation

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Intelligent Automation & Soft Computing 2023年第1期35卷 795-810页

作者： Kiran Jot singh Divneet singh kapoor Mohamed Abouhawwash Jehad F.Al-Amri Shubham Mahajan Amit Kant Pandit Embedded Systems&Robotics Research Group Chandigarh UniversityMohali140413PunjabIndia Department of Mathematics Faculty of ScienceMansoura UniversityMansoura35516Egypt Department of Computational Mathematics Scienceand Engineering(CMSE)Michigan State UniversityEast LansingMI48824USA Department of Information Technology College of Computers and Information TechnologyTaif UniversityTaif21944Saudi Arabia School of Electronics and Communication Shri Mata Vaishno Devi UniversityKatra182320India

Navigation is an essential skill for *** becomes a cumbersome task for the robot in a human-populated environment,and Industry 5.0 is an emerging trend that focuses on the interaction between humans and *** behavior in a social setting is the key to human acceptance while ensuring human comfort and *** the advancement in robotics technology,the true use cases of robots in the tourism and hospitality industry are expanding in *** are very few experimental studies focusing on how people perceive the navigation behavior of a delivery robot.A robotic platform named“PI”has been designed,which incorporates proximity and vision *** robot utilizes a real-time object recognition algorithm based on the You Only Look Once(YOLO)algorithm to detect objects and humans during *** study is aimed towards evaluating human experience,for which we conducted a study among 36 participants to explore the perceived social presence,role,and perception of a delivery robot exhibiting different behavior conditions while navigating in a hotel *** participants’responses were collected and compared for different behavior conditions demonstrated by the robot and results show that humans prefer an assistant role of a robot enabled with audio and visual aids exhibiting social ***,this study can be useful for developers to gain insight into the expected behavior of a delivery robot.

关键词： Human-robot interaction robot navigation robot behavior collaborative spaces industrial IoT industry 5.0

Laser-induced graphene-coated wearable smart textile electrodes for biopotentials signal monitoring

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Frontiers of Materials Science 2024年第1期18卷 95-111页

作者： C.M.Vidhya Yogita Maithani Sakshi kapoor J.P.singh Department of Physics Indian Institute of Technology DelhiHauz KhasNew Delhi 110016India

This paper describes how to produce a wearable dry electrode at a reasonable cost and how to use it for the monitoring of biopotentials in *** textiles in wearable technologies have made a great advancement in the health care management and living standards of *** was manufactured using the low-cost single-step process,laser ablation of polyimide,a commercial *** dispersions were made using solvent isopropyl alcohol which has low boiling point,nontoxicity,and environmental *** successive coating of the graphene dispersion on the cotton fabric to make it conductive,the sheet resistance of the resulting fabric dropped to 3% of its initial *** laser-induced graphene(LIG)cotton dry electrodes thus manufactured are comparable to Ag/AgCl wet electrodes in terms of the skin-to-electrode impedance,measuring between 78.0 and 7.2 kΩ for the frequency between 40 Hz and 1 *** LIG cotton electrode displayed a signal-to-noise ratio of 20.17 *** to its comfort,simplicity,and good performance over a longer period of time,the textile electrode appears suited for medical applications.

关键词： biopotential electrocardiogram electromyogram flexible electrode textile porous graphene

Malignant pleural mesothelioma:The disdained member of thoracic oncology!

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World Journal of Experimental Medicine 2024年第3期14卷 1-10页

作者： Divya Khosla Pawan Kumar singh Bharath A Chhabria Vaishali Kataria Navneet singh Rakesh kapoor Department of Radiotherapy and Oncology Postgraduate Institute of Medical Education and ResearchChandigarh 160012India Department of Pulmonary and Critical Care Medicine Pandit Bhagwat Dayal Sharma Postgraduate Institute of Medical SciencesRohtak 124001India Department of Pulmonary and Critical Care Medicine Ramaiah Memorial HospitalBengaluru 560054India Department of Pulmonary Medicine Postgraduate Institute of Medical Education and ResearchChandigarh 160012India

Pleural mesothelioma is a very aggressive malignancy that arises from the pleural mesothelial cell lining and is linked strongly to prior asbestos *** ban on asbestos has helped to lower the incidence,but in developing countries like India,it is expected to *** has an extended latency period usually progressing over decades and presents with nonspecific *** has a median survival ranging between 10-22 *** diagnosis of malignant pleural mesothelioma is challenging and is done using computed tomography(CT),magnetic resonance imaging,or positron emission tomography-CT,with the last two predicting the resectability of the tumor better than CT alone.A pleural biopsy along with an array of immunohistochemical markers,such as p16,BRCA1 associated protein 1,and claudin-4,are required for a definitive *** genetic alterations have prognostic significance as *** current histological subtype identification is indispensable for decision making because of the new therapeutic avenues being *** combination of nivolumab and ipilimumab-based immunotherapy outperformed platinum and pemetrexed-based chemotherapy in terms of survival benefit and improved quality of life especially for non-epithelioid ***,the latter continues to be a robust treatment option for patients with the epithelioid *** is recommended for resectable cases with radiotherapy being indicated in neoadjuvant,adjuvant,and palliative settings along with systemic *** review article provides an overview of epidemiology,etiology,clinical manifestations,diagnostic approaches(including immunohistochemical and genetic markers),staging,and multidisciplinary approaches to current treatment for malignant pleural mesothelioma using surgery,chemotherapy,immunotherapy,and *** also sheds light on some recent studies(EMPHACIS,CALGB30901,Checkmate-743,etc.)that have led to significant developments in recent years with clinically mean

关键词： Chemotherapy Diagnosis Immunotherapy Malignant pleural mesothelioma Radiotherapy

Development of mix design method based on statistical analysis of different factors for geopolymer concrete

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Frontiers of Structural and Civil Engineering 2022年第10期16卷 1315-1335页

作者： Paramveer singh Kanish kapoor Department of Civil Engineering Dr B R Ambedkar National Institute of TechnologyJalandhar 144011India

The present study proposes the mix design method of Fly Ash(FA)based geopolymer concrete using Response Surface Methodology(RSM).In this method,different factors,including binder content,alkali/binder ratio,NS/NH ratio(sodium silicate/sodium hydroxide),NH molarity,and water/solids ratio were considered for the mix design of geopolymer *** 2D contour plots were used to setup the mix design method to achieve the target compressive *** proposed mix design method of geopolymer concrete is divided into three categories based on curing regime,specifically one ambient curing(25°C)and two heat curing(60 and 90°C).The proposed mix design method of geopolymer concrete was validated through experimentation of M30,M50,and M70 concrete mixes at all curing *** observed experimental compressive strength results validate the mix design method by more than 90%of their target ***,the current study concluded that the required compressive strength can be achieved by varying any factor in the mix *** addition,the factor analysis revealed that the NS/NH ratio significantly affects the compressive strength of geopolymer concrete.

关键词： geopolymer concrete mix design fly ash response surface methodology compressive strength stress—strain

Contrast-free air cholangiography-assisted unilateral plastic stenting in malignant hilar biliary obstruction

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Hepatobiliary & Pancreatic Diseases International 2010年第1期9卷 88-92页

作者： Virendra singh Gurpreet singh Vikas Gupta Rajesh Gupta Rakesh kapoor Departments of Hepatology Postgraduate Institute of Medical Education and Research Departments of Surgery Postgraduate Institute of Medical Education and Research Departments of Radiotherapy Postgraduate Institute of Medical Education and Research

BACKGROUND:Endoscopic palliation in malignant hilar biliary obstruction requires endoscopic retrograde cholangiopancreatography (ERCP),whereas contrast injection leads to ***-free metal stenting with or without magnetic resonance cholangiopancreatography (MRCP) has shown encouraging results,but MRCP and metal stents are *** have been no reports on the use of air ***:We prospectively evaluated the role of air cholangiography-assisted unilateral plastic stenting in 10 patients with type Ⅱ malignant hilar biliary obstruction.A retrospectively analysed group of 10 patients treated with contrast-free unilateral metal stenting served as historical ***:Ten patients with unresectable type Ⅱ malignant hilar biliary obstruction were *** cholangiography detected type Ⅱ obstruction in all patients,similar to *** patients underwent unilateral *** endoscopic drainage was achieved in all *** mean patency of the stent was 95.8±17.5 days in the study group and 143.9±115.1 days in the control group (P=0.20).The mean survival was 121.8±41.6 days in the study group and 154.9±122.5 days in the control group (P=0.42).KaplanMeier analysis showed an estimated median survival of 100:95% CI (65.9,134.1) days in the study group and 98:95% CI (84.1,111.9) days in the control group (P=0.62).Cholangitis occurred in none of the patients and there were no 30-day deaths nor major *** cholangiographyassisted unilateral plastic stenting was cheaper than contrastfree unilateral metal ***:Air cholangiography-assisted unilateral plastic stenting is as safe and effective as contrast-free unilateral metal stenting in type Ⅱ malignant hilar biliary obstruction for palliating patients,but it is cheaper.

关键词： air cholangiogram hilar obstruction malignant plastic stent metal stent unilateral

Anemia in cirrhosis:An underestimated entity

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World Journal of Clinical Cases 2022年第3期10卷 777-789页

作者： Manish Manrai Saurabh Dawra Rajan kapoor Sharad Srivastava Anupam singh Department of Internal Medicine Armed Forces Medical CollegePune 411040India Department of Medicine and Gastroenterology Command HospitalPune 411040India Department of Medicine Command HospitalKolkata 70027India Department of Gastroenterology Post Graduate Institute of Medical Education and ResearchChandigarh 160012India

Anemia in a patient with cirrhosis is a clinically pertinent but often overlooked clinical *** guidelines highlight the algorithmic approach of managing a patient of cirrhosis presenting with acute variceal hemorrhage but day-to-day management in hospital and out-patient raises multiple dilemmas:Whether anemia is a disease complication or a part of the disease spectrum?Should iron,folic acid,and vitamin B complex supplementation and nutritional advice,suffice in those who can perform tasks of daily living but have persistently low *** does one investigate and manage anemia due to multifactorial etiologies in the same patient:Acute or chronic blood loss because of portal hypertension and bone marrow aplasia secondary to hepatitis B or C viremia?To add to the clinician’s woes the prevalence of anemia increases with increasing disease *** thus aim to critically analyze the various pathophysiological mechanisms complicating anemia in a patient with cirrhosis with an emphasis on the diagnostic flowchart in such patients and proposed management protocols thereafter.

关键词： Anemia Cirrhosis Iron deficiency anemia Macrocytic anemia Normocytic anemia