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REMnO3（RE=Pr,Nd,Sm,Eu,Gd） perovskite as efficient catalysts for oxygen reduction reaction

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Journal of Rare Earths 2024年第11期42卷 2078-2087页

作者： Rakesh Ranjan Mahalik Siba Soren Ipsha Hota A.k.Debnath k.P.Muthe Purnendu Parhi Department of Chemistry Ravenshaw University Technical Physics Division Bhabha Atomic Research Centre

Rare earth metal based perovskite emerges as important catalytic material for energy production and *** ABO3type materials are now the focus of research in the field of oxygen reduction and evolution ***,in this work we evaluated the oxygen reduction properties of the synthesized one-dimensional REMnO3（RE=Pr,Nd,Sm,Eu and Gd）.The one-dimensional REMnO3prepared by the hydrothermal synthesis route results in pure phase perovskite on *** perovskite was characte rized with X-ray diffraction,Fourier transform-infrared（FT-IR）,field emission-scanning electron microscopy（FE-SEM）,transmission electron microscopy（TEM） and X-ray photoelectron spectroscopy（XPS）.The oxygen reduction reaction activities were investigated with the help of electrochemical workstation that consists of three-electrode system immersed in 0.1 mol/L kOH electrolyte solution saturated with *** koutechy-Levich plot obtained from rotating ring disk electrode shows all the prepared catalysts follow 4e-processes during oxygen *** effect of "A" site cation variation in REMnO3 on oxygen reduction reaction is ***3showed better onset potential for oxygen reduction reaction among the prepared rare earth ***3having high RE:Mn ratio（A-site rich co mpositions） promotes oxygen reduction reaction（ORR） *** the perovs kites showed good oxygen reduction property with high stability and methanol tolerance.

关键词： Electrocatalytic activity Oxygen reduction reaction (ORR) Perovskite Rare earths REMnO3 SmMnO3

Failure pattern in ceramic metallic target under ballistic impact

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Defence Technology（防务技术） 2024年第10期40卷 173-190页

作者： M.A.Iqbal M.k.khan Department of Civil Engineering Indian Institute of Technology RoorkeeRoorkee 247667India Department of Civil Engineering Aligarh Muslim UniversityAligarh202002India

The ballistic resistance and failure pattern of a bi-layer alumina 99.5%-aluminium alloy 1100-H12 target against steel 4340 ogival nosed projectile has been explored in the present experimental cum numerical *** the experimental investigation,damage induced in the ceramic layer has been quantified in terms of number of cracks developed and failure zone *** resultant damage in the backing layer has been studied with variation in the bulge and perforation hole in the backing layer with the varying incidence *** discussion of the experimental results has been further followed by three dimensional finite element computations using ABAQUS/Explicit finite code to investigate the behaviour of different types of bi-layer targets under multi-hit projectile *** JH-2 constitutive model has been used to reproduce the behaviour of alumina 99.5%and JC constitutive model has been used for steel 4340 and aluminium alloy *** total energy dissipation has been noted to be of lesser magnitude in case of sub-sequential impact in comparison to simultaneous impact of two *** distance between the impact points of two projectiles also effected the ballistic resistance of bi-layer *** ballistic resistance of single tile ceramic front layer and four tile ceramic of equivalent area found to be dependent upon the boundary conditions provided to the target.

关键词： Ballistic resistance Bi-layer target Ceramic metal armour Multi-hit impact Finite element modelling

A Hybrid Machine Learning Approach for Improvised QoE in Video Services over 5G Wireless Networks

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Computers, Materials & Continua 2024年第3期78卷 3195-3213页

作者： k.B.Ajeyprasaath P.Vetrivelan School of Electronics Engineering Vellore Institute of TechnologyChennaiTamil Nadu600127India

Video streaming applications have grown considerably in recent *** a result,this becomes one of the most significant contributors to global internet *** to recent studies,the telecommunications industry loses millions of dollars due to poor video Quality of Experience(QoE)for *** the standard proposals for standardizing the quality of video streaming over internet service providers(ISPs)is the Mean Opinion Score(MOS).However,the accurate finding of QoE by MOS is subjective and laborious,and it varies depending on the user.A fully automated data analytics framework is required to reduce the inter-operator variability characteristic in QoE *** work addresses this concern by suggesting a novel hybrid XGBStackQoE analytical model using a two-level layering *** one combines multiple Machine Learning(ML)models via a layer one Hybrid *** ML models at level one are trained using the entire training data *** level two Hybrid XGBStackQoE-Model is fitted using the outputs(meta-features)of the layer one ML *** proposed model outperformed the conventional models,with an accuracy improvement of 4 to 5 percent,which is still higher than the current traditional *** proposed framework could significantly improve video QoE accuracy.

关键词： Hybrid XGBStackQoE-model machine learning MOS performance metrics QoE 5G video services

Enhancing Multicriteria-Based Recommendations by Alleviating Scalability and Sparsity Issues Using Collaborative Denoising Autoencoder

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Computers, Materials & Continua 2024年第2期78卷 2269-2286页

作者： S.Abinaya k.Uttej kumar School of Computer Science&Engineering Vellore Institute of TechnologyChennaiTamilnadu600127India

A Recommender System(RS)is a crucial part of several firms,particularly those involved in *** conventional RS,a user may only offer a single rating for an item-that is insufficient to perceive consumer ***,businesses in industries like e-learning and tourism enable customers to rate a product using a variety of factors to comprehend customers’*** the other hand,the collaborative filtering(CF)algorithm utilizing AutoEncoder(AE)is seen to be effective in identifying user-interested ***,the cost of these computations increases nonlinearly as the number of items and users *** triumph over the issues,a novel expanded stacked autoencoder(EsaE)with kernel Fuzzy C-Means Clustering(kFCM)technique is proposed with two *** the first phase of offline,the sparse multicriteria rating matrix is smoothened to a complete matrix by predicting the users’intact rating by the EsaE approach and users are clustered using the kFCM *** the next phase of online,the top-N recommendation prediction is made by the EsaE approach involving only the most similar user from multiple *** the EsaE_kFCM model upgrades the prediction accuracy of 98.2%in Top-N recommendation with a minimized recommendation generation *** experimental check on the Yahoo!Movies(YM)movie dataset and TripAdvisor(TA)travel dataset confirmed that the EsaE_kFCM model constantly outperforms conventional RS algorithms on a variety of assessment measures.

关键词： Recommender systems multicriteria rating collaborative filtering sparsity issue scalability issue stacked-autoencoder kernel Fuzzy C-Means Clustering

Hybrid Seagull and Whale Optimization Algorithm-Based Dynamic Clustering Protocol for Improving Network Longevity in Wireless Sensor Networks

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China Communications 2024年第10期21卷 113-131页

作者： P.Vinoth kumar k.Venkatesh Department of Networking and Communications School of ComputingCollege of Engineering and TechnologySRM Institute of Science and TechnologyKattankulathur 603203India

Energy efficiency is the prime concern in Wireless Sensor Networks(WSNs) as maximized energy consumption without essentially limits the energy stability and network lifetime. Clustering is the significant approach essential for minimizing unnecessary transmission energy consumption with sustained network lifetime. This clustering process is identified as the Non-deterministic Polynomial(NP)-hard optimization problems which has the maximized probability of being solved through metaheuristic *** adoption of hybrid metaheuristic algorithm concentrates on the identification of the optimal or nearoptimal solutions which aids in better energy stability during Cluster Head(CH) selection. In this paper,Hybrid Seagull and Whale Optimization Algorithmbased Dynamic Clustering Protocol(HSWOA-DCP)is proposed with the exploitation benefits of WOA and exploration merits of SEOA to optimal CH selection for maintaining energy stability with prolonged network lifetime. This HSWOA-DCP adopted the modified version of SEagull Optimization Algorithm(SEOA) to handle the problem of premature convergence and computational accuracy which is maximally possible during CH selection. The inclusion of SEOA into WOA improved the global searching capability during the selection of CH and prevents worst fitness nodes from being selected as CH, since the spiral attacking behavior of SEOA is similar to the bubble-net characteristics of WOA. This CH selection integrates the spiral attacking principles of SEOA and contraction surrounding mechanism of WOA for improving computation accuracy to prevent frequent election process. It also included the strategy of levy flight strategy into SEOA for potentially avoiding premature convergence to attain better trade-off between the rate of exploration and exploitation in a more effective manner. The simulation results of the proposed HSWOADCP confirmed better network survivability rate, network residual energy and network overall throughput on par wi

关键词： clustering energy stability network lifetime seagull optimization algorithm(SEOA) whale optimization algorithm(WOA) wireless sensor networks(WSNs)

Dispersion effect of nano-structure pyrolytic carbon on mechanical,electrical,and microstructural characteristics of cement mortar composite

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International Journal of Smart and Nano Materials 2024年第3期15卷 534-578页

作者： N.k.karthikeyan S.Elavenil School of Civil Engineering Vellore Institute of TechnologyChennaiIndia

In material science,converting waste into nanomaterials by green technologies highlights the interest in producing sus-tainable carbon nanomaterial(SCN).This study first-ever uti-lized tyre-char as a Nano-Structure Pyrolytic Carbon(NSPC)to develop electrically conductive *** other car-bon nanomaterials,the efficiency of NSPC particle as an SCN in developing electrically conductive composites was investi-gated in terms of dispersion,mechanical,water absorption,electrical resistivity,and *** results of sedi-mentation and zeta potential(-19 mV)showed the excellent dispersion of NSPC particle in water with the combined effect of superplasticizer and *** compressive(40.37%)and flexural strength(10.76%)than that of plain cement mortar composite(CMC)is achieved with 2 wt.%and 1.5 wt.%of NSPC particle,*** water absorption rate and volume of permeable voids were reduced,exhibiting less *** percolation zone of AC and DC resis-tivity of NSPC composite ranges between 1 and 2 wt.%,and the established percolation threshold is at 2 wt.%.XRD analysis showed C-S-H formation consistently increased with curing age,and HR-SEM with EDAX analysis exhibits the dense micro-structure and well-distributed NSPC particle at the *** experimental outcomes significantly enhanced the relia-bility and provided a framework for tailoring NSPC particle as SCN for developing electrically conductive composite.

关键词： Sustainable nanomaterial dispersion mechanical properties electrical resistivity microstructure analysis

A nerve-like self-healable conductive wire

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National Science Review 2024年第6期11卷 89-90页

作者： Xuemei Fu Benjamin C.k.Tee Department of Materials Science and Engineering National University of Singapore Institute for Health Innovation and Technology National University of Singapore

In wearables and robotics, it is often required to deploy electronic devices at different spatially distributed locations for multi-functionality [1–3]. Thus, conductive wires for efficient interconnection of various electronic devices are ***, in practical applications, the frequent motion of wearers and robots will result in high-strain deformations of these wires, which could cause irreparable damage.

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海上丝路与中国天文历法在日本的传播及影响研究

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自然辩证法通讯 2024年第4期46卷 57-65页

作者：萨日娜上海交通大学科学史与科学文化研究院上海200240

经过海上丝路有大量汉文科学典籍传入日本并产生了重要的影响,天文历法知识是其中重要的一个方面。文中通过史料调查和实证考察,探索了魏晋南北朝时期,中国天文知识传日背景;研究隋唐时期,随着海上丝路的发展,日本留学生(僧)把中国天文... 详细信息

经过海上丝路有大量汉文科学典籍传入日本并产生了重要的影响,天文历法知识是其中重要的一个方面。文中通过史料调查和实证考察,探索了魏晋南北朝时期,中国天文知识传日背景;研究隋唐时期,随着海上丝路的发展,日本留学生(僧)把中国天文知识传至日本的详情,尤其考察了唐历《宣明历》在日本使用八百多年之久的缘由;继而分析了宋元明时期,中国传统天文历法持续传日,并对其传统学术建构产生的深远影响。结论认为研究中日传统天文历法的关联性,不仅有助于认识海上丝路文明对日本传统科技的影响,对提升中华传统文化的国际传播力和影响力也有一定的借鉴意义。

关键词：海上丝路天文历法传统科技中日交流

Fish-on-Chips:unveiling neural processing of chemicals in small animals through precise fluidic control

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Neural Regeneration Research 2024年第11期19卷 2351-2353页

作者： samuel k.H.Sy Ho ko Division of Neurology Department of Medicine and TherapeuticsFaculty of MedicineThe Chinese University of Hong KongShatinNew TerritoriesHong Kong Special Administrative RegionChina Li ka Shing Institute of Health Sciences Faculty of MedicineThe Chinese University of Hong KongShatinNew TerritoriesHong Kong Special Administrative RegionChina Department of Electrical and Electronic Engineering Faculty of EngineeringThe University of Hong KongPok Fu LamHong Kong IslandHong Kong Special Administrative RegionChina Advanced Biomedical Instrumentation Center Hong Kong Science ParkPak Shek KokNew TerritoriesHong Kong Special Administrative RegionChina Margaret k.L.Cheung Research Center for Management of Parkinsonism Faculty of MedicineThe Chinese University of Hong KongShatinNew TerritoriesHong Kong Special Administrative RegionChina Lau Tat-chuen Research Center of Brain Degenerative Diseases in Chinese Faculty of MedicineThe Chinese University of Hong KongShatinNew TerritoriesHong Kong Special Administrative RegionChina Gerald Choa Neuroscience Institute The Chinese University of Hong KongShatinNew TerritoriesHong Kong Special Administrative RegionChina

Precise chemical cue presentation alongside advanced brainwide imaging techniques is important to the study of chemosensory processing in ***,the dynamic nature of chemical-carrying media,such as water or air,poses a significant challenge for delivering highly-controlled chemical flow to an animal ***,contact-based cue manipulation and delivery easily shift the position of the animal subject,which is often undesirable for high-quality brain ***,more advanced interfacing tools that align with the diverse range of body part sizes of an animal,ranging from micrometer-scale neurons to meter-long limbs,are much *** is particularly crucial when dealing with dimensions that are beyond the reach of conventional experimental tools.

关键词： dealing precise sizes