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Asymmetric orbital hybridization in Zn-doped antiperovskite Cu_(1-x)Zn_(x)NMn_(3)enables highly efficient electrocatalytic hydrogen production

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Journal of Energy Chemistry 2024年第2期89卷 304-312,I0008页

作者： Yuxiang Yan Yuxin Cao Zhichao wang ka wang Hengdong Ren Shaoqi Zhang Yi wang Jian Chen Yong Zhou Lizhe Liu Jun Dai Xinglong Wu National Laboratory of Solid States Microstructures and School of Physics Nanjing UniversityNanjing 210093JiangsuChina College of Engineering and Applied Sciences Nanjing UniversityNanjing 210093JiangsuChina National Laboratory of Solid States Microstructures and Research Institute of Superconductor Electronics Nanjing UniversityNanjing 210093JiangsuChina School of Mathematics&Physics Jiangsu University Science&TechnologyZhenjiang 212003JiangsuChina

Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(HER)catalysts is a key factor for developing energy conversion ***,antiperovskite nitride CuNMn_(3)has garnered significant interest due to its remarkable properties such as negative/zero thermal expansion and magnetocaloric ***,when utilized as hydrogen evolution catalysts,it encounters large challenge resulting from excessively strong/weak interactions with adsorbed H on Mn/Cu active sites,which leads to low HER *** this study,we introduce an asymmetric orbital hybridization strategy in Zn-doped Cu_(1-x)Zn_(x)NMn_(3)by leveraging the localization of Zn electronic states to reconfigure the electronic structures of Cu and Mn,thereby reducing the energy barrier for water dissociation and optimizing Cu and Mn active sites for hydrogen adsorption and H_(2)*** evaluations reveal that Cu_(0.85)Zn_(0.15)NMn_(3)with x=0.15 demonstrates exceptional electrocatalytic activity in alkaline electrolytes.A low overpotential of 52 mV at 10 mA cm^(-2)and outstanding stability over a 150-h test period are achieved,surpassing commercial Pt/*** research offers a novel strategy for enhancing HER performance by modulating asymmetric hybridization of electron orbitals between multiple metal atoms within a material structure.

关键词： Cu_(1-x)ZnxNMn_(3) Asymmetric orbital hybridization Hydrogen adsorption Hydrogen production

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A Registry-Based Observational Study on the Maternal and Fetal Outcomes of COVID-19 Patients in Hong Kong,China

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Maternal-Fetal Medicine 2024年第3期6卷 156-163页

作者： Hillary HY Leung Teresa WL Ma Florrie NY Yu Meliza CW Kong Tsz Kin Lo Pauline PL So Wing-Cheong Leung Wendy Shu ka wang Cheung Sakita Moungmaithong Chi Chiu wang Liona C.Poon Department of Obstetrics and Gynaecology The Chinese University of HongKongHong Kong 999077China Department of Obstetrics and Gynaecology Queen Elizabeth HospitalHong Kong 999077China Department of Obstetrics and Gynaecology United Christian HospitalHong Kong 999077China Department of Obstetrics and Gynaecology Princess Margaret HospitalHong Kong 999077China Department of Obstetrics and Gynaecology Tuen Mun HospitalHong Kong 999077China Department of Obstetrics and Gynaecology Kwong Wah HospitalHong Kong 999077China Department of Obstetrics and Gynaecology Pamela Youde Nethersole Eastern HospitalHong Kong 999077China Department of Obstetrics and Gynaecology Queen Mary HospitalHong Kong 999077China

Objective:To report the clinical maternal and fetal outcomes of pregnant women with coronavirus disease 2019(COVID-19),along with any associated pregnancy complications,in Hong Kong,China,and to assess the impact of COVID-19 vaccination on these ***:This prospective registry-based observational study included pregnant women who were recruited through convenient sampling and had a laboratory-confirmed severe acute respiratory syndrome coronavirus 2 infection with a cycle threshold(Ct)value result available on admission to eight local hospitals in Hong Kong,*** on clinical symptoms,laboratory results,medical treatments,delivery timing and mode,and pregnancy complications were extracted from the Hospital Authority’s electronic medical record ***,fetal,and pregnancy outcomes were compared between unvaccinated pregnant women with COVID-19 and those who had received at least one dose of COVID-19 vaccine before *** continuous variables and categorical variables were analyzed using the Mann-Whitney U test and the Pearson’s chi-squared test respectively.A P value less than 0.05 was considered statistically ***:A total of 164 pregnant women were included,of whom 78(47.56%)were ***-19 was diagnosed before 28 weeks’gestation in 30(18.29%),while 134(81.71%)were diagnosed at or after 28 weeks’***-two(37.80%)women received at least one dose of COVID-19 *** were no significant differences between vaccinated and unvaccinated groups in the time interval between COVID-19 diagnosis and delivery,the Ct value,and the gestational age at infection onset or delivery(P>0.05).The majority of women were symptomatic at diagnosis regardless of vaccination status 55(88.71%)in vaccinated group vs.78(76.47%)in unvaccinated group(P=0.052).Symptoms did not significantly differ between groups except for cough(62.90%vs.47.06%,P=0.049).The overall rate of severe COVID-19 in pregnant women was *** t

关键词： COVID-19 Maternal outcomes Fetal outcomes Pregnancy complications Severe COVID-19

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不同轨道不平顺激励下线形关键点处列车走行性分析

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石家庄铁道大学学报（自然科学版） 2024年第1期37卷 74-80页

作者：李帅李向国王凯戴汀石家庄铁道大学道路与铁道工程安全保障省部共建教育部重点实验室河北石家庄050043 石家庄铁道大学土木工程学院河北石家庄050043

为探究不同轨道不平顺激励下,列车以更高速度经过缓圆点(HY)、曲中点(QZ)和圆缓点(YH)时,曲线超高、平面圆曲线半径及缓和曲线长度与列车速度之间的匹配关系,以中国某高速动车组为原型,建立了具有50个自由度的车-线动力学分析模型.研究... 详细信息

为探究不同轨道不平顺激励下,列车以更高速度经过缓圆点(HY)、曲中点(QZ)和圆缓点(YH)时,曲线超高、平面圆曲线半径及缓和曲线长度与列车速度之间的匹配关系,以中国某高速动车组为原型,建立了具有50个自由度的车-线动力学分析模型.研究结果表明,中国无砟轨道谱和德国低干扰谱对于列车在道路线形关键点处的动力响应随列车行驶速度和平面线形参数变化的趋势大致相同,但各关键点之间的响应程度不同;超高和圆曲线半径的变化对于列车动力响应的影响程度较缓和曲线长度大.研究结果可为高铁列车更高速度运行时的线路设计及线路平面参数之间的匹配关系提供一定的理论参考.

关键词：高速铁路轨道不平顺谱线路关键点线路平面参数动力学仿真

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复掺纤维对冷拌环氧沥青混合料性能的影响

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中国科技论文 2024年第4期19卷 461-467页

作者：王卡张垚康爱红张永健孔贺誉王本帅扬州大学建筑科学与工程学院江苏扬州225127

为了研究复掺纤维对冷拌环氧SMA-10沥青混合料性能的影响,采用玄武岩纤维(basalt fiber,BF)和聚酯纤维(polyes⁃ter fiber,PF)复掺,分析多种复掺纤维比例对冷拌环氧SMA-10沥青混合料高温性能、低温抗裂性、水稳定性、抗疲劳性能及抗老化... 详细信息

为了研究复掺纤维对冷拌环氧SMA-10沥青混合料性能的影响,采用玄武岩纤维(basalt fiber,BF)和聚酯纤维(polyes⁃ter fiber,PF)复掺,分析多种复掺纤维比例对冷拌环氧SMA-10沥青混合料高温性能、低温抗裂性、水稳定性、抗疲劳性能及抗老化性能的影响。通过数字图像处理和离散元仿真技术构建沥青混合料二维数值模型,提取离散元模型的骨架特征参数以确定纤维最佳掺配长度。复掺纤维掺量变化分别为0.3%PF、0.2%PF+0.1%BF、0.2%BF+0.1%PF、0.3%BF。结果表明:单掺0.3%玄武岩纤维的路用性能、抗疲劳性能、抗老化性能提升效果均优于单掺0.3%聚酯纤维。其中0.2%BF+0.1%PF的性能提升最佳,相较于单掺聚酯纤维和单掺玄武岩纤维,动稳定度分别由37058次·mm^(-1)和42000次·mm^(-1)增到45000次·mm^(-1),增长了21.4%和7.1%,抗弯拉强度由29.01 MPa和30.53 MPa上升为32.08 MPa,提高了10.6%和5.1%,650με应变条件疲劳寿命由163万次和183万次增至197万次,提高了20.9%和7.7%。在冷拌环氧SMA-10沥青混合料中复掺纤维可以提升其路用性能,玄武岩纤维和聚酯纤维复掺效果优于单掺。

关键词：道路工程冷拌环氧沥青离散元仿真 SMA-10 玄武岩纤维纤维复掺路用性能

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Complete androgen insensitivity syndrome caused by the c.2678C>T mutation in the androgen receptor gene:A case report

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World Journal of Clinical Cases 2021年第35期9卷 11036-11042页

作者： ka-Na wang Qing-Qing Chen Yi-Lin Zhu Chun-Lin wang Department of Pediatrics The First Affiliated Hospital of Zhejiang University School of MedicineHangzhou 310000Zhejiang ProvinceChina

BACKGROUND Androgen insensitivity syndrome is an X-linked recessive genetic disease caused by mutations in the androgen receptor gene(AR).However,the underlying molecular mechanisms for the majority of AR variants remain *** this study,we identified a point variant in three patients with complete androgen insensitivity syndrome(CAIS),summarized the correlation analysis,and performed a literature *** SUMMARY The proband was raised as a *** infancy,she was first referred to hospital with a right inguinal *** revealed the absence of a uterus and ovaries,and a testis-like structure located at the inguinal *** diagnostic workup detected a 46,XY karyotype,and fluorescence in situ hybridization analysis showed the presence of the SRY *** analysis revealed the excised tissue to be *** years later,she was admitted to our hospital with a lack of breast *** pubic hair and breasts were Tanner stage *** had normal female external *** hormone tests showed normal testosterone levels,low estradiol levels,and high gonadotropin *** two siblings underwent similar examinations,and all three had a rare hemizygous missense mutation in AR:c.2678C>*** vitro functional analyses revealed decreased nuclear translocation in AR-c.2678C>T mutation *** This case of CAIS was caused by an AR variant(c.2678C>T).Functional studies showed impaired nuclear translocation ability of the mutant protein.

关键词： Androgen insensitivity syndrome 46 XY disorders of sex development Variants Androgen receptor gene Ligand-binding domain Case report

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Effect of ulinastatin combined rivaroxaban on deep vein thrombosis in major orthopedic surgery

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Asian Pacific Journal of Tropical Medicine 2014年第11期7卷 918-921页

作者： Xi Yu Yi Tian ka wang Ying-Lin wang Guo-Yi Lv Guo-Gang Tian Department of Anesthesiology 2nd hospital of Tianjin Medical University Department of Anesthesiology Central South University Xiangya School of Medicine Affiliated Haikou Hospital

Objective:To explore the effect of ulinastatin(UTI) continuous infusion combined Rivaroxaban on the deep vein thrombosis in patients undergoing major orthopedic ***:Forty-five patients undergoing major orthopedic surgery were randomly divided into three groups:ulinastatin continuous infusion(Uc) group,ulinastatin single injection(Us) group and control(C) *** patients received patient-controlled intravenous analgesia(PCIA) after operation,and took Rivaroxaban 10 mg orally 12 hours after ***(5 000 U/kg)was given intravenously to both Uc and Us groups *** C was given isometric normal saline,group Uc was pumped UTI continuous intravenously at the end of surgery(10 000U/kg) to 48 hours through PCIA *** values of hematocrit(HCT),thrombomodulin(TM),Interleukin(IL-6),thrombin-antithrombin complex(TAT),D-Dimer(D-D) were normally tested before surgery(T1),at the end of the surgery(T2),12 hours(T3).24 hours(T4) and 48 hours(T5)after ***:Compared with T1,there was an upward tendency in TM,IL-6,TAT,and D-D after operation in group C group(P 0.05).Conclusions:During the perioperative period,ulinastatin continuous infusion combined Rivaroxaban can correct blood hypercoagulability through different approaches in patients undergoing major orthopedic surgery.

关键词： Ulinastatin Rivaroxaban DVT Orthopedic surgery

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不同直径玄武岩纤维对沥青混合料性能影响

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扬州大学学报（自然科学版） 2024年第1期27卷 74-78页

作者：康爱红王卡孔贺誉祁妍娟吴星寇长江扬州大学建筑科学与工程学院江苏扬州225127 江苏连徐高速公路有限公司江苏徐州221000 江苏润扬大桥发展有限公司江苏镇江212001

为研究玄武岩纤维直径参数对AC-13C型沥青混合料性能的影响,对7, 13, 25μm三种不同直径纤维改性后的沥青混合料的高温性能、低温性能和抗裂性能进行检测和对比分析,并结合滑移理论分析玄武岩纤维的直径对混合料中增强作用的影响.结果表... 详细信息

为研究玄武岩纤维直径参数对AC-13C型沥青混合料性能的影响,对7, 13, 25μm三种不同直径纤维改性后的沥青混合料的高温性能、低温性能和抗裂性能进行检测和对比分析,并结合滑移理论分析玄武岩纤维的直径对混合料中增强作用的影响.结果表明,不同直径的玄武岩纤维在不同程度上增强了沥青混合料的高温、低温、抗裂性能,在相同玄武岩纤维掺量下,纤维的直径越小,其对沥青混合料的增强效果越明显,这是由于纤维直径越小时滑移率越小,混合料性能增强效果越好.

关键词：玄武岩纤维纤维直径路用性能纤维复合材料滑移理论

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Selective deposition of a MOF at the spikes of Au nanostars for SERS detection

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Nano Research 2024年第10期17卷 9166-9173页

作者： Yi Liu ka Kit Chui Xinyue Xia Han Zhang Xiaolu Zhuo Jianfang wang School of Science and Engineering The Chinese University of Hong KongShenzhen 518172China Department of Physics The Chinese University of Hong KongShatinHong Kong 999077China School of Materials Science and Engineering Zhejiang Sci-Tech UniversityHangzhou 310000China

In the pursuit of advancing molecular sensing through surface-enhanced Raman spectroscopy(SERS),the combination of plasmonic nanoparticles and metal-organic frameworks(MOFs)has emerged as a highly effective approach to enhance the sensitivity and selectivity of SERS ***,most prior investigations have predominantly focused on MOF-coated plasmonic nanoparticles in core@shell or layer-by-layer configurations,leaving a notable knowledge gap in exploring alternative *** we present a facile method to construct a particle-on-mirror architecture by selectively coating a MOF,zeolitic imidazolate framework-8(ZIF-8),onto the tips of Au nanostars and subsequently depositing the resultant nanoparticles onto a Au *** design integrates the electric field enhancement at the sharp tips and nanogaps,along with the molecular enrichment function within the porous MOF immobilized at the tips and nanogaps,leading to a substantial boost in the SERS signal *** a unique SERS platform enables consistent and outstanding SERS performance for analytes of different *** work opens up a promising strategy for constructing multifunctional nanostructures for sensitive SERS detection in real-life scenarios.

关键词： electric field enhancement gold nanostars metal-organic frameworks molecular enrichment plasmon coupling surfaceenhanced Raman spectroscopy(SERS)substrates

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Modulation doping of p-type Cu_(12)Sb_(4)S_(13)toward improving thermoelectric performance

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Journal of Materials Science & Technology 2024年第4期171卷 71-79页

作者： Khak Ho Lim Mingquan Li Yu Zhang Yue Wu Qimin Zhou Qingyue wang Xuan Yang Pingwei Liu Wen-Jun wang ka Wai Wong ka Ming Ng Yu Liu Andreu Cabot Institute of Zhejiang University-Quzhou Quzhou 324000China College of Chemical and Biological Engineering Zhejiang UniversityHangzhou 310007China School of Chemistry and Chemical Engineering Hefei University of TechnologyHefei 230009China Materials Research Institute The Pennsylvania State UniversityUniversity ParkPA 16802USA Ostia Technologies Limited United Kingdom Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayHong KongChina ICREA Pg.Lluis Companys 23Barcelona 08010Spain Catalonia Energy Research Institute-IREC Sant Adria del BesosBarcelona 08930Spain

The commercial viability of thermoelectric(TE)devices relies heavily on two factors:cost reduction and efficiency *** this study,we first produce p-type Cu_(12)Sb_(4)S_(16-x)(x=0,3,4)using a low-temperature bottom-up approach and demonstrate Cu_(12)Sb_(4)S_(13)to show the best TE performance among the three tested ***,the TE energy conversion efficiency of Cu_(12)Sb_(4)S_(13)is further enhanced by optimizing its electronic band structure through the incorporation of small amounts of *** an optimal Te content of 5 mol%,more than a twofold increase in the TE figure of merit(zT)is *** gain insight into the mechanism of improvement on the transport properties of the mate-rial,we compare the interphase transport mechanism by incorporating nanodomains of different metals(Ag and Cu)into the Cu_(12)Sb_(4)S_(13)*** improved electrical conductivity obtained with Cu_(12)Sb_(4)S_(13)-Te nanocomposites is attributed to a charge flooding of the Cu_(12)Sb_(4)S_(13)*** contrast,excessive down-ward band-bending at the interphases of Ag/Cu metal-semiconductor drastically reduces the electrical ***,a weighted mobility(μw)analysis shows a dominant thermal activation of carri-ers in Cu_(12)Sb_(4)S_(13)-Te *** this material,a strong decrease in lattice thermal conductivity is also found,which is associated with a phonon-carrier scattering *** work shows the impor-tance of proper band-engineering in TE nanocomposites to decouple electrical and thermal transport to enhance TE performance,and the efficacy ofμw for electrical and thermal transport analysis.

关键词： Modulation doping Thermoelectric Interphase transport Charge flooding Phonon-carrier scattering

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Recent progress of self-supported air electrodes for flexible Zn-air batteries

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Journal of Energy Chemistry 2024年第2期89卷 110-136,I0004页

作者： Chen Xu Yanli Niu Vonika ka-Man Au Shuaiqi Gong Xuan Liu Jianying wang Deli Wu Zuofeng Chen School of Chemical Science and Engineering Tongji UniversityShanghai 200092China College of Environmental Science&Engineering Tongji UniversityShanghai 200092China Department of Science and Environmental Studies The Education University of Hong KongHong KongChina

Smart wearable devices are regarded to be the next prevailing technology product after smartphones and smart homes,and thus there has recently been rapid development in flexible electronic energy storage *** them,flexible solid-state zinc-air batteries have received widespread attention because of their high energy density,good safety,and *** bifunctional oxygen electrocatalysts are the primary consideration in the development of flexible solid-state zinc-air batteries,and self-supported air cathodes are strong candidates because of their advantages including simplified fabrication process,reduced interfacial resistance,accelerated electron transfer,and good *** review outlines the research progress in the design and construction of nanoarray bifunctional oxygen *** from the configuration and basic principles of zinc-air batteries and the strategies for the design of bifunctional oxygen electrocatalysts,a detailed discussion of self-supported air cathodes on carbon and metal substrates and their uses in flexible zinc-air batteries will ***,the challenges and opportunities in the development of flexible zinc-air batteries will be discussed.

关键词： Bifunctional electrocatalysts Oxygen reduction reaction Oxygen evolution reaction Self-supported air electrodes Flexible zinc-air batteries

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