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S-scheme heterojunction of crystalline carbon nitride nanosheets and ultrafine WO_(3)nanoparticles for photocatalytic CO_(2)reduction

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Journal of Environmental Sciences 2024年第6期140卷 103-112页

作者： Gongjie Chen Ziruo Zhou Bifang Li Xiahui lin Can Yang Yuanxing fang Wei lin Yidong Hou Guigang Zhang Sibo Wang State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFujian 350116China

Highly crystalline carbon nitride polymers have shown great opportunities in overall water photosplitting;however,their mission in light-driven CO_(2)conversion remains to be *** this work,crystalline carbon nitride(CCN)nanosheets of poly triazine imide(PTI)embedded with melon domains are fabricated by KCl/LiCl-mediated polycondensation of dicyandiamide,the surface of which is subsequently deposited with ultrafine WO_(3)nanoparticles to construct the CCN/WO_(3)heterostructure with a S-scheme *** characterizations have been conducted to reveal the compositions and structures of the S-scheme CCN/WO_(3)hybrid,featuring strengthened optical capture,enhanced CO_(2)adsorption and activation,attractive textural properties,as well as spatial separation and directed movement of light-triggered charge *** mild conditions,the CCN/WO_(3)catalyst with optimized composition displays a high photocatalytic activity for reducing CO_(2)to CO in a rate of 23.0μmol/hr(i.e.,2300μmol/(hr·g)),which is about 7-fold that of pristine CCN,along with a high CO selectivity of 90.6%against ***,it also manifests high stability and fine reusability for the CO_(2)conversion *** CO_(2)adsorption and conversion processes on the catalyst are monitored by in-situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS),identifying the crucial intermediates of CO_(2)^(*)-,COOH^(*)and CO^(*),which integrated with the results of performance evaluation proposes the possible CO_(2)reduction mechanism.

关键词： Crystalline carbon nitride Photocatalysis CO_(2)reduction S-scheme WO_(3)

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Assessment of Crop Yield in China Simulated by Thirteen Global Gridded Crop Models

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Advances in Atmospheric Sciences 2024年第3期41卷 420-434页

作者： Dezhen YIN fang LI Yaqiong LU Xiaodong ZENG Zhongda lin Yanqing ZHOU International Center for Climate and Environment Sciences Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China University of Chinese Academy of Sciences Beijing 100049China Institute of Mountain Hazards and Environment Chinese Academy of SciencesChengdu 610041China State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China State Key Laboratory of Desert and Oasis Ecology Xinjiang Institute of Ecology and GeographyChinese Academy of SciencesUrumqi 830011China

Global gridded crop models(GGCMs) have been broadly applied to assess the impacts of climate and environmental change and adaptation on agricultural production. China is a major grain producing country, but thus far only a few studies have assessed the performance of GGCMs in China, and these studies mainly focused on the average and interannual variability of national and regional yields. Here, a systematic national-and provincial-scale evaluation of the simulations by13 GGCMs [12 from the GGCM Intercomparison(GGCMI) project, phase 1, and CLM5-crop] of the yields of four crops(wheat, maize, rice, and soybean) in China during 1980–2009 was carried out through comparison with crop yield statistics collected from the National Bureau of Statistics of China. Results showed that GGCMI models generally underestimate the national yield of rice but overestimate it for the other three crops, while CLM5-crop can reproduce the national yields of wheat, maize, and rice well. Most GGCMs struggle to simulate the spatial patterns of crop yields. In terms of temporal variability, GGCMI models generally fail to capture the observed significant increases, but some can skillfully simulate the interannual variability. Conversely, CLM5-crop can represent the increases in wheat, maize, and rice, but works less well in simulating the interannual variability. At least one model can skillfully reproduce the temporal variability of yields in the top-10 producing provinces in China, albeit with a few exceptions. This study, for the first time, provides a complete picture of GGCM performance in China, which is important for GGCM development and understanding the reliability and uncertainty of national-and provincial-scale crop yield prediction in China.

关键词： global gridded crop model historical crop yield China multi-model evaluation

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Evaluating the tumor stratification with a lysosomal pH sensitive-probe by fluorescence lifetime imaging

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Chinese Chemical Letters 2024年第3期35卷 262-267页

作者： jun Yan Xing Liang Qian Zhang Luolin Wang Weiying lin Guangxi Key Laboratory of Electrochemical Energy Materials Institute of Optical Materials and Chemical BiologySchool of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China

Owing to the anaerobic metabolism in the tumor,abundant acidic metabolites are produced and accumulated in the ***,the cells in different tumor layers are directly linked to the pH ***,due to the lack of robust tools,the high-efficient evaluation of the acidic micro-environment of tumor stratification faces the challenge of accurate *** designed a new pH sensitive fluorescent lifetime probe target to *** we expected,the fluorescence lifetime of PLN possesses a good linear fit to the pH value,which could detect the pH change at a single lysosome level in real time,and then evaluate the different acidity of tumor *** probe PLN is successfully used to evaluate the tumor stratification by fluorescence lifetime imaging microscopy(FLIM)for the first time,which is of great significance in the preoperative diagnosis of clinical tumor treatment or evaluation of drug delivery effect.

关键词： FLIM pH Fluorescence imaging Lysosome Tumor imaging

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Sequential enantioselective Ugi-4CR/post-Ugi transformation strategy:a precise construction of structurally diverse azaspiro polycyclic scaffolds

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Science China Chemistry 2024年第2期67卷 576-586页

作者： Xiao-Bao Wu jun-Xiu Shi Yi-Ming Ou Hua-Jie Jiang Yi-jun fang Qi-Ming Wang Quan Gao Jie Yu Department of Applied Chemistry Anhui Province Engineering Laboratory for Green Pesticide Development and ApplicationAnhui Province Key Laboratory of Crop Integrated Pest ManagementAnhui Agricultural UniversityHefei230036China

A privileged strategy has been developed for the precise construction of enantioenriched azaspiro polycyclic *** diverse azaspiro polycycles bearing multiple contiguous stereocenters are obtained with excellent results(up to 99:1 e.r.,>95:5 d.r.) via sequential enantioselective four-component Ugi reactions/post-Ugi transformations with substrates containing prerequisite functional groups in the presence of anionic stereogenic-at-cobalt(Ⅲ) complexes.

关键词： asymmetric catalysis post-Ugi transformation anionic stereogenic-at-cobalt(Ⅲ)complex azaspiro polycyclic scaffold one-pot synthesis

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Risk factors for postpartum posttraumatic stress disorder after emergency admission

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World Journal of Emergency Medicine 2024年第2期15卷 121-125页

作者： Fengxia Du jun Zha Yan Li Lichao fang Shuyu Xia Youjia Yu Department of Obstetrics Suzhou Xiangcheng People’s HospitalSuzhou 215131China Department of Anesthesiology the Second Affiliated Hospital of Wannan Medical CollegeWuhu 241000China Department of Anesthesiology Suzhou Xiangcheng People’s HospitalSuzhou 215131China Department of Emergency and Intensive Care Unit Suzhou Xiangcheng People’s HospitalSuzhou 215131China

BACKGROUND:Postpartum posttraumatic stress disorder(PTSD)can occur in women who give birth after emergency *** identification of risk factors for this condition is crucial for developing effective preventive *** retrospective study aimed to explore the incidence and risk factors for postpartum PTSD in women who give birth after emergency ***:Medical records of women who gave birth after emergency admission were collected between March 2021 and April *** patients’general conditions and perinatal clinical indicators were *** puerperae were divided into PTSD group and control group based on symptom occurrence at six weeks *** logistic regression analysis was performed to identify risk ***:A total of 276 puerperae were included,with a PTSD incidence of 20.3% at six weeks *** logistic regression analysis identified emergency cesarean section(odds ratio[OR]=2.102;95%confidence interval[CI]:1.114-3.966,P=0.022),admission to the emergency department after midnight(12:00 AM)(OR=2.245;95%CI:1.170-4.305,P<0.001),and cervical dilation(OR=3.203;95%CI:1.670–6.141,P=0.039)as independent risk factors for postpartum *** pump use(OR=0.500;95%CI:0.259–0.966,P=0.015)was found to be a protective factor against postpartum ***:Emergency cesarean section,admission to the emergency department after midnight,and cervical dilation were identified as independent risk factors for postpartum PTSD,while analgesic pump use was a protective *** findings provide insights for developing more effective preventive measures for women who give birth after emergency admission.

关键词： Risk factors Posttraumatic stress disorder Emergency Delivery

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Overexpression of Kdm6b induces testicular differentiation in a temperature-dependent sex determination system

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Zoological Research 2024年第5期45卷 1108-1115页

作者： Qiran Chen Wei Sun lin Jin Yingjie Zhou fang Li Chutian Ge College of Biological and Environmental Sciences Zhejiang Wanli UniversityNingboZhejiang 315100China Institute of Animal Sex and Development Zhejiang Wanli UniversityNingboZhejiang 315100China

In reptiles,such as the red-eared slider turtle(Trachemys scripta elegans),gonadal sex determination is highly dependent on the environmental temperature during embryonic *** complex process,which leads to differentiation into either testes or ovaries,is governed by the finely tuned expression of upstream genes,notably the testis-promoting gene Dmrt1 and the ovary-promoting gene *** studies have identified epigenetic regulation as a crucial factor in testis development,with the H3K27me3 demethylase KDM6B being essential for Dmrt1 expression in ***,whether KDM6B alone can induce testicular differentiation remains *** this study,we found that overexpression of Kdm6b in *** embryos induced the male development pathway,accompanied by a rapid increase in the gonadal expression of Dmrt1 at 31°C,a temperature typically resulting in female ***,this sex reversal could be entirely rescued by Dmrt1 *** findings demonstrate that Kdm6b is sufficient for commitment to the male pathway,underscoring its role as a critical epigenetic regulator in the sex determination of the red-eared slider turtle.

关键词： Temperature-dependent sex determination Sex reversal Kdm6b Dmrt1 T.s.elegans

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FIBTNet:Building Change Detection for Remote Sensing Images Using Feature Interactive Bi-Temporal Network

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Computers, Materials & Continua 2024年第9期80卷 4621-4641页

作者： Jing Wang Tianwen lin Chen Zhang jun Peng School of Geographic Information and Tourism Chuzhou UniversityChuzhou239000China Anhui Province Key Laboratory of Physical Geographic Environment Chuzhou UniversityChuzhou239000China

In this paper,a feature interactive bi-temporal change detection network(FIBTNet)is designed to solve the problem of pseudo change in remote sensing image building change *** network improves the accuracy of change detection through bi-temporal feature *** designs a bi-temporal feature exchange architecture(EXA)and a bi-temporal difference extraction architecture(DFA).EXA improves the feature exchange ability of the model encoding process through multiple space,channel or hybrid feature exchange methods,while DFA uses the change residual(CR)module to improve the ability of the model decoding process to extract different features at multiple ***,at the junction of encoder and decoder,channel exchange is combined with the CR module to achieve an adaptive channel exchange,which further improves the decision-making performance of model feature *** results on the LEVIR-CD and S2Looking datasets demonstrate that iCDNet achieves superior F1 scores,Intersection over Union(IoU),and Recall compared to mainstream building change detectionmodels,confirming its effectiveness and superiority in the field of remote sensing image change detection.

关键词： Change detection change residual module feature exchange mechanism feature fusion

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Structural engineering of BaWO_(4)/CsPbX_(3)/CsPb_(2)X_(5)(X=Cl,Br,I)heterostructures towards ultrastable and tunable photoluminescence

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Nano Research 2024年第3期17卷 1636-1645页

作者： Peng Liu Yan Xu Bohan Li Yuchi Zhang Hongzhou Lian jun lin Department of Chemistry College of SciencesNortheastern UniversityShenyang 110819China State Key Laboratory of Rare Earth Resource Utilization Chang Chun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

Construction of lead halide perovskite nanocrystals(LHP NCs)heterostructures is essential to obtain highly stable photoluminescence and expand their ***,a novel self-assembly strategy combining with a solvent-free thermal-assisted synthesis and a water-triggered reaction is developed to subsequently grow BaWO_(4)/CsPbX_(3)/CsPb_(2)X_(5)(X=Cl,Br,I)heterostructures at low nucleation temperature with high *** as-obtained ternary BaWO_(4)/CsPbX_(3)/CsPb_(2)X_(5)(X=Cl,Br,I)heterostructures exhibit remarkably enhanced panchromatic emission and ultrastable luminescence ascribing to the low-defect growth based on lattice *** white light-emitting diodes(WLEDs)have been constructed with a high correlated color temperature(CCT)of 7225 K and luminous efficiency of 74.4 lm·***^(3+)-doped BaWO_(4)/CsPbX_(3)/CsPb_(2)X_(5)(Ln^(3+)=Eu^(3+),Tb^(3+),Dy^(3+),Sm^(3+),Yb^(3+)/Er^(3+))nanocomposites are further designed with excitation-dependent photoluminescence and thermochromic properties,making them excellent candidates for high-level anti-counterfeiting and *** work offers a green and universal approach in assembling CsPbX_(3)(X=Cl,Br,I)on lattice-matched tungstate with adjustable panchromatic emission for versatile optical applications.

关键词： inorganic lead halide perovskites solvent-free synthesis panchromatic emission anti-counterfeiting and encryption application

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Decision-making method for high-speed rail early warning system in complex earthquake situations

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Transportation Safety and Environment 2024年第3期6卷 47-61页

作者： Minjia Tan Qizhou Hu Yikai Wu Juanjuan lin Xin fang School of Automation Nanjing University of Science and TechnologyNanjing 210094JiangsuChina

To address the shortcomings in decision-making methods for ground motion threshold warning models in high-speed rail earthquake early warning systems(HSREEWs),we propose a dual judgement method and corresponding early warning process for earthquake early warning decisions based on joint peak ground acceleration(PGA)and complex earthquake environmental risk evaluation(ERE)***,we analyse the characteristics of four complex earthquake environments based on the characteristics of high-speed rail(HSR)operating ***,we establish an earthquake environmental risk evaluation index system and propose an adversarial interpretive structure modelling method-based complex earthquake situation evaluation model(AISM-based ESEM).The AISM method firstly evaluates the proximity by the TOPSIS(technique for order preference by similarity to an ideal solution)method,then effectively rank targets with fuzzy attributes through opposite hierarchical extraction rules without sacrificing system *** PGA can reflect the current size of earthquake energy,combining PGA thresholds with ESEM-derived values of ERE can effectively determine the risk status of each train and make decisions on the most appropriate alarm form and control measures for that ***,case analysis results under the background of Wenchuan Earthquake show that the new early warning decisionmaking method accurately assesses environmental risks in affected areas and provides corresponding warning levels as a supplement to existing HSREEWs warning models.

关键词： high-speed rail(HSR) earthquake situation earthquake risk decision-making earthquake early warning

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Unraveling the atomic interdiffusion mechanism of NiFe_(2_)O_(4)oxygen carriers during chemical looping CO_(2)conversion

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Carbon Energy 2024年第8期6卷 105-121页

作者： Da Song Yan lin Shiwen fang Yang Li Kun Zhao Xinfei Chen Zhen Huang fang He Zengli Zhao Hongyu Huang Fanxing Li Guangzhou Institute of Energy Conversion Chinese Academy of SciencesGuangzhouChina School of Energy Science and Engineering University of Science and Technology of ChinaHefeiChina College of Mechanical and Electrical Engineering Zhongkai University of Agriculture and EngineeringGuangzhouChina College of Chemistry and Bioengineering Guilin University of TechnologyGuilinChina North Carolina State University RaleighNorth CarolinaUSA

By employing metal oxides as oxygen carriers,chemical looping demonstrates its effectiveness in transferring oxygen between reduction and oxidation environments to partially oxidize fuels into syngas and convert CO_(2)into ***,NiFe_(2_)O_(4)oxygen carriers have demonstrated remarkable efficiency in chemical looping CO_(2)***,the intricate process of atomic migration and evolution within the internal structure of bimetallic oxygen carriers during continuous high‐temperature redox cycling remains ***,the lack of a fundamental understanding of the complex ionic migration and oxygen transfer associated with energy conversion processes hampers the design of high‐performance oxygen ***,in this study,we employed in situ characterization techniques and theoretical calculations to investigate the ion migration behavior and structural evolution in the bulk of NiFe_(2_)O_(4)oxygen carriers during H2 reduction and CO_(2)/lab air oxidation *** discovered that during the H2 reduction step,lattice oxygen rapidly migrates to vacancy layers to replenish consumed active oxygen species,while Ni leaches from the material and migrates to the *** the CO_(2)splitting step,Ni migrates toward the core of the bimetallic oxygen carrier,forming Fe–Ni *** the air oxidation step,Fe–Ni migrates outward,creating a hollow structure owing to the Kirkendall effect triggered by the swift transfer of lattice *** metal atom migration paths depend on the oxygen transfer *** discoveries highlight the significance of regulating the release–recovery rate of lattice oxygen to uphold the structures and reactivity of oxygen *** work offers a comprehensive understanding of the oxidation/reduction‐driven atomic interdiffusion behavior of bimetallic oxygen carriers.

关键词： chemical looping CO_(2)splitting density functional theory in situ characterization ionic migration

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