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A review on biomedical and dental applications of cerium oxide nanoparticles——Unearthing the potential of this rare earth metal

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Journal of Rare Earths 2023年第11期41卷 1645-1661,I0001页

作者： Lalitha S Jairam Akshatha Chandrashekar T.Niranjana Prabhu sunil babu kotha M.S.Girish Indira Mysuru Devraj M.Dhanya Shri k.Prashantha Department of Pediatric and Preventive Dentistry Faculty of Dental SciencesM.S.Ramaiah University of Applied SciencesNew BEL RoadMSR NagarBangalore560054India Department of Chemistry Faculty of Mathematical and Physical SciencesM.S.Ramaiah University of Applied SciencesNo.470-PIV PhasePeenya Industrial AreaBangalore560058India Department of Preventive Dentistry Pediatric Dentistry DivisionCollege of DentistryRiyadh Elm UniversityRiyadhKingdom of Saudi Arabia Department of Pediatric and Preventive Dentistry JSS Dental College&HospitalJSS Academy of Higher Education&ResearchMysuruIndia Center for Research and Innovation Adichunchanagiri School of Natural SciencesAdichunchanagiri UniversityBGSITB.G.Nagara571448India

Nanotechnology deals with particles ranging from 1 to 100 nm in size called as *** nano particles exhibit unique properties which find an application in many industries and medical fields.A growing body of evidence points out the newer developing technologies adopted in the field of medicine in terms of target therapies,imaging systems,drug deliveries,*** through the incorporation of *** oxide nanoparticles have gained attention in the last decade due to exceptional properties such as redox activity,biofilm inhibition,antibacterial activity,anti-inflammatory activity,*** method of synthesis of cerium oxide nanoparticles plays a pivotal role in its *** exhibits redox properties and catalytic activity and thus has found its use in biomedical *** are incorporated into dental materials such as restorative cements/sealants,adhesives,and denture systems to improve their *** the various metal oxide nanoparticles,ce rium oxide nanoparticles(CeO_(2)NPs)are known to exhibit lower toxicity to mammalian cells and possess unique antibacterial *** addition,they exhibit potent properties such as antitumor,antiinflammatory,antibacterial activities,and functions as an ***_(2)NPs have excellent scavenging properties for reactive oxygen species,which is why they are being considered for therapeutic *** this review,various methods of synthesis of CeO_(2)NPs are *** factors that determine the particle size and morphology of these materials are important for biomedical and dental *** is given to preparation methods and variables such as calcination temperature,which have a profound effect on particle size and *** article also presents various applications of CeO_(2)NPs in the biomedical and dental fields.

关键词： Cerium oxide nanoparticles Synthesis Antibacterial activity Biomedical applications Dental applications Rare earths

Preclinical animal studies in ischemic stroke:Challenges and some solutions

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Animal Models and Experimental Medicine 2021年第2期4卷 104-115页

作者： sunil k.Narayan Simy Grace Cherian Prakash babu Phaniti Saravana babu Chidambaram A.Hannah Rachel Vasanthi Murugesan Arumugam Comprehensive Stroke Care and Neurobiology Centre Department of NeurologyJawaharlal Institute of Postgraduate Medical Education and ResearchPuducherryIndia Department of Biotechnology&School of Medical Sciences University of HyderabadHyderabadIndia Department of Pharmacology JSS Medical CollegeMysoreIndia Department of Biotechnology School of Life scienceUniversity of PondicherryPondicherryIndia

Despite the impressive efficacies demonstrated in preclinical research,hundreds of potentially neuroprotective drugs have failed to provide effective neuroprotec-tion for ischemic stroke in human clinical *** of a powerful animal model for human ischemic stroke could be a major reason for the failure to develop successful neuroprotective drugs for ischemic *** review recapitulates the available cerebral ischemia animal models,provides an anatomical comparison of the circle of Willis of each species,and describes the functional assessment tests used in these ischemic stroke *** distinct differences between human ischemic stroke and experimental stroke in available animal models is *** animal models more closely resembling human strokes,better techniques in functional out-come assessment and better experimental designs generating clearer and stronger evidence may help realise the development of truly neuroprotective drugs that will benefit human ischemic stroke *** may involve use of newer molecules or revisiting earlier studies with new experimental *** of any resultant successes may then be tested in human clinical trials with greater confidence and optimism.

关键词： cerebral ischemia circle of Willis focal ischemic models functional assessment tests neuroprotection preclinical model

Comparative investigation of coal-and oil-fired boilers based on emission factors,ozone and secondary organic aerosol formation potentials of VOCs

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Journal of Environmental Sciences 2020年第6期32卷 245-255页

作者： Hsi-Hsien Yang sunil kumar Gupta Narayan babu Dhital Lin-Chi Wang Suresh Pandian Elumalai Department of Environmental Engineering and Management Chaoyang University of TechnologyTaichungChinese Taipei Department of Applied Chemistry Chaoyang University of TechnologyTaichungChinese Taipei Department of Environmental Science Patan Multiple CampusTribhuvan UniversityLalitpurNepal Department of Environmental Engineering Chung Yuan Christian UniversityTaoyuanChinese Taipei Department of Environmental Science and Engineering Indian Institute of Technology(Indian School of Mines)DhanbadIndia

Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate *** this study,VOC emission factors,O3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3)and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired *** factors ofΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg)than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired ***,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired *** OFP ranged from 3.99 to 11.39 mg-O3/kg for coal-fired *** oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O3/***,total secondary organic aerosol potential(SOAP)ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively.

关键词： Coal-and oil-fired boilers Volatile organic compounds Emission factor Ozone formation potential Secondary organic aerosol potential

Enhanced visible-light-driven photocatalysis of Bi2YO4CI heterostructures functionallized by bimetallic RhNi nanoparticles

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Frontiers of Materials Science 2018年第4期12卷 405-414页

作者： Palepu Teja RAVINDAR Vidya Sagar CHOPPELLA Anil kumar MOkSHAGUNDAM M.kIRUBA sunil G.babu korupolu Raghu babu L.John BERCHMANS Gosipathala SREEDHAR Electropyro Metallurgy Division CSIR-Central Electrochemical Research InstituteKaraikudi 630003Tamil NaduIndia Department of Engineering Chemistry Andhra University Collge of EngineeringAndhra UniversityVisakhapatnam-530003India School of Bio-Sciences and Biotechnology Babasaheb Bhimrao Ambedkar UniversityLucknow-226025India

Bismuth-based Sillen-Aurivillius compounds are being explored as efficient photocatalyst materials for the degradation of organic pollutants due to their unique layered structure that favours effective separation of electron-hole pairs. In this work, we synthesized Sillen-Aurivillius-related Bi2YO4Cl with the bandgap of 2.5 eV by a simple solid-state reaction and sensitized with rhodium nickel (RhNi) nanoparticles (NPs) to form the RhNi/Bi2YO4Cl heterostructure. Photocatalytic activities of BiOCl, Bi2YO4Cl and the RhNi/Bi2YO4Cl heterostructure were examined for the degradation of rhodamine- 6G under visible-light illumination. Results demonstrated that the photocatalytic dye degradation efficiency of RhNi/Bi2YO4Cl heterostructures is higher than those of BiOCl and Bi2YO4Cl, attributed to the synergistic molecular-scale alloying effect of bimetallic RhNi NPs. The plausible mechanism for the degradation of rhodamine-6G and the effective electron-hole pair utilization mechanism were discussed.

关键词： BiOCl Bi 2 YO 4 Cl RhNi catalyst rhodamine-6G photocatalysis

Conservation and Management of Forest Resources in India: Ancient and Current Perspectives

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Natural Resources 2015年第4期6卷 256-272页

作者： M. S. Umesh babu sunil Nautiyal Centre for Ecological Economics and Natural Resources Institute for Social and Economic Change Bangalore India

This paper brings out the issues related to natural resource exists, management and erosion right from the ancient to modern era. The natural resource such as forests and forest products were found as a basic source of survival for living organisms during the initial period. Later, the natural resources started degrading slowly and steadily due to increased human activities. In the beginning, natural resources were the primary assets for the growth of agriculture, industry, urbanization etc. Subsequently, increased anthropogenic activities started degrading the forest cover on a large scale through extending the agricultural land scape and other developmental activities in the country. The importance of traditional knowledge regarding resource conservation, protection of sacred grooves, endangered species etc. started declining in modern India. Innovativeness and policy framework for resource conservation and utilization became unfriendly in addition to gradual decline of community management. The key findings of the study point to major gaps existing such as between line departments and institutions in the promotion and management of forests, human welfare, agriculture, animal husbandry etc. Moreover, people tend to be more inclined towards the utilization of natural resources rather than conservation. From an observational and practical point of view, the natural resource has been declining rapidly in India. Therefore, this study strongly suggests that a due attention be directed towards developing people-friendly and environment friendly conservation strategies.

关键词： Theory Practice Natural Resources Approaches Management

A Study on Vibrational Spectra of PH3 and NF3: An Algebraic Approach

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Open Journal of Microphysics 2013年第2期3卷 47-51页

作者： S. R. karumuri G. Srinivas Vijayasekhar Jaliparthi k. sunil babu V. Sundara Siva kumar A. Hanumaiah Department of Electronics & Instrumentation Engineering Lakireddy Bali Reddy College of Engineering Vijayawada India Department of Physics KL University Guntur India Research Scholar Department of Mathematics Jawaharlal Nehru Technological University Kakinada India Department of Physics Miracle Engineering College Bhogapuram India Department of Electronics & Instrumentation Rajeev Gandhi Memorial Engineering College Nandyal India Department of Physics Lara’s Vignan Institute of Technology and Science Vadlamudi India

With the new theoretical approach i.e. lie algebraic approach, we have calculated the infrared spectra of Phosphine in the range from 3000 cm-1 to 9500 cm-1 and Nitrogen Trifluoride in the range from 900 cm-1 to 4500 cm-1. The model Hamiltonian, so constructed, seems to describe the P-H and N-F stretching modes accurately with only four numbers of parameters.

关键词： Vibrational Spectra Lie Algebraic Model Hamiltonian

Joining of AZ31 and AZ91 Mg alloys by friction stir welding

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Journal of Magnesium and Alloys 2015年第4期3卷 330-334页

作者： B.Ratna sunil G.Pradeep kumar Reddy A.S.N.Mounika P.Navya Sree P.Rama Pinneswari I.Ambica R.Ajay babu P.Amarnadh Department of Mechanical Engineering Rajiv Gandhi University of Knowledge Technologies(AP-IIIT)Nuzvid 521202India Department of Mechanical Engineering Vignana Bharathi Institute of TechnologyHyderabad 501301India

Two dissimilar magnesium(Mg)alloy sheets,one with low aluminium(AZ31)and another with high aluminium(AZ91)content,were successfully joined by friction stir welding(FSW).The effect of process parameters on the formation of hot cracks was investigated.A sound metallurgical joint was obtained at optimized process parameters(1400 rpm with 25 mm/min feed)which contained fine grains and distributed β(Mg_(17)Al_(12))phase within the nugget *** increasing trend in the hardness measurements has also confirmed more amount of dissolution of aluminium within the nugget zone.A sharp interface between nugget zone and thermo mechanical affected zone(TMAZ)was clearly noticed at the AZ31 Mg alloy side(advancing)but not on the AZ91 Mg alloy side(retreating).From the results it can be concluded that FSW can be effectively used to join dissimilar metals,particularly difficult to process metals such as Mg alloys,and hot cracking can be completely eliminated by choosing appropriate process parameters to achieve sound joint.

关键词： Dissimilar metal joining Magnesium alloys Friction stir welding AZ31 AZ91