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Synthesis of nanostructured Li_2FeSiO_4/C cathode for lithium-ion battery by solution method

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Transactions of Nonferrous Metals Society of China 2012年第10期22卷 2529-2534页

作者：杨蓉刘晓艳曲冶雷京 jou-hyeon ahn 西安理工大学理学院西安710048 Department of Chemical and Biological Engineering and Engineering Research Institute Gyeongsang National University900 Gajwa-dongJinju 600-701Korea

Nanosphere-like Li2FeSiO4/C was synthesized via a solution method using sucrose as carbon sources under a mild condition of time-saving and energy-saving, followed by sintering at high temperatures for crystallization. The amount of carbon in the composite is less than 10% （mass fraction）, and the X-ray diffraction result confirms that the sample is of pure single phase indexed with the orthorhombic Pmn21 space group. The particle size of the Li2FeSiO4/C synthesized at 700 °C for 9 h is very fine and spherical-like with a size of 200 nm. The electrochemical performance of this material, including reversible capacity, cycle number, and charge-discharge characteristics, were tested. The cell of this sample can deliver a discharge capacity of 166 mA-h/g at C/20 rate in the first three cycles. After 30 cycles, the capacity decreases to 158 mA-h/g, and the capacity retention is up to 95%. The results show that this method can prepare nanosphere-like Li2FeSiO4/C composite with good electrochemical performance.

关键词： lithium-ion batteries cathode material Li2FeSiO4/C solution method

Improved Cycle Properties of FeS_2 Cathode Material with Metallic Additives

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材料科学与工程学报 2007年第6期25卷 910-913页

作者： Jae-Won Choi Jae-Kwang Kim Gouri Cheruvally jou-hyeon ahn Ki-Won Kim Hyo-Jun ahn Dong-Kyu Park Department of Chemical & Biological Engineering and Engineering Research Institute Gyeongsang National University900 Gajwa-dongJinju660-701Korea School of Nano and Advanced Materials Engineering and Engineering Research Institute Gyeongsang National University900 Gajwa-dongJinju660-701Korea Kaya Advanced Material Art Inc. Baekrok-Ri 1010-1Yangsan 626-862Korea

Iron disulfide(FeS_2)cathode active material was prepared from iron and sulfur at room temperature by high energy mechanical *** FeS_2 composites containing Co or Ni transition metal powders as additives were also prepared by the same *** cells with these FeS_2 cathodes were studied for charge-discharge properties at room temperature using 0.5M LiTFSI in tetra(ethylene glycol)dimethyl ether(TEGDME)*** voltammetry showed two anodic oxidation peaks at 1.8 and 2.5V and two cathodic reduction peaks at 2.0 and 1.3 V for FeS_2 with metal *** addition of 5wt% Co and 3wt% Ni resulted in an enhancement of the first discharge capacity giving 571 and 844mAh/g respectively at *** cycle performance was also enhanced remarkably by the addition of these electrically conductive transition metals in the active ***_2 with 5wt% Co exhibited a stable cycle performance delivering a reversible capacity of 338mAh/g(37.8% of theoretical capacity)after 20 cycles.

关键词：阴极材料二硫化铁锂离子电池循环性能

Electrochemical Intercalation of Sodium into Silicon Thin Film

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材料科学与工程学报 2008年第1期26卷 141-144页

作者： Dong-Yeon Kim Hyo-Jun ahn Gyu-Bong Cho Jong-Seon Kim Ho-Suk Ryu Ki-Won Kim jou-hyeon ahn Won-Cheol Shin I-cube center nano advanced materials Engineering Gyeongsang National Uhiversity Jinju 660-701 Korea Department of Chemical ＆ Biological Engineering Gyeongsang National University J inju 660-701 Korea INOSTEK Inc Gyeonggi Technopark 1271-11 Sal-dong Sangnok-gu Ansan-si Gyeonggi-do 426-901 Korea

In order to investigate the possibility of Si thin film as an anode for Na battery,we studied the electrochemical intercalation of sodium into the Si *** Si thin film electrode was prepared using DC magnetron *** ion could intercalate into Si thin film upto Na0.52Si,i.e.530mAh·*** first discharge capacity was 80mAh·g-1-Si,which meant reversible amount of sodium *** discharge capacity slightly decreased to 70mAh·g-1-Si after 10 cycles.

关键词：钠插层反应电池硅薄膜电极直流电磁控溅射

Fibrinogen’s potential role in connecting cerebrovascular abnormalities with glymphatic dysfunction in Alzheimer’s disease

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Neural Regeneration Research 2025年第1期20卷 203-204页

作者： Vishal Singh Arnab Choudhury Hyung Jin ahn Department of Pharmacology Physiology and NeurosciencesRutgers-New Jersey Medical SchoolNewarkNJUSA Brain Health Institute Rutgers UniversityPiscatawayNJUSA

Alzheimer’s disease(AD)stands out as the primary manifestation of age-related dementia,portraying a chronic neurodegenerative disorder distinguished by the accumulation of fibrillar amyloid-β(Aβ)plaques and neurofibrillary tangles of hyperphosphorylated ***,from a clinical standpoint,AD presents itself as a complex condition with a spectrum of dysfunctions rather than a singular pathological *** often-overlooked aspect of the disease is the presence of extensive cerebrovascular abnormalities,given that the majority of AD patients experience altered cerebral blood flow,damaged vasculature,increased microinfarcts and *** models of AD further support this observation,showing cerebrovascular dysfunction such as impaired cerebral blood flow and altered cerebrovascular reactivity(Tataryn et al.,2021;Gareau et al.,2023).

关键词： cerebrovascular dysfunction Alzheimer

Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

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journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won Department of Chemical and Biological Engineering Korea University Department of Chemical Engineering (Integrated process) Kyung Hee University Department of Chemical Engineering and Materials Science Ewha Womans University Department of Chemical Engineering Pukyong National University Resources Engineering Plant Research Department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeconomy

Prominent cycling reversibility and kinetics enabled by CaTiO3 protective layer on Zn metal for aqueous Zn-ion batteries

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journal of Energy Chemistry 2025年第1期100卷 245-258页

作者： Gaeun Lee Yong Nam ahn Seongjoon So Chanwoo Park Jong-Seong Bae Taehyun Park Il Tae Kim Jaehyun Hur School of Chemical Biological and Battery Engineering Gachon University Seongnam Busan Center Korea Basic Science Institute

Aqueous Zn-ion batteries （AZIBs） have received considerable attention owing to their various advantages such as safety,low cost,simple battery assembly conditions,and high ionic ***,they still suffer from serious problems,including uncontrollable dendrite growth,corrosion,hydrogen evolution reaction （HER） from water decomposition,electrode passivation,and unexpected *** creation of a uniform artificial nanocrystal layer on the Zn anode surface is a promising strategy for resolving these ***,we propose the use of a perovskite CaTiO3（CTO） protective layer on Zn（CTO@Zn） as a promising approach for improving the performance of *** CTO artificial layer provides an efficient pathway for Zn ion diffusion towards the Zn metal because of the high dielectric constant （εr=180） and ferroelectric characteristics that enable the alignment of dipole moments and redistribute the Zn2+ions in the CTO *** avoiding the direct contact of the Zn anode with the electrolyte solution,the uneven dendrite growth,corrosion,parasitic side reactions,and HER are mitigated,while CTO retains its mechanical and chemical robustness during ***,CTO@Zn demonstrates an improved lifespan in a symmetric cell configuration compared with bare ***@Zn shows steady overpotential （～68 m V） for 1500 h at 1 mA cm-2/0.5 mA h cm-2,excelling bare ***,when paired with the V2O5-C cathode,the CTO@Zn//V2O5-C full battery delivers 148.4 mA h g-1（based on the mass of the cathode） after 300 *** study provides new insights into Zn metal anodes and the development of high-performance AZIBs.

关键词： Artificial layer Dielectric constant Zn metal anode Zinc aqueous battery

Notch1 and Notch4 are markers for poor prognosis of hepatocellular carcinoma

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Hepatobiliary & Pancreatic Diseases International 2013年第3期12卷 286-294页

作者： Soomin ahn Jiyeon hyeon Cheol-Keun Park Department of Pathology Samsung Medical Center Sungkyunkwan University School of Medicine

BACKGROUND: Notch signaling is critical to physiologic angiogenesis and has been implicated in tumor angiogenesis and metastasis. Notch signaling was reported to exert either oncogenic or tumor-suppressive function in hepatocellular carcinoma (HCC) tumorigenesis. However, the prognostic significance of Notch receptors in HCC remains uncertain. In this study, we investigated the roles of Notch receptors in the prognosis of HCC. METHODS: We investigated the expressions of Notch receptors in tumor tissue microarrays of 288 patients with primary HCC who had undergone curative resection using immunohistochemistry. Additionally, prognostic factors of HCC were examined by univariate and multivariate analyses. The median follow-up period was 97.1 months. Tumor recurrence was detected in 189 patients (65.6%), and 99 (34.4%) died of HCC. RESULTS: Cytoplasmic expression of Notch1, cytoplasmic expression of Notch3, coexistent nuclear expression of Notch3, and cytoplasmic Notch4 overexpression were observed in 145 (50.3%), 60 (20.8%), 17 (5.9%), and 172 (59.7%) of the 288 HCCs, respectively. Multivariate analyses revealed that Notch1 expression (P=0.029), Edmondson grade Ⅲ (P=0.038), and higher BCLC stage (P<0.001) were independent predictors of shorter disease-free survival. Cytoplasmic Notch3 expression tended to be an independent predictor of shorter disease-free survival (P=0.055). Notch1 expression (P=0.039), Notch4 overexpression (P=0.012), and higher BCLC stage (P<0.001) were independent predictors of shorter disease-specific survival. On univariate analysis, Notch1 expression tended to show an unfavorable influence on disease-specific survival (P=0.063) and Notch4 overexpression did not show an unfavorable influence on disease-specific survival (P=0.103). CONCLUSIONS: Notch1 expression might be an independent predictor of both shorter disease-free survival and shorter disease-specific survival in HCC patients after curative resection. Notch4 overexpression might be

关键词： Notch1 Notch4 hepatocellular carcinoma recurrence survival

Piezoelectric strain sensor with high sensitivity and high stretchability based on kirigami design cutting

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npj Flexible Electronics 2022年第1期6卷 529-536页

作者： Young-Gyun Kim Ji-hyeon Song Seongheon Hong Sung-Hoon ahn Department of Mechanical Engineering Seoul National UniversityGwanak-ro 1Gwanak-guSeoul 08826Republic of Korea MX Division Samsung ElectronicsSamsungro 129Suwon-siGyeonggi-do 16677Republic of Korea Department of Mechanical Engineering Dankook UniversityJukjeon-ro 152Suji-guYongin 16890Republic of Korea Institute of Advanced Machines and Design Seoul National UniversityGwanak-ro 1Gwanak-guSeoul 08826Republic of Korea

Wearable technology requires high-performance sensors with properties such as small size,flexibility,and wireless ***,sensitivity,and tunability are crucial sensor properties;stretchability and sensitivity ensure user comfort and accurate sensing performance,while tunability is essential for implementing sensors in diverse applications with different ranges of *** this study,we developed a high performance kirigami piezoelectric strain *** finite element analysis,the sensing performance was evaluated,and the kirigami patterns were *** electromechanical properties of sensors with four different kirigami patterns were analyzed.A sensor voltage measurement circuit was also designed,amplifying the output voltage 86.5 times by improving measurement accuracy.A piezoelectric kirigami sensor was constructed with a sensitivity of 9.86 V/cm^(2) and a stretchability of 320.8%,higher than those of previously reported kirigami piezoelectric strain ***,the fabricated sensor was successfully applied in a haptic glove for playing musical instruments.

关键词： stretch strain piezoelectric

Lamellar sulfonated acid polymer-initiated in situ construction of robust LiF-rich SEI enabling superior charge transport for ultrastable and fast charging silicon anodes

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journal of Energy Chemistry 2024年第11期98卷 134-143页

作者： Jungsoo Park Song Kyu Kang Junhyuk Ji Hwichan ahn Gwan hyeon Park Minho Kim Won Bae Kim Graduate Institute of Ferrous&Eco Materials Technology(GIFT) Pohang University of Science and Technology(POSTECH)77 Cheongam-roNam-guPohang-siGyeongsangbuk-do 37673Republic of Korea Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)77 Cheongam-RoNam-guPohang-siGyeongsangbuk-do 37673Republic of Korea

The extreme volume expansion of the silicon(Si) anodes during repeated cycles seriously induces undesirable interfacial side reactions,forming an unstable solid electrolyte interphase(SEI) that degrades the electrode integrity and cycle stability in lithium-ion batteries,limiting their practical *** considerable efforts to stabilize the SEI through surface modification,challenges persist in the development of high-performance Si anodes that effectively regulate intrinsic SEI properties and simultaneously facilitate electron/ion ***,a highly conductive and organic electrolyte-compatible lamellar p-toluenesulfonic acid-doped polyaniline(pTAP) layer is proposed for constructing a robust artificial SEI on Si nanoparticles to achieve fast charging,lo ng-term cycle lifespan and high areal *** spatially uniform pTAP layer,formed through a facile direct-encapsulation approach assisted by enriched hydrogen bonding,contributes to the effective formation of in situ SEI with an even distribution of the LiF-rich phase in its interlamination ***,the integrated artificial SEI facilitates isotropic ion/electron transport,increased robustness,and effectively dissipates stress from volume ***,a notably high rate performance of 570 mA h g^(-1),even at a substantially high current density of 10 A g^(-1),is achieved with excellent cyclic stability by showing a superior capacity over 1430 mA h g^(-1) at 1 A g^(-1) after 250 cycles and a high areal capacity of ca.2 mA h cm^(-2) at 0.5 C in a full cell *** study demonstrates that the rational design of conductive polymers with SEI modulation for surface protection has great potential for use in high-energy-density Si anodes.

关键词： Lithium-ion battery Silicon anode Conductive polymers Solid electrolyte interphase