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Constructing globally consecutive 3D conductive network using P-doped biochar cotton fiber for superior performance of silicon-based anodes

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Journal of Materials Science & Technology 2024年第6期173卷 181-191页

作者： jun Cao Jianhong Gao Kun Wang Zhuoying Wu Xinxin Zhu Han Li Min Ling {1.gdu Liang jun {1. Zhejiang Provincial Key Laboratory of Advanced Chemical engineering Manufacture Technology College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China Institute of Zhejiang University-Quzhou Zheda Road 99Quzhou 324000China

The inferior conductivity and drastic volume expansion of silicon still remain the bottleneck in achieving high energy density Lithium-ion Batteries(LIBs).The design of the three-dimensional structure of electrodes by compositing silicon and carbon materials has been employed to tackle the above challenges,however,the exorbitant costs and the uncertainty of the conductive structure persist,leaving ample room for ***,silicon nanoparticles were innovatively composited with eco-friendly biochar sourced from cotton to fabricate a 3D globally consecutive conductive *** network serves a dual purpose:enhancing overall electrode conductivity and serving as a scaffold to maintain electrode *** conductivity of the network was further augmented by introducing P-doping at the optimum doping temperature of 350℃.Unlike the local conductive sites formed by the mere mixing of silicon and conductive agents,the consecutive network can affirm the improvement of the conductivity at a macro ***,first-principle calculations further validated that the rapid diffusion of Li^(+)is attributed to the tailored electronic microstructure and charge rearrangement of the *** prepared consecutive conductive Si@P-doped carbonized cotton fiber anode outperforms the inconsecutive Si@Graphite anode in both cycling performance(capacity retention of 1.77.1. mAh g^(-1. vs.682.56 mAh g^(-1. after 1.0 cycles at 0.3 C)and rate performance(1.44.24 mAh g^(-1. vs.370.28 mAh g^(-1. at 2.0 C).The findings of this study may open up new avenues for the development of globally interconnected conductive networks in Si-based anodes,thereby enabling the fabrication of high-performance LIBs.

关键词： 3D conductive network Biochar carbon-silicon anode Heteroatoms doping strategy DFT calculation Lithium-ion battery

An attention-based teacher-student model for multivariate short-term landslide displacement prediction incorporating weather forecast data

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Journal of Mountain Science 2024年第8期21卷 2739-2753页

作者： chen {1. HU Wang ZHANG Yu QIU Hongzhi WANG Renchao Sichuan Artificial Intelligence Research Institute Yibin 644000China school of Computer Science and {1. University of Electronic Science and Technology of ChinaChengdu 611731China school of Architecture and Civil {1. Chengdu UniversityChengdu 610106China

Predicting the displacement of landslide is of utmost practical importance as the landslide can pose serious threats to both human life and ***,traditional methods have the limitation of random selection in sliding window selection and seldom incorporate weather forecast data for displacement prediction,while a single structural model cannot handle input sequences of different lengths at the same *** order to solve these limitations,in this study,a new approach is proposed that utilizes weather forecast data and incorporates the maximum information coefficient(MIC),long short-term memory network(LSTM),and attention mechanism to establish a teacher-student coupling model with parallel structure for short-term landslide displacement *** MIC,a suitable input sequence length is selected for the LSTM *** investigate the influence of rainfall on landslides during different seasons,a parallel teacher-student coupling model is developed that is able to learn sequential information from various time series of different *** teacher model learns sequence information from rainfall intensity time series while incorporating reliable short-term weather forecast data from platforms such as China Meteorological Administration(CMA)and Reliable Prognosis(https://***)to improve the model’s expression capability,and the student model learns sequence information from other time *** attention module is then designed to integrate different sequence information to derive a context vector,representing seasonal temporal attention ***,the predicted displacement is obtained through a linear *** proposed method demonstrates superior prediction accuracies,surpassing those of the support vector machine(SVM),LSTM,recurrent neural network(RNN),temporal convolutional network(TCN),and LSTM-Attention *** achieves a mean absolute error(MAE)of 0.072 mm,root mean square error(RMSE)of 0.096 mm,and pearson correlation coefficients(PC

关键词： Landslide prediction MIC LSTM Attention mechanism Teacher Student model Prediction stability and interpretability

Spray pyrolysis-derived W-doped MoSe_(2)/rGO paper-like microspheres:optimization of microstructure and mesostructure for enhanced lithium storage

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Rare Metals 2024年第7期43卷 3019-3031页

作者： Wei Wang jun-Yu {1. Jie Ouyang Hong Yin Ao-Jie Li Liang {1. jun-Lin Huang Yu-Can Zhu Gang-Yong Li Zhao-Hui Hou Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and TechnologyYueyang 414006China school of Chemistry and Chemical {1. Hunan Institute of Science and TechnologyYueyang414006China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology Material Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China International Iberian Nanotechnology Laboratory(INL) AvMestre Jose Veiga4715-330 BragaPortuga

Two-dimensional MoSe_(2) is a promising candidate for lithium-ion battery ***,its conductivity and lithium storage volumetric effect still need to be *** this work,W-doped MoSe_(2)/rGO paper-like microspheres are successfully prepared through ultrasonic spray pyrolysis,achieving optimization at both the microstructure and mesostructure to enhance the lithium storage performance of the ***,by utilizing the similar two-dimensional structure between MoSe_(2) and rGO,self-assembly is achieved through spray pyrolysis,resulting in a well-defined van der Waals heterostructure at the interface on the microscale,enhancing the electron and ion transfer capability of the ***,the mesoscale paper-like microsphere morphology provides additional volume expansion buffering ***,W-doping not only increases the interlayer spacing of MoSe_(2)(0.73 nm),thereby reducing the diffusion resistance of Li+,but also allow for the modulation of the energy band structure of the *** functional theory(DFT)calculations confirm that W-doped MoSe_(2)/rGO exhibits the narrowest bandgap(0.892 eV).Therefore,the composite demonstrates excellent lithium storage performance,maintaining a specific capacity of 732.9 mAh·g^(-1.after 300 cycles at a current density of 1.A·g^(-1..

关键词： Molybdenum selenide Heterostructure Microspheres Li-ion batteries Kinetics

Occurrence and vertical distribution of aluminum and rare earths in weathered crust elution-deposited rare earth ore:Effect of soil solution pH and clay minerals

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Journal of Rare Earths 2024年第7期42卷 1394-1402,I0007页

作者： Jiaxin Pan Longsheng Zhao Zheng Li Xiaowei Huang Zongyu Feng jun {1. National engineering Research Center for Rare Earth China GRINM Group Co.Ltd.Beijing100088China school of Metallurgical and Ecological {1. University of Science and Technology Beijing(USTB)Beijing100083China GRIREM Hi–Tech Co. Ltd.Langfang065201China GRIREM Advanced Materials Co. Ltd.Beijing100088China GRIMAT engineering Institute Co. Ltd.Beijing101407China

Weathered crust elution-deposited rare earth ore is crucial source of medium and heavy rare earths,with in-situ leaching being the most common mining *** high contents of impurity of aluminum in the leach solution are a significant challenge for the subsequent enrichment process of rare earths.A comprehensive understanding of the occurrences and vertical distribution of aluminum and rare earths within typical vertical profiles can provide valuable insights into entire design of the in-situ *** paper improves a five-step sequential extraction method to analyze the occurrence and vertical distribution of rare earths and aluminum in vertical profiles from Chongzuo and *** results demonstrate that soil solution pH is the main factor affecting the vertical distribution of ionexchangeable rare *** samples have distinct areas of enrichment for ion-exchangeable rare earths or ***-exchangeable rare earths are primary concentrated in the middle and lower parts of the ore layer(4-1. m in Chongzuo,1.-22 m in Longyan),while the ion-exchangeable aluminum is mainly enriched in the upper part of the ore layer(1.5 m in Chongzuo,and 2-1. m in Longyan).The vertical distribution of inorganic hydroxy aluminum is likely influenced by the micromorphology and particle size of the clay *** inorganic hydroxy aluminum concentration in Chongzuo samples decreases continuously from 41..65 to 1.0.95 mg/kg with increasing sampling depth,whereas the concentration in Longyan samples(1.0.55-1.1.27 mg/kg)is almost independence with sampling *** results provide direct guidance for the entire design of the injection well depth and the leaching parameters,thereby inhibiting the leaching of impurity of aluminum and lower the consumption of leaching agent.

关键词： Weathered crust elution-deposited rare earth ore Sequential extraction Occurrence Aluminum Rare earth elements

Phosphorylated cellulose nanofibers establishing reliable ion-sieving barriers for durable lithium-sulfur batteries

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Journal of Energy Chemistry 2024年第5期92卷 619-628页

作者： Zihao Li Pengsen Qian Hongyang Li He Xiao jun {1. Gaoran Li school of Materials Science and {1. Nanjing University of Science and TechnologyNanjing 210094JiangsuChina National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials Fuzhou 350108FujianChina

The shuttle effect is among the most characteristic and formidable challenges in the pursuit of high-performance lithium-sulfur(Li-S)***,phosphorylated cellulose nanofibers(pCNF)are intentionally engineered to establish an ion-sieving barrier against polysulfide shuttling and thereby improve battery *** phosphorylation,involving the grafting of phosphate groups onto the cellulose backbone,imparts an exceptional electronegativity that repels the polysulfide anions from penetrating through the ***,the electrolyte wettability and Li^(+)transfer can be significantly promoted by the polar nature of pCNF and the facile Li^(+)*** such,rational ion management is realized,contributing to enhanced reversibility in both sulfur and lithium *** a result,Li-S cells equipped with the self-standing pCNF separator demonstrate outstanding long-term cyclability with a minimum fading rate of 0.01.%per cycle over 1.00 cycles at 1.C,and a decent areal capacity of 5.37 mA h cm^(-2) even under elevated sulfur loading of 5.0 mg cm^(-2) and limited electrolyte of 6.0 mL g^(-1..This work provides a facile and effective pathway toward the well-tamed shuttle effect and highly durable Li-S batteries.

关键词： Lithium-sulfur batteries Cellulose Phosphorylation Ion-sieving Shuttle effect

Extracting multi-objective multigraph features for the shortest path cost prediction:Statistics-based or learning-based?

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Green Energy and Intelligent Transportation 2024年第1期3卷 1-15页

作者： Songwei Liu Xinwei Wang Michal Weiszer jun {1. school of {1. and Materials Science Queen Mary University of LondonMile End RoadLondon E14NSUnited Kingdom

Efficient airport airside ground movement(AAGM)is key to successful operations of urban air *** studies have introduced the use of multi-objective multigraphs(MOMGs)as the conceptual prototype to formulate *** calculation of the shortest path costs is crucial for the algorithmic heuristic search on MOMGs,however,previous work chiefly focused on single-objective simple graphs(SOSGs),treated cost enquires as search problems,and failed to keep a low level of computational time and storage *** paper concentrates on the conceptual prototype MOMG,and investigates its node feature extraction,which lays the foundation for efficient prediction of shortest path *** extraction methods are implemented and compared:a statistics-based method that summarises 22 node physical patterns from graph theory principles,and a learning-based method that employs node embedding technique to encode graph structures into a discriminative vector *** former method can effectively evaluate the node physical patterns and reveals their individual importance for distance prediction,while the latter provides novel practices on processing multigraphs for node embedding algorithms that can merely handle *** regression models are applied to predict the shortest path costs to demonstrate the performance of *** experiments on randomly generated benchmark MOMGs show that(i)the statistics-based method underperforms on characterising small distance values due to severe overestimation;(ii)A subset of essential physical patterns can achieve comparable or slightly better prediction accuracy than that based on a complete set of patterns;and(iii)the learning-based method consistently outperforms the statistics-based method,while maintaining a competitive level of computational complexity.

关键词： Multi-objective multigraph Feature extraction Shortest path cost prediction Node patterns Node embeddings Regression

Solid polymer electrolyte-based high areal capacity all-solid-state batteries enabled with ceramic interlayers

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Nano Research 2024年第10期17卷 8803-8808页

作者： chenji Hu Daiqian chen Yage Huang Guoyong Xue Xi Liu Jingshu Wang jun Ma Bowen chen Qi chen Linsen Li Yanbin Shen Liwei chen school of Chemistry and Chemical {1. in-situ Center for Physical SciencesShanghai Electrochemical Energy Device Research Center(SEED)and Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong UniversityShanghai 200240China i-Lab CAS Center for Excellence in NanoscienceSuzhou Institute of Nano-Tech and Nano-Bionics(SINANO)Chinese Academy of SciencesSuzhou 215123China IDONANO Co Ltd Shanghai 201614China Future Battery Research Center Global Institute of Future TechnologyShanghai Jiao Tong UniversityShanghai 200240China

Solid polymer electrolytes(SPEs)based all-solid-state batteries(ASSBs)have attracted extensive attention as a promising candidate for next-generation energy storage *** ASSBs require high fabrication pressure to achieve high areal capacity,under which,however,SPEs struggle and risk damage or failure due to their low mechanical *** is also a lack of study on complex stress and strain SPEs experience during ASSB cell assembly ***,ceramic solid electrolytes are selected as interlayers to address the stress-strain conditions during *** a result,high areal capacity ASSBs with a LiCoO2 loading of 1. mg·cm^(-2) were assembled with SPE-based composite *** 200 cycles were carried out for these cells at a current density of 1.mA·cm^(-2) under room *** capacity decay of the battery at 200 cycles is observed to be as low as 0.06% per *** work identifies a critical issue for application of SPEs in ASSBs and provides a potential strategy for the design of SPE-based ASSBs with high specific energy and long cycle life.

关键词： all-solid-state batteries ceramic interlayer solid polymer electrolyte high areal capacity

Cycloaddition Reactions of Epoxides and CO_(2)Catalyzed by Bifunctional Rare-Earth Metal Complexes Bearing Amino-Bridged Tris(phenolato)Ligands

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Chinese Journal of Chemistry 2024年第14期42卷 1571-1581页

作者： Yongjie chen Yanwei Wang {1. Nong Dan Yuan Yingming Yao Key Laboratory of Organic Synthesis of Jiangsu Province College of ChemistryChemical Engineering and Materials ScienceDushu Lake CampusSoochow UniversitySuzhouJiangsu215123 China

Eight zwitterionic rare earth metal complexes stabilized by amino-bridged tris(phenolato)ligands bearing quaternary ammonium side-arms were synthesized and *** complexes were used as single-component catalysts for the cycloaddition of CO_(2)and epoxides,and their catalytic activities are obviously higher than those of their binary *** studies revealed that the halide anions(Cl^(–),Br^(–),I^(–))and the metal complexes influenced the catalytic activity,and the lanthanum complex bearing iodide anion showed the highest catalytic activity for this addition reaction.A variety of mono-substituted epoxides were converted to cyclic carbonates in good to excellent yields(55%—99%)with high selectivity(>99%)at 30℃and 1.bar CO_(2),whereas internal epoxides required higher both reaction temperatures(60—1.0℃)and catalyst loading(2 mol%)for high *** catalyst was recyclable for four times without noticeable loss of catalytic *** on the results of kinetic studies and in℃situ IR reactions,a plausible reaction mechanism was proposed.

关键词： Bifunctional catalyst Carbon dioxide Cyclic carbonate Rare-earth metal Tris(phenolato)ligand Insertion Cycloaddition C1.building blocks

Dynamic lithium-compensation mechanism for densification of garnet-type Li_(7)La_(3)Zr_(2)O_(1.)electrolyte by Li_(2)O atmosphere buffer pair

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Nano Research 2024年第7期17卷 6184-6191页

作者： Chujun Zheng Ya {1. Haoxin Dong Yan Lu jun Jin Zhaoyin Wen CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of CeramicsChinese Academy of ScienceShanghai 200050China State Key Lab High Performance Ceram and Superfine Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China Center of Materials Science and Optoelectronics {1. University of Chinese Academy of SciencesBeijing 100049China

Solid-state lithium metal batteries are one of the most promising options for next-generation batteries pursuing high-energy density and ***,the inevitable volatilization of lithium compounds during sintering leads to low relative density and low ionic conductivity of solid-state ***,the dynamic lithium-compensation mechanism is proposed to facilitate the densification of Ta-substituted garnet-type electrolyte(Li_(6.5)La_(3)Zr_(1.5)Ta_(0.5)O_(1.)(LLZT))through the reversible manipulating of Li_(2)O ***_(2)ZrO_(3)is used as mother powder additive,which reacts with Li_(2)O in sintering atmosphere and forms Li_(6)Zr_(2)O_(7).Li_(2)ZrO_(3)/Li_(6)Zr_(2)O_(7)buffer pair manipulates the sintering Li_(2)O atmosphere,which is vital for LLZT,within the Li_(2)O partial pressure range corresponding to Li_(2)ZrO_(3)and Li_(6)Zr_(2)O_(7).Furthermore,the reversibility mechanism of buffer pair for Li_(2)O absorption and release is *** obtained LLZT exhibits a relative density of over 96%and an ionic conductivity exceeding 7×1.^(−4)S·cm^(−1.with no abnormal grain *** symmetric cell demonstrates an excellent lithium dendrite suppressing ability(stable cycling at a current density of 0.3 mA·cm^(−2)for over 1.00 h).Such dynamic lithium-compensation strategy has been successfully applied in atmosphere manipulation of LLZT sintering process,which reduces the dependence of LLZT on the Li_(2)O atmosphere,making it conducive to large-scale preparation of electrolyte ceramics.

关键词： solid-state batteries garnet-type electrolyte high-density electrolyte dynamic lithium-compensation buffer pair