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Chinese Journal of Chemistry 2011年第7期29卷 1483-1488页

作者： Muthyala, Manoj kumar rao, v. kameswara kumar, Anil Department of Chemistry Birla Institute of Technology and Science Pilani 333 031 India

A facile and efficient one-pot three-component synthesis of bis（5-methyl-2-furyl）methanes has been achieved via the reaction of 2-methylfuran with a series of aliphatic and aromatic aldehydes and aliphatic ketones in presence of copper（II） triflate under solvent free conditions. The bis（5-methyl-2-furyl）methanes were obtained in 34%--72% yields and the catalyst was recycled up to four successive cycles without much loss in catalytic activity.

关键词： Lewis acid copper(II) triflate 2-methylfuran bis(5-methyl-2-furyl)methane multicomponent condensation solvent free condition

Microstructure and Mechanical Properties of Friction Stir Lap Welded Aluminum Alloy AA2014

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Journal of Materials Science & Technology 2012年第5期28卷 414-426页

作者： S. Babu G.D. Janaki Ram P.v. venkitakrishnan G. Madhusudhan Reddy k. Prasad rao Dept. of Metallurgical and Materials Engineering Indian Institute of Technology Madras Chennai India Liquid Propulsion Systems Centre Indian Space Research Organisation Tiruvananthapuram India Defence Metallurgical Research Laboratory Hyderabad India

Friction stir lap welds were produced in 3 mm thick Alclad sheets of Al alloy 2014-T4 using two different tools （with triangular and threaded taper cylindrical pins）. The effects of tool geometry on weld microstructure, lap-shear performance and failure mode were investigated. The pin profile was found to significantly influence the hook geometry, which in turn strongly influenced the joint strength and the failure mode. Welds produced in alloy 2014-T4 Alclad sheets by using triangular and threaded taper cylindrical tools exhibited an average lap-shear failure load of 16.5 and 19.5 kN, respectively, while the average failure load for standard riveted joints was only 3.4 kN. Welds produced in alloy 2014-T6 Alclad sheets and in alloy 2014-T4 bare sheets （i.e., no Alclad） were comparatively evaluated with those produced in alloy 2014-T4 Alclad sheets. While the welds made （with threaded taper cylindrical tool） in T6 and T4 conditions showed very similar lap-shear failure loads, the joint efficiency of the welds made in T6 condition （43%） was considerably lower （because of the higher base material strength） than those made in T4 condition （51%）. The Alclad layers were found to present no special problems in friction stir lap welding. Welds made with triangular tool in alloy 2014-T4 Alclad and bare sheets showed very similar lap-shear failure loads. The present work provides some useful insights into the use of friction stir welding for joining Al alloys in lap configuration.

关键词： Aluminum alloys Friction stir welding Lap joints Lap-shear testing

Prediction of photovoltaic power output based on different non-linear autoregressive artificial neural network algorithms

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Global Energy Interconnection 2022年第2期5卷 226-235页

作者： Adriano Pamain P.v.kanaka rao Frank Nicodem Tilya Department of Physics The University of DodomaDodomaTanzania

Prediction of power output plays a vital role in the installation and operation of photovoltaic *** this paper,two photovoltaic module technologies,amorphous silicon and copper indium gallium selenide installed outdoors on the rooftop of the University of Dodoma,located at 6.5738°S and 36.2631°E in Tanzania,were used to record the power output during the winter *** average data of ambient temperature,module temperature,solar irradiance,relative humidity,and wind speed recorded is used to predict the power output using a non-linear autoregressive artificial neural *** consider the Levenberg-Marquardt optimization,Bayesian regularization,resilient propagation,and scaled conjugate gradient algorithms to understand their abilities in training,testing and validating the data.A comparison with reference to the performance indices:coefficient of determination,root mean square error,mean absolute percentage error,and mean absolute bias error is drawn for both *** to the findings of our investigation,the predicted results are in good agreement with the experimental *** the algorithms performed better,and the predicted power out of both modules using the Bayesian regularization algorithm is observed to exhibit good processing capabilities compared to the other three algorithms that are evident from the measured performance indices.

关键词： Photovoltaic Artificial neural network Training algorithms Ambient parameters Power output

Ca(Ⅱ)、Mg(Ⅱ)和Zn(Ⅱ)与丙二醇-水混合体系中L-多巴的二元配合物的生成平衡(英文)

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无机化学学报 2013年第6期29卷 1235-1242页

作者： Santhee Devi k v Ramaraju B Nageswara rao G 安得拉大学无机和分析化学系

在303 k恒温条件下，以NaCl为电解质保持离子强度为0．16mol·L-1，用pH滴定法研究了M（Ⅱ）-Dopa（多巴）二元配合物在0-60％（v/v）的丙二醇（PG）-水体系中的生成平衡。在PG-水体系中，Ca（Ⅱ）和Mg（Ⅱ）的典型配合物为MLH，ML2，M... 详细信息

在303 k恒温条件下，以NaCl为电解质保持离子强度为0．16mol·L-1，用pH滴定法研究了M（Ⅱ）-Dopa（多巴）二元配合物在0-60％（v/v）的丙二醇（PG）-水体系中的生成平衡。在PG-水体系中，Ca（Ⅱ）和Mg（Ⅱ）的典型配合物为MLH，ML2，ML2H和ML2H2，而Zn（Ⅱ）的典型配合物为ML，MLH，ML2，ML2H和ML2H2。根据静电和非静电力解释了稳定常数随介质的介电常数而变化的倾向。还讨论了在不同组成的丙二醇（PG）-水体系中配合物物种随pH值变化的情况。

关键词：二元物种金属配体丙二醇 pH滴定

ETP-AkEP: enhanced three-party authenticated key exchange protocols for data integrity in cloud environments

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Journal of Control and Decision 2023年第1期10卷 126-133页

作者： kalluri Rama krishna C.v.Guru rao Faculty of Informatics Osmania UniversityHyderabadIndia School of Computer Science&Artificial Intelligence S.R.UniversityWarangalIndia

With key exchange protocols, a secure session key is generated between two remote users, andservers and exchanged between them. It is generally used to prevent unauthorised users fromgaining access to sensitive data. This article presents an enhanced three-party authenticated keyexchange protocols (ETP-AkE) protocol that does not depend on symmetric key encryption andinstead uses asymmetric key encryption. A key component of the proposed ETP-AkE protocol isusing elliptic curve encryption in conjunction with a one-way hash function. Its integrity certificationwas confirmed via the usage of the AvISPA tool package. Our proposed protocol is intendedto protect against various security threats, including the man-in-the-middle assault, the parallelattack, and the key-compromise attack, among others.

关键词： ECC hash function cloud integrity third party key exchange

Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO2 nano material under visible light irradiation

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Chinese Journal of Chemical Engineering 2019年第7期27卷 1630-1641页

作者： k.v.Divya Lakshmi T.Siva rao J.Swathi Padmaja I.Manga Raju M.Ravi kumar Department of Inorganic and Analytical Chemistry Andhra University

Undoped and Ni–S co-doped mesoporous TiO2 nano materials were synthesized by using sol–gel *** characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical *** characterization results of the samples revealed that all the samples exhibited anatase phase(XRD),decreasing band gap(2.68 ev)(Uv–vis-DRS),small particle size(9.2 nm)(TEM),high surface area(142.156 m^2·g^-1)(BET),particles with spherical shape and smooth morphology(SEM);there is a frequency shift observed for co-doped sample(FT-IR)and the elemental composition electronic states and position of the doped elements(Ni and S)in the TiO2 lattice analyzed by XPS and *** results supported the photocatalytic degradation of Bismarck Brown Red(BBR)achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus(MTCC-3160),Pseudomonas fluorescence(MTCC-1688)under visible light irradiation.

关键词： Sol–gel Ni–S co-doped TiO2 Photocatalysis under visible light Degradation of Bismarck Brown Red Antibacterial activity

Antihyperglycemic activity,antihyperlipedemic activity,haematological effects and histopathological analysis of Sapindus mukorossi Gaerten fruits in streptozotocin induced diabetic rats

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Asian Pacific Journal of Tropical Medicine 2012年第7期5卷 518-522页

作者： Neeraj verma G Amresh P k Sahu Neelam Mishra Anil P Singh Ch v rao Department of Pharmacology Goel Institute of Pharmacy & SciencesFaizabad Road(Near Indira Canal) Lucknow 227105Uttar PradeshIndia Department of Pharmacology School of Pharmaceutical SciencesSiksha 'O' Anusandhan UniversityKalinga NagarGhatikiaBhubaneswar 751003 OrissaIndia Department of Pharmacology Pharmacognosy and Ethnopharmacology DivisionNational Botanical Research Institute(Council of Scientific and Industrial Research)Rana Pratap MargP.O.Box No.436Lucknow 226001Uttar PradeshIndia

Objective:To investigate the antihyperglycemic and antihyperlipidemie properties of hydroalcoholic extract of fruits of Sapindus mukorossi Caerlen and its beneficial effect on haeniatological parameters with histopathological analysis in streptpzotocin induced diabetic ***:Sapindus mukorossi fruits extract(250 and 500 mg/kg body weight) and standard drug glybenclamide(0.5 mg/kg body weight) were administered to diabetic *** of extract on hyperglycemia,hyperlipidemia and hematological parameters was studied in diabetic *** changes in diabetic rat pancreas were also observed after extract and glybenclamide ***:Daily oral administration of Sapindus mukorossi fruits extract(250 and 500 mg/kg body weight) and glybenclamide for 20 days showed beneficial effects on blood glucose level(Pvorable effect on the histopathological changes of the pancreas in streptozotocin induced ***: These findings reveal that the hydroalcoholic extract of Sapindus mukorossi fruits extract possesses antihyperglycemic and antihyperlipidemie *** *** extract can prevent various complications of diabetes and improve some haeniatological parameters.

关键词： Antihyperglycemic Antihyperlipidemic Streptozotocin Sapindus mukorossi

Rift-associated ultramafic lamprophyre(damtjernite) from the middle part of the Lower Cretaceous(125 Ma) succession of kutch,northwestern India: Tectonomagmatic implications

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Geoscience Frontiers 2018年第6期9卷 1883-1902页

作者： Rohit PANDey N.v.Chalapathi rao Prashant Dhote Dinesh PANDit A.k.Choudhary Samarendra Sahoo B.Lehmann Electron Probe Micro Analyzer Laboratory Department of Geology Centre of Advanced Study Banaras Hindu University Bhumi Geoservices 1 & 2 Maa Bamleshwari Nagar Godhani Railway Institute Instrumentation Centre Indian Institute of Technology Mineral Resources Technical University of Clausthal

Mineralogical,geochemical and isotopic(Sr and Nd) studies on the recently reported ca. 124 Ma'anorogenic lamproite' dyke from the Palanpur area, kutch seismogenic rift zone, northwestern India, are presented. We propose a new classification for the dyke as a damtjernite(ultramafic lamprophyre; UML)based on its porphyritic-panidiomorphic texture, abundance of phlogopite, presence of nepheline in the groundmass, and the composition of liquidus phases such as olivine, phlogopite, magnetite, and clinopyroxene(diopside). The Palanpur UML is primitive(Mg# =74-77),silica-undersaturated(SiO_2kingly similar to the ～69 Ma UML dykes and sills of the Tethyan Indus suture zone, which are considered as the earliest yet known manifestations of the Deccan Large Igneous Province(LIP). Bulk-rock(^(87)Sr/^(86)Sr)_i(0.70460-0.70461) and ε_(N)d(t)(+2.56 to-0.69) of the Palanpur UML signify derivation from a slightly depleted mantle source similar to that of asthenospheric magmas such as OIB. This is further attested to by the high incompatible trace element ratios(viz., La/Ba, Nb/U, Nb/La and Ta/Yb) that are typical of plume-type magmas. However, the Neoproterozoic T_(DM) depleted mantle Nd model ages( ～655-919 Ma) also necessitate some involvement of a lithospheric mantle component in its genesis. High bulk-rock Fe_2 O_3~t and TiO_2 contents require the involvement of a fertile peridotitic mantle source, whereas high La/Yb(60-80) implies a control by residual garnet. Higher Rb/Sr and lower Ba/Rb suggest phlogopite as a residual phase and high Nb and lower La/Sm favour carbonatite, rather than silicate melt as metasomatising agent. Low degrees of partial melting of a primitive garnet lherzolite mantle can account for the observed REE patterns in the Palanpur UML. The Palanpur UML shares a temporal similarity to the kerguelen plume-derived Rajmahal basalts and associated alkaline rocks from the eastern India. The tectonomagmatic

关键词： Tectonomagmatism Cretaceous Ultramafic lamprophyre Rift kutch India

Enhancement of wear and ballistic resistance of armour grade AA7075 aluminium alloy using friction stir processing

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Defence Technology（防务技术） 2015年第1期11卷 10-17页

作者： I.SUDHAkAR v.MADHU G.MADHUSUDHAN REDDY k.SRINIvASA rao Department of Mechanical Engineering MVGRCE Vizianagaram India Defence Metallurgical Research Laboratory Hyderabad India Department of Metallurgical Engineering Andhra University Visakhapatnam India

Industrial applications of aluminium and its alloys are restricted because of their poor tribological properties. Thermal spraying, laser surfacing, electron beam welding are the most widely used techniques to alter the surface morphology of base metal. Preliminary studies reveal that the coating and layering of aluminium alloys with ceramic particles enhance the ballistic resistance. Furthermore, among aluminium alloys,7075 aluminium alloy exhibits high strength which can be compared to that of steels and has profound applications in the designing of lightweight fortification structures and integrated protection systems. Having limitations such as poor bond integrity, formation of detrimental phases and interfacial reaction between reinforcement and substrate using fusion route to deposit hard particles paves the way to adopt friction stir processing for fabricating surface composites using different sizes of boron carbide particles as reinforcement on armour grade 7075 aluminium alloy as matrix in the present investigation. Wear and ballistic tests were carried out to assess the performance of friction stir processed AA7075 alloy. Significant improvement in wear resistance of friction stir processed surface composites is attributed to the change in wear mechanism from abrasion to adhesion. It has also been observed that the surface metal matrix composites have shown better ballistic resistance compared to the substrate AA7075 alloy. Addition of solid lubricant Mo S2 has reduced the depth of penetration of the projectile to half that of base metal AA7075 alloy. For the first time, the friction stir processing technique was successfully used to improve the wear and ballistic resistances of armour grade high strength AA7075 alloy.

关键词： Armour grade aluminium alloy Friction stir processing Boron carbide Molybdenum disulphide Wear Ballistic resistance

Co(Ⅱ),Ni(Ⅱ)和Cu(Ⅱ)与L-多巴和1,10-菲咯啉在低介电介质中三元配合物体系的化学物种(英文)

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无机化学学报 2012年第4期28卷 785-794页

作者： Ramaraju R Santhee Devi k v Nageswara rao G 安得那大学无机和分析化学系印度维沙卡帕特530003

对M髤[M=Co,Ni and Cu]与L-多巴（L）和1,10-菲咯啉（X）在的1,4-二氧杂环己烷（DOX）-水混合物【0~60%（v/v）】三元配合物体系在（303.0±0.1）k和离子强度为0.16 mol.L-1情况下进行pH滴定。结果表明：对Co髤和Cu髤而言,三元物种为MLX... 详细信息

对M髤[M=Co,Ni and Cu]与L-多巴（L）和1,10-菲咯啉（X）在的1,4-二氧杂环己烷（DOX）-水混合物【0~60%（v/v）】三元配合物体系在（303.0±0.1）k和离子强度为0.16 mol.L-1情况下进行pH滴定。结果表明：对Co髤和Cu髤而言,三元物种为MLX2H,MLXH,ML2X和MLX,但对Ni髤而言,三元物种为MLX2H,MLXH和MLX。三元物种的稳定性和浓度随介质的介电常数的变化趋势根据静电和非静电力作出解释。同时还给出了物种在不同pH值的DOX-水混合物中的分布图。根据滴定曲线推论了各种二元和三元配合物的生成。用两种方法解释了三元配合物比对应的二元配合物稳定的原因。

关键词：稳定常数 pH-滴定化学物种金属配体 1,4-二氧杂环己烷