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Boosting the catalytic activity toward oxygen reduction via a heterostructure of porous iron oxide-decorated 2D NiO/NG nanosheets

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Journal of Energy Chemistry 2024年第6期93卷 669-681,I0016页

作者： Kakali Maiti Matthew T.Curnan hyung Jun kim Kyeounghak kim Jeong Woo Han Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbuk 37673Republic of Korea Department of Materials Science and Engineering Research Institute of Advanced MaterialsSeoul National UniversitySeoul 08826Republic of Korea Department of Chemical Engineering Clean-Energy Research InstituteHanyang UniversitySeoul 04763Republic of Korea CSIR-Institute of Minerals and Materials Technology RRL CampusAcharya ViharBhubaneswarOdisha 751013India

As a noble metal substitute,two-dimensional(2D)hierarchical nano-frame structures have attracted great interest as candidate catalysts due to their remarkable advantages-high intrinsic activity,high electron mobility,and straightforward surface ***,they may replace Pt-based catalysts in oxygen reduction reaction(ORR)***,a simple method is developed to design hierarchical nano-frame structures assembled via 2D NiO and N-doped graphene(NG)*** procedure can yield nanostructures that satisfy the criteria correlated with improved electrocatalytic performance,such as large surface area,numerous undercoordinated atoms,and high defect ***,porous NG nanosheet architectures,featuring NiO nanosheets densely coordinated with accessible holey Fe_(2)O_(3) moieties,can enhance mesoporosity and balance *** improvements can facilitate charge transport and expose formerly inaccessible reaction sites,maximizing active site density *** functional theory(DFT)calculations reveal favored O_(2) adsorption and dissociation on Fe_(2)O_(3) hybrid structures when supported by 2D NiO and NG nanomaterials,given 2D materials donated charge to Fe_(2)O_(3) active *** systematic studies reveal that synergistic contributions are responsible for enriching the catalytic activity of Fe_(2)O_(3)@NiO/NG in alkaline media-encompassing internal voids and pores,unique hierarchical support structures,and concentrated N-dopant and bimetallic atomic ***,this work expands the toolbox for designing and synthesizing highly efficient 2D/2D shelled functional nanomaterials with transition metals,endeavoring to benefit energy conversion and related ORR applications.

关键词： N-doped graphene Holey Fe_(2)O_(3)nanocrystals NiO nanosheets High catalytic performance ORR

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Genome wide expression analysis of the effect of Socheongryong Tang in asthma model of mice

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Journal of Traditional Chinese Medicine 2015年第2期35卷 168-174页

作者： Chi-Yeon Lim hyung-Woo kim Bu-Yeo kim Su-In Cho College of Medicine Dongguk University School of Korean Medicine Pusan National University Herbal Medicine Research Division Korea Institute of Oriental Medicine

OBJECTIVE:To investigate the molecular effect of Socheongryong Tang(SCRT,Xiaoqinglong Tang in Chinese) on whole genome level in asthma mouse model by microarray ***:Asthma was induced by intranasal instillation of ovalbumin in *** administration of SCRT on asthma-induced mouse,the expression of genes in lung tissue was measured using whole genome *** functional implication of differentially expressed genes was performed using ontological analysis and the similarity of promoter structure of genes was also ***:Treatment of SCRT restored expression level of many up- or down-regulated genes in asthma model,and this recovery rate means SCRT could regulate a set of genes having specific TFBS binding ***:In this study,we identified a set of genes subjected to similar regulation by SCRT in asthma model in mice.

关键词： Asthma Transcription factors Microarray analysis Genome wide expression Socheongryong Tang(Xiaoqinglong Tang)

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Prominent cycling reversibility and kinetics enabled by CaTiO3 protective layer on Zn metal for aqueous Zn-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 245-258页

作者： Gaeun Lee Yong Nam Ahn Seongjoon So Chanwoo Park Jong-Seong Bae Taehyun Park Il Tae kim Jaehyun Hur School of Chemical Biological and Battery Engineering Gachon University Seongnam Busan Center Korea Basic Science Institute

Aqueous Zn-ion batteries （AZIBs） have received considerable attention owing to their various advantages such as safety,low cost,simple battery assembly conditions,and high ionic ***,they still suffer from serious problems,including uncontrollable dendrite growth,corrosion,hydrogen evolution reaction （HER） from water decomposition,electrode passivation,and unexpected *** creation of a uniform artificial nanocrystal layer on the Zn anode surface is a promising strategy for resolving these ***,we propose the use of a perovskite CaTiO3（CTO） protective layer on Zn（CTO@Zn） as a promising approach for improving the performance of *** CTO artificial layer provides an efficient pathway for Zn ion diffusion towards the Zn metal because of the high dielectric constant （εr=180） and ferroelectric characteristics that enable the alignment of dipole moments and redistribute the Zn2+ions in the CTO *** avoiding the direct contact of the Zn anode with the electrolyte solution,the uneven dendrite growth,corrosion,parasitic side reactions,and HER are mitigated,while CTO retains its mechanical and chemical robustness during ***,CTO@Zn demonstrates an improved lifespan in a symmetric cell configuration compared with bare ***@Zn shows steady overpotential （～68 m V） for 1500 h at 1 mA cm-2/0.5 mA h cm-2,excelling bare ***,when paired with the V2O5-C cathode,the CTO@Zn//V2O5-C full battery delivers 148.4 mA h g-1（based on the mass of the cathode） after 300 *** study provides new insights into Zn metal anodes and the development of high-performance AZIBs.

关键词： Artificial layer Dielectric constant Zn metal anode Zinc aqueous battery

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Cryptogenic organizing pneumonia associated with pregnancy:A case report

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World Journal of Clinical Cases 2022年第6期10卷 1946-1951页

作者： Young joo Lee Young Sun kim Department of Obstetrics and Gynecology Kyung Hee University Medical CenterSeoul 02447South Korea

BACKGROUND Cryptogenic organizing pneumonia(COP),formerly known as bronchiolitis obliterans organizing pneumonia,is an extremely rare disease in *** this case,we report on COP diagnosed in recurrent pneumonia that does not respond to antibiotics in pregnant *** SUMMARY A 35-year-old woman with no prior lung disease presented with concerns of chest pain with cough,sputum,dyspnea,and mild fever at 11 wk’*** was diagnosed with community-acquired pneumonia and treated with antibiotics;her symptoms improved *** weeks after discharge,she was readmitted with aggravated *** computed tomography demonstrated multifocal patchy airspace consolidation and ground-glass opacities at the basal segments of the right lower lobe,at the lateral basal segment of the lower lobe,and at the lingular segment of the left upper *** lavage revealed an increased lymphocyte count and a decreased CD4/CD8 ***(0.5 mg/kg/d)was administered for 10 d after the second *** improved after 3 d of steroid treatment and other symptoms improved on the 5th day of steroid ***-delivery transbronchial lung biopsy further revealed the presence of granulation tissue with fibroblasts in smallbronchiole *** This case suggests that it is important to differentiate COP from atypical pneumonia in the deteriorated condition despite antibiotic treatment.

关键词： Antibiotics Bronchiolitis obliterans organizing pneumonia Corticosteroid Cryptogenic organizing pneumonia Pregnancy Case report

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Flapping dynamics of a flexible propulsor near ground

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Acta Mechanica Sinica 2016年第6期32卷 991-1000页

作者： Jaeha Ryu Sung Goon Park Boyoung kim hyung Jin Sung Department of Mechanical Engineering Korea Advanced Institute of Science and Technology

The flapping motion of a flexible propulsor near the ground was simulated using the immersed boundary method. The hydrodynamic benefits of the propulsor near the ground were explored by varying the heaving frequency (St) of the leading edge of the flexible propulsor. Propulsion near the ground had some advantages in generating thrust and propelling faster than propulsion away from the ground. The mode analysis and flapping amplitude along the Lagrangian coordinate were examined to analyze the kinematics as a function of the ground proximity (d) and St. The trailing edge amplitude (\(a_\mathrm{tail}\)) and the net thrust (\(\overline{{F}}_x\)) were influenced by St of the flexible propulsor. The vortical structures in the wake were analyzed for different flapping conditions.

关键词： Flexible propulsor Ground effect Immersed boundary method Mode analysis

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Management of antiviral drug resistance in chronic hepatitis B

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World Journal of Gastroenterology 2014年第33期20卷 11641-11649页

作者： Ki Bae Bang Hong joo kim Department of Internal Medicine Sungkyunkwan University Kangbuk Samsung Hospital Seoul 110-746 South Korea

Rescue antiviral treatment for patients with resistance to preexisting nucleos(t)ide analogues remains a clinical challenge. The correct choice of a first-line treatment of high potency and with a high genetic barrier to achieve sustained long-term suppression of viral replication provides the best chance of preventing treatment failure and the emergence of drug resistance. The management of treatment failure and drug resistance requires a precise and accurate clinical and virologic monitoring. Combination treatment with antiviral drugs that belong to different groups is associated with a lower chance of developing resistance to rescue drugs. To guarantee better control of viral replication in patients with drug resistance, the addition of another drug without a cross resistance profile should be given as early as possible, preferably at the time when genotypic resistance emerges. Long-term surveillance for treatment efficacy and possible emergence of drug resistance should be continued to prevent the emergence of multidrug-resistant strains.

关键词： Chronic hepatitis B Antiviral resistance Rescue treatment Multidrug resistance Cross resistance

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Development of single-action,two-step clinching system using finite element analysis

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中国有色金属学会会刊：英文版 2009年第B9期19卷 266-270页

作者： Seong-Wook LEE Tae-hyung kim Geun-Jo HAN Power & Industrial Systems R&D Center Hyosung Corporation Department of Mechanical Engineering Department of Mechanical Engineering Dong-A University

Traditional manufacturing processes for bending and combining the upper and lower heat insulation plates for a car catalytic converter need two kinds of bending dies. This study was carried out to develop a single-action, two-step clinching system for clinching heat insulation plates. To design the operating mechanism for this clinching system, finite element analysis was used to estimate the bending load needed and to predict the bent shape of the heat insulation plate. Then a recovery and cushioning system was designed for the bending die. It is expected that this new process will improve the manufacturing quality of heat insulation plates and will reduce manufacturing cost. And a higher value-added technique for mold and pressing systems was introduced.

关键词：缓冲系统有限元分析开发汽车催化转化器单动模具技术隔热板板弯曲

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Quantification of Tc-99m-ethyl cysteinate dimer brain single photon emission computed tomography images using statistical probabilistic brain atlas in depressive end-stage renal disease patients:Correlation with disease severity and symptom factors

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Neural Regeneration Research 2012年第27期7卷 2151-2159页

作者： Heeyoung kim In joo kim Seong-Jang kim Sang Heon Song Kyoungjune Pak Keunyoung kim Department of Nuclear Medicine Pusan National University HospitalBusanRepublic of Korea Biomedical Research Institute Pusan NationalBusanRepublic of Korea Department of Internal Medicine Pusan National University HospitalBusanRepublic of Korea

This study adapted a statistical probabilistic anatomical map of the brain for single photon emission computed tomography images of depressive end-stage renal disease patients. This research aimed to investigate the relationship between symptom clusters, disease severity, and cerebral blood flow. Twenty-seven patients （16 males, 11 females） with stages 4 and 5 end-stage renal disease were enrolled, along with 25 healthy controls. All patients underwent depressive mood assessment and brain single photon emission computed tomography. The statistical probabilistic anatomical map images were used to calculate the brain single photon emission computed tomography counts. Asymmetric index was acquired and Pearson correlation analysis was performed to analyze the correlation between symptom factors, severity, and regional cerebral blood flow. The depression factors of the Hamilton Depression Rating Scale showed a negative correlation with cerebral blood flow in the left amygdale. The insomnia factor showed negative correlations with cerebral blood flow in the left amygdala, right superior frontal gyrus, right middle frontal gyrus, and left middle frontal gyrus. The anxiety factor showed a positive correlation with cerebral glucose metabolism in the cerebellar vermis and a negative correlation with cerebral glucose metabolism in the left globus pailidus, right inferior frontal gyrus, both temporal poles, and left parahippocampus. The overall depression severity （total scores of Hamilton Depression Rating Scale） was negatively correlated with the statistical probabilistic anatomical map results in the left amygdala and right inferior frontal gyrus. In conclusion, our results demonstrated that the disease severity and extent of cerebral blood flow quantified by a probabilistic brain atlas was related to various brain areas in terms of the overall severity and symptom factors in end-stage renal disease patients.

关键词： single photon emission computed tomography end-stage renal disease depression statisticalprobabilistic brain atlas disease severity cerebral blood flow symptom brain neural regeneration

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Fatigue strength evaluation of self-piercing riveted joints of AZ31 Mg alloy and cold-rolled steel sheets

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Journal of Magnesium and Alloys 2020年第1期8卷 241-251页

作者： Se-hyung Kang Dong-Woon Han Ho-Kyung kim Graduate School Seoul National University of Science and TechnologySeoul01811South Korea Department of Mechanical and Automotive Engineering Seoul National University of Science and TechnologySeoul01811 South Korea

The application of magnesium alloys to automobiles is increasing due to their superior specific strength and specific *** this study,an upper sheet of AZ31 magnesium alloy and a lower sheet of cold-rolled steel were joined by self-piercing riveting(SPR),a method commonly used to join automotive panels.A cross-shaped specimen was fabricated with a punching force of 35 kN,which exhibited the best joint strength for the SPR joint specimen *** and fatigue strengths were evaluated using cross-shaped specimens at loading angles of 0°,45°,and 90°.The load amplitude corresponding to the fatigue endurance limit was assumed to be at 106 cycles,and the fatigue ratios(=fatigue endurance limit/static strength)at the loading angles of 0°,45°,and 90°are 22%,13%,and 9%,*** all three loading angle specimens,fatigue cracks initiated at the triple point where the rivet shank,the upper sheet and the lower sheet are in contact with each other,with the cracks propagating through the thickness of the upper sheet and ultimately leading to *** fatigue lifetimes were evaluated through the von-Mises stress,maximum principal stress,and equivalent stress intensity *** was found that the fatigue lifetimes could be evaluated most appropriately through the maximum principal stress.

关键词： Self-piercing riveting Magnesium alloy Fatigue strength Maximum principal stress Fatigue lifetime

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Counter-balancing effects of Si on C partitioning and stacking fault energy of austenite in 10Mn quenching and partitioning steel

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Journal of Materials Science & Technology 2022年第3期98卷 248-257页

作者： Dong Hwi kim Jee-Hyun Kang Hojun Gwon joo Hyun Ryu Sung-joon kim Graduate Institute for Ferrous Technology Pohang University of Science and TechnologyPohang 37673Republic of Korea School of Materials Science and Engineering Institute of Materials TechnologyYeungnam UniversityGyeongsan 38541Republic of Korea POSCO Technical Research Laboratories POSCOGwangyang 57807Republic of Korea

Silicon is an essential alloying element in quenching and partitioning(Q&P)steels,because it is known to suppress carbide precipitation during partitioning step and promote carbon partitioning to stabilize *** 2 wt%Si was added to 10Mn-2Al-0.2C steel,the size and fraction of the carbides formed during partitioning became smaller than in the Si-free ***,the suppression of carbide formation promoted C partitioning into austenite as ***,austenite stability was always lower with Si under the equivalent partitioning condition because Si effectively decreased the stacking fault energy of *** partitioning progressed,the both yield and tensile strengths of the Si-added steel exceeded that of the Si-free steel with the similar ductility *** was because Si was an effective solid solution strengthener,and the austenite in the Si-added steel exhibited the appropriate stability to gradually transform into martensite throughout the *** resulting strengthening effect compensated for the softening caused by martensite ***,strain hardening rate decreased continuously throughout deformation,which resulted in high tensile strength and ductility.

关键词： Steels Q&P steel Silicon Austenite stability Tensile deformation Stacking fault energy Medium Mn steel

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